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1. 发明申请

WO0248214A3 DEVICE FOR FEEDING REACTOR INITIATORS 审中-公开
标题翻译： DEVICE喂养发起者REACTORS
公开(公告)号：WO0248214A3
公开(公告)日：2002-09-19
申请号：PCT/EP0113788
申请日：2001-11-27
申请人： BASELL POLYOLEFINE GMBH , GROOS GEORG , MAEHLING FRANK-OLAF , DAISS ANDREAS , LITTMANN DIETER , EVERTZ KASPAR
发明人： GROOS GEORG , MAEHLING FRANK-OLAF , DAISS ANDREAS , LITTMANN DIETER , EVERTZ KASPAR
IPC分类号： B01F5/00 , B01F5/04 , B01F5/06 , B01F13/10 , B01J3/04 , B01J19/24 , B01J19/26 , C08F2/00 , C08F2/01 , C08F10/00 , C08F10/02 , B01J8/06
CPC分类号： C08F10/02 , B01F5/0473 , B01F5/0656 , B01F2005/0017 , B01F2013/1091 , B01F2215/0049 , B01J3/042 , B01J19/2415 , B01J19/26 , B01J2208/00646 , B01J2208/00716 , B01J2208/00946 , B01J2219/00094 , B01J2219/00121 , B01J2219/00164 , B01J2219/00772 , C08F2/01 , C08F2/00
摘要： The invention relates to a method for producing polyethylene in tubular reactors with or without autoclaves, whereby a liquid medium current containing ethylene and comonomers is supplied to a radical chain initiator with or without cold ethylene. Torsion is produced between two currents (61, 62) to be mixed at an angle (66), or a torsion element (20, 80) is provided in the cross-section of the current (27, 28). A contraction of the cross-section (63, 67, 71) is formed in the region of a feeding point (72, 81) for a radical chain initiator, at which point the radical chain initiator is supplied in the current having torsion (61, 62, 70), through an eccentric, optimised outlet (44) of a feeding finger (40).
摘要翻译：本发明涉及一种用于制备在管式反应器的聚乙烯具有或不具有高压釜中，在其中含移动流动介质乙烯，补加的共聚单体，自由基引发剂，有或没有冷乙烯。它接线两者之间的扭转以一角度（66）是混合流（61，62）中产生，或通过在流动横截面（27,28）提供一个Dralelementes（20，80）。在用于自由基引发剂的进料点（72，81）的区域是一个截面收缩（63，67，71）形成，其中通过Einspeisefinger的优化出口开口（44）（40）到所述回旋流（61偏心地设置在所述自由基引发剂， 62，70）被启动。

