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    • 2. 发明申请
    • O-BENZYL OXIME ETHER DERIVATIVES AND THEIR USE AS PESTICIDES
    • O-BENZYL OXIME醚衍生物及其作为杀虫剂的用途
    • WO1996016026A1
    • 1996-05-30
    • PCT/EP1995004357
    • 1995-11-06
    • CIBA-GEIGY AGZURFLÜH, RenéZIEGLER, HugoTRAH, Stephan
    • CIBA-GEIGY AG
    • C07C255/62
    • C07D295/185A01N37/50A01N37/52C07C251/38C07C251/48C07C255/64C07C257/06C07C257/14C07C257/22C07C2601/02C07D295/30
    • Compounds of formula (I), wherein Y is hydrogen, C1-C4alkyl, C1-C4alkoxy, OH, CN, NO2, Si(CH3)3, CF3 or halogen, and T is a group (a) or (b), and wherein the remaining substituents have the following definitions: X is O, S or NR13; A is O or NR4; R1 is hydrogen, C1-C4alkyl, halo-C1-C4alkyl, cyclopropyl, C1-C4alkoxymethyl, C1-C4alkoxy, C1-C4alkylthio or cyano; R2 is hydrogen, C1-C6alkyl, C3-C6cycloalkyl, cyano unsubstituted or substituted C1-C6alkoxycarbonyl, unsubstituted or substituted di(C1-C6alkyl)aminocarbonyl, unsubstituted or substituted C1-C6alkyl-S(O)q, unsubstituted or substituted aryl-S(O)q, unsubstituted or substituted heteroaryl, unsubstituted or substituted heterocyclyl, unsubstituted or substituted heterocyclylcarbonyl or unsubstituted or substituted phenyl; and R3 is hydrogen, unsubstituted or substituted alkyl, unsubstituted or substituted C3-C6cycloalkyl, unsubstituted or substituted phenyl or unsubstituted or substituted pyridyl; and wherein the remaining substituents are as defined herein, are pesticidal active ingredients. They can be used in pest control, especially as microbicides, insecticides and acaricides in agriculture, in horticulture and in the hygiene sector.
    • 式(I)化合物,其中Y为氢,C 1 -C 4烷基,C 1 -C 4烷氧基,OH,CN,NO 2,Si(CH 3)3,CF 3或卤素,T为(a)或(b) 其中剩余取代基具有以下定义:X为O,S或NR 13; A为O或NR4; R 1是氢,C 1 -C 4烷基,卤代C 1 -C 4烷基,环丙基,C 1 -C 4烷氧基甲基,C 1 -C 4烷氧基,C 1 -C 4烷硫基或氰基; 未取代或取代的二(C 1 -C 6烷基)氨基羰基,未取代或取代的C 1 -C 6烷基-S(O)q,未取代或取代的芳基-S(O)q,C 1 -C 6烷基,C 3 -C 6环烷基,氰基未取代或取代的C 1 -C 6烷氧基羰基, (O)q,未取代或取代的杂芳基,未取代或取代的杂环基,未取代或取代的杂环基羰基或未取代或取代的苯基; 未取代或取代的烷基,未取代或取代的C 3 -C 6环烷基,未取代或取代的苯基或未取代或取代的吡啶基; 并且其中剩余的取代基如本文所定义,是杀虫活性成分。 它们可用于病虫害防治,特别是作为农业,园艺和卫生领域的杀菌剂,杀虫剂和杀螨剂。
    • 3. 发明申请
    • THIOAMIDES S-OXIDES FOR USE AS PESTICIDES
    • 用作杀虫剂的硫氧化物S-氧化物
    • WO1997000859A1
    • 1997-01-09
    • PCT/EP1996002520
    • 1996-06-10
    • CIBA-GEIGY AGZURFLÜH, René
    • CIBA-GEIGY AG
    • C07C327/60
    • A01N43/80A01N41/02C07C327/60C07D261/20
    • Thioamide S-oxides of formula (I) are suitable as fungicidally, insecticidally and acaricidally active ingredients in crop protection, in which R1 is hydrogen or C1-C4alkyl, and R2 is hydrogen, C1-C4alkyl, C2-C4alkenyl, C2-C4alkynyl or C3-C6cycloalkyl, and in which R3 and R4 independently of one another are hydrogen, cyano, C1-C4alkyl, halo-C1-C4alkyl, C2-C4alkenyl, C2-C4alkynyl, C3-C6cycloalkyl, cyclopropylmethyl, C1-C4alkoxy, C2-C5alkoxyalkyl, C1-C4alkoxycarbonyl, C1-C4alkylthio, C2-C5alkylthioalkyl; an unsubstituted or up to trisubstituted ring which has not more than 15 ring carbon atoms, which can be polycyclic and which contains 0-3 hetero atoms N, O or S, it being possible for this ring to be bonded via an aliphatic bridge having not more than 4 carbon atoms and/or via either CO, oxygen or sulfur; or in which R3 and R4 together with the joint carbon atom form an unsubstituted or up to trisubstituted ring which has not more than 15 ring carbon atoms, which can be polycyclic and which contains 0-3 hereto atoms N, O or S. They can be used on their own or as formulated compositions, preferably for controlling or preventing infestation with microorganisms.
