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1. 发明申请

WO2013019614A3 LOW EQUIVALENT WEIGHT POLYMERS 审中-公开
标题翻译：低等量重量聚合物
公开(公告)号：WO2013019614A3
公开(公告)日：2013-04-04
申请号：PCT/US2012048532
申请日：2012-07-27
申请人： 3M INNOVATIVE PROPERTIES CO , LOCHHAAS KAI HELMUT , HAMROCK STEVEN J , HINTZER KLAUS
发明人： LOCHHAAS KAI HELMUT , HAMROCK STEVEN J , HINTZER KLAUS
IPC分类号： C08L27/12 , C08L41/00 , C08L101/02 , H01M4/94 , H01M8/02
CPC分类号： H01M8/102 , C08F214/18 , C08J5/2237 , C08L41/00 , H01M8/1023 , H01M8/1032 , H01M8/1039 , H01M8/1051 , H01M8/1072 , H01M8/109 , H01M2300/0082 , Y02P70/56
摘要： Described herein is a composition comprising: a polymer derived from (a) a fluorinated olefin monomer; (b) a highly fluorinated sulfur-containing monomer of the formula: CX1X2=CX3[(CX4X5)w-O-R1-SO2Y] where X1, X2, X3, X4, and X5 are independently selected from H, C1, or F; w is 0 or 1; R1 is a non-fluorinated or fluorinated alkylene group; and Y is selected from F, C1, Br, I, or OM, where M is a cation; and (c) a polyfunctional monomer comprising at least two functional groups, wherein the functional groups are selected from the group consisting of: (i) a fluorovinyl ether group, (ii) a fluoroallyl ether group, (iii) a fluorinated olefinic group, and (iv) combinations thereof; articles thereof; and a method of making such polymers.
摘要翻译：本文描述的组合物包含：衍生自（a）氟化烯烃单体的聚合物; （b）具有下式的高度含氟的含硫单体：CX1X2 = CX3 [（CX4X5）w-O-R1-SO2Y]其中X1，X2，X3，X4和X5独立地选自H，C1或F; w为0或1; R1是非氟化或氟化亚烷基; Y选自F，Cl，Br，I或OM，其中M为阳离子; 和（c）包含至少两个官能团的多官能单体，其中所述官能团选自：（i）氟乙烯基醚基团，（ii）氟烯基醚基团，（iii）氟化烯烃基团，和（iv）它们的组合; 其制品; 以及制造这种聚合物的方法。

2. 发明申请

WO2010021962A2 AZIDE-CONTAINING FLUOROPOLYMERS AND THEIR PREPARATION 审中-公开
标题翻译：含AZIO的氟聚合物及其制备
公开(公告)号：WO2010021962A2
公开(公告)日：2010-02-25
申请号：PCT/US2009053982
申请日：2009-08-17
申请人： 3M INNOVATIVE PROPERTIES CO , HINTZER KLAUS , JUERGENS MICHAEL , KASPAR HARALD , LOCHHAAS KAI HELMUT , SHYSHKOV OLEG , STREITER ANDRE , ZIPPLIES TILMAN C , BEUERMANN SABINE , IMRAN-ULHAQ MUHAMMAD
发明人： HINTZER KLAUS , JUERGENS MICHAEL , KASPAR HARALD , LOCHHAAS KAI HELMUT , SHYSHKOV OLEG , STREITER ANDRE , ZIPPLIES TILMAN C , BEUERMANN SABINE , IMRAN-ULHAQ MUHAMMAD
IPC分类号： C08F8/30 , C08F2/18 , C08F2/22 , C08F14/18 , C08F14/20 , C08F14/22 , C08F214/18 , C08F214/20 , C08F214/22
CPC分类号： C08F8/30 , C08F4/00 , C08F4/02 , C08F114/20 , C08F114/22 , C08G73/00 , Y10T428/139 , Y10T428/1397 , C08F14/18
摘要： Fluoropolymers containing one or more azide group wherein the azide group is not a sulfonyl-azide group and processes of preparing them.
摘要翻译：含有一个或多个叠氮基的含氟聚合物及其制备方法，其中叠氮基不是磺酰基叠氮基。

