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1. 发明申请

WO2007048594A1 PROCESS FOR THE PREPARATION OF A SHAPED BULK CATALYST 审中-公开
标题翻译：制备形状的块状催化剂的方法
公开(公告)号：WO2007048594A1
公开(公告)日：2007-05-03
申请号：PCT/EP2006/010293
申请日：2006-10-25
申请人： ALBEMARLE NETHERLANDS BV , EIJSBOUTS, Sonja , LELIVELD, Bob , SITTERS, John , CERFONTAIN, Marinus, Bruce , OOGJEN, Bob, Gerardus
发明人： EIJSBOUTS, Sonja , LELIVELD, Bob , SITTERS, John , CERFONTAIN, Marinus, Bruce , OOGJEN, Bob, Gerardus
IPC分类号： B01J23/85 , B01J23/881 , B01J23/888 , B01J37/00 , B01J37/04 , B01J37/20 , C10G45/08 , C10G45/50 , C10G45/60 , C10G47/04 , C10G47/02 , C10G45/04
CPC分类号： B01J23/85 , B01J23/002 , B01J23/881 , B01J23/888 , B01J23/8885 , B01J35/0006 , B01J37/0009 , B01J37/0027 , B01J37/04 , B01J37/20 , B01J2523/00 , C10G45/04 , C10G45/08 , C10G45/50 , C10G45/60 , C10G47/02 , C10G47/04 , C10G2300/202 , B01J2523/68 , B01J2523/69 , B01J2523/847
摘要： The invention relates to a process for the preparation of a shaped bulk catalyst comprising metal oxide particles comprising one or more Group VlIl metals and two or more Group VIB metals which process comprises the steps of providing first metal oxidic particles comprising one or more first Group VIII metals and one or more first Group VIB metals, providing separately prepared second metal oxidic particles comprising one or more second Group VIII metals and one or more second Group VIB metals, wherein the composition of Group VIB and Group VIII metals in the first and second metal oxidic particles are different, combining the first and second metal oxidic particles before and/or during shaping and shaping the combined first and second metal oxide particles to form a shaped bulk catalyst. The invention further relates to the shaped bulk catalyst obtainable with the process In sulphided or unsulphided form and the use thereof in hydroprocessing.
摘要翻译：本发明涉及一种制备成形体积催化剂的方法，其包括包含一种或多种第VII1族金属和两种或更多种VIB族金属的金属氧化物颗粒，该方法包括以下步骤：提供第一金属氧化物颗粒，其包含一个或多个第一VIII族金属和一种或多种第一族VIB金属，提供单独制备的包含一种或多种第二族VIII族金属和一种或多种第二族VIB金属的第二金属氧化物颗粒，其中第一和第二金属中的VIB族和第VIII族金属的组成氧化颗粒是不同的，在第一和第二金属氧化物颗粒的成形和成形之前和/或之间组合第一和第二金属氧化物颗粒以形成成型的本体催化剂。本发明还涉及通过硫化或未硫化形式的方法获得的成型体催化剂及其在加氢处理中的用途。

