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    • 1. 发明申请
    • METHOD FOR MAKING POLYLACTIDE FILMS
    • 制备聚酰胺薄膜的方法
    • WO2011060001A1
    • 2011-05-19
    • PCT/US2010/056115
    • 2010-11-10
    • 3M INNOVATIVE PROPERTIES COMPANYAUSEN, Ronald W.MYERS, Sasha B.JENNEN, Jay M.KORBA, Gary A.BANY, Stephen W.
    • AUSEN, Ronald W.MYERS, Sasha B.JENNEN, Jay M.KORBA, Gary A.BANY, Stephen W.
    • C08J5/18C08G63/00
    • C08J5/18B29C47/0021B29C47/003B29C47/0033B29C47/525B29C47/8845C08J2367/04
    • A method for forming a polylactide film includes the steps (a) through (c). In step (a), a treated tool surface is provided with a release coating. The treated tool surface is maintained at a predetermined temperature of about the glass transition temperature of the polylactide or higher. In step (b) the treated tool surface is contacted with a molten polylactide composition to provide a polylactide film. The film is at least partially crystalline, and the crystallinity of the polylactide film is enhanced due to exposure of the molten polylactide composition to the treated tool surface at the predetermined temperature. In step (c) the polylactide film is removed from the treated tool surface. Additionally, a film is provided that is made by the foregoing method, and the film may be formed into an article or a part of an article. In some cases, the article is a disposable garment such as a diaper. In other cases, the article may be a tape made with the foregoing film, where the film includes first and second major surfaces and a layer of adhesive on at least one of the major surfaces.
    • 形成聚丙交酯膜的方法包括步骤(a)至(c)。 在步骤(a)中,经处理的工具表面设置有剥离涂层。 经处理的工具表面保持在约聚丙交酯的玻璃化转变温度或更高的预定温度。 在步骤(b)中,将经处理的工具表面与熔融的聚丙交酯组合物接触以提供聚丙交酯膜。 膜至少部分结晶,并且由于在预定温度下将熔融的聚丙交酯组合物暴露于经处理的工具表面,聚丙交酯膜的结晶度得到增强。 在步骤(c)中,从经处理的工具表面除去聚丙交酯膜。 另外,通过上述方法制成薄膜,并且薄膜可以形成制品或制品的一部分。 在一些情况下,该物品是诸如尿布的一次性衣物。 在其他情况下,制品可以是用上述膜制成的带,其中膜包括第一和第二主表面以及至少一个主表面上的粘合剂层。
    • 6. 发明申请
    • METHOD OF MAKING PACKAGED VISCOELASTIC COMPOSITIONS BY POLYMERIZING ETHYLENICALLY-UNSATURATED MATERIALS USING IONIZING RADIATION
    • 通过使用离子辐射聚合乙烯基不饱和材料制备包装的粘弹性组合物的方法
    • WO2014093141A1
    • 2014-06-19
    • PCT/US2013/073455
    • 2013-12-06
    • 3M INNOVATIVE PROPERTIES COMPANY
    • O'NEAL, Daniel J.MYERS, Sasha B.RICHTER, Karl B.TRAN, Thu-Van T.HAMER, Craig E.
    • C09J201/00C09J11/00C09J4/02
    • C09J133/08C08K3/01C08K5/0008C09J7/385C09J133/02
    • Methods of forming an adhesive composition including the steps of (a) combining a non-deaerated mixture comprising at least one free radically (co)polymerizable ethylenically-unsaturated material with a sealable packaging, wherein the packaging contains the non-deaerated mixture; (b) sealing the non-deaerated mixture in the packaging to form a sealed packaging; and (c) exposing the non-deaerated mixture in the sealed packaging to a source of ionizing radiation for a time sufficient to initiate (co)polymerization of at least a portion of the at least one free radically (co)polymerizable ethylenically-unsaturated material to form an adhesive composition in the sealed packaging. The (co)polymerization takes place essentially non-adiabatically. At least a portion of the packaging is meltable and mixable with the adhesive composition so as to provide a flowable coatable adhesive composition when the sealed packaging containing the adhesive composition is heated to a temperature sufficient to melt at least a portion of the packaging.
    • 形成粘合剂组合物的方法包括以下步骤:(a)将包含至少一种自由基(共)可聚合烯属不饱和材料的非脱气混合物与可密封包装组合,其中所述包装含有非脱气混合物; (b)密封包装中的非脱气混合物以形成密封包装; 和(c)将密封包装中的未脱气的混合物暴露于电离辐射源,时间足以引发至少一部分自由基(共)可聚合烯属不饱和材料的(共)聚合 以在密封包装中形成粘合剂组合物。 (共)聚合基本上是非绝热的。 包装的至少一部分可熔融并与粘合剂组合物混合,以便当将含有粘合剂组合物的密封包装加热至足以熔化至少一部分包装的温度时,提供可流动的可涂覆粘合剂组合物。