    • 式(I)的硫酰胺S-氧化物在作物保护中适合作为杀真菌,杀虫和杀螨活性成分,其中R1是氢或C1-C4烷基,R2是氢,C1-C4烷基,C2-C4链烯基,C2-C4炔基或 C 3 -C 6环烷基,其中R 3和R 4彼此独立地是氢,氰基,C 1 -C 4烷基,卤代-C 1 -C 4烷基,C 2 -C 4烯基,C 2 -C 4炔基,C 3 -C 6环烷基,环丙基甲基,C 1 -C 4烷氧基,C 2 -C 5烷氧基烷基 ,C 1 -C 4烷氧基羰基,C 1 -C 4烷硫基,C 2 -C 5烷硫基烷基; 具有不多于15个环碳原子的未被取代或最多三取代的环,其可以是多环的并且含有0-3个杂原子N,O或S,该环可能通过没有 多于4个碳原子和/或经由CO,氧或硫; 或其中R 3和R 4与连接碳原子一起形成具有不多于15个环碳原子的未取代或至多三取代的环,其可以是多环的并且含有0-3个原子N ,O或S.它们可以单独使用或作为配制的组合物使用,优选用于控制或预防用微生物侵染。
    • 6. 发明申请
    • N-(ORTHO-SUBSTITUTED BENZYLOXY)IMINE DERIVATIVES AND THEIR USE AS FUNGICIDES, ACARICIDES OR INSECTICIDES
    • N-(ORTHO-取代的苄基)衍生物及其作为杀真菌剂,杀虫剂或杀虫剂的用途
    • WO1996011183A1
    • 1996-04-18
    • PCT/EP1995003802
    • 1995-09-26
    • CIBA-GEIGY AGZIEGLER, HugoTRAH, StephanZURFLÜH, René
    • CIBA-GEIGY AG
    • C07C255/64
    • C07D239/26C07C251/36C07C251/60C07C255/14C07C255/29C07C255/64C07C381/00C07C2601/02C07D213/53C07D213/61C07D261/08C07D263/10C07D265/08C07D277/10C07D277/64C07D285/06C07D295/185C07D307/52
    • The present invention relates to oxime ethers of general formula (I) and to their isomers and isomer mixtures which are possible in which (a) X is an N atom and Y is an oxygen atom or NH, or (b) X is CH and Y is an oxygen atom, in which furthermore R1 is C1-C4 alkyl; R2 is hydrogen, C1-C4 alkyl, cyclopropyl or cyano; R3 is cyano, substituted or unsubstituted C1-C6 alkoxycarbonyl, substituted or unsubstituted di(C1-C6 alkyl)aminocarbonyl, substituted or unsubstituted C1-C6 alkyl-S(O)n, substituted or unsubstituted aryl-S(O)n, substituted or unsubstituted heteroaryl, substituted or unsubstituted heterocyclyl or substituted or unsubstituted heterocyclylcarbonyl; and R4 is C1-C6 alkyl; C1-C6 haloalkyl having 1 to 5 halogen atoms; C1-C4 alkoxy-C1-C2 alkyl; C2-C6 alkenyl which is unsubstituted or substituted by 1 to 3 halogen atoms; C3-C6 alkynyl; C3-C6 cycloalkyl-C1-C4 alkyl which is unsubstituted or substituted by 1 to 4 halogen atoms, and n assumes a value of 1 or 2. These compounds can be used in the form of crop protection products for controlling plant diseases, insects and pests from the order Acarina.
