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1. 发明申请

WO2010138253A3 POLYOLEFIN ADHESIVE COMPOSITIONS AND METHOD OF MAKING THEREOF 审中-公开
标题翻译：聚烯烃胶粘剂组合物及其制备方法
公开(公告)号：WO2010138253A3
公开(公告)日：2011-01-13
申请号：PCT/US2010031354
申请日：2010-04-16
申请人： EXXONMOBIL CHEM PATENTS INC , RODRIGUEZ GEORGE , SHIPLEY FRAN , JIANG PEIJUN , SIMS CHARLES , LEWTAS KEN
发明人： RODRIGUEZ GEORGE , SHIPLEY FRAN , JIANG PEIJUN , SIMS CHARLES , LEWTAS KEN
IPC分类号： C09J123/10 , C09J11/06 , C09J11/08 , C09J123/00
CPC分类号： C09J123/10 , C08L23/0853 , C08L23/0869 , C08L51/06 , C08L91/06 , C08L2666/02 , C09J123/14
摘要： The packaging industry desires adhesive compositions having a fast set time, such as those setting in less than five seconds from a molten state at conventional packaging operating temperatures to a solid or quasi solid having favorable Dot T-Peel, set time, and/or fiber tear adhesion properties. Polymer based adhesives performing within this window are a favorable alternative to conventional formulated adhesives. The provided adhesive compositions exhibit a favorable balance of properties such as high adhesive strength, wide temperature operating window, and fast set time. Provided are adhesive compositions composed of a polyolefin composition comprising at least about 50 mol% polypropylene, at least one wax and at least one wax modifier.
摘要翻译：包装工业期望具有快速固化时间的粘合剂组合物，例如在常规包装操作温度下从熔融状态设定为固体或准固体的不到5秒钟的粘合剂组合物，其具有良好的点T形剥离，凝固时间和/或纤维撕裂粘合性能。在该窗口内执行的基于聚合物的粘合剂是常规配制粘合剂的有利替代物。所提供的粘合剂组合物表现出良好的性能平衡，例如高粘合强度，宽温度操作窗口和快速凝固时间。提供由包含至少约50mol％聚丙烯，至少一种蜡和至少一种蜡改性剂的聚烯烃组合物组成的粘合剂组合物。

2. 发明申请

WO2007018893A1 SYNTHESIS OF BENZYL-METAL COMPOUNDS 审中-公开
标题翻译：苄基金属化合物的合成
公开(公告)号：WO2007018893A1
公开(公告)日：2007-02-15
申请号：PCT/US2006/026718
申请日：2006-07-11
申请人： UNIVATION TECHNOLOGIES, LLC , RODRIGUEZ, George , CANO, David, A. , MCCONVILLE, David , RIX, Frank, C.
发明人： RODRIGUEZ, George , CANO, David, A. , MCCONVILLE, David , RIX, Frank, C.
IPC分类号： C07F7/00 , C07F19/00
CPC分类号： C07F7/00
摘要： Disclosed are methods of producing di-, tri- or tetrabenzyl-metal compounds comprising combining a metal salt with a (benzyl) n MgX 2-n compound at from less than 3O°C, wherein n is 1 or 2 and X is a monoanionic group; wherein the combining takes place in a diluent mixture comprising from 0 to 80 % by volume of an ether diluent and a diluent selected from the group consisting of aromatic diluents, halogenated hydrocarbon diluents, and mixtures thereof. The methods are characterized by employing various mixtures of diluents, and in some cases, minimal to no ether diluent.
摘要翻译：公开了生产二 - ，三 - 或四 - 苄基 - 金属化合物的方法，包括将金属盐与（苄基）亚磺酰氧基二异氰酸酯化合物的混合物的含量小于30 ℃，其中n为1或2，X为单阴离子基团; 其中所述组合在包含0至80体积％的醚稀释剂和选自芳族稀释剂，卤代烃稀释剂及其混合物的稀释剂的稀释剂混合物中进行。该方法的特征在于使用各种稀释剂的混合物，并且在一些情况下，最少至没有乙醚稀释剂。

