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    • 1. 发明申请
    • AMIDRAZONE COMPOUNDS FOR COMBATING ANIMAL PESTS
    • 用于组合动物疫苗的咪唑啉酮化合物
    • WO2006097279A8
    • 2007-05-18
    • PCT/EP2006002331
    • 2006-03-14
    • BASF AGKORADIN CHRISTOPHERDEYN WOLFGANG VONRACK MICHAELKUHN DAVID GCULBERTSON DEBORAH LANSPAUGH DOUGLASOLOUMI-SADEGHI HASSAN
    • KORADIN CHRISTOPHERVON DEYN WOLFGANGRACK MICHAELKUHN DAVID GCULBERTSON DEBORAH LANSPAUGH DOUGLASOLOUMI-SADEGHI HASSAN
    • A01N37/52A01P5/00A01P7/00A01P7/04C07C259/20
    • C07C259/20A01N37/52C07C2601/02
    • The present invention relates to new amidrazone compounds which are useful for combating animal pests, in particular insects, arachnids and nematodes. The invention also relates to a method for combating insects, nematodes and arachnids. The amidrazone compounds are of the general formula (I) including the tautomers of I and the salts thereof; wherein X and Y are hydrogen or together form a chemical bond; Ar is an aromatic radical selected from phenyl and a 5- or 6-membered heteroaryl having 1 , 2, 3 or 4 heteroatoms as ring members, which are selected, independently of one another, from O, N and S, and where the aromatic radical may have 1 , 2, 3, 4 or 5 substituents R a ; R 1 is selected from the group consisiting of C 1 -C 1O -alkyl, C 1 -C 4 -alkoxy-C 1 -C 4 -alkyl, cyano-C 1 -C 4 -alkyl, hydroxy-C 1- C 4 -alkyl, C 1 -C 10 -haloalkyl, tri-(C 1 -C 4 -alkyl)-silyl-C 1 - C 4 -alkyl, C 2 -C 10 -alkenyl, C 2 -C 10 -haloalkenyl, C 2 -C 10 -alkynyl, C 2 -C 10 -haloalkynyl, C 3 -C 10 -cycloalkyl, phenyl, heteroaryl, C 3 -C 10 -cycloalkyl-C 1 C 4 -alkyl, phenyl-C 1 -C 4 - alkyl and heteroaryl-C 1 C 4 alkyl, wherein C 3 -C 10 -cycloalkyl, heteroaryl and phenyl in the last six mentioned radicals may be unsubstituted or carry 1 , 2, 3, 4 or 5 substituents R b as defined above; R 2 is selected from the group consisiting of C 1- C 1 0-alkyl, c 1- c 4 -alkoxy- C 1- C 4 -alkyl, C 1- C 10 -haloalkyl, C 2 -C 10 -alkenyl, C 2 -C 10 -haloalkenyl, C 2 -C 10 -alkynyl, C 2 -C 10 - haloalkynyl,c 3 -C 10 -cycloalkyl, phenyl, heteroaryl, C 3 -C 10 -cycloalkyl-C 1- C 4 -alkyl, phenyl-C 1 -C 4 -alkyl and heteroaryI-C 1- C 4 -alkyl, wherein C 3 -C 10 -cycloalkyl, heteroaryl and phenyl in the last six mentioned radicals may be unsubstituted or carry 1 , 2, 3, 4 or 5 substituents R b as defined above.
