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1. 发明申请

WO2012134721A2 VINYL TERMINATED HIGHER OLEFIN POLYMERS AND METHODS TO PRODUCE THEREOF 审中-公开
标题翻译：乙烯基封端的高级烯烃聚合物及其制备方法
公开(公告)号：WO2012134721A2
公开(公告)日：2012-10-04
申请号：PCT/US2012/027690
申请日：2012-03-05
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , HOLTCAMP, Matthew, W. , RUFF, Charles, J. , CROWTHER, Donna, J. , HAGADORN, John, R. , BRANT, Patrick
发明人： HOLTCAMP, Matthew, W. , RUFF, Charles, J. , CROWTHER, Donna, J. , HAGADORN, John, R. , BRANT, Patrick
IPC分类号： C08F10/14 , C08F210/16 , C08F4/64 , C08F4/6592
CPC分类号： C08F10/14 , C08F4/65908 , C08F4/65912 , C08F210/14 , C08F4/65925 , C08F4/65927 , C08F2500/02
摘要： This invention relates to higher olefin vinyl terminated polymers having an Mn of at least 200 g/mol (measured by lR NMR) including of one or more C4 to C4Q higher olefin derived units, where the higher olefin vinyl terminated polymer comprises substantially no propylene derived units; and wherein the higher olefin polymer has at least 5% allyl chain ends and processes for the production thereof. These vinyl terminated higher olefin polymers may optionally include ethylene derived units.
摘要翻译：本发明涉及具有至少200g / mol（通过1 H NMR测量）的Mn的高级烯烃乙烯基封端的聚合物，其包括一种或多种C 4 -C 40高级烯烃衍生的单元，其中高级烯烃乙烯基封端的聚合物基本不含丙烯衍生的单元并且其中高级烯烃聚合物具有至少5％的烯丙基链端和用于其生产的方法。这些乙烯基封端的高级烯烃聚合物可以任选地包括乙烯衍生的单元。

2. 发明申请

WO2012134718A3 AMINE FUNCTIONALIZED POLYOLEFIN AND METHODS FOR PREPARATION THEREOF 审中-公开
公开(公告)号：WO2012134718A3
公开(公告)日：2012-10-04
申请号：PCT/US2012/027683
申请日：2012-03-05
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , HAGADORN, John, R. , CROWTHER, Donna, J. , GANESH, Renuka, N. , BRANT, Patrick
发明人： HAGADORN, John, R. , CROWTHER, Donna, J. , GANESH, Renuka, N. , BRANT, Patrick
IPC分类号： C08F8/32 , C08F10/06 , C08F4/64 , C08L23/36
摘要： This invention relates to a process to functionalize polyolefins comprising contacting a transition metal amide catalyst with an amine (preferably a secondary amine), and one or more vinyl terminated materials, preferably one or more vinyl terminated polyolefins. This invention further relates to the amine-functionalized polyolefins produced thereby.

3. 发明申请

WO2011014215A1 PROCESS USING POLYPROPYLENE OR POLY (ETHYLENE CO PROPYLENE) SUCCINIMIDE AS ANTIFOULING ADDITIVE IN PETROLEUM REFINERY PROCESSES 审中-公开
标题翻译：在石油炼制工艺中使用聚丙烯或聚（乙烯醇丙烯）磺酰胺作为反应添加剂的方法
公开(公告)号：WO2011014215A1
公开(公告)日：2011-02-03
申请号：PCT/US2009/068837
申请日：2009-12-18
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY , NG, Man, Kit , BRONS, Glen, B. , LEVINE, Steven, W. , MALLORY, Kevin , CHENG, Hong , BRANT, Patrick , CROWTHER, Donna, J.
发明人： NG, Man, Kit , BRONS, Glen, B. , LEVINE, Steven, W. , MALLORY, Kevin , CHENG, Hong , BRANT, Patrick , CROWTHER, Donna, J.
IPC分类号： C10G75/42 , C10G9/18 , C10G7/10
CPC分类号： C10G75/04 , C07D307/60 , C09K15/30 , C10G9/00 , C10G2300/1033 , C10G2300/4075 , C10G2300/80 , C10L1/2383
摘要： The present invention provides a method for reducing fouling, including particulate-induced fouling, in a hydrocarbon refining process including the steps of providing a crude hydrocarbon for a refining process; adding at least one polyalkyl succinic anhydride derivative additive disclosed herein. The additive can be complexed with a boronating agent, such as boric acid, to yield a boron-containing polyalkyl succinic anhydride derivative.
摘要翻译：本发明提供了一种在烃精炼方法中减少包括颗粒引起的结垢的结垢的方法，包括以下步骤：提供用于精制方法的粗烃; 加入本文公开的至少一种聚烷基琥珀酸酐衍生物添加剂。添加剂可与硼化剂如硼酸络合，得到含硼聚烷基琥珀酸酐衍生物。