3. 发明申请

WO2003051892A1 PARTIALLY FLUORINATED NAPHTHYL-BASED BORATES 审中-公开
标题翻译：部分氟化的基于硼酸的硼酸盐
公开(公告)号：WO2003051892A1
公开(公告)日：2003-06-26
申请号：PCT/US2002/036201
申请日：2002-11-12
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , RODRIGUEZ, George , RIX, Francis, C. , RAVISHANKAR, Periagaram, S. , KUCHTA, Matthew, C.
发明人： RODRIGUEZ, George , RIX, Francis, C. , RAVISHANKAR, Periagaram, S. , KUCHTA, Matthew, C.
IPC分类号： C07F5/00
CPC分类号： C08F10/00 , C07F5/027 , C08F4/65912 , C08F4/65927 , C08F210/16 , C08F4/65908 , C08F210/14 , C08F2500/17
摘要： Non-coordinating anions or anion precursors are disclosed. These non-coordinating anions serve as the activator for olefin polymerization catalyst systems. As such, they abstract an alkyl leaving group from a metallocene catalyst precursor leaving an activated catalyst charge balanced by a non-coordinating anion. These anions are formed by 3 or 4 partially fluorinated naphthyl ligands coordinated around boron (or other Group-13 element) creating corresponding tris-borane or tetrakis-borate complexes.
摘要翻译：公开了非配位阴离子或阴离子前体。这些非配位阴离子用作烯烃聚合催化剂体系的活化剂。因此，它们从茂金属催化剂前体中抽出烷基离去基团，留下由非配位阴离子平衡的活化催化剂电荷。这些阴离子由3或4个部分氟化的萘配体形成，硼配位在硼（或其他13族元素）周围，产生相应的三 - 硼烷或四硼酸盐络合物。

4. 发明申请

WO2002083754A1 PROPYLENE ETHYLENE POLYMERS AND PRODUCTION PROCESS 审中-公开
标题翻译：丙烯乙烯聚合物和生产工艺
公开(公告)号：WO2002083754A1
公开(公告)日：2002-10-24
申请号：PCT/US2002/010515
申请日：2002-04-02
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , DATTA, Sudhin , HU, Weiguo , RAVISHANKAR, P. S. , HARRINGTON, Bruce, A. , RODRIGUEZ, George
发明人： DATTA, Sudhin , HU, Weiguo , RAVISHANKAR, P. S. , HARRINGTON, Bruce, A. , RODRIGUEZ, George
IPC分类号： C08F210/16
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F210/06 , Y10S526/941 , Y10S526/943 , C08F2/06 , C08F4/65927 , C08F2500/21 , C08F2500/20 , C08F2500/15 , C08F2500/17
摘要： Ethylene propylene copolymers, substantially free of diene, are described. The copolymers will have a uniform distribution of both tacticity and comonomer between copolymer chains. Further, the copolymers will exhibit a statistically insignificant intramolecular difference of tacticity. The copolymers are made in the presence of a metallocene catalyst.
摘要翻译：描述了基本上不含二烯的乙烯丙烯共聚物。共聚物在共聚物链之间具有均匀分布的立构规整度和共聚单体。此外，共聚物将显示统计学上不明显的立构规整度的分子内差异。共聚物在茂金属催化剂的存在下制备。