    • 本发明涉及可用于对抗动物害虫,特别是昆虫,蜘蛛和线虫的新的氨基腙化合物。 本发明还涉及一种防治昆虫,线虫和蜘蛛的方法。 氨基腙化合物具有通式(I),其包括I的互变异构体及其盐; 其中X和Y是氢或一起形成化学键; Ar是选自苯基和具有1,2,3或4个杂原子作为环成员的5-或6-元杂芳基的芳族基团,其彼此独立地选自O,N和S,并且其中芳族 基团可以具有1,2,3,4或5个取代基R a, R 1选自C 1 -C 10 - 烷基,C 1 -C 1 - 烷基, C 1 -C 4烷基,C 1 -C 4烷基,C 1 -C 4烷基,氰基-C 1 -C 4烷基, C 1 -C 6烷基,羟基-C 1 -C 4 - 亚烷基,C 1 -C 10 - 烷基, 卤代烷基,三 - (C 1 -C 4 - 烷基) - 甲硅烷基-C 1 -C 4 - 烷基,C 2 -C 10 - 烯基,C 2 -C 10 - 卤代烯基,C 1 -C 10 - C 2 -C 10 - 炔基,C 2 -C 10 - 卤代炔基,C 3 - C 10 - 环烷基,苯基,杂芳基,C 3 -C 10 - 环烷基-C 1 -C C 1-4烷基,苯基-C 1 -C 4 - 烷基和杂芳基-C 1 -C 4烷基, 其中C 3 -C 10 - 环烷基,杂芳基和苯基在后面六个提及的基团中可以是未取代的或携带1,2,3,4或4个 5个取代基R b如上所定义; R 2选自C 1 -C 1-4烷基,C 1 -C 4烷基, C 1-4烷基,C 1 -C 10烷基,C 1 -C 4烷基,C 1〜 亚烷基,C 2 -C 10 - 烯基,C 2 -C 10 - 卤代烯基,C C 2 -C 10 - 炔基,C 2 -C 10 - 卤代炔基,C 3 - C 1 -C 10 - 环烷基,苯基,杂芳基,C 3 -C 10 - 环烷基-C 1 - C 1 -C 4 - 烷基,苯基-C 1 -C 4 - 烷基和杂芳基C 1 -C 其中C 3 -C 10 - 环烷基,最后六个所述基团中的杂芳基和苯基可以是未取代的或携带1, 2,3,4或5个如上定义的取代基R b。
    • 6. 发明申请
    • SULFONAMIDE COMPOUNDS
    • 磺酰胺化合物
    • WO2009153285A2
    • 2009-12-23
    • PCT/EP2009057531
    • 2009-06-17
    • BASF SEDEYN WOLFGANG VONPUHL MICHAELPOHLMAN MATTHIASRACK MICHAELPARRA RAPADO LILIANALANGEWALD JUERGENANSPAUGH DOUGLAS DOLOUMI-SADEGHI HASSANCULBERTSON DEBORAH LRANKL NANCY BKAMP HENNICKEVAN RAVENZWAAY BENNARD
    • VON DEYN WOLFGANGPUHL MICHAELPOHLMAN MATTHIASRACK MICHAELPARRA RAPADO LILIANALANGEWALD JUERGENANSPAUGH DOUGLAS DOLOUMI-SADEGHI HASSANCULBERTSON DEBORAH LRANKL NANCY BKAMP HENNICKEVAN RAVENZWAAY BENNARD
    • C07D417/06A01N43/80C07D417/14
    • C07D417/06A01N43/80C02F1/001C02F2209/03C02F2303/16C07D417/14
    • The present invention relates to sulfonamide compounds of formula (I) wherein R1 is H, halogen, CN, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-alkylthio, C2-C6-alkenylthio, C2-C6-alkynylthio, C1-C6-haloalkyl or C1-C6-haloalkoxy; R2 and R3 are H, halogen, CN, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-alkylthio, C2-C6-alkenylthio, C2-C6-alkynylthio, C1-C6-haloalkyl or C1-C6-haloalkoxy; or R2 together with R3 form a fused 5 or 6-membered carbocycle or heterocycle; R4 is halogen, CN, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C6-alkoxy, C1-C6-alkylthio, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkyl, C1-C6-haloalkoxy, C1-C6-haloalkylthio, C1-C6-haloalkylsulfinyl or C1-C6-haloalksulfonyl; n is 0, 1, 2 or 3; R5 is phenyl or a 5- or 6-membered heterocycle; X is O or NRx, wherein Rx is H, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-alkylcarbonyl or C1-C6-alkylcarbonyloxy; Y is N or C(Ry), wherein Ry is H, halogen, CN, C1-C6-alkyl,C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C3-7-cycloalkyl- C1-C4-alkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-alkylthio, C2-C6-alkenylthio, C2-C6-alkynylthio, C1-C6-haloalkyl and C1-C6-haloalkoxy; and Z is a chemical bond, O or N(Rz), wherein Rz is C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C1-C6-alkylcarbonyl or C1-C6-alkylcarbonyloxy; as well as to the N-oxides and salts thereof. These compounds are useful for combating animal pests. The invention also relates to a process for the preparation of these compounds and to intermediate compounds used in said process. The invention further relates to a method for controlling animal pests by using the compounds of formula (I), the N-oxides or the salts thereof, to plant propagation material and to an agricultural and veterinary composition comprising said compounds, the N-oxides or the salts thereof.