2. 发明申请

WO2007048598A2 A BULK CATALYST COMPRISING NICKEL TUNGSTEN METAL OXIDIC PARTICLES 审中-公开
标题翻译：包含镍金属氧化物颗粒的块状催化剂
公开(公告)号：WO2007048598A2
公开(公告)日：2007-05-03
申请号：PCT/EP2006/010300
申请日：2006-10-25
申请人： ALBEMARLE NETHERLANDS BV , EIJSBOUTS, Sonja , LELIVELD, Bob , CERFONTAIN, Marinus, Bruce , PLANTENGA, Frans , VOGT, Eelco, Titus, Carel
发明人： EIJSBOUTS, Sonja , LELIVELD, Bob , CERFONTAIN, Marinus, Bruce , PLANTENGA, Frans , VOGT, Eelco, Titus, Carel
IPC分类号： B01J23/888 , C10G45/08
CPC分类号： B01J23/888 , B01J23/002 , B01J35/002 , B01J37/0009 , B01J37/03 , B01J37/10 , B01J37/20 , B01J2523/00 , C10G45/08 , C10G2300/202 , B01J2523/69 , B01J2523/847 , B01J2523/68 , B01J2523/56
摘要： The invention relates to a nickel tungsten bulk catalyst, to a process for the manufacture of said catalyst and to the use of said catalyst for the hydrotreatment, in particular the hydrodesulphurisation and hydrodenitrogenation of hydrocarbon feedstock. The catalyst comprises nickel tungsten metal oxidic particles obtainable by a process comprising forming a slurry of a first solid metal compound comprising Group VNI metal nickel and a second solid metal compound comprising Group VIB metal tungsten in a protic liquid, reacting the first and second solid metal compounds at elevated temperature whereby the first and second solid metal compounds remain at least partly in the solid state during the entire reaction to form the nickel tungsten oxidic bulk catalyst.
摘要翻译：本发明涉及镍钨体积催化剂，制备所述催化剂的方法以及所述催化剂用于加氢处理的用途，特别是烃原料的加氢脱硫和加氢脱氮。该催化剂包括可通过以下工艺获得的镍钨金属氧化物颗粒，所述方法包括在质子液体中形成包含VNI族金属镍的第一固体金属化合物和包含第VIB族金属钨的第二固体金属化合物的浆料，使第一和第二固体金属化合物在高温下由此第一和第二固体金属化合物在整个反应期间保持至少部分为固体状态以形成镍钨氧化物本体催化剂。

3. 发明申请

WO2005033930A2 PROCESS FOR UPGRADING NAPHTHA 审中-公开
标题翻译：升级NAPHTHA的过程
公开(公告)号：WO2005033930A2
公开(公告)日：2005-04-14
申请号：PCT/US2004/031808
申请日：2004-09-28
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY , RILEY, Kenneth, L. , SOLED, Stuart, L. , MISEO, Sabato , PLANTENGA, Frans, L. , CERFONTAIN, Marinus, Bruce , EIJSBOUTS, Sonja , BREVOORD, Eelko
发明人： RILEY, Kenneth, L. , SOLED, Stuart, L. , MISEO, Sabato , PLANTENGA, Frans, L. , CERFONTAIN, Marinus, Bruce , EIJSBOUTS, Sonja , BREVOORD, Eelko
IPC分类号： G06F9/40
CPC分类号： C07D417/14 , B01J23/8885 , C07D403/12 , C07D413/12 , C07D417/12 , C07D487/04 , C07D487/08 , C07D491/08 , C10G2400/02
摘要： A method for upgrading a naphtha feed to a naphtha product containing less than 10 wppm of nitrogen and less than 15 wppm sulfur, the method comprising contacting said naphtha feed with hydrogen in the presence of a bulk multimetallic catalyst under effective reactor conditions to hydrodesulfurize and hydrodenitrogenize said naphtha feed to produce said naphtha product, wherein said bulk multimetallic catalyst comprises at least one Group VIII non-noble metal and at least two Group VIB metals.
摘要翻译：一种将石脑油进料升级成含有小于10wppm氮和小于15wppm硫的石脑油产品的方法，所述方法包括在有效反应器条件下，在大量多金属催化剂存在下使所述石脑油进料与氢气接触，以加氢脱硫和加氢脱氮所述石脑油原料生产所述石脑油产品，其中所述本体多金属催化剂包含至少一种第VIII族非贵金属和至少两种VIB族金属。

4. 发明申请

WO2002102939A3 PROCESS FOR THE HYDROGENATION OF AROMATICS 审中-公开
公开(公告)号：WO2002102939A3
公开(公告)日：2002-12-27
申请号：PCT/EP2002/005906
申请日：2002-05-29
申请人： AKZO NOBEL N.V. , ATOFINA RESEARCH , LEVIVELD, Robertus, Gerardus , STAADEGAARD, Ron , CERFONTAIN, Marinus, Bruce , VANHAEREN, Xavier, Gilles, Gérard, Lépold
发明人： LEVIVELD, Robertus, Gerardus , STAADEGAARD, Ron , CERFONTAIN, Marinus, Bruce , VANHAEREN, Xavier, Gilles, Gérard, Lépold
IPC分类号： C10G45/52
摘要： The present invention pertains to a process for effecting aromatics hydrogenation which process comprises contacting a hydrocarbon feedstock which contains 10-80 vol.% of aromatics in the presence of a hydrogen-containing gas with a catalyst which comprises hydrogenation metals on a carrier. Wherein (i) the hydrogenation metals comprise a combination of platinum and palladium, and (ii) the carrier comprises silica-alumina dispersed in an alumina binder, wherein the alumina binder is present in an amount of 5-50 wt.%, based on the total weight of the silica-alumina and alumina binder present in the carrier, and wherein the silica-alumina comprises 5-50 wt.% of alumina, based on the weight of the silica-alumina. The use of a catalyst comprising platinum and palladium on a carrier comprising silica-alumina and 5-50 wt.% of an alumina binder, the silica-alumina comprising 5-50 wt.% of alumina, based on the weight of the silica-alumina, leads to an increased aromatics hydrogenation as compared to a catalyst containing only platinum as hydrogenation metal, and as compared to a catalyst containing more than 50 wt.% of an alumina binder and/or more than 50 wt.% of alumina in the silica-alumina contained in the carrier.

