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1. 发明申请

WO1998016463A1 PROCESS FOR THE MANUFACTURE OF HYDROGEN PEROXIDE 审中-公开
标题翻译：工艺生产氢
公开(公告)号：WO1998016463A1
公开(公告)日：1998-04-23
申请号：PCT/EP1997005659
申请日：1997-10-15
申请人： BASF AKTIENGESELLSCHAFT , FISCHER, Martin , KAIBEL, Gerd , STAMMER, Achim , FLICK, Klemens , QUAISER, Stefan , HARDER, Wolfgang , MASSONNE, Klemens
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C01B15/029
CPC分类号： B01J8/0492 , B01J8/0453 , B01J19/2465 , B01J19/2485 , B01J19/26 , B01J2208/00283 , B01J2208/00398 , B01J2208/00407 , C01B15/029
摘要： The present invention relates to a process for the manufacture of hydrogen peroxide solutions with a hydrogen peroxide content of at least 2.5 wt % by continual reaction of hydrogen and oxygen in an aqueous or alcoholic reaction medium on catalyst shaped bodies containing palladium.
摘要翻译：本发明涉及一种用于生产过氧化氢溶液与由在水和/或含有钯的催化剂体的醇反应介质的氢气和氧气的连续反应中的至少2.5重量％的过氧化氢含量。

2. 发明申请

WO1997048466A1 CATALYTIC DISTILLATION PROCESS 审中-公开
标题翻译： PROCESS FOR催化精馏
公开(公告)号：WO1997048466A1
公开(公告)日：1997-12-24
申请号：PCT/EP1997003122
申请日：1997-06-16
申请人： BASF AKTIENGESELLSCHAFT , BRÖCKER, Franz, Josef , FLICK, Klemens , FREIRE ERDBRÜGGER, Cristina , KAIBEL, Gerd , MEYER, Gerald , MÜLLER, Hans-Joachim , POLANEK, Peter , SCHWAB, Ekkehard
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： B01D03/00
CPC分类号： C10G49/002 , B01D3/009 , B01D59/32 , B01J19/2485 , B01J19/2495 , B01J19/32 , B01J35/02 , B01J35/06 , B01J2219/32296 , B01J2219/32408 , B01J2219/32466 , B01J2219/32491 , Y10S203/06
摘要： The use of a catalyst package which can be produced by the vapour deposition and/or sputtering of at least one substance active as a catalyst and/or promotor on fabrics, knitted materials or foils as substrates in a catalytic distillation process in which a heterogeneous-catalytic reaction is combined with simultaneous distillation or rectification on the catalyst package.
摘要翻译：在用于催化蒸馏方法中的用途，其可以通过气相沉积和/或至少一种催化剂和/或助活性物质至组织的溅射产生的催化剂填料，针织织物或片材作为载体材料的，其中具有同时蒸馏或精馏的非均相催化反应是在催化剂填料组合。

