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1. 发明申请

WO2012084787A1 PROCESS FOR THE PREPARATION OF ETHYLENE COPOLYMERS IN THE PRESENCE OF FREE-RADICAL POLYMERIZATION INITIATOR BY COPOLYMERIZING ETHYLENE, A BI- OR MULTIFUNCTIONAL COMONOMER AND OPTIONALLY FURTHER COMONOMERS 审中-公开
标题翻译：通过共聚乙烯，一个或多个功能性的共同体和另外的共同体，在自由基聚合引发剂存在下制备乙烯共聚物的方法
公开(公告)号：WO2012084787A1
公开(公告)日：2012-06-28
申请号：PCT/EP2011/073196
申请日：2011-12-19
申请人： BASELL POLYOLEFINE GMBH , LITTMANN, Dieter , LILGE, Dieter , GALL, Barbara , VITTORIAS, Iakovos , MANNEBACH, Gerd , BUSCH, Markus , HERRMANN, Thomas
发明人： LITTMANN, Dieter , LILGE, Dieter , GALL, Barbara , VITTORIAS, Iakovos , MANNEBACH, Gerd , BUSCH, Markus , HERRMANN, Thomas
IPC分类号： C08F210/02 , C08F2/38
CPC分类号： C08F210/02 , C08F2/38 , C08F2/00 , C08F220/28
摘要： Process for preparing ethylene copolymers in the presence of free-radical polymerization initiator at pressures in the range of from 160 MPa to 350 MPa and temperatures in the range of from 100°C to 350°C in a tubular reactor by copolymerizing ethylene, a bi- or multifunctional comonomer and optionally further comonomers, wherein the bi- or multifunctional comonomer bears at least two different functional groups, of which at least one is a unsaturated group, which can be incorporated into the growing polymer chain, and at least another functional group can act as chain transfer agent in radical ethylene polymerization, ethylene copolymers obtainable by such a process, the use of the ethylene copolymers for extrusion coating and a process for extrusion coating a substrate selected from the group consisting of paper, paperboard, polymeric film, and metal, with such ethylene copolymers.
摘要翻译：在自由基聚合引发剂存在下，在160MPa至350MPa的压力范围内制备乙烯共聚物和在管式反应器中通过乙烯共聚合得到的温度在100℃至350℃范围内的方法， - 或多官能共聚单体和任选的其它共聚单体，其中双或多官能共聚单体具有至少两个不同的官能团，其中至少一个是不饱和基团，其可以并入生长的聚合物链中，并且至少另一个官能团可以作为自由基乙烯聚合中的链转移剂，可通过这种方法获得的乙烯共聚物，使用乙烯共聚物进行挤出涂布，以及用于挤出涂布选自纸，纸板，聚合物膜和金属，与这种乙烯共聚物。

2. 发明申请

WO2010081685A1 METHOD FOR ETHYLENE POLYMERIZATION IN A TUBULAR REACTOR WITH REDUCED OUTPUT 审中-公开
标题翻译：在具有减少输出的管状反应器中乙烯聚合的方法
公开(公告)号：WO2010081685A1
公开(公告)日：2010-07-22
申请号：PCT/EP2010/000142
申请日：2010-01-14
申请人： BASELL POLYOLEFINE GMBH , LITTMANN, Dieter , FINETTE, Andre-Armand , MEINKE, Hans, Joachim
发明人： LITTMANN, Dieter , FINETTE, Andre-Armand , MEINKE, Hans, Joachim
IPC分类号： C08F10/02
CPC分类号： B01J19/2415 , B01J4/008 , C08F10/02 , C08F2/38 , C08F4/38 , C08F2/00
摘要： Process for the preparation of ethylene homopolymers or copolymers in the presence of free-radical polymerization initiators at from 100°C to 350°C and pressures in the range of from 160 MPa to 350 MPa in a tubular reactor with at least two spatially separated initiator injection points, wherein injecting initiator rises the temperature of the reaction mixture in the reaction zone following the injection point, and the first initiator injection point of the tubular reactor is not provided with initiator or is provided with so little initiator that the temperature of the reaction mixture does not rise more than 20°C in the first reaction zone and method for reducing the output of a high pressure tubular reactor for the homo- or copolymerization of ethylene in the presence of free-radical polymerization initiators with at least two initiator injection points, wherein feeding of free-radical polymerization initiator to the first initiator injection point is discontinued or reduced to a level that the temperature of the reaction mixture in the first reaction zone does not rise more than 20°C.
摘要翻译：在具有至少两个空间分离的引发剂的管式反应器中，在100℃至350℃的自由基聚合引发剂存在下制备乙烯均聚物或共聚物的方法，并且在160MPa至350MPa范围内的压力注射点，其中注射引发剂在注射点之后升高反应区域中的反应混合物的温度，并且管式反应器的第一引发剂注入点不具有引发剂，或者设置有少量引发剂，使得反应温度混合物在第一反应区域中不会升高超过20℃，并且在自由基聚合引发剂与至少两个引发剂注入点存在下，降低高压管式反应器的输出以均衡或共聚乙烯的方法其中将自由基聚合引发剂进料至第一引发剂注入点停止或还原成a 使得第一反应区中的反应混合物的温度不升高超过20℃。