3. 发明申请

WO2009026123A3 METHOD OF PREPARING FLUOROPOLYMERS BY AQUEOUS EMULSION POLYMERIZATION 审中-公开
标题翻译：通过水性乳液聚合制备荧光体的方法
公开(公告)号：WO2009026123A3
公开(公告)日：2009-05-22
申请号：PCT/US2008073251
申请日：2008-08-15
申请人： 3M INNOVATIVE PROPERTIES CO , HINTZER KLAUS , JUERGENS MICHAEL , KASPAR HARALD , LOCHHAAS KAI HELMUT , STREITER ANDRE , ZIPPLIES TILMAN , SCHWERTFEGER WERNER
发明人： HINTZER KLAUS , JUERGENS MICHAEL , KASPAR HARALD , LOCHHAAS KAI HELMUT , STREITER ANDRE , ZIPPLIES TILMAN , SCHWERTFEGER WERNER
IPC分类号： C08F16/24 , C08F2/22 , C08F259/08
CPC分类号： C08F14/26 , C08F2/24
摘要： Method of making fluoropolymers by emulsion polymerization of one or more fluorinated monomers in an aqueous phase in the presence of a fluorinated emulsifier, said method comprises adding a doping agent in a weight ratio with respect to the emulsifier of from about 1 : 2 to about 1 : 20, said doping agent has a melting point of equal or less than 30°C and a boiling point of at least about 100°C and is selected from the group consisting of fluorinated cyclic hydrocarbons, fluorinated polyoxyalkenes, fluorinated alkenes and fluorinated polyoxyalkenes.
摘要翻译：在氟化乳化剂存在下，通过在水相中乳液聚合一种或多种含氟单体制备含氟聚合物的方法，所述方法包括将相对于乳化剂的重量比为约1:2至约1的掺杂剂 20，所述掺杂剂的熔点等于或低于30℃，沸点至少为约100℃，并且选自氟化环状烃，氟化聚氧乙烯烯，氟化烯烃和氟化聚氧化烯烃。

4. 发明申请

WO2011014715A3 FLUOROPOLYMER COMPOSITIONS CONTAINING A POLYOL COMPOUND AND METHODS OF MAKING THEM 审中-公开
标题翻译：含多元醇化合物的含氟聚合物组合物及其制备方法
公开(公告)号：WO2011014715A3
公开(公告)日：2011-05-05
申请号：PCT/US2010043805
申请日：2010-07-30
申请人： 3M INNOVATIVE PROPERTIES CO , ZIPPLIES TILMAN C , HINTZER KLAUS , DADALAS MICHAEL C , FREY OLIVER , LOCHHAAS KAI HELMUT
发明人： ZIPPLIES TILMAN C , HINTZER KLAUS , DADALAS MICHAEL C , FREY OLIVER , LOCHHAAS KAI HELMUT
IPC分类号： C08L5/00 , C08F14/18 , C08G18/28 , C08G18/62 , C08L27/12
CPC分类号： C08F14/18 , C08F2/16 , C08K5/053 , C08K5/103 , C08K5/151 , C08L5/00 , C08L27/16 , C08L27/18 , C08L27/20 , C09D127/18 , C08L2666/26
摘要： There are provided compositions comprising (i) at least one non-aromatic polyol compound containing at least one polyol unit having at least two hydroxyl groups and at least one long chain unit containing at least 6 carbon atoms; and (ii) at least one fluoropolymer comprising repeating units derived from a fluorinated olefin. There are also provided methods of improving the shear stability of fluoropolymer dispersions, methods of coating substrates, and substrates coated with the above described composition.
摘要翻译：提供了组合物，其包含（i）至少一种非芳族多元醇化合物，其含有至少一个具有至少两个羟基的多元醇单元和至少一个含有至少6个碳原子的长链单元; 和（ii）至少一种含有衍生自氟化烯烃的重复单元的含氟聚合物。还提供了改善含氟聚合物分散体的剪切稳定性的方法，涂布基材的方法和涂布有上述组合物的基材。

