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1. 发明申请

WO2009144764A3 PHOTOCATALYTIC FLUIDIZED BED REACTOR WITH HIGH ILLUMINATION EFFICIENCY FOR PHOTOCATALYTIC OXIDATION PROCESSES 审中-公开
标题翻译：光化学氧化工艺具有高照明效率的光催化流化床反应器
公开(公告)号：WO2009144764A3
公开(公告)日：2010-05-06
申请号：PCT/IT2009000239
申请日：2009-05-29
申请人： UNIV DEGLI STUDI SALERNO , CIAMBELLI PAOLO , SANNINO DIANA , PALMA VINCENZO , VAIANO VINCENZO
发明人： CIAMBELLI PAOLO , SANNINO DIANA , PALMA VINCENZO , VAIANO VINCENZO
IPC分类号： B01J8/42 , B01D53/88 , B01J19/12 , B01J23/22 , B01J23/28 , B01J35/00 , C07C5/48 , C07C45/29 , C07C45/38
CPC分类号： B01J19/123 , B01D53/885 , B01D2255/20707 , B01D2255/20723 , B01D2255/20769 , B01D2255/2092 , B01D2255/802 , B01D2257/7022 , B01D2257/7027 , B01D2257/708 , B01D2259/804 , B01J8/42 , B01J23/22 , B01J23/28 , B01J35/004 , B01J2208/00513 , B01J2219/0871 , B01J2219/0875 , B01J2219/0892 , C07C5/48 , C07C45/002 , C07C2521/04 , C07C2521/06 , C07C2523/22 , C07C2523/28 , C07C2527/053 , Y02P20/52 , C07C15/46 , C07C15/04 , C07C47/06
摘要： The invention relates to the realization of synthesis of organic com¬ pounds or abatement of volatile organic compounds (VOCs) in gas-solid fluid- ised bed photocatalytic reactor with improved illumination efficiency. The photoreactor consists of a two-dimensional fluidized bed catalytic reactor with two walls transparent to ultraviolet radiation, by an illumination system based on an array of LEDs positioned near its external walls, and heated by Joule effect inside the catalytic bed to control the reaction temperature. Through the use of the reactor it is possible to carry out both partial and total oxidation re¬ actions with high activity and selectivity and, in addition, the illuminated cata¬ lyst surface area per unit of irradiated volume reaches values in the order of 106 m"1, significantly higher than the values typical of microreactors and slurry reactors. The photocatalytic system reported in the present invention is shown to have high illumination efficiency due to the use of UV-LEDs, which, ensur¬ ing a direction of light irradiation orthogonal to the emission point, minimize the dispersion of photons.
摘要翻译：本发明涉及在气体 - 固体流化床光催化反应器中合成有机物或减少挥发性有机化合物（VOC）的实现，其具有改善的照明效率。光反应器由具有两个对紫外线辐射透明的壁的二维流化床催化反应器组成，通过基于位于其外壁附近的LED阵列的照明系统，并且通过焦耳效应在催化床内加热以控制反应温度。通过使用反应器，可以以高活性和选择性进行部分氧化反应和全部氧化反应，此外，每单位辐照体积的照射量表达面积达到106 m量级 “1，显着高于微反应器和浆料反应器的典型值。本发明报道的光催化体系由于使用UV-LED而被证明具有高的照明效率，这确保了光照射的方向正交到发射点，使光子的分散最小化。

