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    • 7. 发明申请
    • INTRODUCTION OF FLUIDIZABLE INERTS INTO REACTORS CONTAINING FLUIDIZED CATALYST
    • 可流化成分引入含有流化催化剂的反应器
    • WO1997039300A1
    • 1997-10-23
    • PCT/US1997002646
    • 1997-02-20
    • ABB LUMMUS GLOBAL INC.TRUBAC, Robert, E.OVERBEEK, Rudolf, A.
    • ABB LUMMUS GLOBAL INC.
    • F27B15/00
    • B01J8/388B01J8/32F27B15/00
    • A gas phase chemical reaction is carried out in a fluidized bed reactor (10) to which a quantity of fluidizable "inert" particles has been added. The chemical reaction is one in which the fluidized particles in the reactor tend to become sticky and agglomerate, which has a negative impact on the hydrodynamics of the fluidized bed and the effectiveness of the catalyst. By employing inert particles having a low surface area, i.e., a BET surface of less than 1 m /g, these problems are reduced or eliminated. The inert particles may range from fines, smaller than the catalyst particles, to particles larger than the catalyst. In an embodiment, fine catalyst particles are omitted, avoiding the loss of expensive catalyst fines. The particles size distribution for proper fluidization and reactor performance, is provided by the addition of inert particles, which includes fines to replace the omitted fine catalyst particles. Any loss of fines due to the inability to separate them or by contamination is in the form of inexpensive inert particles rather than expensive catalyst particles. The presence of low surface area inert particles substantially removes or prevents the adverse impact on hydrodynamics and reaction performances created by the stickiness and/or agglomeration.
    • 在流化床反应器(10)中进行气相化学反应,向其中加入一定量的可流化的“惰性”颗粒。 化学反应是其中反应器中的流化颗粒倾向于变粘和聚集的化学反应,其对流化床的流体动力学和催化剂的有效性具有负面影响。 通过使用具有低表面积,即BET表面小于1m 2 / g的惰性颗粒,这些问题被减少或消除。 惰性颗粒的范围从小于催化剂颗粒的细粒到比催化剂大的颗粒。 在一个实施方案中,省略了细的催化剂颗粒,避免了昂贵的催化剂细粉的损失。 通过添加惰性颗粒提供适当流化和反应器性能的颗粒尺寸分布,其包括细粒以代替省略的细催化剂颗粒。 由于无法将它们分离或污染而导致的细粉损失是廉价的惰性颗粒而不是昂贵的催化剂颗粒的形式。 低表面积惰性颗粒的存在基本上消除或防止由粘性和/或附聚产生的对流体动力学和反应性能的不利影响。