4. 发明申请

WO2010114673A1 MICROPOROUS MEMBRANES AND METHODS FOR PRODUCING AND USING SUCH MEMBRANES 审中-公开
标题翻译：微孔膜和用于生产和使用这种膜的方法
公开(公告)号：WO2010114673A1
公开(公告)日：2010-10-07
申请号：PCT/US2010/026423
申请日：2010-03-05
申请人： TONEN CHEMICAL CORPORATION , ISHIHARA, Takeshi , MIYAOKA, Satoshi , KONO, Koichi , YAMADA, Kazuhiro , CROWTHER, Donna, J. , BRANT, Patrick
发明人： ISHIHARA, Takeshi , MIYAOKA, Satoshi , KONO, Koichi , YAMADA, Kazuhiro , CROWTHER, Donna, J. , BRANT, Patrick
IPC分类号： B01D71/26 , H01M2/16
CPC分类号： B01D71/26 , B01D71/76 , B29C47/00 , B32B27/32 , H01M2/14 , H01M2/16 , H01M2/164 , H01M2/1653
摘要： The invention relates to microporous polymeric membranes suitable for use as battery separator film. The invention also relates to a method for producing such a membrane, batteries containing such membranes as battery separators, methods for making such batteries, and methods for using such batteries.
摘要翻译：本发明涉及适合用作电池隔膜的微孔聚合物膜。本发明还涉及一种生产这种膜的方法，包含诸如电池隔板的膜的电池，制造这种电池的方法以及使用这种电池的方法。

5. 发明申请

WO2010014344A2 CATALYST SYSTEM AND PROCESS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：催化剂体系和烯烃聚合方法
公开(公告)号：WO2010014344A2
公开(公告)日：2010-02-04
申请号：PCT/US2009/049528
申请日：2009-07-02
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , CROWTHER, Donna, J. , JIANG, Peijun , RODRIGUEZ, George
发明人： CROWTHER, Donna, J. , JIANG, Peijun , RODRIGUEZ, George
IPC分类号： C08F10/06 , C08F4/6592 , B01J31/02 , B01J31/14 , B01J31/16 , B01J31/22
CPC分类号： C08F10/06 , B01J31/0239 , B01J31/0268 , B01J31/146 , B01J31/1616 , B01J31/2295 , B01J2231/122 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F110/06 , C08F210/06 , C08F210/16 , Y10S526/943 , C08F4/65908 , C08F2500/08 , C08F2500/20 , C08F2500/03 , C08F2500/17
摘要： The present application relates to a new catalyst system for the polymerization of olefins, comprising a new ionic activator having the formula: [R 1 R 2 R 3 AH] + [Y]", wherein [Y] - is a non- coordinating anion (NCA), A is nitrogen or phosphorus, R 1 and R 2 are hydrocarbyl groups or heteroatom-containing hydrocarbyl groups and together form a first, 3- to 10-membered non- aromatic ring with A, wherein any number of adjacent ring members may optionally be members of at least one second, aromatic or aliphatic ring or aliphatic and/or aromatic ring system of two or more rings, wherein said at least one second ring or ring system is fused to said first ring, and wherein any atom of the first and/or at least one second ring or ring system is a carbon atom or a heteroatom and may be substituted independently by one or more substituents selected from the group consisting of a hydrogen atom, halogen atom, C 1 to C 10 alkyl, C 5 to C 15 aryl, C 6 to C 25 arylalkyl, and C 6 to C 25 alkylaryl, and R 3 is a hydrogen atom or C 1 to C 10 alkyl, or R 3 is a C 1 to C 10 alkylene group that connects to said first ring and/or to said at least one second ring or ring system. The present application also relates to a process for the polymerization of olefins, preferably propylene, using this and other catalyst systems, as well as to polymers made by said process.
摘要翻译：本申请涉及用于烯烃聚合的新型催化剂体系，其包含具有下式的新的离子活化剂：[R 1 R 2 R 3 A H] + [Y]“，其中[Y] - 为非配位阴离子（NCA），A为氮或磷，R 1和R 2是烃基或含杂原子的烃基，并且与A一起形成第一个3至10元非芳族环，其中任何数量的相邻环成员可以任选地是至少一个第二个是两个或更多个环的芳族或脂族环或脂族和/或芳族环系，其中所述至少一个第二环或环系与所述第一环稠合，并且其中第一和/或至少一个第二环或环系是碳原子或杂原子，并且可以被一个或多个选自氢原子，卤素原子，C 1至C 10烷基，C 5至C 15芳基，C 6至C 25芳烷基，和C 6至C 25烷基芳基，R 3是氢基原子或C1至C10烷基，或R3是连接到所述第一环和/或所述至少一个第二环或环系统的C1至C10亚烷基。本申请还涉及使用这种和其它催化剂体系以及通过所述方法制备的聚合物来聚合烯烃，优选丙烯的方法。