2. 发明申请

WO2010016027A3 AUTOTHERMIC CATALYTIC REACTOR WITH FLAT TEMPERATURE PROFILE 审中-公开
标题翻译：具有平坦温度曲线的自动催化反应器
公开(公告)号：WO2010016027A3
公开(公告)日：2010-04-22
申请号：PCT/IB2009053430
申请日：2009-08-06
申请人： UNIV DEGLI STUDI SALERNO , PALMA VINCENZO , CIAMBELLI PAOLO , PALO EMMA , VILLA PIERLUIGI
发明人： PALMA VINCENZO , CIAMBELLI PAOLO , PALO EMMA , VILLA PIERLUIGI
IPC分类号： C01B3/38 , B01J8/02 , C01B3/40
CPC分类号： B01J19/2485 , B01J23/002 , B01J23/464 , B01J35/04 , B01J37/0215 , B01J37/0225 , B01J2219/00063 , B01J2219/00117 , B01J2219/00157 , B01J2523/00 , C01B3/382 , C01B3/40 , C01B2203/0244 , C01B2203/0883 , C01B2203/0894 , C01B2203/1023 , C01B2203/1029 , C01B2203/1047 , C01B2203/1052 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1082 , C01B2203/1294 , C01B2203/1604 , Y02P20/129 , Y02P20/52 , B01J2523/25 , B01J2523/48 , B01J2523/822
摘要： The present invention relates to the make of a heterogeneous gas-solid catalytic reactor operated in autothermic conditions, characterised by a flat temperature profile. This invention concurrently uses three actions to optimise the operation of the ATR reactor both in terms of energy and of catalytic activity: the adoption of a specifically formulated catalyst so as to favour a "direct type" reaction mechanism, the use and the make of the catalyst on a structured support with a high porosity and tortuosity, and characterised by high thermal conductivity and the adoption of a radial flow geometry catalytic bed.
摘要翻译：本发明涉及在自热条件下操作的异相气体 - 固体催化反应器的制备，其特征在于平坦的温度分布。本发明同时采用三种动力来优化ATR反应器在能量和催化活性方面的运行：采用专门配制的催化剂，以有利于“直接型”反应机理，使用和制备催化剂在具有高孔隙率和弯曲度的结构化载体上，并且特征在于高导热性和采用径向流几何催化床。

3. 发明申请

WO2007144905A8 RETAINED MANDREL ROLLING MILL FOR SEAMLESS TUBES 审中-公开
标题翻译：用于无缝管的保留人造滚筒
公开(公告)号：WO2007144905A8
公开(公告)日：2008-02-28
申请号：PCT/IT2006000438
申请日：2006-06-12
申请人： SMS DEMAG INNSE S P A , MARIN PAOLO , RINALDI PATRIZIO , PALMA VINCENZO , BANDINI STEFANO
发明人： MARIN PAOLO , RINALDI PATRIZIO , PALMA VINCENZO , BANDINI STEFANO
IPC分类号： B21B17/04
CPC分类号： B21B17/04 , B21B27/024
摘要： A rolling mill (10) for processing seamless tubes comprises a plurality of rolling units (U) that are sequentially arranged along a rolling axis (L), each of which is provided with at least three removable working rolls (12), which are each equipped with a groove (12a) for accommodating the tube to be worked the rolling mill comprises a mandrel suitable to be fitted in the tube cavity during the process; the tube is worked by being sequentially passed, with the mandrel (22) fitted in the tube cavity, within the grooves (12a) of the rolls (12) of the rolling units (U) such that the outer diameter of the tube (T) is reduced; in order to have low capital and production costs, each roll (12) of each rolling unit (U) has a fixed nominal diameter.
摘要翻译：一种用于处理无缝管的轧机（10）包括沿轧制轴线（L）顺序布置的多个轧制单元（U），每个轧制单元设置有至少三个可移除的工作辊（12），每个可移除的工作辊配备有用于容纳要加工的管的槽（12a），该轧机包括适于在该过程期间装配在管腔中的心轴; 通过将心轴（22）装配在管腔中，在滚动单元（U）的辊（12）的槽（12a）内顺次通过管，使得管（T）的外径）降低了; 为了具有低的资本和生产成本，每个轧制单元（U）的每个辊（12）具有固定的公称直径。