3. 发明申请

WO2010081684A1 ETHYLENE POLYMERIZATION IN A HIGH PRESSURE REACTOR WITH IMPROVED INITIATOR FEEDING 审中-公开
标题翻译：高压反应器乙烯聚合与改进的发动机进料
公开(公告)号：WO2010081684A1
公开(公告)日：2010-07-22
申请号：PCT/EP2010/000141
申请日：2010-01-14
申请人： BASELL POLYOLEFINE GMBH , LITTMANN, Dieter , FINETTE, Andre-Armand , MOHRBUTTER, Jürgen, Peter , WOLFRAM, Sven, Georg
发明人： LITTMANN, Dieter , FINETTE, Andre-Armand , MOHRBUTTER, Jürgen, Peter , WOLFRAM, Sven, Georg
IPC分类号： B01J19/24 , C08F10/00
CPC分类号： B01J19/2415 , B01J4/008 , B01J4/02 , B01J2219/00164 , B01J2219/00182 , B01J2219/00772 , C08F10/02 , C08F110/02 , C08F210/16 , Y10S526/919 , C08F2/00 , C08F2/001 , C08F2/01 , C08F4/38
摘要： Process for the preparation of ethylene homopolymers or copolymers in a high pressure reactor with at least two spatially separated initiator injection points by polymerizing ethylene and optionally further monomers in the presence of at least two different mixtures of free-radical polymerization initiators at from 100°C to 350°C and pressures in the range of from 160 MPa to 350 MPa, wherein the process comprises the following steps: a) providing at least two different initiators as solution in a suitable solvent or in liquid state, b) mixing the initiators and optionally additional solvent in at least two static mixers and c) feeding each of the mixtures to a different initiator injection point of the high pressure reactor, and apparatus for feeding initiator mixtures to a high pressure reactor with at least two spatially separated initiator injection points.
摘要翻译：在具有至少两个空间分离的引发剂注入点的高压反应器中制备乙烯均聚物或共聚物的方法，其通过在100℃下在至少两种不同的自由基聚合引发剂混合物的存在下聚合乙烯和任选的其它单体其中所述方法包括以下步骤：a）提供至少两种不同的引发剂作为溶液在合适的溶剂中或以液体状态，b）将引发剂和任选地在至少两个静态混合器中添加另外的溶剂，和c）将每种混合物进料到高压反应器的不同的引发剂注入点，以及用于将引发剂混合物供入具有至少两个空间分离的引发剂注入点的高压反应器的装置。