5. 发明申请

WO2010009296A2 FLUORINATED ETHER SILANES AND METHODS OF USING THE SAME 审中-公开
标题翻译：氟化硅醚及其使用方法
公开(公告)号：WO2010009296A2
公开(公告)日：2010-01-21
申请号：PCT/US2009050810
申请日：2009-07-16
申请人： 3M INNOVATIVE PROPERTIES CO , MAURER ANDREAS R , KASPAR HARALD , LOCHHAAS KAI HELMUT , JUERGENS MICHAEL , TERRAZAS MICHAEL S , GUERRA MIGUEL A , DAMS RUDOLF J , ZIPPLIES TILMAN C , QIU ZAI-MING , HINTZER KLAUS , SCHWERTFEGER WERNER
发明人： MAURER ANDREAS R , KASPAR HARALD , LOCHHAAS KAI HELMUT , JUERGENS MICHAEL , TERRAZAS MICHAEL S , GUERRA MIGUEL A , DAMS RUDOLF J , ZIPPLIES TILMAN C , QIU ZAI-MING , HINTZER KLAUS , SCHWERTFEGER WERNER
IPC分类号： C07F7/18 , B05D3/02
CPC分类号： C07F7/1836
摘要： Fluorinated compounds represented by formula Rf-Q-X-[Si(R)f(R1)3-f]g. Each Rf is independently a partially fluorinated or fully fluorinated group selected from Rfa-(O)r-CHF-(CF2)n-; [Rfb-(O)t-C(L)H-CF2-O]m-W-; CF3CFH-O-(CF2)p-; CF3-(O-CF2)z-; and CF3-O-(CF2)3-O-CF2-. Methods of treating a surface or a hydrocarbon-bearing formation using the fluorinated compounds and treated articles and treated hydrocarbon-bearing formations are also disclosed.
摘要翻译：由式Rf-Q-X- [Si（R）f（R1）3-f] g表示的氟化化合物。每个Rf独立地为选自Rfa-（O）r-CHF-（CF 2）n - 的部分氟化或完全氟化的基团; [Rfb-（O）T-C（L）H-CF 2 -O] M-W-; CF 3 CFH-O-（CF 2）p - ; CF 3 - （O-CF 2）z - ; 和CF 3 -O-（CF 2）3 -O-CF 2 - 。还公开了使用氟化化合物和经处理的制品和经处理的含烃地层处理表面或含烃地层的方法。

6. 发明申请

WO2009042853A3 FLUORINATED OXY-CARBOXYLIC ACIDS, DERIVATIVES, AND METHODS OF PREPARATION 审中-公开
标题翻译：氟化氧羧酸，衍生物和制备方法
公开(公告)号：WO2009042853A3
公开(公告)日：2010-07-01
申请号：PCT/US2008077834
申请日：2008-09-26
申请人： 3M INNOVATIVE PROPERTIES CO , SCHWERTFEGER WERNER , HINTZER KLAUS , OBERMAIER EGON
发明人： SCHWERTFEGER WERNER , HINTZER KLAUS , OBERMAIER EGON
IPC分类号： C07C69/63 , C07C51/62
CPC分类号： C07C51/58 , C07C67/14 , C07C59/135 , C07C69/708
摘要： Provided are fluorinated oxy-carboxylic acids, derivatives of oxy-carboxylic acids, and methods of preparing oxy-carboxylic acids and derivatives thereof.
摘要翻译：提供氟化含氧羧酸，氧 - 羧酸的衍生物，以及制备含氧羧酸及其衍生物的方法。

7. 发明申请

WO2011162971A3 POLYMERIZABLE COMPOSITIONS FREE OF ORGANIC EMULSIFIER AND POLYMERS AND METHODS OF MAKING THEREOF 审中-公开
标题翻译：无机有机聚合物和聚合物的可聚合组合物及其制备方法
公开(公告)号：WO2011162971A3
公开(公告)日：2012-04-12
申请号：PCT/US2011039772
申请日：2011-06-09
申请人： 3M INNOVATIVE PROPERTIES CO , BARAN JIMMIE R JR , FANSLER DUANE D , HINTZER KLAUS , HUNT WILLIAM J , KASPAR HARALD , ZIPPLIES TILMAN C
发明人： BARAN JIMMIE R JR , FANSLER DUANE D , HINTZER KLAUS , HUNT WILLIAM J , KASPAR HARALD , ZIPPLIES TILMAN C
IPC分类号： C08K3/36 , C08F2/22 , C08J5/18 , C08L25/04 , C08L27/12
CPC分类号： C08F2/10 , C08F2/20 , C08F2/22 , C08K3/36 , C08K2201/011
摘要： Described herein is a polymerizable composition substantially free of an organic emulsifier, methods of making, and articles thereof. The polymerizable composition comprises: a continuous phase; a polymerizable monomer; an initiator; and inorganic nanoparticles, wherein the inorganic nanoparticles are substantially free of groups that will copolymerize with the polymerizable monomer.
摘要翻译：本文描述的是基本上不含有机乳化剂，制备方法及其制品的可聚合组合物。可聚合组合物包括：连续相; 可聚合单体; 发起者和无机纳米颗粒，其中无机纳米颗粒基本上不含将与可聚合单体共聚的基团。

