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    • 6. 发明申请
    • MULTIDIMENSIONAL ELECTROCHEMICALLY ACTIVE STRUCTURES FOR BATTERY ELECTRODES
    • 用于电池电极的多电子电化学活性结构
    • WO2011149958A3
    • 2012-04-19
    • PCT/US2011037767
    • 2011-05-24
    • AMPRIUS INCLOVENESS GHYRN ESTEFAN CONSTANTIN IHAN SONG
    • LOVENESS GHYRN ESTEFAN CONSTANTIN IHAN SONG
    • H01M4/02B82B3/00H01M4/04H01M4/36H01M4/66H01M10/0525
    • H01M4/68H01M4/0421H01M4/134H01M4/36H01M4/70
    • Provided are novel multidimensional electrode structures containing high capacity active materials for use in rechargeable electrochemical cells. These structures include main support structures and multiple nanowires attached to the support structures and extending into different directions away from these supports. The active material may be deposited as a layer (uniform or non-uniform) surrounding the nanowires and, in certain embodiments, the main supports and even substrate. The active material layer may be sufficiently thin to prevent pulverization of the layer at given operating conditions. Interconnections between the electrode structures and/or substrate may be provided by overlaps formed during deposition of the active layer. Silicide-based nanowires structures may be formed on the main supports in a fluidized bed reactor by suspending the metal-containing main supports in a silicon-containing process gas. A layer of silicon may be then deposited over these silicide nanowires.
    • 提供了包含用于可再充电电化学电池的高容量活性材料的新颖的多维电极结构。 这些结构包括主支撑结构和附接到支撑结构并延伸到远离这些支撑的不同方向的多个纳米线。 活性材料可以作为围绕纳米线的层(均匀或不均匀)沉积,并且在某些实施方案中可以沉积在主载体和甚至基底上。 活性材料层可以足够薄以防止在给定操作条件下的层的粉碎。 可以通过在活性层沉积期间形成的重叠来提供电极结构和/或衬底之间的互连。 可以通过将含金属的主载体悬浮在含硅工艺气体中,在流化床反应器中的主要载体上形成基于硅化物的纳米线结构。 然后可以在这些硅化物纳米线上沉积一层硅。
    • 8. 发明申请
    • TEMPLATE ELECTRODE STRUCTURES WITH ENHANCED ADHESION CHARACTERISTICS
    • 具有增强粘附特性的模板电极结构
    • WO2013006583A2
    • 2013-01-10
    • PCT/US2012045313
    • 2012-07-02
    • AMPRIUS INCLOVENESS GHYRN EHAN SONGLIU ZUQIN
    • LOVENESS GHYRN EHAN SONGLIU ZUQIN
    • H01M4/13H01M4/0492H01M4/139H01M4/366H01M4/624H01M4/628H01M4/665H01M4/70
    • Provided herein are novel template electrode materials and structures for lithium ion cells. Related methods are also provided. According to various embodiments, an electrode can include a nanostructured template, an electrochemically active material layer coating the template, and a first intermediate layer between the nanostructured template and the electrochemically active material layer. In one arrangement, the nanostructured template includes silicide nanowires. The electrochemically active material may be any of silicon, tin, germanium, carbon, metal hydrides, silicides, phosphides, and nitrides. The first intermediate layer may facilitate adhesion between the nanostructured template and the electrochemically active material layer, electronic conductivity within the electrode, and/or stress relaxation between the nanostructured template and the electrochemically active material layer.
    • 本文提供了用于锂离子电池的新型模板电极材料和结构。 还提供了相关的方法。 根据各种实施例,电极可以包括纳米结构模板,涂覆模板的电化学活性材料层以及纳米结构模板和电化学活性材料层之间的第一中间层。 在一种布置中,纳米结构模板包括硅化物纳米线。 电化学活性材料可以是硅,锡,锗,碳,金属氢化物,硅化物,磷化物和氮化物中的任何一种。 第一中间层可促进纳米结构模板与电化学活性材料层之间的粘附,电极内的电子传导性和/或纳米结构模板与电化学活性材料层之间的应力松弛。
    • 9. 发明申请
    • BATTERY ELECTRODE STRUCTURES FOR HIGH MASS LOADINGS OF HIGH CAPACITY ACTIVE MATERIALS
    • 用于高容量活性材料的高质量负载的电池电极结构
    • WO2012054767A3
    • 2012-08-02
    • PCT/US2011057159
    • 2011-10-20
    • AMPRIUS INCLIU ZUQINHAN SONGLOVENESS GHYRN E
    • LIU ZUQINHAN SONGLOVENESS GHYRN E
    • H01M4/136B82B3/00H01M4/58H01M4/66H01M10/052
    • H01M4/134H01M4/1395H01M4/661H01M4/667H01M4/80H01M10/052
    • Provided are battery electrode structures that maintain high mass loadings (i.e., large amounts per unit area) of high capacity active materials in the electrodes without deteriorating their cycling performance. These mass loading levels correspond to capacities per electrode unit area that are suitable for commercial electrodes even though the active materials are kept thin and generally below their fracture limits. A battery electrode structure may include multiple template layers. An initial template layer may include nanostructures attached to a substrate and have a controlled density. This initial layer may be formed using a controlled thickness source material layer provided, for example, on a substantially inert substrate. Additional one or more template layers are then formed over the initial layer resulting in a multilayer template structure with specific characteristics, such as a surface area, thickness, and porosity. The multilayer template structure is then coated with a high capacity active material.
    • 提供了在电极中保持高质量负载(即,每单位面积的大量)高容量活性材料而不劣化其循环性能的电池电极结构。 这些质量负载水平对应于适用于商业电极的每个电极单位面积的容量,即使活性材料保持薄并且通常低于其断裂极限。 电池电极结构可以包括多个模板层。 初始模板层可以包括连接到基底并具有受控密度的纳米结构。 该初始层可以使用例如在基本惰性的基底上提供的受控厚度源材料层形成。 然后在初始层上形成另外的一个或多个模板层,得到具有特定特征的多层模板结构,例如表面积,厚度和孔隙率。 然后用高容量活性材料涂覆多层模板结构。