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1. 发明申请

WO1993011109A1 N-('beta'-CARBONYL- AND 'beta'-CYANOVINYL)-2,2,6,6-TETRAMETHYLPIPERIDINE DERIVATIVES AND THEIR USE AS STABILIZERS FOR VARNISHES AND PLASTICS 审中-公开
标题翻译： N-（β-羧乙基 - 和β-氰基乙烯）-2,2,6,6-四甲基哌啶衍生物及其作为稳定剂和塑料的稳定剂的用途
公开(公告)号：WO1993011109A1
公开(公告)日：1993-06-10
申请号：PCT/EP1992002733
申请日：1992-11-27
申请人： BASF AKTIENGESELLSCHAFT , KRAUSE, Alfred , AUMUELLER, Alexander , TRAUTH, Hubert
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07D211/46
CPC分类号： C07D211/58 , C07D211/46 , C08K5/3435
摘要： The invention concerns N-(β-carbonyl- and β-cyanovinyl)-2,2,6,6-tetramethylpiperidine derivatives of general formula (I), in which R1 is COOR?3, COR4, CONR4R5¿ or CN; R2 is the same as R1 or a C¿1?-C12 alkyl group or hydrogen; X is oxygen, sulphur or a grouping of the formula -NR?6-, -NR6¿-CO-, (a), -O-CO-, -O-CO-O-, -O-CO-NR?6 or -NR6-CO-NR6¿-, the bond to the carbon atom at the 4-position in the piperidine ring being through an N-atom or O-atom; and the other substituents are as defined in the description. The invention also concerns the use of such compounds as stabilizers for the protection of plastics and varnishes against the action of light, oxygen and heat.

2. 发明申请

WO1993011111A1 'beta'-AMINOACRYLIC-ACID ESTER DERIVATIVES CONTAINING POLYALKYLPIPERIDINE GROUPS 审中-公开
标题翻译：含有聚对苯二酚组合物的β-亚氨基丙酸酯衍生物
公开(公告)号：WO1993011111A1
公开(公告)日：1993-06-10
申请号：PCT/EP1992002672
申请日：1992-11-20
申请人： BASF AKTIENGESELLSCHAFT , AUMUELLER, Alexander , KRAUSE, Alfred , TRAUTH, Hubert
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07D211/58
CPC分类号： C07D211/58 , C08G63/6858 , C08K5/3435
摘要： Disclosed are β-aminoacrylic-acid ester derivatives containing polyalkylpiperidine groups and having the formula (I), in which n is a number from 1 to 50; R?1 and R2¿, which may be the same or different, are hydrogen, C¿1?-C6 alkyl, formyl, C2-C6 alkanoyl, C1-C12 alkoxy, C5-C6 cycloalkoxy, Cyanomethyl, 2-hydroxyethyl, benzyl or a group of the formula -CR?3¿=CH-CO-OR4, R3 being hydrogen, C¿1?-C6 alkyl or a group of the formula -CO-OR?4 and R4¿ being C¿1?-C18 alkyl, C5-C8 cycloalkyl, C7-C18 aralkyl, phenyl or tolyl; A is C2-C12 alkylene, C5-C8 cycloalkylene, phenylene, biphenylene or a group of the formula (a), (b), (c), (d) or (e) in which m is 2 or 3. If n = 1, Y is hydrogen, C1-C18 alkyl, formyl, C2-C18 alkanoyl, C7-C18 aralkyl or a group of the formula -CH=CH-CO-O-Z; B is a direct linkage and Z is C1-C18 alkyl, C5-C8 cycloalkyl, C7-C18 aralkyl, phenyl, tolyl or a group of the formula -CCH2CH2O)pH or --[CH(CH3)CH2O]pH, p being a number between 1 and 30, and, if n > 1, Y is hydrogen or a group of the formula (f); B is a bridging group of the formula -CH=CH-CO-O-X-, Z being bonded to the C-C double bond in B; X is C2-C18 alkylene, C5-C8cycloalkylene, phenylene, biphenylene or a group of the formula -(CH2CH2O)qCH2CH2- or -[CH(CH3)CH2O]qCH(CH3)CH2-, q being a number from 1 to 30, and Z is a group of the formula (g or h).