2. 发明申请

WO1995009877A1 ETHYLENE-BASED COPOLYMERS AND THEIR USE AS VISCOSITY IMPROVERS IN PETROLEUM DISTILLATES 审中-公开
标题翻译： BASIS乙烯的共聚物及它们在油作为流中间馏分
公开(公告)号：WO1995009877A1
公开(公告)日：1995-04-13
申请号：PCT/EP1994003179
申请日：1994-09-23
申请人： BASF AKTIENGESELLSCHAFT , MÜLLER, Hans-Joachim , WENDEROTH, Bernd , BERGER, Albin , LITTMANN, Dieter , KLIMESCH, Roger , OPPENLÄNDER, Knut , MARCZINKE, Bernd, Lothar , RÜHL, Thomas , HEIDER, Marc
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08F210/02
CPC分类号： C10L1/2366 , C08F210/02 , C10L1/2368 , C08F218/04 , C08F220/34 , C08F226/06 , C08F220/00
摘要： Ethylene-based copolymers suitable as viscosity improvers for petroleum distillates of a) 50 to 94 wt. % ethylene; b) 3 to 30 wt. % one or more vinyl esters of C2-C6 monocarboxylic acids; c) 3 to 20 wt. % one or more aminoalkylene acrylates of general formula (I) in which R is hydrogen or methyl, the radicals R and R may be the same or different and stand for hydrogen or a C1-C6 alkyl radical and A is a straight-chained or branched C2-C10 alkylene radical; and d) 0 to 10 wt. % one or more monomers which can be copolymerised with monomers a) to c), in which such copolymers are excluded in which monomer b) is vinyl acetate and have a number average molecular weight of 5000 to 50000; or of a') 50 to 95.5 wt. % ethylene; b') 4 to 30 wt. % one or more vinyl esters of C2-C6 monocarboxylic acids; c') 0.5 to 20 wt. % one or more vinyl imidazoles of general formula (II) in which the radicals R , R and R may be the same or different and are hydrogen or a C1-C6 alkyl radical, or 0.5 to 20 wt. % one or more aminoalkyl vinyl ethers of general formula (III) in which the substituents are: R , R : C1-C6 alkyl; R , R , R : hydrogen or C1-C6 alkyl; A : C2-C6 alkylene; and d') 0 to 10 wt. % one or more monomers which can be copolymerised with monomers a') to c'). The invention also relates to the use of these copolymers as viscosity improvers for petroleum middle distillates and to pretroleum distillates containing them.
摘要翻译：作为基于的乙烯为矿物油中间馏分合适的共聚物流动改进剂）50至94重量％乙烯的，B）3至30重量的C2的一种或多种乙烯基酯％至C6单羧酸，C）3至20重量的％或多个氨基的通式（I）的丙烯酸酯，<1>，其中R是氢或甲基，R <3>可以相同或不同的<2>和R，代表氢或C1-C6烷基基团和一个<1>表示直链或支链的C2-C10亚烷基残基，和d）0至10重量其是共聚的，其中这样的共聚物中排除单体a）至c）一种或多种单体的％，在其中b是单体）和乙酸乙烯酯具有的平均分子量（数均）为5,000至50,000，或A“）为50〜95.5重量乙烯，b的％”）的4至30重量％的一种的％或更多的乙烯基酯从C2-C6单羧酸，C“）0.5至20重量的一般的一个或多个乙烯基咪唑的％ n式（II），其中基团R <4>，R <5>和R <6>可以相同或不同，是氢或C1-C6烷基，或0.5至20重量 [R <7> - [R <8> NA <2> -O-CR <9> = CR <10> - [R <11>，其中取代基具有以下含义：R的通式（III）的一种或多种氨基烷基乙烯基醚％ <7> - [R <8>，C1-C6烷基; [R <9>，R <10>，R <11>为氢或C1-C6烷基; A <2> C2-C6亚烷基，和d）0至10重量％的一种或多种单体的％可与单体a“共聚）至c”）共聚的，使用这些共聚物作为流动性改进剂为矿物油中间馏分和石油馏出物的含有这些共聚物。

3. 发明申请

WO2010081685A1 METHOD FOR ETHYLENE POLYMERIZATION IN A TUBULAR REACTOR WITH REDUCED OUTPUT 审中-公开
标题翻译：在具有减少输出的管状反应器中乙烯聚合的方法
公开(公告)号：WO2010081685A1
公开(公告)日：2010-07-22
申请号：PCT/EP2010/000142
申请日：2010-01-14
申请人： BASELL POLYOLEFINE GMBH , LITTMANN, Dieter , FINETTE, Andre-Armand , MEINKE, Hans, Joachim
发明人： LITTMANN, Dieter , FINETTE, Andre-Armand , MEINKE, Hans, Joachim
IPC分类号： C08F10/02
CPC分类号： B01J19/2415 , B01J4/008 , C08F10/02 , C08F2/38 , C08F4/38 , C08F2/00
摘要： Process for the preparation of ethylene homopolymers or copolymers in the presence of free-radical polymerization initiators at from 100°C to 350°C and pressures in the range of from 160 MPa to 350 MPa in a tubular reactor with at least two spatially separated initiator injection points, wherein injecting initiator rises the temperature of the reaction mixture in the reaction zone following the injection point, and the first initiator injection point of the tubular reactor is not provided with initiator or is provided with so little initiator that the temperature of the reaction mixture does not rise more than 20°C in the first reaction zone and method for reducing the output of a high pressure tubular reactor for the homo- or copolymerization of ethylene in the presence of free-radical polymerization initiators with at least two initiator injection points, wherein feeding of free-radical polymerization initiator to the first initiator injection point is discontinued or reduced to a level that the temperature of the reaction mixture in the first reaction zone does not rise more than 20°C.
摘要翻译：在具有至少两个空间分离的引发剂的管式反应器中，在100℃至350℃的自由基聚合引发剂存在下制备乙烯均聚物或共聚物的方法，并且在160MPa至350MPa范围内的压力注射点，其中注射引发剂在注射点之后升高反应区域中的反应混合物的温度，并且管式反应器的第一引发剂注入点不具有引发剂，或者设置有少量引发剂，使得反应温度混合物在第一反应区域中不会升高超过20℃，并且在自由基聚合引发剂与至少两个引发剂注入点存在下，降低高压管式反应器的输出以均衡或共聚乙烯的方法其中将自由基聚合引发剂进料至第一引发剂注入点停止或还原成a 使得第一反应区中的反应混合物的温度不升高超过20℃。

