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1. 发明申请

WO2008086437A1 FORMULATIONS FOR REACTION INJECTION MOLDING AND FOR SPRAY SYSTEMS 审中-公开
标题翻译：反应注射成型和喷雾系统的配方
公开(公告)号：WO2008086437A1
公开(公告)日：2008-07-17
申请号：PCT/US2008/050659
申请日：2008-01-09
申请人： ALBEMARLE CORPORATION , BROWN, William, R. , WIGGINS, Paul, L. , LEE, John, Y.
发明人： BROWN, William, R. , WIGGINS, Paul, L. , LEE, John, Y.
IPC分类号： C08G18/66 , C09D175/02
CPC分类号： C09D175/02 , C08G18/10 , C08G18/3228 , C08G18/3234 , C08G18/6685 , C08G2120/00 , C08G2150/50
摘要： This invention provides articles made by reaction injection molding and spray coatings, and processes for forming such articles and coatings. The coatings and articles are polyureas or polyurea-urethanes. The ingredients used to form the coatings and articles comprise at least (A) an aromatic polyisocyanate and (B) a mixture formed from components comprised of (i) at least one polyol and/or at least one polyetheramine, (ii) an aromatic primary diamine, and (iii) an aliphatic secondary diamine which has about twelve to about forty carbon atoms and in which the having amino hydrocarbyl groups are secondary or tertiary hydrocarbyl groups.
摘要翻译：本发明提供了通过反应注射成型和喷涂制成的制品，以及用于形成这种制品和涂料的方法。涂料和制品是聚脲或聚脲 - 氨基甲酸酯。用于形成涂料和制品的成分至少包含（A）芳族多异氰酸酯和（B）由（i）至少一种多元醇和/或至少一种聚醚胺组成的组分形成的混合物，（ii）二胺，和（iii）具有约十二至约四十个碳原子并且其中具有氨基烃基是仲或叔烃基的脂族二胺。

2. 发明申请

WO2010101560A1 BIS[(ALKYLAMINO)ALKYL]AMINES 审中-公开
标题翻译：双[（烷基氨基）烷基] AMINES
公开(公告)号：WO2010101560A1
公开(公告)日：2010-09-10
申请号：PCT/US2009/035633
申请日：2009-03-02
申请人： ALBEMARLE CORPORATION , BROWN, William, R. , LEE, John, Y. , WIGGINS, Paul, L.
发明人： BROWN, William, R. , LEE, John, Y. , WIGGINS, Paul, L.
IPC分类号： C08G18/32 , C08G18/66 , C07C211/14
CPC分类号： C07C211/14 , C08G18/10 , C08G18/3234 , C08G18/325 , C08G18/5024 , C08G18/755 , C09D175/02 , Y02P20/582 , C08G18/6685
摘要： This invention provides compositions which are aliphatic bis [(alkylamino)alkyl] amines represented by the formula NH(R a NHR b ) 2 where each R a is, independently, an aliphatic alkylene group, and each R b is, independently, an aliphatic alkyl group having at least about three carbon atoms. Processes for forming aliphatic bis[(alkylamino)alkyl]amines are also provided.
摘要翻译：本发明提供了由式NH（RaNHRb）2表示的脂族双[（烷基氨基）烷基]胺的组合物，其中每个R a独立地是脂族亚烷基，每个R b独立地是至少具有至少约三个碳原子。还提供了形成脂族双[（烷基氨基）烷基]胺的方法。

3. 发明申请

WO2008100772A1 CHAIN EXTENDERS 审中-公开
标题翻译：链扩展
公开(公告)号：WO2008100772A1
公开(公告)日：2008-08-21
申请号：PCT/US2008/053286
申请日：2008-02-07
申请人： ALBEMARLE CORPORATION , WIGGINS, Paul, L. , LEE, John, Y.
发明人： WIGGINS, Paul, L. , LEE, John, Y.
IPC分类号： C07C209/26 , C08G18/32 , C08G18/66
CPC分类号： C08G18/3228 , C07C209/26 , C07C211/09 , C07C211/12 , C07C211/35 , C08G18/6685 , Y02P20/582
摘要： This invention provides chain extender compositions. These compositions comprise aliphatic secondary diamines in which the amino hydrocarbyl groups are different from each other. Processes for producing polyurethanes, polyureas, and polyurea-urethanes using these aliphatic secondary diamines are also provided.
摘要翻译：本发明提供扩链剂组合物。这些组合物包括其中氨基烃基彼此不同的脂族仲二胺。还提供了使用这些脂族二级二胺生产聚氨酯，聚脲和聚脲 - 聚氨酯的方法。

