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    • 5. 发明申请
    • LASER PATTERNING OF SILVER NANOWIRE - BASED TRANSPARENT ELECTRICALLY CONDUCTING COATINGS
    • 基于银纳米线的透明电导率涂层的激光图案
    • WO2013095971A1
    • 2013-06-27
    • PCT/US2012/068731
    • 2012-12-10
    • 3M INNOVATIVE PROPERTIES COMPANYPELLERITE, Mark J.BAETZOLD, John P.STRADINGER, John J.WU, PingfanLECHUGA, Hyacinth L.NIRMAL, Manoj
    • PELLERITE, Mark J.BAETZOLD, John P.STRADINGER, John J.WU, PingfanLECHUGA, Hyacinth L.NIRMAL, Manoj
    • H01B1/22G02F1/1343B82Y30/00H05K3/02B23K26/36
    • H05K1/0296B23K26/361B23K26/362B23K26/40B23K2201/34B23K2201/38B23K2203/172B82Y30/00G02F1/13439G02F2202/022G02F2202/36H01B1/02H05K3/027H05K3/282H05K2201/0108H05K2201/026Y10T29/49204
    • A transparent electrical conductor (10; 20), comprising a transparent substrate (14; 201); a composite layer (18; 28) comprising an electrically conductive layer (12) disposed on at least a portion of a major surface of the transparent substrate (14; 201) and comprising a plurality of interconnecting metallic nanowires, and a polymeric overcoat layer (16) disposed on at least a portion of the electrically conductive layer (12); wherein a pattern in the composite layer includes an x-axis and a y-axis of an x-y plane of the composite layer and a z- axis into the x-y plane of the composite layer, and the pattern defines a plurality of electrically conductive regions (24, 24') in the x-y plane of the composite layer (18; 28), wherein the electrically conductive regions (24, 24') are separated from each other by electrically insulative traces (21), each of which defines a valley into the z-axis of the x-y plane of the composite layer (18; 28), the valley having a maximum depth (27) in a range from 50 nanometers to 100 nanometers relative to the x-y plane of the composite layer (18; 28), wherein the valley has a cross-sectional width (M1) in a range from 10 micrometers to 1000 micrometers, and wherein the valley further comprises a plurality of crevices (22) having a depth (23) in a range from 50 nanometers to 100 nanometers further into the z-axis of the x-y plane of the composite layer (18; 28). Methods for pattemwise irradiating transparent electrodes (10; 20) to generate electrically insulating traces (21) are also described.
    • 一种透明电导体(10; 20),包括透明衬底(14; 201); 包括设置在所述透明基板(14; 201)的主表面的至少一部分上并且包括多个互连金属纳米线的导电层(12)和聚合物外涂层(18; 28) 16)布置在所述导电层(12)的至少一部分上; 其中所述复合层中的图案包括所述复合层的xy平面的x轴和y轴以及复合层的xy平面中的z轴,并且所述图案限定多个导电区域( 24,24')在所述复合层(18; 28)的xy平面中,其中所述导电区域(24,24')通过电绝缘迹线(21)彼此分离,每个线路限定谷 复合层(18; 28)的xy平面的z轴,相对于复合层(18; 28)的xy平面,具有在50纳米至100纳米范围内的最大深度(27)的谷部分, ,其中所述谷具有在10微米至1000微米范围内的横截面宽度(M1),并且其中所述谷还包括具有在50纳米至100埃范围内的深度(23)的多个缝隙(22) 纳米进一步进入复合层(18; 28)的xy平面的z轴。 还描述了用于图案地照射透明电极(10; 20)以产生电绝缘迹线(21)的方法。