    • 本发明涉及式(I)的磺酰胺化合物,其中R1是H,卤素,CN,C1-C6-烷基,C2-C6-烯基,C2-C6-炔基,C3-C7-环烷基,C3-C7-环烷基 C 1 -C 4 - 烷基,C 1 -C 6 - 烷氧基,C 2 -C 6 - 烯氧基,C 2 -C 6 - 炔氧基,C 1 -C 6 - 烷硫基,C 2 -C 6 - 烯硫基,C 2 -C 6 - 炔硫基,C 1 -C 6 - 卤代烷基或C 1 1 -C 6 - 卤代烷氧基; R2和R3是H,卤素,CN,C1-C6-烷基,C2-C6-烯基,C2-C6-炔基,C3-C7-环烷基,C3-C7-环烷基-C1-C4-烷基,C1-C6- 烷氧基,C 2 -C 6 - 烯氧基,C 2 -C 6 - 炔氧基,C 1 -C 6 - 烷硫基,C 2 -C 6 - 烯硫基,C 2 -C 6炔硫基,C 1 -C 6卤代烷基或C 1 -C 6卤代烷氧基; 或R 2与R 3一起形成稠合的5或6元碳环或杂环; R4是卤素,CN,C1-C6-烷基,C2-C6-烯基,C2-C6-炔基,C1-C6-烷氧基,C1-C6-烷硫基,C1-C6-烷基亚磺酰基,C1-C6-烷基磺酰基,C1- C 1 -C 6卤代烷基,C 1 -C 6卤代烷硫基,C 1 -C 6卤代烷基亚磺酰基或C 1 -C 6卤代磺酰基; n为0,1,2或3; R5是苯基或5-或6-元杂环; X是O或NR x,其中Rx是H,C 1 -C 6烷基,C 2 -C 6 - 烯基,C 2 -C 6 - 炔基,C 3 -C 7 - 环烷基,C 1 -C 6 - 烷氧基,C 2 -C 6 - 烯氧基,C 2 -C 6 - 炔基氧基,C 1 -C 6 - 烷基羰基或C 1 -C 6烷基羰基氧基; Y是N或C(Ry),其中R y是H,卤素,CN,C 1 -C 6烷基,C 2 -C 6 - 烯基,C 2 -C 6炔基,C 3 -C 7 - 环烷基,C 3-7 - C 1 -C 6烷基,C 1 -C 6 - 烷氧基,C 2 -C 6 - 烯氧基,C 2 -C 6 - 炔氧基,C 1 -C 6 - 烷硫基,C 2 -C 6 - 烯硫基,C 2 -C 6 - 炔硫基, 卤代烷氧基; Z为化学键,O或N(Rz),其中Rz为C1-C6-烷基,C2-C6-烯基,C2-C6-炔基,C3-C7-环烷基,C1-C6-烷氧基,C2-C6 - 烯氧基,C1-C6-烷基羰基或C1-C6-烷基羰基氧基; 以及N-氧化物及其盐。 这些化合物可用于对抗动物害虫。 本发明还涉及制备这些化合物的方法和用于所述方法的中间体化合物。 本发明还涉及通过使用式(I)化合物,其N-氧化物或其盐来植物繁殖材料以及包含所述化合物,N-氧化物或其盐的农业和兽医组合物来控制动物害虫的方法 其盐。
    • 7. 发明申请
    • 3-AMINO-1,2-BENZISOTHIAZOLE COMPOUNDS FOR COMBATING ANIMAL PEST II
    • 3-氨基-1,2-苯并二硫唑化合物治疗动物瘟疫II
    • WO2008090048A3
    • 2008-11-20
    • PCT/EP2008050337
    • 2008-01-14
    • BASF AGDEYN WOLFGANG VONPOHLMAN MATTHIASKAISER FLORIANDICKHAUT JOACHIMANSPAUGH DOUGLAS DCULBERTSON DEBORAH LOLOUMI-SADEGHI HASSAN
    • VON DEYN WOLFGANGPOHLMAN MATTHIASKAISER FLORIANDICKHAUT JOACHIMANSPAUGH DOUGLAS DCULBERTSON DEBORAH LOLOUMI-SADEGHI HASSAN
    • C07D275/06A01N43/80C07D275/04C07D417/12C07D417/14
    • C07D417/14A01N43/80A01N43/90C07D275/04C07D275/06C07D417/12
    • The invention provides 3-amino-1,2-benzisothiazole compounds of formula (I) wherein n, R 1 , R 2 , R 3 , R 4 and A are defined as in the description. The invention provides further agricultural compositions comprising an amount of at least one compound of the formula (I) or an enantiomer, diasteromer or salt thereof; the use of a compound of formula (I) or an enantiomer, diasteromer or salt thereof for combating animal pests; a method of combating animal pests which comprises contacting the animal pests, their habit, breeding ground, food supply, plant, seed, soil, area, material or environment in which the animal pests are growing or