4. 发明申请

WO2011083367A1 TUBE ROLLING PLANT 审中-公开
标题翻译：管道轧制厂
公开(公告)号：WO2011083367A1
公开(公告)日：2011-07-14
申请号：PCT/IB2010/050017
申请日：2010-01-05
申请人： SMS INNSE SPA , MARIN, Paolo , PALMA, Vincenzo , ZANELLA, Guido Emilio , GRASSINO, Jacopo
发明人： MARIN, Paolo , PALMA, Vincenzo , ZANELLA, Guido Emilio , GRASSINO, Jacopo
IPC分类号： B21B23/00
CPC分类号： B21B19/04 , B21B13/04 , B21B17/04 , B21B19/08 , B21B23/00 , B21B25/00 , B21B37/78 , B21B38/006 , B21B38/04 , B21B2013/025
摘要： The invention relates to a plant for performing the rolling of seamless tubes, typically with a large diameter. The plant comprises: a furnace for heating billets produced by means of continuous casting; a piercing mill for piercing longitudinally the billets so as to obtain a pierced blank; an expanding-elongating mill for expanding the diameter of the pierced blank and for elongating the pierced blank so as to obtain a semi-finished tube; a continuous main rolling mill of the type comprising stands with two or more rolls, in which the radial position of the rolls is adjustable, for performing rolling of a tube on a retained mandrel; a fixed-roll extracting-reducing mill positioned downstream of the main rolling mill and in series therewith, the extracting-reducing mill being designed to extract the tube from the mandrel and to define a predetermined value for the diameter of the tube; a sizing mill for defining the diameter of the finished tube, the sizing mill being of the type in which the radial position of the rolls is adjustable; and a cooling bed. The plant according to the invention also comprises a by-pass line for feeding the pierced blank leaving the piercing mill directly to the main rolling mill, thereby avoiding the expanding-elongating mill.
摘要翻译：本发明涉及一种用于执行通常具有大直径的无缝管的轧制的设备。该设备包括：用于加热通过连续铸造生产的坯料的炉; 一个穿孔机，用于纵向地穿过坯料，以获得一个穿孔的坯料; 用于使穿孔毛坯的直径扩大并延长穿孔毛坯以获得半成品管的扩展延伸研磨机; 这种类型的连续主轧机包括具有两个或更多个辊的机架，其中辊的径向位置是可调节的，用于在保持的心轴上执行管的滚动; 位于主轧机下游并与其串联的固定辊提取 - 减少磨机，所述提取还原机被设计成从所述心轴提取所述管并且限定所述管的直径的预定值; 用于限定成品管的直径的定径磨机，该定径磨机是可调整辊子的径向位置的类型; 和一个冷却床。根据本发明的设备还包括用于将穿孔毛坯输送到穿孔机的旁路管线直接送到主轧机，从而避免了膨胀延伸的磨机。

5. 发明申请

WO2009144764A2 PHOTOCATALYTIC FLUIDIZED BED REACTOR WITH HIGH ILLUMINATION EFFICIENCY FOR PHOTOCATALYTIC OXIDATION PROCESSES 审中-公开
标题翻译：光化学氧化工艺具有高照明效率的光催化流化床反应器
公开(公告)号：WO2009144764A2
公开(公告)日：2009-12-03
申请号：PCT/IT2009/000239
申请日：2009-05-29
申请人： UNIVERSITA' DEGLI STUDI DI SALERNO , CIAMBELLI, Paolo , SANNINO, Diana , PALMA, Vincenzo , VAIANO, Vincenzo
发明人： CIAMBELLI, Paolo , SANNINO, Diana , PALMA, Vincenzo , VAIANO, Vincenzo
IPC分类号： B01J8/42 , B01J19/12
CPC分类号： B01J19/123 , B01D53/885 , B01D2255/20707 , B01D2255/20723 , B01D2255/20769 , B01D2255/2092 , B01D2255/802 , B01D2257/7022 , B01D2257/7027 , B01D2257/708 , B01D2259/804 , B01J8/42 , B01J23/22 , B01J23/28 , B01J35/004 , B01J2208/00513 , B01J2219/0871 , B01J2219/0875 , B01J2219/0892 , C07C5/48 , C07C45/002 , C07C2521/04 , C07C2521/06 , C07C2523/22 , C07C2523/28 , C07C2527/053 , Y02P20/52 , C07C15/46 , C07C15/04 , C07C47/06
摘要： The invention relates to the realization of synthesis of organic com¬ pounds or abatement of volatile organic compounds (VOCs) in gas-solid fluid- ised bed photocatalytic reactor with improved illumination efficiency. The photoreactor consists of a two-dimensional fluidized bed catalytic reactor with two walls transparent to ultraviolet radiation, by an illumination system based on an array of LEDs positioned near its external walls, and heated by Joule effect inside the catalytic bed to control the reaction temperature. Through the use of the reactor it is possible to carry out both partial and total oxidation re¬ actions with high activity and selectivity and, in addition, the illuminated cata¬ lyst surface area per unit of irradiated volume reaches values in the order of 106 m"1, significantly higher than the values typical of microreactors and slurry reactors. The photocatalytic system reported in the present invention is shown to have high illumination efficiency due to the use of UV-LEDs, which, ensur¬ ing a direction of light irradiation orthogonal to the emission point, minimize the dispersion of photons.
摘要翻译：本发明涉及在气体 - 固体流化床光催化反应器中合成有机物或减少挥发性有机化合物（VOC）的实现，其具有改善的照明效率。光反应器由具有两个对紫外线辐射透明的壁的二维流化床催化反应器组成，通过基于位于其外壁附近的LED阵列的照明系统，并且通过焦耳效应在催化床内加热以控制反应温度。通过使用反应器，可以以高活性和选择性进行部分氧化反应和全部氧化反应，此外，每单位辐照体积的照射量表达面积达到106 m量级 “1，显着高于微反应器和浆料反应器的典型值。本发明报道的光催化体系由于使用UV-LED而被证明具有高的照明效率，这确保了光照射的方向正交到发射点，使光子的分散最小化。