4. 发明申请

WO2017194491A1 HIGH-PRESSURE POLYMERIZATION PROCESS OF ETHYLENICALLY UNSATURATED MONOMERS 审中-公开
标题翻译：乙烯基不饱和单体的高压聚合工艺
公开(公告)号：WO2017194491A1
公开(公告)日：2017-11-16
申请号：PCT/EP2017/060972
申请日：2017-05-09
申请人： BASELL POLYOLEFINE GMBH
发明人： GONIOUKH, Andrei , HERRMANN, Thomas , LITTMANN, Dieter , FINETTE, Andre-Armand , WOLFRAM, Sven
IPC分类号： C08F2/01 , C08F2/34
摘要： A process for polymerizing or copolymerizing ethylenically unsaturated monomers at pressures in the range of from 110 MPa to 500 MPa in a production line comprising a continuously operated polymerization reactor, wherein the process comprises monitoring the surroundings of the production line with respect to an occurrence of a leakage of monomers or of reaction mixture by an IR point detector arrangement of at least three groups of IR point detectors which are capable of detecting hydrocarbons and the groups of IR point detectors are operating according to a voting logic and starting automatically an emergency pressure release program when a group of IR point detectors of the IR point detector arrangement detects the presence of hydrocarbons.
摘要翻译：在包含连续操作的聚合反应器的生产线中，在110MPa至500MPa的压力下聚合或共聚烯属不饱和单体的方法，其中所述方法包括监测生产的环境关于由至少三组能够检测碳氢化合物的IR点检测器的IR点检测器装置发生单体或反应混合物的泄漏，并且IR点检测器组根据投票逻辑进行操作并且当IR点检测器装置的一组IR点检测器检测到存在碳氢化合物时，自动启动紧急压力释放程序。

5. 发明申请

WO2017085097A1 POLYMERIZATION PROCESS WITH A PARTIAL SHUTDOWN PHASE 审中-公开
标题翻译：具有部分关闭相的聚合过程
公开(公告)号：WO2017085097A1
公开(公告)日：2017-05-26
申请号：PCT/EP2016/077813
申请日：2016-11-16
申请人： BASELL POLYOLEFINE GMBH
发明人： NEUMANN, Erich , WOLFRAM, Sven , WOLF, Christoph , MOHRBUTTER, Juergen , LITTMANN, Dieter
IPC分类号： C08F2/01 , B01J19/00
CPC分类号： C08F2/01 , B01J19/00
摘要： A process for polymerizing ethylene to obtain an ethylene-based polymer in a plant, wherein the plant includes a reactor in fluid communication with a recycle connection, wherein the process comprises a polymerization phase, a partial shutdown phase, and the steps of reducing the pressure in the reactor for entering from the polymerization phase into the partial shutdown phase; and increasing the pressure in the reactor for exiting from the partial shutdown phase and re-entering the polymerization phase.
摘要翻译：一种在设备中聚合乙烯以获得基于乙烯的聚合物的方法，其中所述设备包括与再循环连接流体连通的反应器，其中所述方法包括聚合阶段，部分关闭阶段以及降低反应器中用于从聚合阶段进入部分停堆阶段的压力的步骤; 并增加反应器中的压力以退出部分关闭阶段并重新进入聚合阶段。

6. 发明申请

WO2019002100A1 PELLET DRYING AND DEGASSING METHOD 审中-公开
公开(公告)号：WO2019002100A1
公开(公告)日：2019-01-03
申请号：PCT/EP2018/066666
申请日：2018-06-21
申请人： BASELL POLYOLEFINE GMBH
发明人： MEI, Giulia , MOHRBUTTER, Juergen , LITTMANN, Dieter , WOLF, Christoph , FINETTE, Andre-Armand , DEUERLING, Michael , PENZO, Giuseppe
IPC分类号： B29B9/16 , F26B17/22 , F26B17/14 , F26B3/16 , B29B9/06 , B29K105/00 , B29B13/06 , F26B17/00 , B29K23/00
摘要： Method for the preparation of dried polymer pellets in a facility having a dryer with a first chamber and a mechanical agitator, and the facility further having a degassing silo with a second chamber, the method comprises guiding a drying gas flow comprising a first gas mixture for drying wet polymer pellets into the first chamber, transferring the dried polymer pellets into the second chamber, guiding a second gas mixture for degassing the dried polymer pellets into the second chamber thereby transforming the second gas mixture into a third gas mixture and guiding a portion of the third gas mixture into the first chamber; and process for manufacturing LDPE pellets using the aforementioned method.