3. 发明申请

WO1994018202A1 N-VINYL-GROUP-CONTAINING GLYCOL URILE DERIVATIVES AND THEIR USE AS PHOTOPROTECTIVE AGENTS AND STABILISERS FOR ORGANIC MATERIAL 审中-公开
标题翻译：含N-乙烯基甘脲和它们作为光稳定剂和稳定剂用于有机材料
公开(公告)号：WO1994018202A1
公开(公告)日：1994-08-18
申请号：PCT/EP1994000182
申请日：1994-01-25
申请人： BASF AKTIENGESELLSCHAFT , KRAUSE, Alfred , AUMUELLER, Alexander , KORONA, Eckhard , TRAUTH, Hubert
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07D487/22
CPC分类号： C07D487/22 , C08K5/3477 , C09D7/48 , C09K15/30
摘要： N-vinyl-group-containing glycol urile derivatives (I) in which R and R are mutually independently hydrogen, C1 to C12 alkyl, C5 to C8 cycloalkyl, phenyl, tolyl or C7 to C12 phenylalkyl or R and R together are a tri, tetra or pentamethylene grouping, R to R are C1 to C4 alkyl, R is hydrogen, C1 to C8 alkyl, cyano or a radical of formula COOR , R is cyano or a radical of formula COOR , and R is C1 to C12 alkyl, C5 to C8 cycloalkyl, phenyl, tolyl or C7 to C12 phenylalkyl. The compounds (I) are suitable as photoprotective agents and stabilisers for organic materials, especially plastics and paints.

4. 发明申请

WO1994012544A1 MALEIC ACID IMIDE 'alpha'-OLEFIN COPOLYMERS AND THEIR USE AS LIGHT-PROTECTION AGENTS AND STABILIZERS FOR ORGANIC MATERIALS 审中-公开
标题翻译：马来酰亚胺，α-烯烃共聚物及其用途轻保护产品和有机材料稳定剂
公开(公告)号：WO1994012544A1
公开(公告)日：1994-06-09
申请号：PCT/EP1993003202
申请日：1993-11-15
申请人： BASF AKTIENGESELLSCHAFT , KRAUSE, Alfred , DENZINGER, Walter , HETTCHE, Albert , AUMUELLER, Alexander , TRAUTH, Hubert
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08F08/32
CPC分类号： C08F210/14 , C08F8/32 , C08F222/06
摘要： Described are maleic acid imide alpha -olefin copolymers with a mean molecular weight of 1,000 to 50,000, built up of structural units of the formula I, R being a tetramethylpiperidinyl grouping of the formula II in which R is hydrogen, C1 to C6 alkyl, formyl, C2 to C6 alkanoyl, C1 to C12 alkoxy, C5 to C6 cycloalkoxy, cyanomethyl, 2-Hydroxyethyl, benzyl or a group of the formula -CR = CH-CO-OR , R being hydrogen,C1 to C6 alkyl or a group of the formula -CO-OR , and r being C1 to C18 alkyl, C5 to C8 cycloalkyl, C7 to C18 aralkyl, phenyl or tolyl, where R can also denote, in a quantity of up to 8 mole % relative to II, hydrogen, C1 to C22 alkyl or C5 to C8 cycloalkyl, and R is a mixture of C14 to C28 alkyl groups, two of these alkyl groups, which may not differ from each other by more than two C-atoms, constituting at least 30 % of this mixture. The copolymers described are suitable for use as light-protection agents and stabilizers for organic materials, particularlyplastics and paints.

5. 发明申请

WO1994018210A1 USE OF AMINOVINYL PHOSPHONIC ACID ESTERS AS PHOTOPROTECTIVE AGENTS AND STABILIZERS FOR ORGANIC MATERIAL 审中-公开
标题翻译： AMINOVINYLPHOSPHONSÄUREESTERN作为防晒剂有机材料稳定剂使用
公开(公告)号：WO1994018210A1
公开(公告)日：1994-08-18
申请号：PCT/EP1994000254
申请日：1994-01-29
申请人： BASF AKTIENGESELLSCHAFT , HOLDERBAUM, Martin , AUMUELLER, Alexander , TRAUTH, Hubert
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07F09/40
CPC分类号： C09K15/32 , C07F9/4015 , C07F9/58 , C07F9/59 , C08K5/005 , C08K5/53 , C08K5/5353 , C08K5/5373 , C09D7/48
摘要： The present invention pertains to the use of aminovinyl phosphonic acid esters of general formula (I), in which R is cyano, a radical of the formula -CO-OR or a grouping of formula (II), R , R and R are C1 to C20 alkyl, C5 to C8 cycloalkyl, C7 to C18 aralkyl, phenyl or tolyl, R is phenyl, which can be substituted by one to three C1 to C12 alkyl groups, C1 to C12 alkoxy groups, halogen atoms, cyano groups, hydroxyl groups, phenyl groups or groups of formula -CO-OR , -CO-R , -CO-NHR , -O-CO-R or -NH-CO-R , a five- or six-membered unsaturated or saturated heterocyclic ring with up to three heteroatoms from the group of nitrogen, oxygen and sulfur, which ring can also be benzanellated and substituted by one to three C1 to C12 alkyl groups, C1 to C12 alkoxy groups, halogen atoms, cyano groups, hydroxyl groups, phenyl groups, phenoxy groups or C1 to C12 alkoxycarbonyl groups, or a grouping of the formula (III), R is hydrogen or C1 to C12 alkyl, R is hydrogen, C1 to C6 alkyl, formyl, C2 to C6 alkanoyl, C1 to C12 alkoxy, C5 to C6 cycloalkoxy, cyanomethyl, 2-hydroxyethyl, benzyl or a radical of the formula -CR = CH-CO-OR , wherein R is hydrogen, C1 to C6 alkyl or a radical of the formula -CO-OR , and X stands for oxygen or NH, as photoprotective agents and stabilizers for organic material.