may grow, or the materials, plants, seeds, soils, surfaces or spaces to be protected from animal attack or infestation with a pesticidally effective amount of at least one compound of the formula (I) or an enantiomer, diasteromer or salt thereof; a method for protecting crops from attack or infestation by animal pests, which comprises contacting a crop with a pesticidally effective amount of at least one compound of the formula (I) or an enantiomer, diasteromer or salt thereof; a method for the protection of seeds from soil insects and of the seedlings' roots and shoots from soil and foliar insects comprising contacting the seeds before sowing and/or after pregermination with at least one compound of the formula (I), or the enantiomers, diastereomers or salts thereof; and seeds comprising a compound of the formula I or an enantiomer, diasteromer or salt thereof.
    • 本发明提供了式(I)的3-氨基-1,2-苯并异噻唑化合物,其中n,R 1,R 2,R 3, R 4和A如说明书中所定义。 本发明提供了另外的农业组合物,其包含一定量的至少一种式(I)化合物或其对映异构体,非对映异构体或盐; 式(I)化合物或其对映体,非对映体或盐用于对抗动物害虫的用途; 一种防治动物害虫的方法,其包括使动物害虫,其习性,繁殖场,食物供应,植物,种子,土壤,面积,动物害虫正在生长或可能生长的材料或环境,或材料,植物, (I)化合物或其对映异构体,非对映异构体或盐的动物攻击或侵染的种子,土壤,表面或空间; 该方法包括使农作物与杀虫有效量的至少一种式(I)化合物或其对映异构体,非对映异构体或盐接触; 一种保护种子免受土壤昆虫以及幼苗的根和芽以及土壤和叶面昆虫的方法,包括在播种前和/或发芽后使种子与至少一种式(I)化合物或对映异构体接触, 非对映异构体或其盐; 和包含式I化合物或其对映体,非对映体或盐的种子。
    • 8. 发明申请
    • THE USE OF N-ARYLHYDRAZINE DERIVATIVES FOR COMBATING PESTS IN AND ON ANIMALS
    • 使用N-芳基衍生物在动物体内和动物体内
    • WO2005053402A3
    • 2005-08-04
    • PCT/EP2004013685
    • 2004-12-02
    • BASF AGDEYN WOLFGANG VONOLOUMI-SADEGHI HASSANKUHN DAVID GARMES NIGELKORADIN CHRISTOPHERZELLER ALISSA
    • VON DEYN WOLFGANGOLOUMI-SADEGHI HASSANKUHN DAVID GARMES NIGELKORADIN CHRISTOPHERZELLER ALISSA
    • A01N37/52
    • A01N37/52
    • Use of compounds of formula (I) wherein Q is (II), (III), or (IV) ; X is chlorine, bromine, or fluorine; R , R are each independently H, alkyl, alkenyl, alkynyl, or cycloalkyl, alkylamino, dialkylamino, alkylcarbonylamino, alkylsulfonyl, or alkylsulfinyl, wherein the carbon atoms in these groups may be substituted, or R and R may be taken together to form a ring represented by the structure (V); p,m are 1, 2 or 3; X' is oxygen, sulfur, amino, alkylamino, phenylamino, or methylene; Z is alkyl or phenyl; R is H, alkyl, alkenyl, alkynyl, cycloalkyl, wherein the carbon atoms in these groups may be substituted; R, R are H or alkyl, alkoxycarbonyl, alkylaminocarbonyl, or