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    • 2. 发明申请
    • PROCESS FOR MAKING AN OPTICAL FILM AND ROLLS OF OPTICAL FILM
    • 制作光学薄膜和光学薄膜的方法
    • WO2007115137A2
    • 2007-10-11
    • PCT/US2007065571
    • 2007-03-30
    • 3M INNOVATIVE PROPERTIES CO
    • MERRILL WILLIAM WARDOUDERKIRK ANDREW JJOHNSON MATTHEW BHEBRINK TIMOTHY JDENKER MARTIN EO'NEILL MARK B
    • F02M37/10
    • G02B5/3083G02F1/133528G02F1/133634G02F2001/133507Y10T428/24479Y10T428/2457
    • Exemplary methods include includes providing a film comprising at least one polymeric material; widening the film under a first set of processing conditions in a first draw step along the crossweb direction such that in-plane birefringence, if any, created in the film is low; and drawing the film in a second draw step along a downweb direction under a second set of processing conditions, wherein the second set of processing conditions creates in-plane birefringence in at least one polymeric material. Exemplary roll of film includes an oriented optical film characterized by an effective orientation axis. The oriented optical film comprises only one birefringent polymeric material, at least one birefringent material and at least one isotropic material, or a first birefringent material and a second birefringent material, the birefringent materials characterized by effective orientation axes along the MD. The optical film has a width of greater than 0.3 m and a length a length greater than 10 m.
    • 示例性的方法包括提供包含至少一种聚合材料的薄膜; 在沿着横向横向方向的第一拉伸步骤中的第一组加工条件下使膜变宽,使得在膜中产生的面内双折射(如果有的话)低; 以及在第二组加工条件下沿下游方向在第二拉伸步骤中拉伸所述薄膜,其中所述第二组加工条件在至少一种聚合材料中产生平面内双折射。 示例性的薄膜包括以有效取向轴为特征的定向光学薄膜。 定向光学膜仅包含一种双折射聚合材料,至少一种双折射材料和至少一种各向同性材料,或第一双折射材料和第二双折射材料,双折射材料的特征在于沿着MD的有效取向轴。 光学膜的宽度大于0.3μm,长度长度大于10μm。
    • 8. 发明申请
    • MULTI-LAYER ARTICLES CAPABLE OF FORMING COLOR IMAGES AND METHODS OF FORMING COLOR IMAGES
    • 可形成彩色图像的多层文章和形成彩色图像的方法
    • WO2012003247A2
    • 2012-01-05
    • PCT/US2011042478
    • 2011-06-30
    • 3M INNOVATIVE PROPERTIES CODUNN DOUGLAS SMERRILL WILLIAM WARDMARKOWICZ PRZEMYSLAW P
    • DUNN DOUGLAS SMERRILL WILLIAM WARDMARKOWICZ PRZEMYSLAW P
    • B32B27/20B32B27/08
    • G03F7/095B32B7/12B32B27/08B32B27/18B32B27/20B32B27/24B32B27/32B32B27/36B32B27/365B32B27/40B32B2255/10B32B2255/26B32B2307/30B32B2307/4026B32B2307/41B32B2307/416B32B2307/42B32B2425/00B32B2519/00B32B2554/00B41M5/34B41M5/42B41M5/46B41M5/465
    • Multi-layer articles are described that are capable of forming color images. The articles include at least six layers, four thermally activatable layers (layers 1-4) and two blocking layers (layer 5 and 6). The layers are arranged such that layer 5 is disposed between layers 1 and 2 and layer 6 is disposed between layers 3 and 4. Thermally activatable layers 1 and 2 are activatable upon exposure to light of a first write wavelength, and blocking layer 5 is adapted to at least partially block light of the first write wavelength. Thermally activatable layers 3 and 4 are activatable upon exposure to light of a second write wavelength, and blocking layer 6 is adapted to at least partially block light of the second write wavelength. At least one, and possibly all of the thermally activatable layers include a light to heat convertor composition and a color changing compound. Some of the thermally activatable layers may be a group of layers arranged to selectively reflect light by constructive or destructive interference to provide a first reflective characteristic, the group of layers also having a first absorption characteristic suitable to, upon exposure to light comprising a write wavelength, absorptively heat the first group of layers by an amount sufficient to change the first reflective characteristic to a second reflective characteristic while maintaining the structural integrity of the group of layers.
    • 描述能够形成彩色图像的多层制品。 制品包括至少六层,四层热活化层(层1-4)和两层阻挡层(层5和层6)。 这些层被布置成使得层5设置在层1和2之间,层6设置在层3和4之间。可热激活层1和2可以在暴露于第一写入波长的光时被激活,并且阻挡层5被适配 以至少部分地阻挡第一写入波长的光。 可热激活层3和4在暴露于第二写入波长的光时可激活,并且阻挡层6适于至少部分地阻挡第二写入波长的光。 至少一个,并且可能全部的可热激活层包括光至热转化器组合物和变色化合物。 一些可热激活的层可以是一组层,其布置成通过结构性或相消干涉选择性地反射光以提供第一反射特性,所述一组层还具有适于在暴露于包含写入波长的光的第一吸收特性 吸收地将第一组层吸收足以将第一反射特性改变到第二反射特性的量,同时保持该组层的结构完整性。