6. 发明申请

WO2009045625A1 OLEFIN POLYMERIZATION CATALYSTS, THEIR SYNTHESIS AND USE 审中-公开
标题翻译： OLEFIN聚合催化剂，其合成和使用
公开(公告)号：WO2009045625A1
公开(公告)日：2009-04-09
申请号：PCT/US2008/071940
申请日：2008-08-01
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , PEREZ, Celestino, M. , CROWTHER, Donna, J.
发明人： PEREZ, Celestino, M. , CROWTHER, Donna, J.
IPC分类号： C08F10/00 , C08F4/70
CPC分类号： C08F10/00 , C08F110/02 , C08F4/025 , C08F2500/04 , C08F2500/02 , C08F2500/23 , C08F2500/03 , C08F4/7042
摘要： A catalyst system for the polymerization or copolymerization of α-olefins comprises a bis(imino)pyridyl complex of a transition metal on a support having an aluminum halide and/or an alkylaluminum halide chemically or physically bonded thereto.
摘要翻译：用于α-烯烃的聚合或共聚的催化剂体系包括在具有卤化铝和/或与其化学或物理结合的烷基卤化铝的载体上的过渡金属的双（亚氨基）吡啶基复合物。

7. 发明申请

WO2012134716A3 BLOCK COPOLYMERS FROM SILYLATED VINYL TERMINATED MACROMERS 审中-公开
标题翻译：硅烷化乙烯端基大分子嵌段共聚物
公开(公告)号：WO2012134716A3
公开(公告)日：2012-11-22
申请号：PCT/US2012027677
申请日：2012-03-05
申请人： EXXONMOBIL CHEM PATENTS INC , CROWTHER DONNA J , LOVELL JACQUELINE A , BRANT PATRICK
发明人： CROWTHER DONNA J , LOVELL JACQUELINE A , BRANT PATRICK
IPC分类号： C08F8/00 , B01J31/12 , C07F7/00 , C08F10/00
CPC分类号： C08F8/42 , C08F299/00 , C08F2810/40 , C08F10/00
摘要： This invention relates to a process to functionalize polyolefins comprising contacting a metallocene catalyst with a difunctional diblock hydrosilane, and one or more vinyl terminated polyolefins. This invention further relates to the diblock hydrosilane- functionalized polyolefins produced thereby.
摘要翻译：本发明涉及使聚烯烃官能化的方法，其包括使茂金属催化剂与双官能二嵌段氢硅烷和一种或多种乙烯基封端的聚烯烃接触。本发明还涉及由此制得的二嵌段含氢硅烷官能化聚烯烃。

8. 发明申请

WO2012134717A2 VINYL TERMINATED HIGHER OLEFIN POLYMERS AND METHODS TO PRODUCE THEREOF 审中-公开
标题翻译：乙烯基封端的高级烯烃聚合物及其制备方法
公开(公告)号：WO2012134717A2
公开(公告)日：2012-10-04
申请号：PCT/US2012/027682
申请日：2012-03-05
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , CROWTHER, Donna, J. , HOLTCAMP, Matthew, W. , HAGADORN, John, R. , RUFF, Charles, J. , RODRIGUEZ, George , BRANT, Patrick
发明人： CROWTHER, Donna, J. , HOLTCAMP, Matthew, W. , HAGADORN, John, R. , RUFF, Charles, J. , RODRIGUEZ, George , BRANT, Patrick
IPC分类号： C08F210/14 , C08F210/06 , C08L23/18 , C08F4/64 , C10M107/10
CPC分类号： C10M107/10 , C08F4/65908 , C08F4/65925 , C08F4/65927 , C08F210/06 , C08F210/14 , C08L2314/06 , C10M2205/0245 , C10M2205/0265 , C10M2205/0285 , C10N2220/021 , C10N2220/022 , C10N2220/028 , C10N2270/00 , C08F2500/17
摘要： This invention relates to a vinyl terminated higher olefin copolymer having an Mn of 300 g/mol or more (measured by 1 H NMR) comprising: (i) from about 20 to about 99.9 mol% of at least one C 5 to C 40 higher olefin monomer; and (ii) from about 0.1 to about 80 mol% of propylene; wherein the higher olefin copolymer has at least 40% allyl chain ends. The copolymer may also have an isobutyl chain end to allyl chain end ratio of less than 0.7: 1 and/or an allyl chain end to vinylidene chain end ratio of greater than 2:1.
摘要翻译：本发明涉及Mn为300g / mol或更高（通过1 H NMR测量）的乙烯基封端的高级烯烃共聚物，其包含：（i）约20 至约99.9摩尔％的至少一种C≡5至C≡40高级烯烃单体; 和（ii）约0.1至约80摩尔％的丙烯; 其中高级烯烃共聚物具有至少40％的烯丙基链端。该共聚物还可具有小于0.7：1的异丁基链端与烯丙基链端部比例和/或大于2：1的烯丙基链端部与乙烯叉基链端部比率。