dialkylaminocarbonyl, wherein the carbon atoms in the these groups may be substituted; A is C-R or N; B is C-R or N; W is C-R or N; with the proviso that one of A, B and W is other than N; R , R , R are H, halogen, nitro, cyano, amino, mercapto, hydroxy, alkyl, alkenyl, alkynyl, cycloalkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkylsulfonyl, or alkylsulfinyl, wherein the carbon atoms in these groups may be substituted, a 5- to 6-membered aromatic ringsystem which may contain 1 to 4 heteroatoms selected from oxygen, sulfur and nitrogen and which may be substituted; Y is hydrogen, halogen, cyano, nitro, amino, hydroxy, mercapto, alkyl, alkenyl, alkynyl, cycloalkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkylsulfonyl, or alkylsulfinyl, wherein the carbon atoms in these groups may be substituted; n is 0, 1, or 2; for combating parasites in and on animals.
    • 其中Q为(II),(III)或(IV)的式(I)化合物; X 1是氯,溴或氟; R 1,R 2各自独立地为H,烷基,烯基,炔基或环烷基,烷基氨基,二烷基氨基,烷基羰基氨基,烷基磺酰基或烷基亚磺酰基,其中这些基团中的碳原子可以被取代,或R 1, 和R 2可以一起形成由结构(Ⅴ)表示的环; p,m为1,2或3; X'是氧,硫,氨基,烷基氨基,苯基氨基或亚甲基; Z是烷基或苯基; R 3是H,烷基,烯基,炔基,环烷基,其中这些基团中的碳原子可以被取代; R 4是H或烷基,烷氧基羰基,烷基氨基羰基或二烷基氨基羰基,其中这些基团中的碳原子可以被取代; A为C-R 5或N; B是C-R 6或N; W是C-R 7或N; 条件是A,B和W之一不是N; R 5,R 6,R 7是H,卤素,硝基,氰基,氨基,巯基,羟基,烷基,烯基,炔基,环烷基,烷氧基,烷基氨基,二烷基氨基,烷硫基,烷基磺酰基或烷基亚磺酰基, 其中这些基团中的碳原子可以被取代,可以含有1至4个选自氧,硫和氮并且可以被取代的杂原子的5至6元芳族环系统; Y是氢,卤素,氰基,硝基,氨基,羟基,巯基,烷基,烯基,炔基,环烷基,烷氧基,烷基氨基,二烷基氨基,烷硫基,烷基磺酰基或烷基亚磺酰基,其中这些基团中的碳原子可以被取代; n为0,1或2; 用于对抗动物体内及其上的寄生虫。
    • 10. 发明申请
    • PYRAZOLE COMPOUNDS FOR CONTROLLING INVERTEBRATE PESTS
    • 用于控制反相胶束的吡咯化合物
    • WO2010034738A3
    • 2010-10-07
    • PCT/EP2009062318
    • 2009-09-23
    • BASF SEGROS STEFFENKOERBER KARSTENDEYN WOLFGANG VONKAISER FLORIANLE VEZOUET RONANSOERGEL SEBASTIANPOHLMAN MATTHIASDESHMUKH PRASHANTDICKHAUT JOACHIMANSPAUGH DOUGLAS DCULBERTSON DEBORAH LOLOUMI-SADEGHI HASSAN
    • GROS STEFFENKOERBER KARSTENVON DEYN WOLFGANGKAISER FLORIANLE VEZOUET RONANSOERGEL SEBASTIANPOHLMAN MATTHIASDESHMUKH PRASHANTDICKHAUT JOACHIMANSPAUGH DOUGLAS DCULBERTSON DEBORAH LOLOUMI-SADEGHI HASSAN
    • A01N43/90A01P5/00A01P7/02A01P7/04
    • A01N43/90C07D471/04C07D487/04C07D498/04