6. 发明申请

WO1993020960A1 A ROLLING STAND FOR GENERIC ROLLING MILLS HAVING THREE OR MORE ADJUSTABLE DRIVEN ROLLS 审中-公开
标题翻译：具有三个或更多可调节驱动滚子的通用滚筒的滚动台
公开(公告)号：WO1993020960A1
公开(公告)日：1993-10-28
申请号：PCT/EP1993000898
申请日：1993-04-13
申请人： INNSE INNOCENTI ENGINEERING S.P.A. , PALMA, Vincenzo , CATTANEO, Filippo , CERNUSCHI, Ettore , BRIOSCHI, Roberto , BRIGNOLI, Maurizio , BOSSONEY, Roger , BERTELLI, Aristide
发明人： INNSE INNOCENTI ENGINEERING S.P.A.
IPC分类号： B21B13/10
CPC分类号： B21B13/103 , B21B17/04 , B21B17/14 , B21B25/04 , B21B2203/36
摘要： A rolling stand (5) comprises at least three driven rolls (27, 28, 29), having their axes (A1, A2, A3) of rotation which are concurrent one another and lie in a plane perpendicular to a rolling axis along which the rolling stand is located; these rolls (27, 28, 29) are mounted on respective lever arms (19, 20, 21) pivoted on a roll-carrier (10), substantially in the form of a frame, which can be pulled out of a C-shaped support structure (2a, 3) of the stand. The stand of this invention provides the possibility of driving the rolls (27, 28, 29) simultaneously with their single adjustment, together with a great simplification of the operations for their removing and replacement. As a consequence of its features, the stand of this invention can be usefully applied in tube rolling mills, either with or without mandrel, as well as in rolling mills for wires, rods and similar.

