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    • 9. 发明申请
    • IMINO OXYPHENYL ACETIC ACID DERIVATIVES, METHODS AND INTERMEDIATES FOR THEIR PREPARATION AND USE THEREOF
    • IMINOOXYPHENYLESSIGSÄUREDERIVATE,工艺和中间产品和使用
    • WO1997024317A1
    • 1997-07-10
    • PCT/EP1996005642
    • 1996-12-16
    • BASF AKTIENGESELLSCHAFTGROTE, ThomasSAUTER, HubertKIRSTGEN, ReinhardBAYER, HerbertMÜLLER, RuthMÜLLER, BerndOBERDORF, KlausGRAMMENOS, WassiliosGÖTZ, NorbertRACK, MichaelHARREUS, AlbrechtRÖHL, FranzAMMERMANN, EberhardHARRIES, VolkerLORENZ, GiselaSTRATHMANN, Siegfried
    • BASF AKTIENGESELLSCHAFT
    • C07C251/60
    • C07C251/60C07C2601/10C07C2601/14
    • The invention relates to 2-imino oxyphenyl acetic acid derivatives of formula (I) in which the substituents and the index have the following meanings: R is C(CO2CH3)=NOCH3 (Ia), C(CONHCH3)=NOCH3 (Ib), C(CONH2)=NOCH3 (Ic), C(CO2CH3)=CHOCH3 (Id), or C(CO2CH3)=CHCH3 (Ie); R is cyano, nitro, halogen, alkyl, alkyl halide or alkoxy; m is 0,1 or 2; R is hydrogen, cyano, hydroxy, halogen, alkyl, alkyl halide, alkoxy alkyl, alkoxy, alkoxy halide, alkylthio, cyclopropyl, alkenyl, optionally substituted aryloxy alkyl, benzyl or benzyloxy; R is hydrogen, cyano, optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, heterocyclyl, aryl and hetaryl, optionally substituted alkoxy, alkenyloxy, alkinyloxy, cycloalkoxy, heterocyclyloxy, aryloxy and hetaryloxy, optionally substituted arylthio and hetarylthio; -Q-C(R )=N-Y -R or -Q-O-N=CR R ; R and R together with the carbon atom to which they are bound, are an optionally substituted four to eight-membered ring which can contain in addition to carbon atoms one or two oxygen atoms and/or sulphur atoms and/or NH- and/or N(C1-C4-alkyl)groups; wherein R and R are not simultaneously bound via heteroatoms to the carbon atom. The invention also relates to the salts of said derivatives, methods and intermediates for their preparation and use thereof.
    • 式(I),2-Iminooxyphenylessigsäurederivate其中取代基和指数具有以下含义:R t <1> C(CO 2 CH 3)= NOCH 3(Ia)中,C(CONHCH 3)= NOCH 3(Ib)中,C(CONH 2)= NOCH 3(Ic)中,C(CO2CH3)= CHOCH 3(同上)或C(CO2CH3)= CHCH3(IE); [R <2>氰基,硝基,卤素,烷基,卤代烷基或烷氧基; m是0,1或2; [R <3>是氢,氰基,羟基,卤素,烷基,卤代烷基,烷氧基烷基,烷氧基,卤代烷氧基,烷硫基,环丙基,链烯基,未取代的或取代的。 芳氧基烷基,苄基或苄氧基; [R <4>是氢,氰基,未取代的或取代的。 烷基,烯基,炔基,环烷基,杂环基,芳基和杂芳基; 未取代的或取代的。 烷氧基,烯氧基,炔氧基,环烷氧基,杂环氧基,芳氧基和杂芳氧基; 未取代的或取代的。 芳和杂芳硫基; -Q-C(R <5>)= N-Y <1> -R <6>或-Q-O-N = CR <7> - [R <8>; [R <3>和R <4>的碳原子一起形成它们所连接的未取代或取代的。 四到八位元环,其除了碳原子,一个或两个氧和/或硫原子和/或NH和/或N(C1-C4烷基)可以含有基团; 其中R <3>和R <4>不同时经由键合至的碳原子键合的杂原子; 和它们的盐,过程和它们的制备方法和它们的使用的中间体。