    • 本发明涉及通式(I)的肟醚及其异构体和异构体混合物,其中(a)X为N原子,Y为氧原子或NH,或(b)X为CH和 Y是氧原子,此外R1是C1-C4烷基; R2是氢,C1-C4烷基,环丙基或氰基; 取代或未取代的C 1 -C 6烷氧基羰基,取代或未取代的二(C 1 -C 6烷基)氨基羰基,取代或未取代的C 1 -C 6烷基-S(O)n,取代或未取代的芳基-S(O) 或未取代的杂芳基,取代或未取代的杂环基或取代或未取代的杂环基羰基; R4为C1-C6烷基; 具有1至5个卤素原子的C 1 -C 6卤代烷基; C 1 -C 4烷氧基-C 1 -C 2烷基; 未被取代或被1至3个卤素原子取代的C 2 -C 6烯基; C3-C6炔基; 未被取代或被1至4个卤素原子取代的C 3 -C 6环烷基-C 1 -C 4烷基,n表示1或2的值。这些化合物可以以作物防护产品的形式用于防治植物病害,昆虫和 有害生物从订单阿卡里娜。
    • 7. 发明申请
    • PESTICIDES
    • 农药
    • WO1995018789A1
    • 1995-07-13
    • PCT/EP1994004318
    • 1994-12-27
    • CIBA-GEIGY AGZIEGLER, HugoTRAH, StephanFAROOQ, SaleemZURFLÜH, René
    • CIBA-GEIGY AG
    • C07C251/60
    • C07D213/77A01N37/36A01N37/50A01N43/28A01N43/30A01N43/36A01N43/40A01N43/46A01N43/653A01N43/84A01N55/00C07C251/60C07C251/76C07C251/80C07C255/54C07C255/61C07C2601/02C07D231/12C07D233/56C07D249/08C07D295/088C07D295/30C07D317/18C07D317/58C07D333/22
    • Compounds of formula (I) and the isomers, and isomer mixtures thereof, which are possible, in which either a) X is an N atom and Y is OR11 or N(R12)R13, or b) X is CH and Y is OR11, and in which furthermore: R11 is C1-C4alkyl; R12 and R13, independently, are hydrogen or C1-C4alkyl; A is an O atom or the group NR4; R1 is hydrogen, C1-C4alkyl, halo-C1-C4alkyl, cyclopropyl, cyano or methylthio; R2 is hydrogen, C1-C6alkyl, C3-C6cycloalkyl, a group (i), a group (ii), or thienyl; R3 is hydrogen, C1-C6alkyl, C1-C6haloalkyl having 1 to 5 halogen atoms, C1-C4alkoxy-C1-C2alkyl, C2-C4alkenyl-C1-C2alkyl, which is unsubstituted or substituted by 1 to 3 halogen atoms, C2-C4alkynyl-C1-C2-alkyl, C3-C6cycloalkyl which is unsubstituted or substituted by 1 to 4 halogen atoms, C3-C6-cycloalkyl-C1-C4alkyl which is unsubstituted or substituted by 1 to 4 halogen atoms, cyano-C1-C4alkyl; C1-C4alkoxycarbonyl-C1-C2alkyl, C1-C4alkoxycarbamoyl-C1-C2alkyl, phenyl-C1-C3alkyl which is unsubstituted or substituted by halogen, C1-C3alkyl, C1-C4alkoxy, C1-C4haloalkyl, cyano, nitro or C1-C4alkylenedioxy, it being possible for the phenyl group to be monosubstituted to trisubstituted by identical or different substituents; phenyl which is unsubstituted or mono- to disubstituted, independently, by C1-C4alkyl, C1-C4alkoxy, halogen, C1-C2haloalkyl having 1 to 3 halogen atoms, nitro or cyano, or pyridyl which is unsubstituted or mono- to disubstituted, independently, by C1-C4alkyl, C1-C4alkoxy, halogen, C1-C2haloalkyl having 1 to 3 halogen atoms, nitro or cyano; R4 is C1-C4alkyl, phenyl, or R3 and R4 together with the nitrogen atom to which they are bonded form a saturated or unsaturated 5- to 7-membered ring which is unsubstituted or substituted by C1-C4alkyl and which can have 1 to 3 additional hetero atoms selected from amongst N, O and S, and in which the substituents Z, B, D and n are as defined in the present publication, are pesticidal active ingredients. They can be used for pest control, in particular as microbicides, insecticides and acaricides in agriculture, horticulture and in the hygiene sector.
