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1. 发明申请

WO2011053628A3 METHODS OF USING HYDROFLUOROETHERS AS HEAT TRANSFER FLUIDS 审中-公开
标题翻译：使用氢氟醚作为传热流体的方法
公开(公告)号：WO2011053628A3
公开(公告)日：2011-09-22
申请号：PCT/US2010054237
申请日：2010-10-27
申请人： 3M INNOVATIVE PROPERTIES CO , FLYNN RICHARD M , COSTELLO MICHAEL G , BULINSKI MICHAEL J
发明人： FLYNN RICHARD M , COSTELLO MICHAEL G , BULINSKI MICHAEL J
IPC分类号： C09K5/04 , C07C19/08
CPC分类号： C09K5/10
摘要： An apparatus is provided that includes a device and a mechanism for heat transfer. The mechanism includes a hydrofluoroether heat-transfer fluid wherein the heat transfer fluid is represented by the following structure: Y-Rf-CH2OCH2Rf-Y wherein Rf may be the same or different and is, independently, selected from the group consisting of perfluorinated alkylene groups which may be linear, cyclic, or branched having from 1 to 10 carbon atoms, partially fluorinated alkylene groups having from 1 to 10 carbon atoms, and derivatives thereof wherein one or more carbon atoms are replaced by catenated nitrogen or oxygen heteroatoms, wherein each Rf contains at most one hydrogen atom, wherein Y represents H, F, or an RfCH2OCH2- group, and wherein the total number of carbon atoms in the molecule is at least 6. A method of transferring heat including the device and the provided heat-transfer fluid is also provided.
摘要翻译：提供一种装置，其包括装置和用于传热的机构。该机理包括氢氟醚传热流体，其中传热流体由以下结构表示：Y-Rf-CH 2 OCH 2 R f-Y其中R f可以相同或不同，独立地选自全氟化亚烷基其可以是具有1至10个碳原子的直链，环状或支链的，具有1至10个碳原子的部分氟化的亚烷基，以及其中一个或多个碳原子被连接的氮或氧杂原子代替的衍生物，其中每个Rf 含有至多一个氢原子，其中Y表示H，F或RfCH 2 OCH 2 - 基团，并且其中分子中的总碳原子数为至少6.一种传递热量的方法，包括该装置和所提供的传热还提供了流体。

2. 发明申请

WO2012134803A2 FLUORINATED OXIRANES AS ORGANIC RANKINE CYCLE WORKING FLUIDS AND METHODS OF USING SAME 审中-公开
标题翻译：氟化氧化物作为有机RANKINE循环工作流体及其使用方法
公开(公告)号：WO2012134803A2
公开(公告)日：2012-10-04
申请号：PCT/US2012028855
申请日：2012-03-13
申请人： 3M INNOVATIVE PROPERTIES CO , FAYEMI BAMIDELE O , ZHANG ZHONGXING , COSTELLO MICHAEL G , BULINSKI MICHAEL J , OWENS JOHN G , TUMA PHILLIP E , MINDAY RICHARD M , FLYNN RICHARD M
发明人： FAYEMI BAMIDELE O , ZHANG ZHONGXING , COSTELLO MICHAEL G , BULINSKI MICHAEL J , OWENS JOHN G , TUMA PHILLIP E , MINDAY RICHARD M , FLYNN RICHARD M
IPC分类号： F25B15/02 , C07D303/02
CPC分类号： F01K25/08 , C07D303/08 , C07D303/48 , C09K5/04 , F01K25/10
摘要： A process and an apparatus for converting thermal energy into mechanical energy in a Rankine cycle is provided. The process and apparatus include a working fluid that comprises a fluorinated oxirane. The fluorinated oxirane can contain substantially no hydrogen atoms bonded to carbon atoms and can have from about 4 to about 9 carbon atoms. The process can drive a turbine and, in some embodiments, generate electricity.
摘要翻译：提供了一种在兰金循环中将热能转换为机械能的方法和装置。该方法和装置包括包含氟化环氧乙烷的工作流体。氟化环氧乙烷可以基本上不含有与碳原子键合的氢原子，并且可以具有约4-约9个碳原子。该过程可以驱动涡轮机，并且在一些实施例中，发电。