4. 发明申请

WO2008089010A1 PREPARATION OF SECONDARY DIAMINES 审中-公开
标题翻译：二次加工的准备
公开(公告)号：WO2008089010A1
公开(公告)日：2008-07-24
申请号：PCT/US2008/050662
申请日：2008-01-09
申请人： ALBEMARLE CORPORATION , LEE, John, Y. , WIGGINS, Paul, L.
发明人： LEE, John, Y. , WIGGINS, Paul, L.
IPC分类号： C07C209/26 , C07C211/36
CPC分类号： C07C209/26 , C07C2601/14 , Y02P20/582 , C07C211/36
摘要： This invention provides a process for forming secondary diamines. The process comprises bringing together i) at least one aliphatic cyclic ketone, ii) at least one aliphatic primary diamine, iii) hydrogen, and iv) a hydrogenation catalyst. The aliphatic primary diamine is isophoronediamine or an aliphatic primary α,ω-diamine, and the hydrogenation catalyst is selected from platinum on carbon, palladium on carbon, sulfided platinum on carbon, sulfided palladium on carbon, and a mixture of any two of the foregoing. The process is conducted at a temperature in the range of about 200C to about 750C and at a hydrogen pressure in the range of about 1 to about 95 pounds per square inch gauge, such that a secondary diamine is formed.
摘要翻译：本发明提供了形成仲二胺的方法。该方法包括使i）至少一种脂族环酮，ii）至少一种脂族伯二胺，iii）氢，和iv）氢化催化剂。脂族伯二胺是异佛尔酮二胺或脂族伯a，β-二胺，加氢催化剂选自碳铂，碳碳，硫化铂碳，硫化钯碳，以及上述任何两种的混合物。该方法在约200℃至约750℃的温度和约1至约95磅/平方英寸的压力范围内的氢气压力下进行，从而形成二级二胺。

5. 发明申请

WO2007079365A3 BLENDS OF DIAMINES HAVING REDUCED COLOR 审中-公开
公开(公告)号：WO2007079365A3
公开(公告)日：2007-07-12
申请号：PCT/US2006/062493
申请日：2006-12-21
申请人： ALBEMARLE CORPORATION , LEE, John, Y. , OWENS, David, W. , WIGGINS, Paul, L. , GLASS, Richard, D. , WILHELM, Michael, J. , SLICKER, Robert, Phillip
发明人： LEE, John, Y. , OWENS, David, W. , WIGGINS, Paul, L. , GLASS, Richard, D. , WILHELM, Michael, J. , SLICKER, Robert, Phillip
IPC分类号： C08G18/32 , C08G18/50 , C08G18/66 , C07C211/43
摘要： This invention provides a blend which comprises (i) at least one aromatic primary diamine, with which has been blended a color-minimizing amount of at least one N,N- dmydrocarbylhydroxylarnine, wherein the aromatic primary diamine is in the form of one benzene ring having two primary amino groups on the ling, which amino groups are meta or para relative to each other, and in which each position ortho to a primary amino group bears an alkyl group, and (ii) at least one aromatic secondary diamine having a Gardner color number no more than about 7, wherein said aromatic secondary diamine either is in the form of one benzene ring having two secondary amino groups on the ring, or is in the form of two benzene rings connected by an alkylene bridge and having one secondary amino group on each ring. Optionally, at least one N,N-dihydrocarbylhydroxylamine has been blended with the aromatic secondary diamine.