7. 发明申请

WO2011030273A3 PLANT FOR ROLLING TUBES 审中-公开
标题翻译：用于轧管的设备
公开(公告)号：WO2011030273A3
公开(公告)日：2011-03-17
申请号：PCT/IB2010/053993
申请日：2010-09-06
申请人： SMS INNSE SPA , PACHER, Marcello , PALMA, Vincenzo , ZANELLA, Guido, Emilio
发明人： PACHER, Marcello , PALMA, Vincenzo , ZANELLA, Guido, Emilio
IPC分类号： B21B23/00
摘要： The invention relates to a plant for rolling seamless tubes, typically with a large diameter. The plant comprises: a furnace for billets produced by means of continuous casting; a piercer for piercing the billets; a main continuous rolling mill of the retained-mandrel type with stands having three or more adjustable rolls; a fixed-roll extraction/reducing mill; means for measuring the wall thickness of the semi-finished tube; the main rolling mill being designed to adjust the rolls on the basis of the wall thickness of the tube leaving the extraction/reducing mill; a first intermediate furnace for tubes; an expander for expanding the diameter of the semi-finished tube to a value which is close to that of the finished tube; a reeler for ensuring a uniform surface finish inside the tube; a second intermediate furnace for tubes; a first sizing mill with stands having three or more adjustable rolls for defining the finished diameter; the first sizing mill comprising means for measuring the temperature of the incoming tube and means for measuring the diameter of the outgoing tube and being suitable for adjusting the rolls on the basis of the temperature and diameter; and a cooling bed. The plant also comprises, downstream of the extraction/reducing mill, a bifurcation generating a second line comprising a second sizing mill and a cooling bed. The second sizing mill is similar to the first sizing mill and is positioned off-line with respect to the extraction/reducing mill. The invention also relates to a method for rolling seamless tubes.
摘要翻译：本发明涉及通常具有大直径的用于轧制无缝管的设备。该设备包括：用于通过连续铸造生产的坯料的炉子; 用于刺穿钢坯的穿孔机; 具有三个或更多个可调节辊的机架的保持心轴型主连续轧机; 固定辊提取/还原磨机; 用于测量半成品管的壁厚的装置; 主轧机设计用于根据离开提取/减压磨机的管的壁厚来调节辊; 用于管的第一中间炉; 膨胀器，用于将半成品管的直径扩大到接近成品管的直径; 用于确保管内部均匀表面光洁度的卷边机; 用于管的第二中间炉; 具有三个或更多个可调辊的支架的第一定型碾磨机，用于限定成品直径; 第一定型碾磨机包括用于测量进入管温度的装置和用于测量输出管直径并且适于基于温度和直径调节辊的装置; 和一个冷床。该设备还包括在提取/还原磨机下游的分叉，该分叉产生包括第二定型碾磨机和冷却床的第二管线。第二台上浆机与第一台上浆机相似，并且相对于提取/减压机离线。本发明还涉及一种用于轧制无缝管的方法。

8. 发明申请

WO2011030273A2 PLANT FOR ROLLING TUBES 审中-公开
标题翻译：轧钢管厂
公开(公告)号：WO2011030273A2
公开(公告)日：2011-03-17
申请号：PCT/IB2010053993
申请日：2010-09-06
申请人： SMS INNSE SPA , PACHER MARCELLO , PALMA VINCENZO , ZANELLA GUIDO EMILIO
发明人： PACHER MARCELLO , PALMA VINCENZO , ZANELLA GUIDO EMILIO
IPC分类号： B21B23/00
CPC分类号： B21B23/00 , B21B17/04 , B21B17/14 , B21B19/04 , B21B19/08 , B21B19/10 , B21B38/006 , B21B38/04 , B21B39/18 , B21B43/00 , B21B45/004 , B21B2261/08 , B21B2261/20
摘要： The invention relates to a plant for rolling seamless tubes, typically with a large diameter. The plant comprises: a furnace for billets produced by means of continuous casting; a piercer for piercing the billets; a main continuous rolling mill of the retained-mandrel type with stands having three or more adjustable rolls; a fixed-roll extraction/reducing mill; means for measuring the wall thickness of the semi-finished tube; the main rolling mill being designed to adjust the rolls on the basis of the wall thickness of the tube leaving the extraction/reducing mill; a first intermediate furnace for tubes; an expander for expanding the diameter of the semi-finished tube to a value which is close to that of the finished tube; a reeler for ensuring a uniform surface finish inside the tube; a second intermediate furnace for tubes; a first sizing mill with stands having three or more adjustable rolls for defining the finished diameter; the first sizing mill comprising means for measuring the temperature of the incoming tube and means for measuring the diameter of the outgoing tube and being suitable for adjusting the rolls on the basis of the temperature and diameter; and a cooling bed. The plant also comprises, downstream of the extraction/reducing mill, a bifurcation generating a second line comprising a second sizing mill and a cooling bed. The second sizing mill is similar to the first sizing mill and is positioned off-line with respect to the extraction/reducing mill. The invention also relates to a method for rolling seamless tubes.
摘要翻译：本发明涉及通常具有大直径的无缝管的轧制设备。该设备包括：通过连续铸造生产的坯料炉; 用于穿孔的穿孔机; 具有三个或更多个可调节辊的支架的保持心轴型主连续轧机; 固定辊提取/还原磨; 用于测量半成品管壁厚度的方法; 主轧机被设计成基于离开提取/还原轧机的管的壁厚来调节轧辊; 第一个管中间炉; 用于将半成品管的直径扩大到接近成品管的直径的膨胀机; 用于确保管内均匀表面光洁度的卷取机; 用于管的第二中间炉; 具有用于限定最终直径的三个或更多个可调节辊的支架的第一上浆机; 第一定型磨机包括用于测量进入管的温度的装置和用于测量出口管的直径的装置，并且适于基于温度和直径来调节辊; 和一个冷却床。该设备还包括在提取/还原磨机下游的产生包括第二施胶机和冷却床的第二管线的分叉。第二种施胶机类似于第一种施胶机，并且相对于提取/还原磨机离线定位。本发明还涉及无缝管的轧制方法。