3. 发明申请

WO2010002528A2 HYDROFLUOROACETAL COMPOUNDS AND PROCESSES FOR THEIR PREPARATION AND USE 审中-公开
标题翻译：氢氟醚化合物及其制备和使用的方法
公开(公告)号：WO2010002528A2
公开(公告)日：2010-01-07
申请号：PCT/US2009045775
申请日：2009-06-01
申请人： 3M INNOVATIVE PROPERTIES CO , FLYNN RICHARD M , COSTELLO MICHAEL G
发明人： FLYNN RICHARD M , COSTELLO MICHAEL G
IPC分类号： C07C41/54 , C07C43/12 , C09K5/10
CPC分类号： C09K5/10 , A62D1/0085 , C07C41/50 , C07C41/54 , C07C43/313 , C08J9/143 , C09D7/20 , C23G5/032 , Y10T408/44 , Y10T428/31504 , C07C43/317
摘要： The present disclosure provides a compound according to the formula: Rf 1 [CH(-O-CH(3-m)Rf 2m)(-O-CF2-CFH-Rf 3)]n [I] wherein n is 1 or 2, wherein m is 1, 2 or 3, wherein, when n is 1, Rf 1 is selected from the group consisting of highly fluorinated alkyl groups which are linear, branched, cyclic, or a combination thereof, which may optionally be substituted, and which may optionally contain one or more catenated heteroatoms; wherein, when n is 2, Rf 1 is selected from the group consisting of highly fluorinated alkylene groups which are linear, branched, cyclic, or a combination thereof, which may optionally be substituted, and which may optionally contain one or more catenated heteroatoms; wherein each Rf 2 is independently selected from the group consisting of alkyl groups which are linear, branched, cyclic, or a combination thereof, which may optionally be substituted, and which may optionally contain one or more catenated heteroatoms; wherein at least one Rf 2 is highly fluorinated; wherein each Rf 3 is independently selected from the group consisting of fluorine and highly fluorinated alkyl groups which are linear, branched, cyclic, or a combination thereof, which may optionally be substituted, and which may optionally contain one or more catenated heteroatoms. Also provided are methods of use and manufacture of such compounds.
摘要翻译：本公开内容提供了下式的化合物：Rf 1 [CH（-O-CH（3-m）Rf 2m）（ - O-CF 2 -CFH-Rf 3）] n [I]，其中n为1或2 其中m为1,2或3，其中当n为1时，Rf 1选自可任选被取代的直链，支链，环状或其组合的高度氟化的烷基，以及其可以任选地含有一个或多个连接的杂原子; 其中当n为2时，R f 1选自直链，支链，环状或其组合的高度氟化的亚烷基，其可以任选地被取代，并且可以任选地含有一个或多个连接的杂原子; 其中每个Rf 2独立地选自直链，支链，环状或其组合的烷基，其可任选被取代，并且其可以任选地含有一个或多个连接的杂原子; 其中至少一个Rf 2是高度氟化的; 其中每个Rf 3独立地选自氟和高度氟化的烷基，其为直链，支链，环状或其组合，其可任选被取代，并且其可以任选地含有一个或多个连接的杂原子。还提供了使用和制造这些化合物的方法。

