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    • 2. 发明申请
    • N-ACYLIMINO HETEROCYCLIC COMPOUNDS FOR COMBATING INVERTEBRATE PESTS
    • 用于组合反相胶束的N-乙酰氨基杂环化合物
    • WO2015124706A1
    • 2015-08-27
    • PCT/EP2015/053559
    • 2015-02-20
    • BASF SE
    • KÖRBER, KarstenMCLAUGHLIN, Martin JohnGOCKEL, BirgitVON DEYN, WolfgangDIETZ, JochenPOHLMAN, MatthiasKOJIMA, Kenichi
    • C07D413/14A01N43/80
    • C07D413/14
    • The present invention relates to N-acylimino compound of formula (I): wherein X is O or S, in particular O;Cyc is a radical Cyc-1 or Cyc-2 (II) (III) D is CH 2 or CH 2 -CH 2 , where 1 or 2 of the hydrogen atoms may be replaced by R 4 , Y is O, S, CR 5a R 5b or N-R 5 ; Het is a 5 or 6 membered carbon-bound or nitrogen-bound heterocyclic ring, W 1 -W 2 -W 3 -W 4 represents a carbon chain group connected to N and C=N, and thus forming a saturated, unsaturated, or partially unsaturated 5 or 6 membered nitrogen containing heterocycle, wherein W 1 , W 2 , W 3 and W 4 each individually represent 1 CR v R w ; R 1 , R 2 may be hydrogen, halogen, C 1 -C 6 -alkyl etc.; R 3 hydrogen, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 8 -cycloalkyl, C 3 -C 8 - cycloalkyl-C 1 -C 4 -alkyl, etc.; R 4, R 5 , R 5a , R 5b hydrogen, halogen, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 8 -cycloalkyl, C 3 -C 8 -cycloalkyl-C 1 -C 4 -alkyl, etc.; The invention also relates to the use of the N-acylimino heterocyclic compounds, their stereoisomers, their tautomers and their salts,for combating invertebrate pests. Furthermore the invention relates also to methods of combating invertebrate pests, which comprises applying such compounds.
    • 本发明涉及式(I)的N-酰基亚胺基化合物:其中X是O或S,特别是O; Cyc是自由基Cyc 1或Cyc 2(II)(III)D是CH 2或CH 2 -CH 2 其中1或2个氢原子可以被R4代替,Y是O,S,CR5a R5b或N-R5; Het是5或6元碳键或氮键合的杂环,W1-W2-W3 -W4表示与N连接的碳链基团,C = N,从而形成饱和的,不饱和的或部分不饱和的5或 6元含氮杂环,其中W1,W2,W3和W4各自独立地表示1个CRvRw; R1,R2可以是氢,卤素,C1-C6烷基等; R 3,C 1 -C 6 - 烷基,C 2 -C 6 - 烯基,C 2 -C 6 - 炔基,C 3 -C 8 - 环烷基,C 3 -C 8 - 环烷基-C 1 -C 4烷基等。 R4,R5,R5a,R5b氢,卤素,C1-C6-烷基,C2-C6-烯基,C2-C6-炔基,C3-C8-环烷基,C3-C8-环烷基-C1-C4-烷基等。 本发明还涉及N-酰基亚氨基杂环化合物,其立体异构体,其互变异构体及其盐的用途,用于防治无脊椎动物害虫。 此外,本发明还涉及抗无脊椎害虫的方法,其包括应用这些化合物。
    • 4. 发明申请
    • N-SUBSTITUTED IMINO HETEROCYCLIC COMPOUNDS FOR COMBATING INVERTEBRATE PESTS
    • 用于组合反相胶束的N-取代的IMINO杂环化合物
    • WO2015124606A1
    • 2015-08-27
    • PCT/EP2015/053386
    • 2015-02-18
    • BASF SE
    • VON DEYN, WolfgangMCLAUGHLIN, Martin JohnGOCKEL, BirgitKÖRBER, KarstenDIETZ, JochenPOHLMAN, MatthiasKOJIMA, Kenichi