5. 发明申请

WO2011059431A1 POLYOLEFIN ADHESIVE COMPOSITIONS 审中-公开
标题翻译：聚烯烃胶粘组合物
公开(公告)号：WO2011059431A1
公开(公告)日：2011-05-19
申请号：PCT/US2009/064035
申请日：2009-11-11
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , JIANG, Peijun , RODRIGUEZ, George , SHIPLEY, Fran, A. , MEHTA, Aspy, K.
发明人： JIANG, Peijun , RODRIGUEZ, George , SHIPLEY, Fran, A. , MEHTA, Aspy, K.
IPC分类号： C08L23/14 , C09J123/14
CPC分类号： C08L23/142 , C08L51/003 , C08L91/06 , C08L2666/02 , C08L2666/24 , C09J123/142
摘要： An adhesive and method for hot melt application. The adhesive comprises polyolefin base polymer, from 1 to 10 wt% of at least one functionalized polyolefin, and from 1 to 15 wt% of a wax, based on the total weight of the polyolefin base polymer, functionalized polyolefin and wax, wherein the wax has a weight average molecular weight at least 8% of the weight average molecular weight of the polyolefin base polymer, viscosity at 190°C of 60 mPa•s or more, and a crystallization temperature greater than the polyolefin base polymer and greater than 100°C, and wherein the adhesive has at least 5% fiber tear at 2°C, at least 50% fiber tear at 25°C, and a characteristic set time of less than 3 seconds.
摘要翻译：一种用于热熔胶应用的粘合剂和方法。基于聚烯烃基础聚合物，官能化聚烯烃和蜡的总重量，粘合剂包括聚烯烃基聚合物，1至10重量％的至少一种官能化聚烯烃和1至15重量％的蜡，其中蜡重均分子量为聚烯烃基聚合物重均分子量的至少8％，190℃下的粘度为60mPa·s以上，结晶温度大于聚烯烃基聚合物且大于100° 并且其中所述粘合剂在2℃下具有至少5％的纤维撕裂，在25℃下至少50％的纤维撕裂，以及小于3秒的特征设定时间。

6. 发明申请

WO2010138142A1 POLYOLEFIN ADHESIVE COMPOSITIONS 审中-公开
标题翻译：聚氨酯胶粘剂组合物
公开(公告)号：WO2010138142A1
公开(公告)日：2010-12-02
申请号：PCT/US2009/067328
申请日：2009-12-09
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , RODRIGUEZ, George , SHIPLEY, Fran, A. , JIANG, Peijun
发明人： RODRIGUEZ, George , SHIPLEY, Fran, A. , JIANG, Peijun
IPC分类号： C09J123/02
CPC分类号： C09J5/06 , C08L23/02 , C08L23/06 , C08L51/003 , C08L51/06 , C08L91/06 , C08L2666/02 , C09J123/142
摘要： An adhesive and method for hot melt adhesive application. The adhesive comprises polyolefin base polymer and from 1 to 15 wt% of a at least two wax components, based on the total weight of the polyolefin base polymer and the at least two wax components, wherein the at least two wax components comprise a first wax component having a relatively low weight average molecular weight at least 1000 g/mole less than a second wax component having a relatively high weight average molecular weight. The adhesive may have at least 50% fiber tear at 25°C, and a characteristic set time of less than 3 seconds. The adhesive may also include from 1 to 10 wt% of at least one functionalized polyolefin.
摘要翻译：一种用于热熔胶应用的粘合剂和方法。基于聚烯烃基础聚合物和至少两种蜡组分的总重量，粘合剂包含聚烯烃基聚合物和1至15重量％的至少两种蜡组分，其中至少两种蜡组分包含第一蜡具有比具有相对高的重均分子量的第二蜡组分的重均分子量相对低至少1000g /摩尔的组分。粘合剂在25℃下可能具有至少50％的纤维撕裂，并且特征设定时间小于3秒。粘合剂还可以包含1至10重量％的至少一种官能化聚烯烃。