6. 发明申请

WO2008130721A1 PREPARATION OF SECONDARY DIAMINES 审中-公开
标题翻译：二次加工的准备
公开(公告)号：WO2008130721A1
公开(公告)日：2008-10-30
申请号：PCT/US2008/050664
申请日：2008-01-09
申请人： ALBEMARLE CORPORATION , LEE, John, Y. , WIGGINS, Paul, L. , GLASS, Richard, D. , ORGAD, Judit
发明人： LEE, John, Y. , WIGGINS, Paul, L. , GLASS, Richard, D. , ORGAD, Judit
IPC分类号： C07C209/26 , C07C211/12 , C07C211/14
CPC分类号： C07C209/26 , C07C211/14 , Y02P20/582 , C07C211/12
摘要： This invention provides a process for forming secondary diamines. The process comprises bringing together a) at least one aliphatic hydrocarbyl ketone or aldehyde in which the carbon atom(s) alpha to the carbonyl group are primary or secondary and the hydrocarbyl portion of the ketone or aldehyde is linear or branched; b) at least one aliphatic primary diamine which is an aliphatic primary α,ω-diamine, c) hydrogen; and d) a hydrogenation catalyst selected from platinum on carbon, palladium on carbon, sulfided platinum on carbon, sulfided palladium on carbon, and a mixture of any two of the foregoing. The process is conducted at a temperature in the range of about 20 °C to about 76 °C and at a hydrogen pressure in the range of about 1 to about 85 pounds per square inch gauge, such that a secondary diamine is formed.
摘要翻译：本发明提供了形成仲二胺的方法。该方法包括将a）至少一种脂族烃基酮或醛，其中羰基的α原子是伯或仲的，酮或醛的烃基部分是直链或支链的; b）至少一种脂族伯二胺，其为脂族伯a，β-二胺，c）氢; 和d）选自铂碳，钯碳，硫化铂在碳上的氢化催化剂，硫化钯碳，以及上述任何两种的混合物。该方法在约20℃至约76℃的温度和约1至约85磅/平方英寸表压的氢气压力下进行，使得形成二级二胺。

7. 发明申请

WO2008039715A1 CHAIN EXTENDERS 审中-公开
标题翻译：链扩展
公开(公告)号：WO2008039715A1
公开(公告)日：2008-04-03
申请号：PCT/US2007/079291
申请日：2007-09-24
申请人： ALBEMARLE CORPORATION , WIGGINS, Paul, L. , LEE, John, Y. , ORGAD, Judit , WILHELM, Michael, J.
发明人： WIGGINS, Paul, L. , LEE, John, Y. , ORGAD, Judit , WILHELM, Michael, J.
IPC分类号： C08G18/32 , C08G18/66
CPC分类号： C08G18/6685 , C08G18/3237
摘要： This invention provides chain extender compositions. These compositions comprise (i) an aromatic primary diamine in which at least one position ortho to each amino group bears a hydrocarbyl group, and which aromatic primary diamine is in the form of one phenyl ring having two amino groups on the ring, and (ii) an aromatic primary diamine in which at least one position ortho to each amino group bears a tertiary hydrocarbyl group, and which aromatic primary diamine is in the form of two phenyl rings connected by an alkylene bridge and having one amino group on each ring. Processes for producing polyurethanes, polyureas, and polyurea-urethanes are also provided.
摘要翻译：本发明提供扩链剂组合物。这些组合物包含（i）芳族伯二胺，其中每个氨基的邻位至少有一个位置具有烃基，哪一个芳族伯二胺为环上具有两个氨基的一个苯环的形式，和（ii ）芳族伯二胺，其中每个氨基的至少一个位置具有叔烃基，并且哪一个芳族伯二胺是由亚烷基桥连接并在每个环上具有一个氨基的两个苯环的形式。还提供了生产聚氨酯，聚脲和聚脲 - 聚氨酯的方法。

8. 发明申请

WO2007079367A1 DIAMINES HAVING REDUCED COLOR 审中-公开
标题翻译：具有减少颜色的DIAMINES
公开(公告)号：WO2007079367A1
公开(公告)日：2007-07-12
申请号：PCT/US2006/062501
申请日：2006-12-21
申请人： ALBEMARLE CORPORATION , LEE, John, Y. , OWENS, David, W. , GLASS, Richard, D. , WIGGINS, Paul, L.
发明人： LEE, John, Y. , OWENS, David, W. , GLASS, Richard, D. , WIGGINS, Paul, L.
IPC分类号： C07C209/26 , C07C211/51
CPC分类号： C07C211/50 , C07C209/26 , C07C209/84
摘要： This invention provides compositions which comprise at least one aromatic secondary diamine having a Gardner color number no more than about 6. The aromatic secondary diamine either is in the form of one benzene ring having two secondary amino groups on the ring, or is in the form of two benzene rings connected by an alkylene bridge and having one secondary amino group on each ring. At least one N,N-dihydrocarbylhydroxylamine is optionally present in the composition. Processes for producing such compositions are also provided.
摘要翻译：本发明提供了包含至少一种具有加德纳色数不超过约6的芳族仲胺的组合物。芳族仲胺是环上具有两个仲氨基的一个苯环的形式，或其形式为的两个苯环通过亚烷基桥连接并且在每个环上具有一个仲氨基。至少一种N，N-二烃基羟胺任选存在于组合物中。还提供了用于生产这种组合物的方法。