7. 发明申请

WO2016202766A1 POLYMERIZATION PLANT HAVING PARALLEL COOLING CHANNELS IN A RECYCLE CONNECTION 审中-公开
标题翻译：在循环连接中具有平行冷却通道的聚合工厂
公开(公告)号：WO2016202766A1
公开(公告)日：2016-12-22
申请号：PCT/EP2016/063562
申请日：2016-06-14
申请人： BASELL POLYOLEFINE GMBH
发明人： WOLF, Christoph , FINETTE, Andre-Armand , GONIOUKH, Andrei , LITTMANN, Dieter , HERRMANN, Thomas , GROOS, Georg
IPC分类号： C08F2/04 , B01J19/18 , B01J19/24
CPC分类号： C08F110/02 , B01J19/2415 , B01J19/2465 , B01J2219/00081 , B01J2219/00092 , B01J2219/24 , C08F2/04 , Y02P20/582
摘要： A plant for polymerization, preferably of ethylene, having a recycle connection with two or more cooling channels arranged in parallel, a process for polymerization and downstream processes, and a plant for polymerization, comprising the following plant components in fluid communication: a) A reactor with an inlet side and an outlet side; b) A recycle connection positioned in fluid communication between the outlet side of the reactor and the inlet side of the reactor; wherein the recycle connection comprises two or more cooling channels arranged in parallel.
摘要翻译：具有与两个或多个平行布置的冷却通道的再循环连接的聚合装置，聚合和下游方法的聚合工艺以及用于聚合的设备，其包含流体连通的以下工厂组件：a）反应器具有入口侧和出口侧; b）在反应器的出口侧和反应器的入口侧之间流体连通地设置的再循环连接件; 其中所述循环连接包括并联布置的两个或多个冷却通道。

8. 发明申请

WO2015082565A1 PROCESS FOR SEPARATING COMPONENTS OF A REACTION MIXTURE OBTAINED BY HIGH-PRESSURE POLYMERIZATION OF ETHYLENICALLY UNSATURATED MONOMERS 审中-公开
标题翻译：用于分离由乙烯基不饱和单体的高压聚合获得的反应混合物组分的方法
公开(公告)号：WO2015082565A1
公开(公告)日：2015-06-11
申请号：PCT/EP2014/076460
申请日：2014-12-03
申请人： BASELL POLYOLEFINE GMBH
发明人： GROOS, Georg , NEUMANN, Erich , DEUERLING, Michael , LITTMANN, Dieter
IPC分类号： C08F6/10 , C08F6/12 , C08J11/02 , C08F10/00 , C08F6/00
CPC分类号： C08F6/12 , C08F2/01 , C08F2/02 , C08F2/34 , C08F6/001 , C08F6/10 , C08J11/02 , Y02P20/582 , C08L23/04 , C08F10/02 , C08F2/00 , C08F110/02 , C08F210/16 , C08F2500/08
摘要： Process for separating polymeric and gaseous components of a reaction mixture obtained by high-pressure polymerization of ethylenically unsaturated monomers in the presence of free-radical polymerization initiators, the process comprising the steps of entering the reaction mixture into a separation vessel; separating the reaction mixture into in a gaseous fraction and a liquid fraction; and withdrawing the gaseous fraction from the top of the separation vessel and withdrawing the liquid fraction from the bottom of the separation vessel, wherein the separation is carried out at a pressure of from 15 MPa to 50 MPa and a temperature of from 120°C to 300°C; the separation vessel has a vertically arranged cylindrical shape with a ratio of length to diameter L/D of from 4 to 10 and is equipped with an inlet pipe for introducing the reaction mixture into the separation vessel; the inlet pipe extends vertically from the top into the separation vessel; and the ratio of the inner diameter of the inlet pipe at its lower end and the inner diameter of the separating vessel in its cylindrical part is in the range of from 0.2 to 0.4 and process for preparing ethylene homopolymers or copolymers from ethylenically unsaturated monomers in the presence of free-radical polymerization initiators at temperatures from 100°C to 350°C and pressures in the range of from 110 MPa to 500 MPa in a polymerization reactor comprising a such process for separating polymeric and gaseous components.
摘要翻译：在自由基聚合引发剂存在下，通过烯属不饱和单体的高压聚合获得的反应混合物的聚合物和气态组分的分离方法，该方法包括以下步骤：将反应混合物进入分离容器; 将反应混合物分离成气态馏分和液体馏分; 并从分离容器的顶部取出气体馏分并从分离容器的底部排出液体部分，其中分离在15MPa至50MPa的压力和120℃至120℃的温度下进行 300℃; 分离容器具有垂直排列的圆柱形，长度与直径L / D之比为4至10，并具有用于将反应混合物引入分离容器的入口管; 入口管从顶部垂直延伸到分离容器中; 并且其下端的入口管的内径与其圆柱形部分中的分离容器的内径的比率在0.2至0.4的范围内以及在烯属不饱和单体中制备乙烯均聚物或共聚物的方法在聚合反应器中存在自由基聚合引发剂，其温度为100℃至350℃，压力范围为110MPa至500MPa，包括用于分离聚合物和气态组分的方法。