6. 发明申请

WO1993001164A1 AMINOMETHYLENECYANOACETIC ACID ESTERS AND AMIDES 审中-公开
标题翻译：氨基酸亚硝酸酯和氨基酸
公开(公告)号：WO1993001164A1
公开(公告)日：1993-01-21
申请号：PCT/EP1992001432
申请日：1992-06-25
申请人： BASF AKTIENGESELLSCHAFT , HOLDERBAUM, Martin , AUMUELLER, Alexander , TRAUTH, Hubert
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07C255/30
CPC分类号： C07D213/74 , C07C255/30 , C07C2601/14
摘要： Disclosed are aminomethylenecyanoacetic acid esters and amides of formula (I), in which R?1 and R2¿, independently of each other, are phenyl, naphthyl, biphenyl or a five- or six-membered hetero-aryl group which has one, two or three nitrogen atoms or one oxygen atom or one sulphur atom or one nitrogen and one oxygen atom or one nitrogen and one sulphur atom, and which may be benzannulated, whereby these groups may be substituted by one to three C¿1?-C12-alkyl groups, C1-C12-alkoxy groups, halogen atoms, cyano groups, hydroxy groups or groups of the formulae COOR?3 COR3, CONHR3, OCOR3¿ or NHCOR3, where R3 is C1-C12-alkyl, C5-C8-cycloalkyl or phenyl; X is a C2-C30-alkylene group which may contain non-adjacent oxygen atoms, a C4-C12-alkylene or C4-C12-alkinylene group (the unsaturated bonds not being adjacent to the ester oxygen atoms), a C5-C8-cycloalkylene group or a phenylene group; and Y is O or NH. These compounds can be used as stabilizers for organic materials.

7. 发明申请

WO1993009173A1 USE OF 3-AMINO-2(BENZOYLAMINO)ACRYLIC ACID ESTERS AS STABILISERS FOR ORGANIC MATERIALS 审中-公开
标题翻译： 3-氨基-2-（苯甲酰氨基）丙烯酸酯作为有机材料稳定剂的应用
公开(公告)号：WO1993009173A1
公开(公告)日：1993-05-13
申请号：PCT/EP1992002455
申请日：1992-10-28
申请人： BASF AKTIENGESELLSCHAFT , HOLDERBAUM, Martin , AUMUELLER, Alexander , TRAUTH, Hubert
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08K05/34
CPC分类号： C08K5/34 , A61K8/44 , A61K8/4966 , A61K8/4973 , A61Q17/04 , C07D213/74 , C07D239/42 , C07D241/20
摘要： Use of 3-amino-2(benzoylamino)acrylic acid esters (I) in which R1 is C1 to C20-alkyl which may be interrupted by one or more non-adjacent O atoms or NR5 groups and may bear one or more hydroxyl groups, C¿2? to C20-alkenyl, C5 to C8-alkenyl, C5 to C8-cycloalkyl or phenyl which may be substituted by one to three C1 to C4-alkyl groups, C1 to C4-alkoxy groups, C1 to C4-alkoxy groups, halogen atoms, hydroxyl groups, phenoxy groups, phenyl radicals, cyano groups or C1 to C4-alkoxy carbonyl groups; R?2¿ is hydrogen or C¿1? to C20-alkyl; R?3¿ is a five or six-component unsaturated or saturated heterocyclic ring with up to three hetero atoms from the group nitrogen, oxygen and sulphur, which is additionally benzannulated and may be substituted by one to three C¿1? to C4-alkyl groups, C1 to C4-alkoxy groups, halogen atoms, hydroxyl groups, phenoxy groups, phenyl radicals, cyano groups or C1 to C4-alkoxycarbonyl groups; R?4¿ is hydrogen, C¿1? to C12-alkyl, C1 to C12-alkoxy, halogen, hydroxyl, phenoxy, phenyl, cyano or a grouping of the formula -CO-OR?5, -CO-R5¿, -O-CO-R5 of -NH-CO-R?5; R5 is C¿1 to C12-alkyl, C5 to C8-cycloalkyl or phenyl; and n is 1 to 3, as stabilisers for organic materials.