7. 发明申请

WO2010014344A2 CATALYST SYSTEM AND PROCESS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：催化剂体系和烯烃聚合方法
公开(公告)号：WO2010014344A2
公开(公告)日：2010-02-04
申请号：PCT/US2009/049528
申请日：2009-07-02
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , CROWTHER, Donna, J. , JIANG, Peijun , RODRIGUEZ, George
发明人： CROWTHER, Donna, J. , JIANG, Peijun , RODRIGUEZ, George
IPC分类号： C08F10/06 , C08F4/6592 , B01J31/02 , B01J31/14 , B01J31/16 , B01J31/22
CPC分类号： C08F10/06 , B01J31/0239 , B01J31/0268 , B01J31/146 , B01J31/1616 , B01J31/2295 , B01J2231/122 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F110/06 , C08F210/06 , C08F210/16 , Y10S526/943 , C08F4/65908 , C08F2500/08 , C08F2500/20 , C08F2500/03 , C08F2500/17
摘要： The present application relates to a new catalyst system for the polymerization of olefins, comprising a new ionic activator having the formula: [R 1 R 2 R 3 AH] + [Y]", wherein [Y] - is a non- coordinating anion (NCA), A is nitrogen or phosphorus, R 1 and R 2 are hydrocarbyl groups or heteroatom-containing hydrocarbyl groups and together form a first, 3- to 10-membered non- aromatic ring with A, wherein any number of adjacent ring members may optionally be members of at least one second, aromatic or aliphatic ring or aliphatic and/or aromatic ring system of two or more rings, wherein said at least one second ring or ring system is fused to said first ring, and wherein any atom of the first and/or at least one second ring or ring system is a carbon atom or a heteroatom and may be substituted independently by one or more substituents selected from the group consisting of a hydrogen atom, halogen atom, C 1 to C 10 alkyl, C 5 to C 15 aryl, C 6 to C 25 arylalkyl, and C 6 to C 25 alkylaryl, and R 3 is a hydrogen atom or C 1 to C 10 alkyl, or R 3 is a C 1 to C 10 alkylene group that connects to said first ring and/or to said at least one second ring or ring system. The present application also relates to a process for the polymerization of olefins, preferably propylene, using this and other catalyst systems, as well as to polymers made by said process.
摘要翻译：本申请涉及用于烯烃聚合的新型催化剂体系，其包含具有下式的新的离子活化剂：[R 1 R 2 R 3 A H] + [Y]“，其中[Y] - 为非配位阴离子（NCA），A为氮或磷，R 1和R 2是烃基或含杂原子的烃基，并且与A一起形成第一个3至10元非芳族环，其中任何数量的相邻环成员可以任选地是至少一个第二个是两个或更多个环的芳族或脂族环或脂族和/或芳族环系，其中所述至少一个第二环或环系与所述第一环稠合，并且其中第一和/或至少一个第二环或环系是碳原子或杂原子，并且可以被一个或多个选自氢原子，卤素原子，C 1至C 10烷基，C 5至C 15芳基，C 6至C 25芳烷基，和C 6至C 25烷基芳基，R 3是氢基原子或C1至C10烷基，或R3是连接到所述第一环和/或所述至少一个第二环或环系统的C1至C10亚烷基。本申请还涉及使用这种和其它催化剂体系以及通过所述方法制备的聚合物来聚合烯烃，优选丙烯的方法。

8. 发明申请

WO2007018743A1 FLUOROPHENYLBORATES AND THEIR USE AS ACTIVATORS IN CATALYST SYSTEMS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：氟聚合物及其在催化剂体系中用作烯烃聚合的活化剂
公开(公告)号：WO2007018743A1
公开(公告)日：2007-02-15
申请号：PCT/US2006/023404
申请日：2006-06-16
申请人： EXXONMOBIL CHEMICAL PATENTS, INC. , RODRIGUEZ, George
发明人： RODRIGUEZ, George
IPC分类号： C07F5/02 , C08F10/00 , C08F4/00
CPC分类号： C07F5/027
摘要： A fluorophenylborate useful as an activator for an olefin polymerization catalyst is represented by the formula: Ct + [B-(Ar f R n ) 4 ] - where Ct + is a cation capable of extracting an alkyl group from, or breaking a carbon-metal bond of, an organo metallic compound; Ar f is a fluorophenyl group; n is 1 or 2; and each R is independently selected from a fluorophenyl group and a fluoronaphthyl group, provided that when n=l, each R group is connected at the 3- position relative the connection between the associated Ar f group and the boron atom and, when n=2; the R groups are connected at the 3-position and the 5- position respectively relative the connection between the associated Ar f group and the boron atom.
摘要翻译：可用作烯烃聚合催化剂的活化剂的氟苯基硼酸盐由下式表示：Ct + + - - - （B）其中Ct + +是能够从有机金属化合物中提取烷基或断裂碳 - 金属键的阳离子 ; 芳基是氟苯基; n为1或2; 并且每个R独立地选自氟苯基和氟萘基，条件是当n = 1时，每个R基相对于相关联的ArF 1基团和当n = 2时， R基分别相对于相关联的Ar 1组和硼原子之间的连接在3位和5位相连。

