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2. 发明申请

WO2011121078A1 FLUOROPOLYMER-BASED HYBRID ORGANIC/INORGANIC COMPOSITES 审中-公开
标题翻译：基于荧光聚合物的混合有机/无机复合材料
公开(公告)号：WO2011121078A1
公开(公告)日：2011-10-06
申请号：PCT/EP2011/055019
申请日：2011-03-31
申请人： SOLVAY SOLEXIS S.P.A. , ABUSLEME, Julio A. , PIERI, Riccardo , PAGIN, Ivan
发明人： ABUSLEME, Julio A. , PIERI, Riccardo , PAGIN, Ivan
IPC分类号： C08F214/18
CPC分类号： C08F214/18 , B01D67/0079 , B01D69/148 , B01D71/022 , B01D71/027 , B01D71/34 , B01D71/70 , B01D2323/38 , B82Y30/00 , C08F8/00 , C08F214/182 , C08F214/186 , C08F214/225 , C08F214/245 , C08F220/06 , C08F220/20 , C08F2800/10 , C08F2810/20 , C08F2810/50 , C08J5/005 , C08J5/2281 , C08J2333/10 , C08K3/346 , C09D127/16 , H01M2/145 , H01M2/166 , H01M8/1046 , Y02P70/56 , C08F8/12 , C08F8/42 , C08F210/02 , C08K3/36
摘要： The invention pertains to a process for manufacturing a fluoropolymer hybrid organic/inorganic composite, said process comprising: (i) providing a mixture of: - at least one fluoropolymer comprising recurring units derived from at least one (meth)acrylic monomer [monomer (MA)] of formula: wherein each of R1, R2, R3, equal or different from each other, is independently a hydrogen atom or a C 1 -C 3 hydrocarbon group, and R OH is a hydrogen atom or a C 1-C 5 hydrocarbon moiety comprising at least one hydroxyl group [polymer (F)]; and - at least one metal compound [compound (M)] of formula: X 4-m AY m wherein m is an integer from 1 to 4, and, according to certain embodiments, from 1 to 3, A is a metal selected from the group consisting of Si, Ti and Zr, Y is a hydrolysable group, X is a hydrocarbon group, optionally comprising one or more functional groups; - reacting at least a fraction of hydroxyl groups of the ROH groups of said monomer (MA) of said polymer (F) with at least a fraction of said compound (M), so as to obtain a grafted polymer comprising pendant -Y m-1 AX 4-m groups, with m, Y, A and X having same meaning as above detailed; - hydrolyzing and/or polycondensing compound (M) and/or pendant -Y m-1 AX 4-m groups, as above detailed to yield a fluoropolymer hybrid organic/inorganic composite comprising inorganic domains, to fluoropolymer hybrid organic/inorganic composites obtained therefrom and to the use of the same in several fields of use.
摘要翻译：本发明涉及一种制备含氟聚合物杂化有机/无机复合材料的方法，所述方法包括：（i）提供以下混合物： - 至少一种含有至少一种（甲基）丙烯酸单体衍生的重复单元的含氟聚合物[单体（MA ）]，其中R 1，R 2，R 3彼此相同或不同，各自独立地为氢原子或C1-C3烃基，ROH为氢原子或C 1 -C 5烃部分，其包含在至少一个羟基[聚合物（F）]; 和 - 至少一种式：X4-mAYm的金属化合物[化合物（M）]，其中m是1至4的整数，并且根据某些实施方案，从1至3，A是选自以下的金属：的Si，Ti和Zr，Y是可水解基团，X是烃基，任选地包含一个或多个官能团; - 将所述聚合物（F）的所述单体（MA）的ROH基团的至少一部分羟基与至少一部分所述化合物（M）反应，以获得包含侧基-Ym-1AX4的接枝聚合物 -m组，m，Y，A和X具有与上述相同的含义; - 水解和/或缩聚化合物（M）和/或侧基-Ym-1AX4-m基团，如上所述，以产生含有无机结构域的含氟聚合物杂化有机/无机复合材料，由其获得的含氟聚合物杂化有机/无机复合材料和在几个使用领域使用相同。

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