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    • 4. 发明申请
    • METHOD FOR THE CONTINUOUS PRODUCTION OF ALDEHYDES
    • 连续生产醛的方法
    • WO2005042458A3
    • 2005-06-09
    • PCT/EP2004011530
    • 2004-10-14
    • BASF AGVOLLAND MARTINMACKEWITZ THOMASAHLERS WOLFGANGSCHAEFER ANSGARRICHTER WOLFGANGPACIELLO ROCCO
    • VOLLAND MARTINMACKEWITZ THOMASAHLERS WOLFGANGSCHAEFER ANSGARRICHTER WOLFGANGPACIELLO ROCCO
    • B01J31/18B01J31/24C07C45/50C07C47/02
    • B01J31/186B01J2231/321B01J2531/822C07C45/50C07C47/02
    • The invention relates to a method for the continuous production of aldehydes comprising between 5 and 21 carbon atoms, by the isomerising hydroformylation in a homogenous phase of olefin compositions comprising between 4 and 20 carbon atoms and containing alpha-olefins and olefins with internal double bonds, by means of a synthesis gas, in the presence of a homogeneous rhodium catalyst that is complexed with an organophosphorus ligand containing oxygen atoms and/or nitrogen atoms and a free ligand. Said production is carried out at high temperature and high pressure in a multi-stage reaction system consisting of at least two reaction zones. According to said method, the olefin composition is first reacted in a first reaction zone or a group of several first reaction zones at a total pressure of between 10 and 40 bar, using a synthesis gas with a CO/H2 molar ratio of between 4:1 and 1:2 until a 40 to 95 % conversion of the alpha-olefins is obtained. The hydroformylation product from the first reaction zone or group of several first reaction zones is then reacted in a subsequent reaction zone or group of several reaction zones at a total pressure of between 5 and 30 bar, using a synthesis gas with a CO/H2 molar ratio of between 1:4 and 1:1000. The total pressure in the subsequent reaction zone or zones is respectively 1 to (G1-Gf) bar lower than that of the preceding reaction zone, whereby G1 represents the total pressure in the respective preceding reaction zone and Gf represents the total pressure in the respective reaction zone that succeeds said first reaction zone or zones, with the proviso that the difference between G1 and Gf is greater than 1 bar and the partial CO pressure in the subsequent reaction zone or zones is respectively lower than that of the preceding reaction zone.
    • 用于连续制备含有内部双键具有4至20个碳原子的烯烃组合物由合成气的装置在含具有一个氧和/或氮原子的有机磷配体的存在下,通过在α-烯烃的均相异构化的加氢甲酰化的5至21个碳原子的醛和烯烃的配位过程 均相铑催化剂,并在升高的温度和在包括至少两个反应区的多阶段反应系统中升高的压力游离配位体,其中一个最初的烯烃的一组中的一个或多个第一反应区中在10至40巴的总压力与合成气 的CO / H2摩尔比为4:1至1:2的一组的一个或多个在反应至40的α-烯烃的转化率,以95%和加氢甲酰化混合物从该组下方的一个或多个第一反应区 反应1000,其中在一个或多个随后的反应区中的总压力通过1巴下,以(G1 GF):在5〜30巴以1:1的CO / H 2摩尔比的总压力与合成气连接的反应区:4至1 比在各自的前一反应区中,其中G 1表示用于在一个或多个第一反应区的每个后续反应区中的总压各自的前一反应区和GF的总压力,条件是不同的是G1 GF大于1巴的条件, 并且其中所述一个或多个后续反应区中的CO分压在每种情况下低于在前面的反应区中的CO分压。
    • 6. 发明申请
    • METHOD FOR PRODUCING ALDEHYDES
    • 用于生产醛
    • WO0185662A2
    • 2001-11-15
    • PCT/EP0105406
    • 2001-05-11
    • BASF AGAHLERS WOLFGANGSLANY MICHAEL
    • AHLERS WOLFGANGSLANY MICHAEL
    • C07C45/50C07C67/347C07C253/30
    • C07C45/50C07C47/02
    • According to the inventive method for producing aldehydes, at least one compound with a vinyl or vinylidene group is reacted with carbon monoxide and hydrogen in the presence of a source of a metal of subgroup VIII and a bidentate diphosphine ligand, said bidentate diphosphine ligand being of general formula (I), wherein (A), together with the phosphorus atom to which it is bonded, forms a 2-phospha-tricyclo [3.3.1.1.{3,7}] decyl radical, respectively, in which one or more non-adjacent carbon atoms are optionally replaced by oxygen atoms and which is optionally substituted, and wherein X represents a bridging chain with 1 to 10 atoms and the molar ratio of diphosphine-ligand to metal is at least 5. The method produces predominantly n-aldehydes.
    • 描述了一种制备醛类,该方法包括在VIII。子组的金属,并与一氧化碳和氢气的双齿二膦配位体源的存在下具有乙烯基或亚乙烯基团的至少一种化合物反应,其中所述二膦配体具有以下通式的处理 式(I),其中(a)癸基团与磷原子一起它被结合,在每种情况下一个2-磷杂 - 三环[3.3.1.1。3,7 {}],其中任选地一个或多个非相邻的碳原子 通过氧原子被取代且任选被取代,且x是具有1至10个原子的桥连链,和二膦配体与金属的至少的摩尔比5 该方法提供主要正醛。