    • C07D401/14C07D413/14A01N43/40A01N43/54C07D409/14C07D417/14
    • C07D401/14A01N43/40A01N43/50A01N43/54A01N43/56A01N43/58A01N43/60A01N43/653A01N43/76A01N43/78A01N43/80A01N43/82C07D409/14C07D413/14C07D417/14
    • The present invention relates to N-acylimino compound of formula (I), wherein; Cyc is (i) a 3-, 4-, 5-, 6- or 7-membered, saturated, partially unsaturated or maximally unsaturated heteromonocycle having 1, 2, 3 or 4 heteroatoms or heteroatom groups as ring members, which are selected from O, S, N, NO, S(O) and S(O) 2 , which is unsubstituted or carries one or more, in particular 1, 2, 3, 4, 5 or 6 subsitutents R 3 , or (ii) a 8-, 9- or 10-membered, saturated, partially unsaturated or maximally unsaturated heterobicycle having 1, 2, 3 or 4 heteroatoms or heteroatom groups as ring members, which are selected from O, S, N, NO, S(O) and S(O) 2 , which is unsubstituted or carries one or more, in particular 1, 2, 3, 4, 5 or 6 subsitutents R 4 ; Het is a 5- or 6-membered carbon-bound or nitrogen-bound heterocyclic ring, W 1 =W 2 -W 3 =W 4 represents an unsaturated carbon chain group connected to N and C=N, and thus forming a unsaturated or partially unsaturated 5-or 6-membered nitrogen containing heterocycle, wherein W 1 , W 2 , W 3 and W 4 each individually represent CR V or one of W1=W 2 or W 3 =W 4 may also be CR V R W ; R 1 , R 2 may be hydrogen, halogen, C 1 -C 6 -alkyl etc. The invention also relates to the use of the N-acylimino heterocyclic compounds, their ste¬ reoisomers, their tautomers and their salts, for combating invertebrate pests. Furthermore the invention relates also to methods of combating invertebrate pests, which comprises applying such compounds.
    • 本发明涉及式(I)的N-酰基亚氨基化合物,其中: Cyc是(i)具有1,2,3或4个杂原子或杂原子作为环成员的3-,4-,5-,6-或7-元饱和,部分不饱和或最大不饱和杂单环,其选自 O,S,N,NO,S(O)和S(O)2,其是未取代的或携带一个或多个,特别是1,2,3,4,5或6个子化合物R3,或(ii) 具有1,2,3或4个杂原子或杂原子基团的9-或10-元饱和的,部分不饱和的或最不饱和的杂双环,其选自O,S,N,NO,S(O)和 S(O)2,其是未取代的或携带一个或多个,特别是1,2,3,4,5或6个子化合物R4; Het是5或6元碳键或氮键合的杂环,W1 = W2-W3 = W4表示与N和C = N连接的不饱和碳链基团,因此形成不饱和或部分不饱和5- 或6元含氮杂环,其中W1,W2,W3和W4各自独立地表示CRV或W1 = W2或W3 = W4中的一个也可以是CRVRW; R 1,R 2可以是氢,卤素,C 1 -C 6烷基等。本发明还涉及N-酰基亚氨基杂环化合物,它们的互变异构体,它们的互变异构体及其盐用于对抗无脊椎动物害虫的用途。 此外,本发明还涉及防治无脊椎害虫的方法,其包括施用这样的化合物。
    • 9. 发明申请
    • N-ACYLIMINO HETEROCYCLIC COMPOUNDS
    • N-乙酰氨基杂环化合物
    • WO2016062678A1
    • 2016-04-28
    • PCT/EP2015/074196
    • 2015-10-20
    • BASF SE
    • KÖRBER, KarstenMCLAUGHLIN, Martin JohnGOCKEL, BirgitVON DEYN, WolfgangKOJIMA, Kenichi