9. 发明申请

WO2006138132A2 COMMERCIAL ADMA PRODUCTS HAVING REDUCED SALTS AND ODOR AND THE NOVEL PROCESS FOR PREPARING SAME 审中-公开
标题翻译：具有减少油和气味的商业ADMA产品及其制备方法
公开(公告)号：WO2006138132A2
公开(公告)日：2006-12-28
申请号：PCT/US2006/022204
申请日：2006-06-05
申请人： ALBEMARLE CORPORATION , LEE, John, Y. , BRANDT, Vernon, O. , SAUER, Joe, P. , WIGGINS, Paul, L. , KUANG, Wenfeng , ADAMS, Jamer, R. , OWENS, David, W. , GLASS, Richard, D. , NGUYEN, Chau
发明人： LEE, John, Y. , BRANDT, Vernon, O. , SAUER, Joe, P. , WIGGINS, Paul, L. , KUANG, Wenfeng , ADAMS, Jamer, R. , OWENS, David, W. , GLASS, Richard, D. , NGUYEN, Chau
IPC分类号： C07C209/84 , C07C211/08
CPC分类号： C08F2/50 , C07C209/84 , C07C209/90 , C09D4/00 , G03F7/031 , C07C211/08
摘要： The preset invention relates to low odor ADMA (alkyldimethylamine) products, a process for purifying malodorous impure ADMA products, purified ADMA products, products produced by the purification process, and the use of and the use of the ADMA products as synergists in photopolymerization reactions .
摘要翻译：本发明涉及低气味的ADMA（烷基二甲基胺）产物，用于净化恶臭的不纯ADMA产物的方法，纯化的ADMA产物，通过纯化过程产生的产物，以及在光聚合反应中使用和使用ADMA产品作为增效剂。

10. 发明申请

WO2008112636A1 CHAIN EXTENDERS 审中-公开
标题翻译：链扩展
公开(公告)号：WO2008112636A1
公开(公告)日：2008-09-18
申请号：PCT/US2008/056415
申请日：2008-03-10
申请人： ALBEMARLE CORPORATION , LEE, John, Y. , WIGGINS, Paul, L.
发明人： LEE, John, Y. , WIGGINS, Paul, L.
IPC分类号： C08G18/32 , C08G59/60
CPC分类号： C08G18/325 , C08G59/50
摘要： This invention provides chain extender compositions. These compositions comprise either (i) N,N'-dicyclohexyl- 1,6-hexanediamine or (ii) an aliphatic secondary α,ω- diamine having a secondary amino straight chain. When said composition comprises (i), said composition is also comprised of a component selected from the group consisting of (a) an aliphatic secondary diamine, (b) an aliphatic secondary diamine and an aliphatic primary diamine, (c) an aliphatic diimine, (d) an aromatic primary diamine, and (e) a combination of any two or more of (a) through (d). When said composition comprises (ii), said composition is also comprised of a component selected from the group consisting of (a) an aliphatic secondary diamine, (d) an aromatic primary diamine, (f) an aliphatic secondary α,ω-diamine having at least one internal secondary amino group, and (g) a combination of any two or more of (a), (d), and (f). Processes for producing polyurethanes, polyureas, and polyurea-urethanes are also provided.
摘要翻译：本发明提供扩链剂组合物。这些组合物包含（i）N，N'-二环己基-1,6-己二胺或（ii）具有仲氨基直链的脂肪族仲α，β-二胺。当所述组合物包含（i）时，所述组合物还包括选自（a）脂族二胺，（b）脂族二胺和脂族伯二胺的组分，（c）脂族二亚胺，（d）芳族伯二胺，（e）（a）〜（d）中任意两种以上的组合。当所述组合物包含（ii）时，所述组合物还包括选自（a）脂族二胺，（d）芳族伯二胺，（f）脂族仲烷基，至少一个内部仲氨基，和（g）（a），（d）和（f）中任意两个或更多个的组合。还提供了生产聚氨酯，聚脲和聚脲 - 聚氨酯的方法。

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