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    • 5. 发明申请
    • ELECTROOPTICAL LIQUID CRYSTAL SYSTEM
    • 电液体水晶系统
    • WO1993022397A1
    • 1993-11-11
    • PCT/EP1993000989
    • 1993-04-23
    • MERCK PATENT GMBHCOATES, DavidPARRI, Owain, LlyrGREENFIELD, SimonTILLIN, Martin, DavidGOULDING, Mark, JohnNOLAN, Patrick
    • MERCK PATENT GMBH
    • C09K19/54
    • C09K19/3469C09K19/12C09K19/14C09K19/2007C09K19/322C09K19/3444C09K19/38C09K19/544C09K2019/0448C09K2019/0481Y10T428/10Y10T428/1077
    • Electrooptical system with improved switching time especially at low temperatures: which between 2 electrode layers contains a PDLC film comprising a liquid crystal mixture forming microdroplets in an optically isotropic, transparent polymer matrix, the precursor of the PDLC film comprises one or more monomers, oligomers and/or prepolymers and a photoinitiator, and is cured photoradically, the liquid crystal mixture of which comprises one or more compounds of formula (I) in which Z and Z , independently of one another, are a single bond, -CH2CH2-, -COO-, -OCO- or -C=C-, (a) and (b), independently of one another, are trans-1,4-cyclohexylene, 1,4-phenylene, 2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene, 2,3-difluoro-1,4-phenylene or 3,5-difluoro-1,4-phenylene and one of (a) and (b) may also be pyrimidine-2,5-diyl, pyridine-2,5-diyl or trans-1,3-dioxane-2,5-diyl, X and X , independently from one another, are H or F, Q is -CF2, -OCF2, -C2F4, -OC2F4 or a single bond, Y is -H, -F, -C1 or -CN, n is 0, 1 or 2 and R is alkyl having up to 13 C atoms, in which one or two non-adjacent CH2 groups can also be replaced by -O- and/or -CH=CH- and additionally one or more reactive liquid crystalline compounds preferably containing terminal ene-group.
    • 具有改善的切换时间,特别是在低温下的电光学系统:其中2个电极层之间包含PDLC膜,其包含在光学各向同性的透明聚合物基质中形成微滴的液晶混合物,PDLC膜的前体包含一种或多种单体,低聚物和 光学引发剂,并且光电偶联地固化,其液晶混合物包含一种或多种式(I)化合物,其中Z 1和Z 2彼此独立地是单键, -CH 2 CH 2 - , - COO-,-OCO-或-C = C - ,(a)和(b)彼此独立地为反式-1,4-亚环己基,1,4-亚苯基, 1,4-亚苯基,3-氟-1,4-亚苯基,2,3-二氟-1,4-亚苯基或3,5-二氟-1,4-亚苯基和(a)和(b)之一可以 吡啶-2,5-二基或反式-1,3-二恶烷-2,5-二基,X 1和X 2彼此独立地为H或 F,Q是-CF 2,-OCF 2,-C 2 F 4,-OC 2 F 4或单键,Y是-H,-F, -C 1或-CN,n为0,1或2,R为具有多达13个C原子的烷基,其中一个或两个不相邻的CH 2基团也可以被-O-和/或-CH = CH- 以及另外一种或多种优选含有末端烯基的反应性液晶化合物。