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    • 5. 发明申请
    • METHOD AND APPARATUS FOR A HIGH RESOLUTION DOWNHOLE SPECTROMETER
    • 高分辨率卧式光谱仪的方法和装置
    • WO2003102372A1
    • 2003-12-11
    • PCT/US2003/017572
    • 2003-06-04
    • BAKER HUGHES INCORPORATED
    • DIFOGGIO, RoccoWALKOW, ArnoldBERGREN, Paul
    • E21B49/00
    • G01J3/26E21B47/102E21B49/08G01J3/0202G01J3/0262G01J3/06G01J3/433G01N21/0317G01N21/3504G01N21/3577G01N21/359G01N2021/855
    • The present invention provides a method and apparatus incorporating a spinning, oscillating or stepping optical interference filter (109) to change the angle at which light (102) passes through the filters after passing through a sample (105) under analysis downhole. As each filter is tilted, the color or wavelength of light passed by the filter changes. Black plates are placed between the filters to isolate each filter's photodiode. The spectrometer of the present invention is suitable for use with a wire line formation tester to provide supplemental analysis and monitoring of sample clean up. The present invention is also suitable for deployment in a monitoring while drilling environment. The present invention provides a high resolution spectometer which enables quantification of a crude oil's percentage of aromatics, olefins, and saturates to estimate a sample's gas oil ratio (GOR). Gases such as CO 2 are also detectable. The percentage of oil-based mud filtrate contamination in a crude oil sample can be estimated with the present invention by using a suitable training set and chemometrics, a neural network, or other type of correlation method.
    • 本发明提供了一种方法和装置,其包括旋转,振荡或步进光学干涉滤光器(109),以改变通过在井下分析的样品(105)之后光(102)穿过过滤器的角度。 当每个滤光片倾斜时,由滤光片传出的光线的颜色或波长发生变化。 过滤器之间放置黑色板,以隔离每个过滤器的光电二极管。 本发明的光谱仪适用于线路形成测试仪,以提供对样品清理的补充分析和监测。 本发明也适用于在钻井环境中进行监测。 本发明提供了一种高分辨率光谱仪,其能够定量原油的芳烃,烯烃和饱和物的百分比,以估计样品的瓦斯油比(GOR)。 气体如二氧化碳也是可以检测的。 通过使用合适的训练集和化学计量学,神经网络或其他类型的相关方法,可以用本发明估算原油样品中油基泥浆滤液污染物的百分比。
    • 8. 发明申请
    • METHOD AND APPARATUS FOR A DERIVATIVE SPECTROMETER
    • 衍生光谱仪的方法和装置
    • WO2003102520A1
    • 2003-12-11
    • PCT/US2003/017648
    • 2003-06-04
    • BAKER HUGHES INCORPORATED
    • DIFOGGIO, RoccoWALKOW, ArnoldBERGREN, Paul
    • G01J3/433
    • G01J3/433G01J3/26
    • The invention comprises a method of adapting derivative spectrometry for use in a downhole environment and addresses problems that are inherent in this environment. Such problems include, but are not limited to, elevated temperatures and scattering from particles residing within dirty fluid samples. Under such conditions, the photometric resolution of a spectrometer decreases at the same time that the need for better resolution increases. The invention improves the resolution by measuring the first derivative of the spectrum. The derivative spectrometer of this invention operates by vibrating a linear variable interference filter back and forth along the plane of the filter or by oscillating a circular variable filter about some angle. The effect is to oscillate the wavelength of light that is received by each photodetector. The photodetector signal can be electronically filtered to reject signals that are not at the oscillation frequency and which do not have a fixed phase relative to it. In a preferred embodiment, a vibrating actuator is the means to achieve the required oscillations about a given wavelength. Derivative spectrometry gives a higher resolution than normal methods of spectrometry. Through improved resolution, it is possible to estimate the contamination percentage of the crude oil in real time. Furthermore, it is possible to determine whether a contamination percentage is leveling off over time. It is expected that high-resolution spectra enable an improved estimation of the percentages of methane (natural gas), aromatic, olefins, saturates, and other crude oil properties.
    • 本发明包括一种使衍生光谱法适用于井下环境并解决在该环境中固有的问题的方法。 这些问题包括但不限于高温和散布在脏污液体样品中的颗粒。 在这种条件下,光谱仪的光度分辨率在增加分辨率需求的同时降低。 本发明通过测量光谱的一阶导数来提高分辨率。 本发明的导数光谱仪通过沿着滤光器的平面来回振荡线性可变干涉滤光器或通过绕一定角度振荡圆形可变滤波器来操作。 其效果是振荡由每个光电检测器接收的光的波长。 光电检测器信号可以被电子滤波以拒绝不处于振荡频率且相对于其没有固定相位的信号。 在优选实施例中,振动致动器是实现关于给定波长的所需振荡的手段。 衍生光谱法比普通光谱法提供更高的分辨率。 通过提高分辨率,可以实时估算原油的污染百分比。 此外,可以确定污染百分比随着时间流逝是否平整。 预计高分辨率光谱可以更好地估计甲烷(天然气),芳烃,烯烃,饱和物和其他原油性质的百分比。