8. 发明申请

WO1993022376A2 AMINO COMPOUNDS AS PROCESSING STABILISERS FOR THERMOPLASTIC MATERIALS 审中-公开
标题翻译：氨基化合物作为热塑性塑料加工稳定剂
公开(公告)号：WO1993022376A2
公开(公告)日：1993-11-11
申请号：PCT/EP1993000951
申请日：1993-04-20
申请人： BASF AKTIENGESELLSCHAFT , AUMUELLER, Alexander , TRAUTH, Hubert
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08K05/17
CPC分类号： C08K5/3462 , C08K5/17 , C08K5/3445
摘要： The invention relates to the use of compounds of general formula (I) or (II) as processing stabilisers for thermoplastic materials. In said formulae, m is 2 or 3; n is a number from 1 to 6; R and R are, independently, hydrogen, C1 to C18 alkyl, C3 to C8 alkenyl, C5 to C12 cycloalkyl, C7 to C12 phenylalkyl, in which the phenyl nucleus may be substituted by up to 3 C1 to C12 alkyl groups or C1 to C12 alkoxy groups; X is oxygen or NR ; R is a radical R or a grouping of formula (III); B is the completion to a 3 to 12-membered heterocycle; A, with n = 1, is an aliphatic radical or optionally substituted phenyl; and A, with n > 1, is a divalent organic radical.

9. 发明申请

WO1993020051A1 ACETIC ACID AND 3-AMINOACRYLIC ACID DERIVATIVES CONTAINING POLYALKYL PIPERADINE GROUPS 审中-公开
标题翻译：多烷基GROUPS含乙酸和3-氨基丙烯酸衍生物
公开(公告)号：WO1993020051A1
公开(公告)日：1993-10-14
申请号：PCT/EP1993000739
申请日：1993-03-26
申请人： BASF AKTIENGESELLSCHAFT , HOLDERBAUM, Martin , AUMUELLER, Alexander , TRAUTH, Hubert
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07D211/46
CPC分类号： C07D401/12 , C07D211/46 , C07D211/94 , C08K5/3435 , C09D7/48
摘要： PCT No. PCT/EP93/00739 Sec. 371 Date Oct. 7, 1994 Sec. 102(e) Date Oct. 7, 1994 PCT Filed Mar. 26, 1993 PCT Pub. No. WO93/20051 PCT Pub. Date Oct. 14, 1993Polyalkylpiperidine-containing acetic acid and 3-aminoacrylic acid derivatives I I where R1 is hydrogen, C1- to C6-alkyl, formyl, C2- to C6-alkanoyl, C1- to C12-alkoxy, C5- to C6-cycloalkoxy, cyanomethyl, hydroxymethyl, 2-hydroxyethyl or a radical of the formula -CR3=CH-CO-OR4, where R3 is hydrogen, C1-to C6-alkyl or a radical of the formula -CO-OR4 and R4 is C1- to C20-alkyl, C5- to C8-cycloalkyl, C7- to C18-aralkyl, phenyl, tolyl or a radical of the formula -(CH2CH2O)nH or -[CH(CH3)CH2O]nH, where n is a number from 1 to 30, X is O, NH or NR6, where R6 is C1- to C12-alkyl, and Y is hydrogen or a group of the formula =CH-NHR7 or =CH-NR6R7, where R7 is phenyl which can be substituted by one to three C1- to C12-alkyl, C1- to C12-alkoxy, halogen, cyano, hydroxyl, phenyl or groups of the formula -CO-OR5, -CO-R5, -CO-NHR5, -O-CO-R5 or -NH-CO-R5, is a 5- or 6-membered unsaturated or saturated heterocyclic ring having up to three hetero atoms from the group comprising nitrogen, oxygen and sulfur, which can additionally be benzo-fused and substituted by one to three C1- to C12-alkyl, C1- to C12-alkoxy, halogen, cyano, hydroxyl, phenyl, phenoxy or C1- to C12-alkoxycarbonyl are described.