4. 发明申请

WO0040775A3 METHOD FOR COATING REACTORS FOR HIGH PRESSURE POLYMERISATION OF 1-OLEFINS 审中-公开
标题翻译：用于涂覆1-烯烃高压聚合反应器的方法
公开(公告)号：WO0040775A3
公开(公告)日：2000-11-09
申请号：PCT/EP9910372
申请日：1999-12-24
申请人： BASF AG , HUEFFER STEPHAN , DECKERS ANDREAS , WEBER WILHELM , KLIMESCH ROGER , LITTMANN DIETER , STURM JUERGEN , LERCH GOETZ
发明人： HUEFFER STEPHAN , DECKERS ANDREAS , WEBER WILHELM , KLIMESCH ROGER , LITTMANN DIETER , STURM JUERGEN , LERCH GOETZ
IPC分类号： C08F2/01 , C08F10/00 , C23C18/16 , C23C18/31 , C23C18/34 , C23C18/36 , C23C18/40 , C23C18/48 , C23C18/50 , C23C18/52 , F28F19/02 , F28F19/06
CPC分类号： F28F19/02 , C23C18/1616 , C23C18/1662 , C23C18/36 , Y10T428/12556 , Y10T428/12944 , Y10T428/31678
摘要： The invention relates to a method for coating a reactor. Said method is characterised in that a metal layer or a metal polymer dispersion layer is deposited on the inner surface of the reactor in a currentless manner by contacting the surfaces to a metal electrolytic solution which contains a reduction means and a halogenated polymer in dispersed form in addition to the metal electrolyte. Said halogenated polymer can optionally be deposited.
摘要翻译：一种通常由表面与金属电解质溶液接触涂覆的反应器，其特征在于，沉积金属层或反应器内部表面上的金属 - 聚合物分散体层方法，其中，除了金属电解质，还原剂和任选地，一个被沉积卤化含有分散形式的聚合物。

5. 发明申请

WO2010081684A1 ETHYLENE POLYMERIZATION IN A HIGH PRESSURE REACTOR WITH IMPROVED INITIATOR FEEDING 审中-公开
标题翻译：高压反应器乙烯聚合与改进的发动机进料
公开(公告)号：WO2010081684A1
公开(公告)日：2010-07-22
申请号：PCT/EP2010/000141
申请日：2010-01-14
申请人： BASELL POLYOLEFINE GMBH , LITTMANN, Dieter , FINETTE, Andre-Armand , MOHRBUTTER, Jürgen, Peter , WOLFRAM, Sven, Georg
发明人： LITTMANN, Dieter , FINETTE, Andre-Armand , MOHRBUTTER, Jürgen, Peter , WOLFRAM, Sven, Georg
IPC分类号： B01J19/24 , C08F10/00
CPC分类号： B01J19/2415 , B01J4/008 , B01J4/02 , B01J2219/00164 , B01J2219/00182 , B01J2219/00772 , C08F10/02 , C08F110/02 , C08F210/16 , Y10S526/919 , C08F2/00 , C08F2/001 , C08F2/01 , C08F4/38
摘要： Process for the preparation of ethylene homopolymers or copolymers in a high pressure reactor with at least two spatially separated initiator injection points by polymerizing ethylene and optionally further monomers in the presence of at least two different mixtures of free-radical polymerization initiators at from 100°C to 350°C and pressures in the range of from 160 MPa to 350 MPa, wherein the process comprises the following steps: a) providing at least two different initiators as solution in a suitable solvent or in liquid state, b) mixing the initiators and optionally additional solvent in at least two static mixers and c) feeding each of the mixtures to a different initiator injection point of the high pressure reactor, and apparatus for feeding initiator mixtures to a high pressure reactor with at least two spatially separated initiator injection points.
摘要翻译：在具有至少两个空间分离的引发剂注入点的高压反应器中制备乙烯均聚物或共聚物的方法，其通过在100℃下在至少两种不同的自由基聚合引发剂混合物的存在下聚合乙烯和任选的其它单体其中所述方法包括以下步骤：a）提供至少两种不同的引发剂作为溶液在合适的溶剂中或以液体状态，b）将引发剂和任选地在至少两个静态混合器中添加另外的溶剂，和c）将每种混合物进料到高压反应器的不同的引发剂注入点，以及用于将引发剂混合物供入具有至少两个空间分离的引发剂注入点的高压反应器的装置。