3. 发明申请

WO1996020166A1 PROCESS FOR PREPARING ALIPHATIC ALPHA,OMEGA-AMINONITRILES 审中-公开
标题翻译：用于生产脂肪族α，ω-氨基腈
公开(公告)号：WO1996020166A1
公开(公告)日：1996-07-04
申请号：PCT/EP1995004985
申请日：1995-12-16
申请人： BASF AKTIENGESELLSCHAFT , MELDER, Johann-Peter , SCHNURR, Werner , FLICK, Klemens , EBEL, Klaus , WITZEL, Tom , FISCHER, Rolf , HARDER, Wolfgang , REHFINGER, Alwin
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07C253/30
CPC分类号： B01J23/8898 , B01J23/76 , B01J23/8892 , B01J37/0201 , C07C253/30 , C07C255/24
摘要： Aliphatic alpha,omega-aminonitriles are prepared by partially hydrogenating aliphatic alpha,omega-dinitriles at an increased temperature and pressure in the presence of a solvent and a catalyst. The catalyst contains (a) a compound based on a metal selected from the group made up of nickel, cobalt, iron, ruthenium and rhodium; (b) 0.01 to 25 % by weight in relation to (a) of a promoter based on a metal selected from the group comprising of palladium, platinum, iridium, osmium, copper, silver, gold, chromium, molybdenum, tungsten, manganese, rhenium, zinc, cadmium, lead, aluminium, tin, phosphorus, arsenic, antimony, bismuth, silicium, titanium, zirconium and rare earth metals; and (c) 0 to 5 % by weight in relation to (a) of a compound based on an alkaline or alkaline-earth metal, provided that component (a) not be based on iron or iron and a metal selected from the group comprising cobalt, ruthenium and rhodium when (b) is a promoter based on a metal selected from the group comprising titanium, manganese, chromium and molybdenum. Moreover, when component (a) is a compound based only on ruthenium or on rhodium, ruthenium and rhodium, or nickel and rhodium, promoter (b) may be dispensed with.
摘要翻译：通过在升高的温度和升高的压力下，在溶剂和催化剂的存在下的脂族α，ω-二腈的部分氢化的脂族α，ω-氨基腈的制备，通过使用包括（a）基于金属的化合物的催化剂，选自由镍，钴，铁，钌，铑，和（b）是组成的组中为0.01〜25重量％，基于（a），选自基于金属的启动子的选自由钯，铂，铱，锇，铜，银，金，铬，钼，钨，锰，铼，锌，镉，铅，铝，锡，磷，砷，锑，铋，硅，钛组成的组中含从0锆和稀土金属，和（c）至5重量％，基于（a）中，基于碱金属或碱土金属的化合物，条件是组分（a）是不上的基于铁或铁和德 [R选自由钴，钌和铑的组中选择的金属，是当（b）是基于从由钛，锰，铬和钼组成的组中选择的金属的启动子，是以及与所述另一当作为组分（a）被选择条件仅基于钌或铑或钌，铑或镍和铑的化合物，该启动子可被省略（b）中。

4. 发明申请

WO1997037964A1 METHOD OF SIMULTANEOUSLY PRODUCING 6-AMINOCAPRONITRILE AND HEXAMETHYLENEDIAMINE 审中-公开
标题翻译：操作法，6-氨基己腈和己二胺同时生产
公开(公告)号：WO1997037964A1
公开(公告)日：1997-10-16
申请号：PCT/EP1997001685
申请日：1997-04-04
申请人： BASF AKTIENGESELLSCHAFT , SCHNURR, Werner , VOIT, Guido , FLICK, Klemens , MELDER, Johann-Peter , FISCHER, Rolf , HARDER, Wolfgang
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07C209/48
CPC分类号： C07C209/48 , C07C253/30 , Y02P20/584
摘要： The invention concerns a method of simultaneously producing 6-aminocapronitrile (ACN) and hexamethylenediamine (HMD) by reacting adipodinitrile (ADN) with hydrogen in the presence of a catalyst containing nickel, at a temperature not below room temperature and at an elevated hydrogen partial pressure, optionally in the presence of a solvent. If the yield, based on the amount of ADN consumed, and/or the selectivity, based on the amount of ACN produced, drop(s) below a defined value, a) the reaction of ADN with hydrogen is interrupted by stopping the feed of ADN and, if present, also the solvent; b) the catalyst is treated with hydrogen at a temperature in the range 150 to 400 DEG C, using a hydrogen pressure of 0.1 to 30 MPa and a treatment time of 2 to 48 h; and c) the hydrogenation is subsequently continued using the catalyst treated in stage (b).
摘要翻译：同时产生6-氨基己腈（“ACN”）的，和六亚甲基二胺（“HMD”）通过在含镍催化剂的温度不低于室温的温度和升高的氢分压的存在下处理二腈（“ADN”）与氢的，如果需要，在溶剂的存在下，通过中断ADN的处理减少的营业额，基于ADN和/或选择性基于下面限定的值（a）用氢通过ADN的进料和ACN，如果需要，现有溶剂停止时，（b）该催化剂在用氢处理在150℃至400℃的范围内的温度，其中一个选择在0.1〜30兆帕的氢气压力和在2至48小时的范围内的处理时间，和（ c）中，然后继续ADN与（根据步骤b）处理过的催化剂的氢化。