    • The present invention relates to a method for controlling invertebrate pests which method comprises treating the pests, their food supply, their habitat or their breeding ground or a plant, seed, soil, area, material or environment in which the pests are growing or may grow, or the materials, plants, seeds, soils, surfaces or spaces to be protected from pest attack or infestation with a pesticidally effective amount of a pyrazole compound of formulae I or II or a salt or an N-oxide thereof, wherein A is a pyrazole radical of the formulae A1 or A2, wherein # denotes the binding; D is a 5- or 6-membered heterocyclic radical fused to the pyrazole moiety; Rp1, Rp2 and Rpx are H, halogen, CN, NO2, C1-C10-alkyl, C2-C10- alkenyl, C2-C10-alkynyl, etc.; n is 0 to 4; or two radicals Rpx bound to the same ring- member may form an oxo substituent, or two radicals Rpx bound to adjacent ring- members may form a 3- to 7-membered fused cyclic radical; B is N or CR4, wherein R4 is H, halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, etc.; X1 is S, O or NR1a, wherein R1a is H, C1-C10-alkyl, etc.; X2 is O2a, NR2bR2c or S(O)mR2d, wherein m is 0, 1 or 2; R2a is C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, etc.; R2b, R2c are H, C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, etc.; R2d is C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, etc.; R1 is H, CN, C1-C10-alkyl, C1-C10-haloalkyl, C3-C10-cycloalkyl, etc.; R2, R3 and R5 are H, halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, etc.; to a method for protecting plant propagation material and/or the plants which grow therefrom, to plant propagation material comprising at least one compound of formulae I or II, to a method for treating or protecting an animal from infestation or infection by parasites, to novel pyrazole compounds of formulae I or Il and agricultural composition containing those compounds.
    • 本发明涉及一种控制无脊椎害虫的方法,该方法包括处理害虫,其食物供应,栖息地或其繁殖地,或害虫生长或可能生长的植物,种子,土壤,面积,物质或环境 ,或用农药有效量的式I或II的吡唑化合物或其盐或N-氧化物防止害虫侵袭或侵染的材料,植物,种子,土壤,表面或空间,其中A为 式A1或A2的吡唑基,其中#表示结合; D是与吡唑部分稠合的5或6元杂环基; Rp1,Rp2和Rpx是H,卤素,CN,NO2,C1-C10-烷基,C2-C10-烯基,C2-C10-炔基等; n为0〜4; 或者与相同环成员结合的两个基团R px可以形成氧代取代基,或者与相邻环 - 成员键合的两个基团R px可以形成3-至7-元稠合的环状基团; B是N或CR 4,其中R 4是H,卤素,CN,NO 2,C 1 -C 4烷基,C 1 -C 4卤代烷基,C 1 -C 4 - 烷氧基等; X1是S,O或NR1a,其中R1a是H,C1-C10-烷基等; X 2是O 2 a,NR 2 b R 2c或S(O)m R 2d,其中m是0,1或2; R 2a是C 1 -C 4烷基,C 1 -C 4卤代烷基,C 3 -C 6环烷基等; R2b,R2c为H,C1-C4-烷基,C1-C4卤代烷基,C3-C6-环烷基等; R2d是C1-C4-烷基,C1-C4卤代烷基,C3-C6-环烷基等; R1是H,CN,C1-C10-烷基,C1-C10-卤代烷基,C3-C10-环烷基等; R2,R3和R5是H,卤素,CN,NO2,C1-C4-烷基,C1-C4-卤代烷基,C1-C4-烷氧基等; 涉及一种用于保护植物繁殖材料和/或从其生长的植物的方法,将包含至少一种式I或II化合物的植物繁殖材料用于治疗或保护动物免受寄生虫感染或感染的方法,用于新颖的 式I或II的吡唑化合物和含有这些化合物的农业组合物。