6. 发明申请

WO0193225A3 METHOD FOR HIGH PRESSURE POLYMERIZATION OF ETHYLENE IN THE PRESENCE OF SUPERCRITICAL WATER 审中-公开
标题翻译：方法高压乙烯超临界水的存在下
公开(公告)号：WO0193225A3
公开(公告)日：2002-04-04
申请号：PCT/EP0105996
申请日：2001-05-25
申请人： BASELL POLYOLEFINE GMBH , HAEFFNER ECKHARD , LITTMANN DIETER , MAEHLING FRANK OLAF , KOEHLER GERNOT
发明人： HAEFFNER ECKHARD , LITTMANN DIETER , MAEHLING FRANK-OLAF , KOEHLER GERNOT
IPC分类号： C08F2/00 , C08F2/06 , C08F10/00 , C08F210/02
CPC分类号： C08F210/02 , Y02P20/544 , C08F2/00 , C08F2/005
摘要： A method for polymerizing ethylene and optionally other monomers in a high-pressure reactor at pressures of 1000 - 4000 bars and temperatures of between 140 and 320 DEG C at temperatures and pressures when the water behaves in a supercritical manner. According to the inventive method, water is introduced into the reactor in a continuous or intermittent manner.
摘要翻译：一种用于乙烯和任选的其它单体的在1000至4000巴，140-320℃下的温度之间的压力的高压反应器中的聚合过程，但在压力和温度条件下的任何情况下，在其下的水显示超临界行为，其中一个连续或间歇地将水引入反应器中。

7. 发明申请

WO0168723A3 METHOD FOR THE PRODUCTION OF POLYETHYLENE 审中-公开
标题翻译：用于生产聚乙烯
公开(公告)号：WO0168723A3
公开(公告)日：2002-02-14
申请号：PCT/EP0102796
申请日：2001-03-13
申请人： BASELL POLYOLEFINE GMBH , GONIOUKH ANDREI , WITTKOWSKI LARS , DROEGE THOMAS , FISCHER ERNST , KLIMESCH ROGER , ROSENDORFER PHILIPP , KOEHLER GERNOT , LITTMANN DIETER
发明人： GONIOUKH ANDREI , WITTKOWSKI LARS , DROEGE THOMAS , FISCHER ERNST , KLIMESCH ROGER , ROSENDORFER PHILIPP , KOEHLER GERNOT , LITTMANN DIETER
IPC分类号： C08F4/38 , C08F10/00 , C08F10/02 , C08F110/02 , C08F2/00 , C08J5/18
CPC分类号： C08F10/02 , C08F110/02 , C08F4/38 , C08F4/36 , C08F2/00 , C08F2500/12 , C08F2500/26
摘要： The invention relates to a method for the production of ethylene homopolymers and copolymers in a tubular reactor at temperatures of from 160 DEG C to 350 DEG C and pressures in the range from 500 to 50000 bar, optionally with the use of molecular mass regulators. The invention is characterised in that a peroxide mixture is used as polymerisation initiator, which contains 1 to 95 mol % of at least one cyclic peroxide of formula (I), based upon the total amount of the peroxide mixture, where the group R is either the same or different and may be chosen from alkyl or aryl groups.
摘要翻译：一种用于生产乙烯均聚物和共聚物中，在160℃下的温度至350℃，压力在500的范围内的管式反应器至5000巴，任选使用摩尔质量调节剂，其特征在于使用的过程是过氧化物混合物作为聚合引发剂时，1 〜95摩尔％，基于过氧化物的混合物，式中的至少一种环状过氧化物（I）的总量，其中所述基团R相同或不同并选自烷基或芳基团的选择。