9. 发明申请

WO2020127079A1 HIGH-PRESSURE POLYMERIZATION PROCESS OF ETHYLENICALLY UNSATURATED MONOMERS IN A POLYMERIZATION REACTOR 审中-公开
公开(公告)号：WO2020127079A1
公开(公告)日：2020-06-25
申请号：PCT/EP2019/085394
申请日：2019-12-16
申请人： BASELL POLYOLEFINE GMBH
发明人： LITTMANN, Dieter , FINETTE, Andre-Armand , WOLF, Christoph , DEUERLING, Michael , MOHRBUTTER, Juergen , KHAYRULLIN, Danir , MEI, Giulia , NEUMANN, Erich
IPC分类号： C08F2/01 , C08F2/02 , C08F10/02 , B01J19/24 , B01J8/00
摘要： A process for polymerizing ethylene in a high-pressure polymerization system comprising a continuously operated polymerization reactor and a reactor blow down system comprising an emergency valve, a reactor blow down vessel containing an aqueous medium and a reactor blow down dump vessel, wherein the process comprises monitoring the polymerization system with respect to an occurrence of a disturbance, opening the emergency valve in case of a disturbance to allow the content of the polymerization system to expand into the reactor blow down vessel, contacting content in the reactor blow down vessel with the aqueous medium to obtain an aqueous polymer slurry, separating the polymer slurry and gaseous components and transferring the polymer slurry to the reactor blow down dump vessel.

10. 发明申请

WO2017194494A1 HIGH-PRESSURE POLYMERIZATION PROCESS OF ETHYLENICALLY UNSATURATED MONOMERS IN A PRODUCTION LINE HAVING FLANGES COVERED BY A CHIMNEY CONSTRUCTION 审中-公开
标题翻译：烟囱结构覆盖法兰生产线中乙烯基不饱和单体的高压聚合工艺
公开(公告)号：WO2017194494A1
公开(公告)日：2017-11-16
申请号：PCT/EP2017/060977
申请日：2017-05-09
申请人： BASELL POLYOLEFINE GMBH
发明人： GONIOUKH, Andrei , HERRMANN, Thomas , LITTMANN, Dieter , FINETTE, Andre-Armand , WOLFRAM, Sven
IPC分类号： C08F2/01 , C08F2/34
摘要： A process for polymerizing or copolymerizing ethylenically unsaturated monomers at pressures in the range of from 110 MPa to 500 MPa in a production line comprising a continuously operated polymerization reactor, wherein at least one of a pre-heater or pre-cooler, a polymerization reactor or a post reactor cooler is composed of tubes of a length from 5 m to 25 m which are flanged together, either directly or via bends, and the flanges are covered by a chimney construction, and wherein air is conveyed through the chimney construction and the air exiting the chimney construction is monitored with respect to the hydrocarbon concentration.
摘要翻译：在包含连续操作的聚合反应器的生产线中，在110MPa至500MPa的压力下聚合或共聚烯属不饱和单体的方法，其中预热器或预热器中的至少一个预冷却器，聚合反应器或后反应器冷却器由长度为5m至25m的管组成，所述管直接或通过弯曲法兰连接在一起，并且法兰由烟囱结构覆盖，并且其中空气通过烟囱结构传送，并且关于碳氢化合物浓度监测排出烟囱结构的空气。

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