5. 发明申请

WO1998014455A1 PROCESS FOR PREPARING PHENYLCHLOROPHOSPHINES 审中-公开
标题翻译：用于生产PHENYLCHLORPHOSPHINEN
公开(公告)号：WO1998014455A1
公开(公告)日：1998-04-09
申请号：PCT/EP1997005033
申请日：1997-09-15
申请人： BASF AKTIENGESELLSCHAFT , MASSONNE, Klemens , FISCHER, Martin
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07F09/52
CPC分类号： C07F9/025 , C07F9/52
摘要： The invention concerns a process for preparing phenylchlorophosphines of formula (I): Clx-p-(-C6H5)y, in which x has the value 1 or 2, and the total of x + y is 3, or mixtures of compounds (I) by reacting phosphorus trichloride (PCl3) with triphenylphosphine (P-(C6H5)3) in a molar ratio of PCl3 to P-(C6H5)3 of between 1:5 and 5:1 at a temperature of between 280 and 450 DEG C, the mixture produced by this reaction, before being distilled, being reacted with between 1.5 and 15 mol elemental chlorine per mol of elemental phosphorus present in the reaction mixture.
摘要翻译：一种用于制备式（I）的过程Phenylchlorphosphinen：CLX-P - （ - C 6 H 5）Y，其中x具有值1或2，并且x + y之和为3，或化合物（I）通过的混合物 5至5：在（C6H5）3 1的PCl 3 / P的摩尔比的三氯化磷（PCL3）（（P-C 6 H 5）3）与三苯基膦反应，在280〜450℃的温度下1中，其中一个在该反应所得的反应混合物与每在反应混合物中的元素氯的摩尔为1.5〜15摩尔蒸馏前含元素磷反应。

6. 发明申请

WO1996002323A1 OXIDATION CATALYST, PROCESS FOR ITS PREPARATION AND OXIDATION PROCESS USING SAID OXIDATION CATALYST 审中-公开
标题翻译：氧化催化剂的方法用于生产和氧化过程中使用氧化催化剂
公开(公告)号：WO1996002323A1
公开(公告)日：1996-02-01
申请号：PCT/EP1995002651
申请日：1995-07-07
申请人： BASF AKTIENGESELLSCHAFT , MÜLLER, Ulrich , LINGELBACH, Peter , BASSLER, Peter , HARDER, Wolfgang , ELLER, Karsten , KOHL, Veronika , DEMBOWSKI, Jürgen , RIEBER, Norbert , FISCHER, Martin
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： B01J29/04
CPC分类号： B01J29/89 , B01J23/40 , C01B15/029 , C07D301/04 , C07D301/12
摘要： The invention concerns a titanium or vanadium silicalite-based oxidation catalyst having a zeolite structure and containing between 0.01 and 20 wt % of one or a plurality of platinum metals from the group comprising ruthenium, rhodium, palladium, osmium, iridium and platinum. The invention is characterized in that the platinum metals are each present in at least two different bond energy states and preferably do not contain any metal-to-metal bonds.
摘要翻译：基于钛或钒硅沸石具有沸石结构且含有从0.01至20重量选自钌，铑，钯，锇，铱和铂中选择的一种或多种铂族金属％，其特征在于，在氧化催化剂，该铂族金属在每至少两个不同的键的能量状态存在，并优选没有金属 - 金属键。

7. 发明申请

WO1998001437A1 PROCESS FOR PREPARING PHTHALIDES 审中-公开
标题翻译：用于生产苯酞
公开(公告)号：WO1998001437A1
公开(公告)日：1998-01-15
申请号：PCT/EP1997003137
申请日：1997-06-17
申请人： BASF AKTIENGESELLSCHAFT , MASSONNE, Klemens , BECKER, Rainer , REIF, Wolfgang , NEUHAUSER, Horst , GIESELER, Andreas , MUNDINGER, Klaus
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07D307/88
CPC分类号： C07D307/88
摘要： The invention concerns a process for preparing phthalides of general formula (I) in which R , R , R and R , independently of each, other mean hydrogen, C1-C4 alkyl or C1-C4 alkoxy, by the catalytic hydrogenation of phthalic acid anhydrides of general formula (II), in which the groups R , R , R and R have the above meanings, in a solvent, the phthalide (I), which is produced as a reaction product during the catalytic hydrogenation process, being used as solvent.
摘要翻译：本发明涉及一种用于制备通式（I）中R <1>，R <2>，R <3>和R <4>独立地是氢，C1-C4烷基或C1-的苯酞 C4烷氧基，由通式（II）中，邻苯二甲酸酐的催化氢化，其中所述基团R <1>，R <2>，R <3>和R <4>的定义同上，在溶剂中，其中苯并呋喃酮（I）中的催化氢化反应产物产生，用作溶剂。