9. 发明申请

WO2009155471A8 HIGH VINYL TERMINATED PROPYLENE BASED OLIGOMERS 审中-公开
标题翻译：高乙烯终止丙烯基低聚物
公开(公告)号：WO2009155471A8
公开(公告)日：2010-05-14
申请号：PCT/US2009047880
申请日：2009-06-19
申请人： EXXONMOBIL CHEM PATENTS INC , BRANT PATRICK , CROWTHER DONNA J , NARVAEZ ANDREW G JR
发明人： BRANT PATRICK , CROWTHER DONNA J , NARVAEZ ANDREW G JR
IPC分类号： C08F210/16 , C08F4/65 , C08F4/6592 , C08F8/00 , C08F210/06
CPC分类号： C08F210/16 , C08F4/65925 , C08F4/65927 , C08F210/06 , C08F4/65908 , C08F2500/20 , C08F2500/02
摘要： This invention relates to a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol% propylene and 10 to 90 mol% of ethylene, wherein the oligomer has at least X% allyl chain ends, where: I) X = (-0.94 (mole% ethylene incorporated) + 100), when 10 to 60 mole% ethylene is present in the co-oligomer, and 2) X = 45, when greater than 60 and less than 70 mole% ethylene is present in the co-oligomer, and 3) X = (1.83* (mole% ethylene incorporated) -83), when 70 to 90 mole% ethylene is present in the co-oligomer. This invention also relates to a homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum. This invention also relates to a process of making homo-oligomer, comprising propylene, wherein the productivity is greater than 4500 g/mmol Hf (or Zr)/hour.
摘要翻译：本发明涉及具有300至30,000g / mol的Mn的共低聚物，其包含10至90mol％的丙烯和10至90mol％的乙烯，其中所述低聚物具有至少X％的烯丙基链端，其中：I）当共聚低聚物中存在10至60摩尔％的乙烯时，X =（ - 0.94（摩尔％乙烯掺入）+ 100），和2）X = 45，当存在大于60且小于70摩尔％的乙烯存在时在共低聚物中，3）X =（1.83 *（摩尔％乙烯掺入）-83），当共聚低聚物中存在70至90摩尔％的乙烯时。本发明还涉及包含丙烯的均聚物，其中低聚物具有：至少93％的烯丙基链端，约500至约20,000g / mol的Mn，异丁基链端至烯丙基乙烯基的比例为0.8： 1至1.2：1.0和小于100ppm的铝。本发明还涉及制备包含丙烯的均聚物的方法，其中生产率大于4500g / mmol Hf（或Zr）/小时。

10. 发明申请

WO2012134716A8 BLOCK COPOLYMERS FROM SILYLATED VINYL TERMINATED MACROMERS 审中-公开
标题翻译：苯乙烯封端的MACROMERS嵌段共聚物
公开(公告)号：WO2012134716A8
公开(公告)日：2013-10-03
申请号：PCT/US2012027677
申请日：2012-03-05
申请人： EXXONMOBIL CHEM PATENTS INC , CROWTHER DONNA J , LOVELL JACQUELINE A , BRANT PATRICK
发明人： CROWTHER DONNA J , LOVELL JACQUELINE A , BRANT PATRICK
IPC分类号： C08F8/00 , B01J31/12 , C07F7/00 , C08F10/00
CPC分类号： C08F8/42 , C08F299/00 , C08F2810/40 , C08F10/00
摘要： This invention relates to a process to functionalize polyolefins comprising contacting a metallocene catalyst with a difunctional diblock hydrosilane, and one or more vinyl terminated polyolefins. This invention further relates to the diblock hydrosilane-functionalized polyolefins produced thereby.
摘要翻译：本发明涉及使聚烯烃官能化的方法，包括使茂金属催化剂与双官能二嵌段氢化硅烷和一种或多种乙烯基封端的聚烯烃接触。本发明还涉及由此制备的二嵌段氢硅烷官能化的聚烯烃。

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