5. 发明申请

WO2002102939A2 PROCESS FOR THE HYDROGENATION OF AROMATICS 审中-公开
标题翻译：芳烃加氢方法
公开(公告)号：WO2002102939A2
公开(公告)日：2002-12-27
申请号：PCT/EP2002/005906
申请日：2002-05-29
申请人： AKZO NOBEL N.V. , ATOFINA RESEARCH , LEVIVELD, Robertus, Gerardus , STAADEGAARD, Ron , CERFONTAIN, Marinus, Bruce , VANHAEREN, Xavier, Gilles, Gérard, Lépold
发明人： LEVIVELD, Robertus, Gerardus , STAADEGAARD, Ron , CERFONTAIN, Marinus, Bruce , VANHAEREN, Xavier, Gilles, Gérard, Lépold
IPC分类号： C10G45/52
CPC分类号： C10G45/52 , B01J21/12 , B01J23/40 , B01J23/42 , B01J23/44 , B01J37/0009
摘要： The present invention pertains to a process for effecting aromatics hydrogenation which process comprises contacting a hydrocarbon feedstock which contains 10-80 vol.% of aromatics in the presence of a hydrogen-containing gas with a catalyst which comprises hydrogenation metals on a carrier. Wherein (i) the hydrogenation metals comprise a combination of platinum and palladium, and (ii) the carrier comprises silica-alumina dispersed in an alumina binder, wherein the alumina binder is present in an amount of 5-50 wt.%, based on the total weight of the silica-alumina and alumina binder present in the carrier, and wherein the silica-alumina comprises 5-50 wt.% of alumina, based on the weight of the silica-alumina. The use of a catalyst comprising platinum and palladium on a carrier comprising silica-alumina and 5-50 wt.% of an alumina binder, the silica-alumina comprising 5-50 wt.% of alumina, based on the weight of the silica-alumina, leads to an increased aromatics hydrogenation as compared to a catalyst containing only platinum as hydrogenation metal, and as compared to a catalyst containing more than 50 wt.% of an alumina binder and/or more than 50 wt.% of alumina in the silica-alumina contained in the carrier.
摘要翻译：本发明涉及一种进行芳族化合物氢化的方法，该方法包括在含氢气体存在下，将含有10-80体积％芳族化合物的烃原料与载体上含氢化金属的催化剂接触。其中（i）氢化金属包括铂和钯的组合，和（ii）载体包含分散在氧化铝粘合剂中的二氧化硅 - 氧化铝，其中氧化铝粘合剂的存在量为5-50重量％，基于存在于载体中的二氧化硅 - 氧化铝和氧化铝粘合剂的总重量，并且其中所述二氧化硅 - 氧化铝包含基于二氧化硅 - 氧化铝重量的5-50重量％的氧化铝。在包含二氧化硅 - 氧化铝和5-50重量％氧化铝粘合剂的载体上使用包含铂和钯的催化剂，所述二氧化硅 - 氧化铝包含5-50重量％的氧化铝，基于二氧化硅 - 氧化铝与仅含有铂作为氢化金属的催化剂相比，导致增加的芳烃氢化，并且与含有超过50重量％的氧化铝粘合剂和/或大于50重量％的氧化铝的催化剂相比，在载体中含有二氧化硅 - 氧化铝。

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