8. 发明申请

WO2010009191A3 FLUORINATED ETHER COMPOUNDS AND METHODS OF USING THE SAME 审中-公开
标题翻译：氟化醚化合物及其使用方法
公开(公告)号：WO2010009191A3
公开(公告)日：2010-07-22
申请号：PCT/US2009050627
申请日：2009-07-15
申请人： 3M INNOVATIVE PROPERTIES CO , DAMS RUDOLF J , TERRAZAS MICHAEL S , HINTZER KLAUS , QIU ZAI-MING , GUERRA MIGUEL A , MAURER ANDREAS R , KASPAR HARALD , LOCHHAAS KAI H , JUERGENS MICHAEL , ZIPPLIES TILMAN C , SCHWERTFEGER WERNER
发明人： DAMS RUDOLF J , TERRAZAS MICHAEL S , HINTZER KLAUS , QIU ZAI-MING , GUERRA MIGUEL A , MAURER ANDREAS R , KASPAR HARALD , LOCHHAAS KAI H , JUERGENS MICHAEL , ZIPPLIES TILMAN C , SCHWERTFEGER WERNER
IPC分类号： C07C235/10 , C07C217/28 , C07C219/06
CPC分类号： C07C235/10 , C07C69/708 , C07C211/11 , C07C211/14 , C07C291/04 , C07C309/14 , C07F9/091 , C07F9/3808 , C08G65/007
摘要： Compounds represented by formula (Rf-Q-X)s-Z. Each Rf is independently a partially fluorinated or fully fluorinated group selected from Rfa-(O)r-CHF-(CF2)n-; [Rfb-(O)t-C(L)H-CF2-O]m-W-; CF3CFH-O-(CF2)p-; CF3-(O-CF2)z-; and CF3-O-(CF2)3-O-CF2-. Methods of reducing surface tension of a liquid, making foams, and treating a surface using the compounds are also disclosed.
摘要翻译：由式（Rf-Q-X）s-Z表示的化合物。每个Rf独立地为选自Rfa-（O）r-CHF-（CF 2）n - 的部分氟化或完全氟化的基团; [Rfb-（O）T-C（L）H-CF 2 -O] M-W-; CF 3 CFH-O-（CF 2）p - ; CF 3 - （O-CF 2）z - ; 和CF 3 -O-（CF 2）3 -O-CF 2 - 。还公开了降低液体表面张力，制造泡沫和使用该化合物处理表面的方法。

9. 发明申请

WO2011050131A3 METHODS OF PREPARING FLUORINATED CARBOXYLIC ACIDS AND THEIR SALTS 审中-公开
标题翻译：制备氟化羧酸及其盐的方法
公开(公告)号：WO2011050131A3
公开(公告)日：2011-08-25
申请号：PCT/US2010053480
申请日：2010-10-21
申请人： 3M INNOVATIVE PROPERTIES CO , HINTZER KLAUS , VOGEL DENNIS E , GUERRA MIGUEL A , IGNATOWSKA JOLANTA , ROESCHENTHALER GERD-VOLKER , SHYSHKOV OLEG , VOGEL KIM M , ZIPPLIES TILMAN C
发明人： HINTZER KLAUS , VOGEL DENNIS E , GUERRA MIGUEL A , IGNATOWSKA JOLANTA , ROESCHENTHALER GERD-VOLKER , SHYSHKOV OLEG , VOGEL KIM M , ZIPPLIES TILMAN C
IPC分类号： C07C51/27 , C07C53/18 , C07C53/21 , C07C59/125 , C07C59/135
CPC分类号： C07C51/27 , C07C53/21 , C07C59/135
摘要： A method for preparing fluorinated carboxylic acids and theirs salts is described comprising subjecting a fluorinated alcohol of the general formula (A): A-CH2-OH to at least one first and at least one second oxidizing agent to produce a highly fluorinated carboxylic acid or their salts of the general formula (B): A-COO M+, wherein M+ represents a cation and wherein A in formulas (A) and (B) is the same and A represents the residue: Rf-[0]p-CX"Y"-[0]m-CX'Y'-[0]n-CXY- wherein Rf represents a fluorinated alkyl residue which may or may not contain one or more catenary oxygen atoms, p, m and n are independently from each other either 1 or O, X, X', X", Y, Y' and Y" are independently from each other H, F, CF3, or C2F5 with the proviso that not all of X, X', X", Y, Y' and Y' ' are H; or A represents the residue: R-CFX- wherein X and R are independently selected from a hydrogen, a halogen, or an alkyl, alkenyl, cycloalkyl, or aryl residue, which may or may not contain one or more fluorine atoms and which may or may not contain one or more catenary oxygen atoms; wherein said at least one first oxidizing agent is a compound that can be converted, by action of the second oxidizing agent, into a reactive species capable of oxidizing the fluorinated alcohol.
摘要翻译：描述了制备氟化羧酸及其盐的方法，包括使通式（A）的氟化醇：A-CH 2 -OH经历至少一种第一和至少一种第二氧化剂以产生高度氟化的羧酸或它们的通式（B）的盐：A-COO M +，其中M +表示阳离子，并且其中式（A）和（B）中的A相同且A表示残基：Rf- [O] p-CX“ 其中Rf表示可以含有或不含有一个或多个悬链氧原子的氟化烷基，p，m和n彼此独立地为 X'，X'，Y'，Y'和Y“各自独立地为H，F，CF 3或C 2 F 5，条件是不是所有的X，X'，X” Y'和Y“是H;或者A代表残基：R-CFX-，其中X和R独立地选自氢，卤素或烷基，烯基，环烷基或芳基残基，其可以或不可以含有一个或多个氟原子 ms并且可能包含或不包含一个或多个悬链氧原子; 其中所述至少一种第一氧化剂是能够通过所述第二氧化剂的作用转化为能够氧化所述氟化醇的反应性物质的化合物。