    • C07D401/06C07D405/06C07D413/06C07D417/06A01N43/50A01N43/76A01N43/78
    • C07D401/06A01N43/50A01N43/76A01N43/78A01N43/88A01N53/00C07D405/06C07D413/06C07D417/06
    • The present invention relates to N-acylimino compound of formula (I): (I) wherein X 1 is O or S, in particular O; X 2 is CN or NO 2 ; m is an integer selected from 0, 1, 2, 3, 4, 5 and 6; Het is a 5- or 6- membered carbon-bound or nitrogen-bound heterocyclic or heteroaromatic ring, W 1 is O, S or NR w1 ; W 2 -W 3 -W 4 isa bivalent radical selected from -C(R v2 R w2 )-C(R v3 R w3 )-, -C(R v4 )=C(R v5 )- and - C(R v2 R w2 )-O-C(R v3 R w3 )-; R 1 , R 2 may be hydrogen, halogen, etc. R 3 may be hydrogen, halogen, CN, C 1 -C 6 -alkyl, etc. R 4a , R 4b if present, may be hydrogen, halogen, C 1 -C 6 -alkyl, etc. R 5 may be hydrogen, halogen, C 1 -C 6 -alkyl, C 1 -C 6 -alkenyl, C 1 -C 6 -alkynyl, C 3 -C 8 - cycloalkyl, S(O) n NR 9a R 9b , NR 9a R 9b , C(=O)OR 8 , C(=O)NR 9a R 9b , C(=S)NR 9a R 9b , C(=O)R 7a , C(=S)R 7a , NR 9a -C(=O)R 7a , NR 9a -C(=S)R 7a , NR 9a -S(O) n R 8a , a moitey Q-phenyl, where the phenyl ring is optionally substituted with one or more, e.g. 1, 2, 3, 4 or 5 identical or different substituents R 10 , or a moiety Q-Het # , or R 3 and R 5 together may also form with the carbon atom they are bound to, a 3-, 4-, 5- or 6- membered saturated partially unsaturated carbocycle or heterocycle, wherein R w1 , R w2 , R w3 , R v2 , R v3 , R v5 , R 7a , R 8 , R 8a , R 9a , R 9b , Q, Het # are as defomed in the claims. The invention also relates to the use of the N-acylimino heterocyclic compounds, their stereoisomers, their tautomers and their salts, for combating invertebrate pests. Furthermore the invention relates also to methods of combating invertebrate pests, which comprises applying such compounds.
    • 本发明涉及式(I)的N-酰基亚氨基化合物:(I)其中X1是O或S,特别是O; X2为CN或NO2; m是选自0,1,2,3,4,5和6的整数; Het是5-或6-元碳键或氮键合的杂环或杂芳环,W1是O,S或NRw1; W2-W3-W4是选自-C(Rv2Rw2)-C(Rv3Rw3) - , - C(Rv4)= C(Rv5) - 和-C(Rv2Rw2)-O-C(Rv3Rw3) - 的二价基团。 R 1,R 2可以是氢,卤素等。R 3可以是氢,卤素,CN,C 1 -C 6烷基等。如果存在,R 4a,R 4b可以是氢,卤素,C 1 -C 6烷基等。 C 1 -C 6 - 烷基,C 1 -C 6 - 烯基,C 1 -C 6 - 炔基,C 3 -C 8环烷基,S(O)n NR 9 a R 9 b,NR 9 a R 9 b,C(= O)OR 8,C(= O)NR 9a R 9b ,C(= S)NR9aR9b,C(= O)R7a,C(= S)R7a,NR9a-C(= O)R7a,NR9a-C(= S)R7a,NR9a-S(O)nR8a, Q-苯基,其中苯环任选被一个或多个例如, 1,2,3或4或5个相同或不同的取代基R10或部分Q-Het#,或R3和R5一起也可以与它们所键合的碳原子形成,3-,4-,5-或 6-元饱和部分不饱和碳环或杂环,其中Rw1,Rw2,Rw3,Rv2,Rv3,Rv5,R7a,R8,R8a,R9a,R9b,Q,Het#如权利要求中所述。 本发明还涉及N-酰基亚氨基杂环化合物,其立体异构体,其互变异构体及其盐的用途,用于防治无脊椎动物害虫。 此外,本发明还涉及防治无脊椎害虫的方法,其包括施用这样的化合物。