9. 发明申请

WO2005075526A3 HYDROPHOBIZATION AND SILICA FOR SUPPORTED CATALYST 审中-公开
标题翻译：负载型催化剂的疏水化和二氧化硅
公开(公告)号：WO2005075526A3
公开(公告)日：2005-11-03
申请号：PCT/US2004040859
申请日：2004-12-07
申请人： EXXONMOBIL CHEM PATENTS INC , RODRIGUEZ GEORGE , SPECA ANTHONY , KUCHTA MATTHEW C , MCCONVILLE DAVID H , BURKHARDT TERRY J
发明人： RODRIGUEZ GEORGE , SPECA ANTHONY , KUCHTA MATTHEW C , MCCONVILLE DAVID H , BURKHARDT TERRY J
IPC分类号： C08F4/6592 , C08F110/06 , C08F4/02 , C08F4/643 , C08F10/06
CPC分类号： C08F110/06 , C08F4/65927 , Y10T428/31678 , C08F4/65908 , C08F4/65916 , C08F2500/18 , C08F2500/12
摘要： This invention relates to a catalyst support comprising the result of the combination of: (a) a support comprising hydroxyl groups; (b) a capping agent comprising a boron containing Lewis acid; and (c) an ionic activator, wherein at least some of the capping agent does not form a support bound activator.
摘要翻译：本发明涉及催化剂载体，其包含以下组合的结果：（a）包含羟基的载体; （b）包含含硼路易斯酸的封端剂; 和（c）离子活化剂，其中至少一些封端剂不形成载体结合的活化剂。

10. 发明申请

WO03000740A3 POLYOLEFINS MADE BY CATALYST COMPRISING A NONCOORDINATING ANION AND ARTICLES COMPRISING THEM 审中-公开
标题翻译：由包含非离子阴离子的催化剂制成的聚烯烃和包含它们的制品
公开(公告)号：WO03000740A3
公开(公告)日：2003-04-10
申请号：PCT/US0218610
申请日：2002-05-16
申请人： EXXONMOBIL CHEM PATENTS INC , PEHLERT GEORGE J , RODRIGUEZ GEORGE , HARRINGTON BRUCE A
发明人： PEHLERT GEORGE J , RODRIGUEZ GEORGE , HARRINGTON BRUCE A
IPC分类号： C08F2/00 , C08F4/6592 , C08F10/00 , C08F210/16 , C09K11/06 , B32B15/08 , H01B3/44
CPC分类号： C09K11/06 , C08F4/65927 , C08F10/00 , C08F210/16 , Y10S526/943 , Y10T428/31692 , Y10T428/31855 , Y10T428/31938 , C08F4/65908 , C08F210/08 , C08F2500/12 , C08F2500/08 , C08F2500/17 , C08F210/14 , C08F210/06
摘要： Polymers made by transition metal catalyst systems comprising a bulky noncoordinating anion (NCA) as cocatalyst component. In comparison to polymers containing a conventional NCA, these polymers show a considerably lower dielectric loss, making them suitable for insulation applications such as for power cable.
摘要翻译：由过渡金属催化剂体系制成的聚合物包含庞大的非配位阴离子（NCA）作为助催化剂组分。与含有常规NCA的聚合物相比，这些聚合物具有相当低的介电损耗，使其适用于电力电缆等绝缘应用。

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