10. 发明申请

WO2009079534A3 DENTAL COMPOSITION CONTAINING A SURFACTANT AND AN F-CONTAINING COMPOUND, PROCESS OF PRODUCTION AND USE THEREOF 审中-公开
标题翻译：含有表面活性剂和含F化合物的牙科组合物，其生产方法和用途
公开(公告)号：WO2009079534A3
公开(公告)日：2009-11-26
申请号：PCT/US2008087087
申请日：2008-12-17
申请人： 3M INNOVATIVE PROPERTIES CO , ZECH JOACHIM W , OSSWALD PETER , HOFFMANN HENNING , MAURER ANDREAS R , BISSINGER PETER , HINTZER KLAUS
发明人： ZECH JOACHIM W , OSSWALD PETER , HOFFMANN HENNING , MAURER ANDREAS R , BISSINGER PETER , HINTZER KLAUS
IPC分类号： A61K6/083 , A61K6/093 , A61K6/10
CPC分类号： A61K6/10 , A61K6/083 , C08L51/085 , C08L51/08
摘要： The invention relates to a curable dental composition comprising a) a curable organopolysiloxane polymer, b) a crosslinker compound capable of crosslinking said organopolysiloxane polymer, c) a catalyst capable of catalyzing a crosslinking reaction of component (A) and component (B), d) a surfactant, e) a F-containing compound, wherein the F-containing compound has the following formula: (G1-L1-O)s-Rfa-O-L2-G2 wherein: G1 and G2 each independently represents a non-ionic endgroup that is free of polyoxyalkylene groups or contains polyoxyalkylene such that the total amount thereof in the F-containing compound is not more than 10% by weight based on the molecular weight of the F-containing ompound; L1 and L2 each independently represents an aliphatic hydrocarbon group or a partially or fully fluorinated aliphatic hydrocarbon group; Rfa represents a mono-valent or divalent partially or fully fluorinated aliphatic group or a partially or fully fluorinated aliphatic group interrupted by one or more oxygen atoms; with the proviso that at least one of the following conditions is fulfilled: (i) at least one of the moieties L1-G1 and L2-G2 is partially or fully fluorinated or (ii) Rf is a partially or fully fluorinated aliphatic group interrupted by one or more oxygen atoms. The invention also relates to a kit of parts and a method of producing a dental composition as well as the use of the dental composition for the preparation of or as impression material or for the preparation of crowns and bridges.
摘要翻译：本发明涉及可固化牙科用组合物，其包含a）可固化的有机聚硅氧烷聚合物，b）能够交联所述有机聚硅氧烷聚合物的交联剂化合物，c）能够催化组分（A）和组分（B）的交联反应的催化剂，d ）表面活性剂，e）含F化合物，其中所述含F化合物具有下式：（G1-L1-O）s-Rfa-O-L2-G2其中：G1和G2各自独立地表示非 - 不含聚氧化烯基团或含有聚氧化烯的非离子型端基，使得基于含F化合物的分子量，其在含F化合物中的总量不超过10重量％; L1和L2各自独立地表示脂族烃基或部分或完全氟化的脂族烃基; Rfa表示单价或二价的部分或完全氟化的脂肪族基团或被一个或多个氧原子间隔的部分或完全氟化的脂肪族基团; 条件是满足以下条件中的至少一个：（i）部分L 1 -G 1和L 2 -G 2中的至少一个部分或完全氟化或（ii）R f是部分或完全氟化的脂族基团，一个或多个氧原子。本发明还涉及制备牙科用组合物的部件套件和方法以及该牙科用组合物用于制备印模材料或用于制备牙冠和牙桥的用途。

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