4. 发明申请

WO2007030297A2 ELECTROLYTE COMPOSITION 审中-公开
标题翻译：电解液组合物
公开(公告)号：WO2007030297A2
公开(公告)日：2007-03-15
申请号：PCT/US2006032439
申请日：2006-08-21
申请人： 3M INNOVATIVE PROPERTIES CO
发明人： COSTELLO MICHAEL G , FLYNN RICHARD M , SEGAWA HARUKI
IPC分类号： H01M10/40 , H01M4/02 , H01M4/131 , H01M4/133 , H01M10/0568 , H01M10/0569
CPC分类号： H01M10/0568 , H01M4/131 , H01M4/133 , H01M10/0569
摘要： An electrolyte composition includes (a) a solvent composition including at least one hydrofluoroether compound, the hydrofluoroether compound including two terminal fluoroalkyl groups and an intervening substituted or unsubstituted oxymethylene group, each of the fluoroalkyl groups including only one hydrogen atom and, optionally, at least one catenated (that is, in-chain) heteroatom, with the proviso that, when the oxymethylene group is unsubstituted, at least one of the terminal fluoroalkyl groups is branched and/or includes at least one catenated heteroatom; and (b) at least one electrolyte salt.
摘要翻译：一种电解质组合物，其包含：（a）包含至少一种氢氟醚化合物的溶剂组合物，所述氢氟醚化合物包含两个末端氟烷基和插入的取代或未取代的氧化亚甲基，每个氟烷基仅包含一个氢原子，并且任选地至少（即链内）杂原子，条件是当氧亚甲基未被取代时，至少一个末端氟代烷基是支化的和/或包含至少一个连接的杂原子; 和（b）至少一种电解质盐。

5. 发明申请

WO0105468A3 USE OF FLUORINATED KETONES IN FIRE EXTINGUISHING COMPOSITIONS 审中-公开
标题翻译：氟化灭碱剂在灭火组合物中的应用
公开(公告)号：WO0105468A3
公开(公告)日：2002-09-12
申请号：PCT/US0019693
申请日：2000-07-19
申请人： 3M INNOVATIVE PROPERTIES CO
发明人： RIVERS PAUL E , MINDAY RICHARD M , BEHR FRED E , VITCAK DANIEL R , FLYNN RICHARD M , COSTELLO MICHAEL G , PARENT MICHAEL J , OWENS JOHN G , ZHANG ZHONGXING
IPC分类号： A62C2/00 , A62C3/00 , A62C35/02 , A62C35/13 , A62C35/62 , A62C37/40 , A62D1/00 , A62D1/02 , A62D1/08 , C07C49/16 , C07C49/175
CPC分类号： A62D1/0057 , A62D1/0085
摘要： Fire extinguishing compositions and methods for extinguishing, controlling, or preventing fires are described wherein the extinguishing agent is a fluorinated ketone having up to two hydrogen atoms, alone, or in admixture with a co-extinguishing agent selected from hydrofluorocarbons, hydrochlorofluorocarbons, perfluorocarbons, perfluoropolyethers, hydrofluoroethers, hydrofluoropolyethers, chlorofluorocarbons, bromofluorocarbons, bromochlorofluorocarbons, iodofluorocarbons, hydrobromofluorocarbons, and mixtures thereof.
摘要翻译：描述灭火组合物和灭火，控制或预防火灾的方法，其中灭火剂是具有至多两个氢原子的单独的氟化酮，或与选自氢氟碳化合物，氢氯氟烃，全氟化碳，全氟聚醚的共灭火剂混合，氢氟醚，氢氟聚醚，氯氟烃，溴氟碳氟化合物，溴氯氟碳氟化合物，碘氟碳氟化合物，氢氟碳氟化合物及其混合物。

6. 发明申请

WO2005060434A3 HYDROFLUOROETHER AS A HEAT-TRANSFER FLUID 审中-公开
标题翻译：氢氟烃作为传热流体
公开(公告)号：WO2005060434A3
公开(公告)日：2006-02-02
申请号：PCT/US2004035721
申请日：2004-10-28
申请人： 3M INNOVATIVE PROPERTIES CO
发明人： COSTELLO MICHAEL G , FLYNN RICHARD M , BEHR FREDERICK E
IPC分类号： C09K5/10 , C09K5/00 , C07C41/00
CPC分类号： C07C43/126 , C09K5/10
摘要： The present invention provides an apparatus comprising a device and a mechanism for heat transfer comprising a hydrofluoroether heat-transfer fluid wherein the heat transfer fluid is represented by the following structure:R f -O-R h -O-R f' wherein: O is oxygen; R f and R f' are, independently, a fluoroaliphatic group, wherein each Rf and R f' contain 1 hydrogen atom; R h is independently a linear, branched or cyclic alkylene group having from 2 to about 8 carbon atoms and at least 4 hydrogen atoms, and wherein the hydrofluoroether compound is free of -O-CH 2 -O-. Another embodiment of the present invention is a method therefor
摘要翻译：本发明提供了一种装置，其包括装置和用于传热的机构，其包括氢氟醚传热流体，其中传热流体由以下结构表示：R f -OR h 其中：O是氧; R f和R f'独立地是氟代脂族基团，其中每个R f和R f'包含1个氢原子; R h分别是具有2至约8个碳原子和至少4个氢原子的直链，支链或环状亚烷基，其中所述氢氟醚化合物不含-O-CH 2 -O-。本发明的另一个实施方案是其方法