8. 发明申请

WO1993005082A1 HIGH-PRESSURE PROCESS FOR PRODUCING POLYPROPYLENE 审中-公开
标题翻译：用于生产聚丙烯的高压工艺
公开(公告)号：WO1993005082A1
公开(公告)日：1993-03-18
申请号：PCT/EP1992002017
申请日：1992-09-02
申请人： BASF AKTIENGESELLSCHAFT , LITTMANN, Dieter , EVERTZ, Kaspar , SCHLUND, Rueger , MUEHLENBERND, Thomas , KONRAD, Rainer , KLIMESCH, Roger , KERTH, Juergen , SCHWEIER, Guenther
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08F10/06
CPC分类号： C08F10/06 , C08F110/06 , C08F210/06 , C08F2/06 , C08F2500/02 , C08F210/16
摘要： A process is disclosed for producing homopolymers of propylene or copolymers of propylene with other olefins or their mixtures. Polymerisation is carried out under pressures from 100 to 3000 bars and at temperatures from 100 to 330° C, using as catalyst a metallocene catalyst system.

9. 发明申请

WO2012084787A1 PROCESS FOR THE PREPARATION OF ETHYLENE COPOLYMERS IN THE PRESENCE OF FREE-RADICAL POLYMERIZATION INITIATOR BY COPOLYMERIZING ETHYLENE, A BI- OR MULTIFUNCTIONAL COMONOMER AND OPTIONALLY FURTHER COMONOMERS 审中-公开
标题翻译：通过共聚乙烯，一个或多个功能性的共同体和另外的共同体，在自由基聚合引发剂存在下制备乙烯共聚物的方法
公开(公告)号：WO2012084787A1
公开(公告)日：2012-06-28
申请号：PCT/EP2011/073196
申请日：2011-12-19
申请人： BASELL POLYOLEFINE GMBH , LITTMANN, Dieter , LILGE, Dieter , GALL, Barbara , VITTORIAS, Iakovos , MANNEBACH, Gerd , BUSCH, Markus , HERRMANN, Thomas
发明人： LITTMANN, Dieter , LILGE, Dieter , GALL, Barbara , VITTORIAS, Iakovos , MANNEBACH, Gerd , BUSCH, Markus , HERRMANN, Thomas
IPC分类号： C08F210/02 , C08F2/38
CPC分类号： C08F210/02 , C08F2/38 , C08F2/00 , C08F220/28
摘要： Process for preparing ethylene copolymers in the presence of free-radical polymerization initiator at pressures in the range of from 160 MPa to 350 MPa and temperatures in the range of from 100°C to 350°C in a tubular reactor by copolymerizing ethylene, a bi- or multifunctional comonomer and optionally further comonomers, wherein the bi- or multifunctional comonomer bears at least two different functional groups, of which at least one is a unsaturated group, which can be incorporated into the growing polymer chain, and at least another functional group can act as chain transfer agent in radical ethylene polymerization, ethylene copolymers obtainable by such a process, the use of the ethylene copolymers for extrusion coating and a process for extrusion coating a substrate selected from the group consisting of paper, paperboard, polymeric film, and metal, with such ethylene copolymers.
摘要翻译：在自由基聚合引发剂存在下，在160MPa至350MPa的压力范围内制备乙烯共聚物和在管式反应器中通过乙烯共聚合得到的温度在100℃至350℃范围内的方法， - 或多官能共聚单体和任选的其它共聚单体，其中双或多官能共聚单体具有至少两个不同的官能团，其中至少一个是不饱和基团，其可以并入生长的聚合物链中，并且至少另一个官能团可以作为自由基乙烯聚合中的链转移剂，可通过这种方法获得的乙烯共聚物，使用乙烯共聚物进行挤出涂布，以及用于挤出涂布选自纸，纸板，聚合物膜和金属，与这种乙烯共聚物。

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