10. 发明申请

WO1997049751A1 POLYCONDENSATES CONTAINING TETRAMETHYLPIPERIDINE GROUPS 审中-公开
标题翻译：四甲基哌啶缩聚物含
公开(公告)号：WO1997049751A1
公开(公告)日：1997-12-31
申请号：PCT/EP1997003043
申请日：1997-06-12
申请人： BASF AKTIENGESELLSCHAFT , KRAUSE, Alfred , AUMÜLLER, Alexander , TRAUTH, Hubert , LANGGUTH, Ernst
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08G63/685
CPC分类号： C08K5/3435 , C07D211/58 , C08G63/6858 , C08G73/02 , C08G75/26 , C08L79/04 , C09D7/65 , C09K15/30
摘要： Polycondensates containing tetramethylpiperidine groups of general formula (I) in which the variables have the following meaning: R , R are hydrogen, C1-C12-alkyl, C2-C4-hydroxyalkyl, C1-C20-alkoxy, oxyl, hydroxyl, allyl, benzyl, formyl or a residue of formula (a), R is hydroxy, C1-C12-alkoxy, C3-C8-cycloalkoxy, C3-C8-cycloalkylmethoxy, phenoxy or a residue (b), R is hydrogen or a residue (c), R is -COOR , -COR , -CONR R or cyano, R is an R residue, hydrogen or C1-C12-alkyl, R is hydrogen, C1-C12-alkyl, C3-C8-cycloalkyl, C3-C8-cycloalkylmethyl or phenyl, R is hydrogen, C1-C8-alkyl, C5-C8-cycloalkyl, C3-C5-alkenyl or phenyl, which can be substituted by one to three methyl or ethyl residues, C1-C4-alkoxy residues, C1-C4-alkoxycarbonyl residues, halogens, hydroxy groups, phenoxy groups, phenyl groups, tolyl residues or xylyl residues, R , R are hydrogen, C1-C12-alkyl, C5-C8-cycloalkyl or phenyl, which can be substituted by one to three methyl or ethyl residues, C1-C4-alkoxy residues, C1-C4-alkoxycarbonyl residues, halogens, hydroxy groups, phenoxy groups, phenyl groups, tolyl residues or xylyl residues, X is oxygen, sulphur or -NR -, A is C2-C30-alkylene, wherein non-adjacent CH2 groups can be replaced by oxygen, C3-C8-cycloalkylene, C3-C8-cycloalkyl-bismethylene, phenylene, biphenylene or the residues (d), (e), (f), (g) or (h), (i) or (j) in which n means 2 to 12, m means 1 to 2 000 and o means 2 or 3.
摘要翻译：含有通式（I），其中各变量具有以下含义的缩聚物四甲基哌啶，R <1>，R <2>为氢，C1-C12烷基，C2-C4羟基烷基，C1-C20烷氧基，氧基，羟基，烯丙基，苄基，甲酰基或基团的式（a）中，R <3>是羟基，C1-C12烷氧基，C3-C8-环烷氧基，C3-C8-cycloalkylmethoxy，苯氧基或基团（b）中，R < 4>是氢或基团（c）中，R <5> -COOR <8>，-COR <9>，-CONR <9> - [R <10>或氰基，R <6>是基团R <5>氢或C 1 -C 12烷基，R <7>是氢，C1-C12烷基，C3-C8环烷基，C3-C8环烷基甲基或苯基，R <8>是氢，C1-C8烷基，C5-C8环烷基，C3-C5链烯基或苯基，其可以被一个1-3个甲基或乙基，C1-C4烷氧基，C1-C4烷氧羰基，卤素，羟基，苯氧基，苯基，甲苯基或二甲苯基，R <9> ，R <10>为氢，C1-C12烷基，C5-C8环烷基或苯基，其被一至三个甲基或乙基 C1-C4烷氧基，C1-C4烷氧羰基，卤素，羟基，苯氧基，苯基，甲苯基或二甲苯基可被取代，X为氧，硫或-NR <9> - ，A C2-C30亚烷基，其中不相邻的CH 2 基团可以被氧替代，C3-C8亚环烷基，C3-C8环烷基二亚甲基，亚苯基，亚联苯基或基团（D），（C），（F），（G）或（h），（I）或（j），其中n是2〜12，m为1〜2000和o是2或3。

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