7. 发明申请

WO2007136948A2 CYCLIC HYDROFLUOROETHER COMPOUNDS AND PROCESSES FOR THEIR PREPARATION AND USE 审中-公开
标题翻译：循环氢氟醚化合物及其制备和使用的方法
公开(公告)号：WO2007136948A2
公开(公告)日：2007-11-29
申请号：PCT/US2007066707
申请日：2007-04-16
申请人： 3M INNOVATIVE PROPERTIES CO
发明人： VITCAK DANIEL R , FLYNN RICHARD M , COSTELLO MICHAEL G
IPC分类号： C07D307/20 , C07D309/10
CPC分类号： C07D307/20 , C07D309/10
摘要： A hydrofluoroether compound comprises at least one five- or six-membered, perfluorinated heterocyclic ring, each ring comprising four or five ring carbon atoms and one or two catenated heteroatoms selected from divalent ether oxygen atoms and trivalent nitrogen atoms, at least one of the catenated heteroatoms being a divalent ether oxygen atom, and each of the ring carbon atoms adjacent to the divalent ether oxygen atom bearing a fluorochemical group that comprises a tetrafluoroethylidene moiety (-(CF 3 )CF-) that is directly bonded to the ring carbon atom, the fluorochemical group optionally comprising at least one catenated heteroatom selected from divalent ether oxygen atoms and trivalent nitrogen atoms.
摘要翻译：氢氟醚化合物包含至少一个五元或六元全氟化杂环，每个环包含四个或五个环碳原子和一个或两个选自二价醚氧原子和三价氮原子的连接杂原子，至少一个连接的杂原子是二价醚氧原子，并且与具有含氟化学基团的二价醚氧原子相邻的环碳原子中的每一个包含四氟亚乙基部分（ - （CF 3 C 3 -CF）），其直接键合到环碳原子上，含氟基团任选地包含至少一个选自二价醚氧原子和三价氮原子的链状杂原子。

8. 发明申请

WO2011041208A3 APPARATUS INCLUDING HYDROFLUOROETHER WITH HIGH TEMPERATURE STABILITY AND USES THEREOF 审中-公开
标题翻译：装置包括具有高温稳定性的氢氟醚及其用途
公开(公告)号：WO2011041208A3
公开(公告)日：2011-07-28
申请号：PCT/US2010050090
申请日：2010-09-24
申请人： 3M INNOVATIVE PROPERTIES CO
发明人： FLYNN RICHARD M , COSTELLO MICHAEL G , BULINSKI MICHAEL J
IPC分类号： C09K5/04 , F28F23/00
CPC分类号： C07C43/126 , C09K5/10 , F24J2/4649
摘要： An apparatus is provided that includes a device and a mechanism for heat transfer that includes a provided hydrofluoroether having high temperature stability. Also provided is a method of transferring heat and a composition that includes a provided hydrofluoroether.
摘要翻译：提供一种装置，其包括装置和用于传热的机构，其包括提供的具有高温度稳定性的氢氟醚。还提供了一种传递热量的方法和包含所提供的氢氟醚的组合物。