    • 其中a)X为N原子,Y为OR 11或N(R 12)R 13或b)X为CH且Y为OR 11的式(I)化合物及其异构体及其异构体混合物, ,此外:R 11是C 1 -C 4烷基; R 12和R 13独立地是氢或C 1 -C 4烷基; A是O原子或NR4基团; R1是氢,C1-C4烷基,卤代-C1-C4烷基,环丙基,氰基或甲硫基; R2是氢,C1-C6烷基,C3-C6环烷基,基团(ⅰ),基团(ⅱ)或噻吩基; R3是氢,C1-C6烷基,具有1-5个卤素原子的C1-C6卤代烷基,C1-C4烷氧基C1-C2烷基,未被取代或被1-3个卤素原子取代的C2-C4链烯基C1-C2烷基,C2-C4炔基 - C 1 -C 2烷基,未被取代或被1至4个卤素原子取代的C 3 -C 6环烷基,未被取代或被1至4个卤素原子取代的C 3 -C 6环烷基-C 1 -C 4烷基,氰基-C 1 -C 4烷基; C 1 -C 4烷氧基羰基-C 1 -C 2烷基,C 1 -C 4烷氧基氨基甲酰基-C 1 -C 2烷基,未被取代或被卤素,C 1 -C 3烷基,C 1 -C 4烷氧基,C 1 -C 4卤代烷基,氰基,硝基或C 1 -C 4亚烷基二氧基取代的苯基-C 1 -C 3烷基 苯基可被相同或不同取代基单取代三取代; 苯基,其未被取代或独立地被C 1 -C 4烷基,C 1 -C 4烷氧基,卤素,具有1至3个卤素原子的C 1 -C 2卤代烷基,硝基或氰基或未取代或单取代的吡啶基, C 1 -C 4烷基,C 1 -C 4烷氧基,卤素,具有1至3个卤素原子的C 1 -C 2卤代烷基,硝基或氰基; R4是C1-C4烷基,苯基或R3和R4与它们所键合的氮原子一起形成饱和或不饱和的5-至7-元环,其未被取代或被C 1 -C 4烷基取代,并且可以具有1至3个 选自N,O和S,并且其中取代基Z,B,D和n如本出版物中所定义的另外的杂原子是杀虫活性成分。 它们可以用于害虫控制,特别是作为农业,园艺和卫生领域的杀菌剂,杀虫剂和杀螨剂。
    • 8. 发明申请
    • O-BENZYL OXIME ETHER DERIVATIVES AND THEIR USE AS PESTICIDES
    • O-BENZYL OXIME醚衍生物及其作为杀虫剂的用途
    • WO1994026700A1
    • 1994-11-24
    • PCT/EP1994001457
    • 1994-05-06
    • CIBA-GEIGY AGZURFLÜH, René
    • CIBA-GEIGY AG
    • C07C257/06
    • C07D295/135A01N37/50A01N37/52C07C255/62C07C257/06C07C257/14C07C259/10C07C259/14C07C259/20C07C271/64C07C327/44C07C327/58C07C2601/02C07C2602/08C07C2602/10C07C2603/18C07D295/13C07F7/081
    • Compounds of formula (I) in which Y is hydrogen, C1-C4alkyl, C1-C4alkoxy, OH, CN, NO2, Si(CH3)3, CF3 or halogen, Z is a group (a) or (b) and R1 is hydrogen, C1-C4alkyl, C2-C4alkenyl, C2-C4-alkynyl, C3-C6cycloalkyl, phenyl which is unsubstituted or at most trisubstituted by halogen, C1-C4alkyl, C1-C4alkoxy, C1-C4alkylthio, or benzyl which is unsubstituted or at most trisubstituted in the aromatic ring in the same manner; or is cyclopropylmethyl, C1-C4haloalkyl, C2-C5alkoxyalkyl, cyanomethyl, CO-R6, OH, NH2, C1-C4alkylamine or C1-C4alkoxycarbonyl-C1-C2alkyl; X is oxygen, sulfur or NR5; R2 is hydrogen, C1-C4alkyl, C2-C4alkenyl, C2-C4alkynyl, C3-C6cycloalkyl, C(O)R6, OH or C1-C4alkoxy, NH2 