8. 发明申请

WO1998011051A1 PROCESS FOR SIMULTANEOUSLY PREPARING 6-AMINOCAPRONITRILE AND HEXAMETHYLENE DIAMINE 审中-公开
标题翻译：操作法，6-氨基己腈和己二胺同时生产
公开(公告)号：WO1998011051A1
公开(公告)日：1998-03-19
申请号：PCT/EP1997004542
申请日：1997-08-21
申请人： BASF AKTIENGESELLSCHAFT , VOIT, Guido , FLICK, Klemens , LUYKEN, Hermann , REHFINGER, Alwin , BASSLER, Peter
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07C209/48
CPC分类号： C07C209/48 , C07C253/30
摘要： The invention concerns a process for simultaneously preparing 6-aminocapronitrile and hexamethylene diamine proceeding from a mixture which contains a phosphorated compound and substantially adipodinitrile and is obtained by reacting butadiene with hydrocyanic acid in the presence of a catalyst containing a phosphorated compound. The process is characterized in that: (1) the portion by weight of a phosphorated compound, calculated as phosphorus, in the mixture is reduced; (2) the resultant mixture is partially hydrogenated in the presence of a catalyst in order to form an alpha-, omega aminonitrile; and (3) 6-aminocapronitrile and hexamethylene diamine are separated from the mixture.
摘要翻译：为6-氨基己腈和六亚甲基二胺的同时制备从混合物含有含磷化合物和基本上己二腈，并通过与氢氰酸在含含磷化合物的催化剂的存在下，其特征在于，一个丁二烯的反应而得到的起始（1的方法）将得到的混合物氢化，在催化剂的存在下，以形成从所述混合物中分离（重量）的含磷化合物，如磷计算的比例的α，ω-二氨基腈部分和（3）6-氨基己腈和六亚甲基二胺，在混合物中降低，并且（2）。

9. 发明申请

WO1998000417A1 PROCESS FOR PURIFYING PHTHALIDE 审中-公开
标题翻译：程序对清洁酞
公开(公告)号：WO1998000417A1
公开(公告)日：1998-01-08
申请号：PCT/EP1997003045
申请日：1997-06-12
申请人： BASF AKTIENGESELLSCHAFT , REIF, Wolfgang , MASSONNE, Klemens , NEUHAUSER, Horst
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07D307/88
CPC分类号： C07D307/88
摘要： The present invention relates to a process for purifying phthalide contamined with carboxylic acids and/or their derivatives, in which polyethyene glycol and/or polypropylene glycol is added to the phthalide to be purified and then subjected to fractional distillation.
摘要翻译：本发明涉及一种用于由羧酸和/或其衍生物，其中一个增加了苯酞污染净化酞待纯化聚乙二醇和/或聚丙二醇，然后分馏。

10. 发明申请

WO1998014441A1 PROCESS FOR PREPARING PHTHALIDES 审中-公开
标题翻译：用于生产苯酞
公开(公告)号：WO1998014441A1
公开(公告)日：1998-04-09
申请号：PCT/EP1997005186
申请日：1997-09-22
申请人： BASF AKTIENGESELLSCHAFT , MASSONNE, Klemens , BECKER, Rainer , NEUHAUSER, Horst , ZIMMERMANN, Horst , REIF, Wolfgang , CRAMERS, Peter , NARDIN, Daniel
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07D307/88
CPC分类号： C07D307/88
摘要： The invention concerns a process for preparing phthalides of general formula (I), in which R , R , R and R , independently of one another, designate hydrogen, C1-C4 alkyl or C1-C4 alkoxy, by hydrogenating phthalic acid anhydrides of general formula (II), in which the groups R , R , R and R have the above meanings, with hydrogen in the presence of suspended Raney-type catalysts in a hydrogenating device by mixing a liquid phase containing the catalyst and the phthalic acid anhydride used and the resultant phthalide and a gaseous phase containing the hydrogenating hydrogen using a mixing device which has a mixing output of at least 50 W/l in the liquid phase
摘要翻译：本发明涉及一种用于制备通式（I）中R <1>，R <2>，R <3>和R <4>独立地是氢，C1-C4烷基或C1-的苯酞 C4烷氧基，通过氢化上述通式（II），邻苯二甲酸酐，其中基团R <1>，R <2>，R <3>和R <4>具有上述含义，与在存在氢混合的催化剂和所用的邻苯二甲酸酐和所产生的含酞 - 液相和一个通过一个混合装置，其特征在于，混合至少50瓦的容量的输入由所述混合装置的装置到液相中的装置含有氢化氢的气相/升下，在氢化装置中的阮内型的悬浮催化剂，

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