9. 发明申请

WO2010062486A3 METHODS OF MAKING FLUORINATED ETHERS, FLUORINATED ETHERS, AND USES THEREOF 审中-公开
标题翻译：制备氟化物，氟化物及其用途的方法
公开(公告)号：WO2010062486A3
公开(公告)日：2011-02-24
申请号：PCT/US2009060326
申请日：2009-10-12
申请人： 3M INNOVATIVE PROPERTIES CO
发明人： FLYNN RICHARD M , BULINSKI MICHAEL J , COSTELLO MICHAEL G
IPC分类号： C07C41/16 , C07C43/12
CPC分类号： C07C41/16 , C07C43/123 , C07C43/126 , C07C213/06 , C07C217/26
摘要： A method of making a fluorinated ether includes combining, in a polar aprotic solvent: a fluorinated alcohol represented by the formula X-Rf1CH2OH, and a fluorinated sulfonate ester represented by the formula Rf2CH2OS(=O)2Rf3, and base; and obtaining a fluorinated ether represented by the formula Y-Rf1CF2OCF2Rf2-Y. Rf1 is selected from perfluorinated C1-C10 alkylene groups having from 1 to 10 carbon atoms and partially fluorinated C1 -C10 alkylene groups, and derivatives thereof having catenated heteroatom(s). X represents H, F, or an HOCH2- group. Rf2 is selected from perfluorinated C1 -C10 alkyl groups and partially fluorinated C1 -C10 alkyl groups, and derivatives thereof having catenated heteroatom(s). Rf3 is a C1-C4 alkyl group. Y represents H, F, or an Rf2CH2OCF2- group. A variant method, useful for preparing symmetric fluorinated ethers, is also disclosed. The present disclosure also provides fluorinated ethers preparable according to the methods. Use of fluorinated ethers in various applications is also disclosed.
摘要翻译：制备氟化醚的方法包括在极性非质子溶剂中：将由式X-Rf 1 CH 2 OH表示的氟化醇和由式Rf2CH2OS（= O）2Rf3表示的氟化磺酸酯和碱反应; 得到由式Y-Rf1CF2OCF2Rf2-Y表示的氟化醚。 Rf1选自具有1至10个碳原子的全氟化C 1 -C 10亚烷基和部分氟化的C 1 -C 10亚烷基，以及其具有连接的杂原子的衍生物。 X表示H，F或HOCH 2 - 基团。 Rf2选自全氟化的C 1 -C 10烷基和部分氟化的C 1 -C 10烷基，以及其具有连接的杂原子的衍生物。 Rf 3是C 1 -C 4烷基。 Y表示H，F或Rf2CH2OCF2-基团。还公开了可用于制备对称氟化醚的变体方法。本公开还提供了根据该方法可制备的氟化醚。还公开了在各种应用中使用氟化醚。

10. 发明申请

WO2007030314A3 HYDROFLUOROETHER COMPOUNDS AND PROCESSES FOR THEIR PREPARATION AND USE 审中-公开
标题翻译：氢氟醚化合物及其制备和使用的方法
公开(公告)号：WO2007030314A3
公开(公告)日：2007-05-03
申请号：PCT/US2006032704
申请日：2006-08-23
申请人： 3M INNOVATIVE PROPERTIES CO
发明人： FLYNN RICHARD M , COSTELLO MICHAEL G
IPC分类号： C07C43/12 , C09K5/10
CPC分类号： C09K5/10 , C07C43/126 , Y10T83/04
摘要： A hydrofluoroether compound comprises two terminal fluoroalkyl groups and an intervening substituted or unsubstituted oxymethylene group, each of the fluoroalkyl groups comprising only one hydrogen atom and, optionally, at least one catenated (that is, in-chain) heteroatom; with the proviso that the hydrogen atom is part of a monofluoromethylene moiety.
摘要翻译：氢氟醚化合物包括两个末端氟代烷基和中间取代或未取代的氧亚甲基，每个氟代烷基仅包含一个氢原子，和任选至少一个连接（即在链内）的杂原子; 条件是氢原子是单氟代亚甲基部分的一部分。

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