or C1-C4alkylamine; R5 is hydrogen, C1-C4alkyl, C2-C4alkenyl or C2-C4alkynyl; R6 is hydrogen, C1-C4alkyl, C1-C4haloalkyl, C1-C4alkoxy, C3-C6cycloalkyl, C1-C4alkoxycarbonyl or phenyl which is unsubstituted or at most trisubstituted; and in which R3 and R4 independently of one another are hydrogen, cyano, C1-C4alkyl, halo-C1-C4alkyl, C2-C4alkenyl, C2-C4alkynyl, C3-C6cycloalkyl, cyclopropylmethyl, C1-C4alkoxy, C2-C5-alkoxyalkyl, C1-C4alkoxycarbonyl, C1-C4alkylthio, C2-C5alkylthioalkyl; a ring having not more than 15 ring carbon atoms which can be polymembered and is unsubstituted or at most trisubstituted and has 0-3 hetero atoms N, O or S, it being possible for this ring to be bonded via an aliphatic bridge having not more than 4 carbon atoms and/or via either CO, oxygen or sulfur; or in which R?3? and R?4? together with the shared carbon atom are a ring or polymembered ring system having not more than 15 ring carbon atoms which is unsubstituted or at most trisubstituted and has 0-3 hetero atoms N, O or S; are suitable for controlling and preventing attack by microorganisms of plants. They can be used in the form of commercially available formulated compositions.
    • 其中Y为氢,C1-C4烷基,C1-C4烷氧基,OH,CN,NO2,Si(CH3)3,CF3或卤素的式(Ⅰ)化合物,Z为基团(a)或(b),R1为 C 1 -C 4烷基,C 1 -C 4烷基,C 2 -C 4链烯基,C 2 -C 4炔基,C 3 -C 6环烷基,未被取代或至多被卤素,C 1 -C 4烷基,C 1 -C 4烷氧基,C 1 -C 4烷硫基或未被取代或在 以相同的方式在芳环中最多取代; 或环丙基甲基,C 1 -C 4卤代烷基,C 2 -C 5烷氧基烷基,氰基甲基,CO-R 6,OH,NH 2,C 1 -C 4烷基胺或C 1 -C 4烷氧基羰基-C 1 -C 2烷基; X是氧,硫或NR5; R2是氢,C1-C4烷基,C2-C4链烯基,C2-C4炔基,C3-C6环烷基,C(O)R6,OH或C1-C4烷氧基,NH2或C1-C4烷基胺; R5是氢,C1-C4烷基,C2-C4链烯基或C2-C4炔基; R6是氢,C1-C4烷基,C1-C4卤代烷基,C1-C4烷氧基,C3-C6环烷基,C1-C4烷氧基羰基或未取代或至多三取代的苯基; 并且其中R 3和R 4彼此独立地是氢,氰基,C 1 -C 4烷基,卤代-C 1 -C 4烷基,C 2 -C 4烯基,C 2 -C 4炔基,C 3 -C 6环烷基,环丙基甲基,C 1 -C 4烷氧基,C 2 -C 5 - 烷氧基烷基,C 1 C 1-4烷氧基羰基,C 1 -C 4烷硫基,C 2 -C 5烷硫基烷基; 具有不超过15个环碳原子的环,其可以被聚合并且是未取代的或至多三取代的且具有0-3个杂原子N,O或S,该环可能通过不具有更多的脂族桥键合 不超过4个碳原子和/或通过CO,氧或硫; 或其中R 3 和R 4 与共享碳原子一起是具有不多于15个环碳原子的环或多元环系,其未被取代或至多三取代并具有0-3个杂原子N,O或S; 适用于控制和防止植物微生物侵袭。 它们可以以市售配方组合物的形式使用。