9. 发明申请

WO2010146546A1 TUBE ROLLING PLANT 审中-公开
标题翻译：管道轧制厂
公开(公告)号：WO2010146546A1
公开(公告)日：2010-12-23
申请号：PCT/IB2010/052699
申请日：2010-06-16
申请人： SMS INNSE SPA , MARIN, Paolo , PALMA, Vincenzo , GHISOLFI, Marco , ZANELLA, Guido Emilio , GRASSINO, Jacopo , BREGANTE, Alberto Vittorio Maria
发明人： MARIN, Paolo , PALMA, Vincenzo , GHISOLFI, Marco , ZANELLA, Guido Emilio , GRASSINO, Jacopo , BREGANTE, Alberto Vittorio Maria
IPC分类号： B21B23/00
CPC分类号： B21B23/00 , B21B17/04 , B21B19/04 , B21B19/08 , B21B25/00 , B21B38/006 , B21B38/04 , B21B45/004 , B21B2015/0014 , B21B2045/0227
摘要： The present invention relates to a plant for rolling a seamless tube, typically with a medium-to-large diameter. The plant comprises a main rolling mill with adjustable rolls for mandrel-rolling a semifinished tube. The plant also comprises a fixed-roll extracting/reducing mill positioned downstream of the main rolling mill and in series therewith. The extracting/reducing mill is designed to extract the semifinished tube from the mandrel and reduce its diameter to a predetermined value close to that desired for the finished tube. Finally, the plant comprises a adjustable-roll sizing mill. The sizing mill is positioned downstream of the extracting/reducing mill and off-line with respect to the latter. This sizing mill is designed to adjust the radial position of the rolls and define the diameter of the outgoing tube. The invention also relates to a method for rolling a seamless tube.
摘要翻译：本发明涉及一种通常具有中至大直径的无缝管的轧制设备。该设备包括一个主轧机，可调节轧辊，用于芯棒轧制半成品管。该设备还包括位于主轧机下游并与其串联的固定辊提取/还原磨机。提取/还原研磨机被设计成从心轴提取半成品管，并将其直径减小到接近成品管所需的预定值。最后，该设备包括一个可调节辊式上浆机。定型磨机位于提取/还原磨机的下游，并且相对于后者而离线。该定型磨机设计用于调节辊子的径向位置并限定出料管的直径。本发明还涉及一种轧制无缝管的方法。

10. 发明申请

WO2010016027A2 AUTOTHERMIC CATALYTIC REACTOR WITH FLAT TEMPERATURE PROFILE FOR THE PRODUCTION OF HYDROGEN FROM LIGHT HYDROCARBONS 审中-公开
标题翻译：具有平面温度曲线的自动催化反应器，用于从轻烃生产氢
公开(公告)号：WO2010016027A2
公开(公告)日：2010-02-11
申请号：PCT/IB2009/053430
申请日：2009-08-06
申请人： UNIVERSITA DEGLI STUDI DI SALERNO , PALMA, Vincenzo , CIAMBELLI, Paolo , PALO, Emma , VILLA, Pierluigi
发明人： PALMA, Vincenzo , CIAMBELLI, Paolo , PALO, Emma , VILLA, Pierluigi
IPC分类号： C01B3/38 , C01B3/40 , B01J8/02
CPC分类号： B01J19/2485 , B01J23/002 , B01J23/464 , B01J35/04 , B01J37/0215 , B01J37/0225 , B01J2219/00063 , B01J2219/00117 , B01J2219/00157 , B01J2523/00 , C01B3/382 , C01B3/40 , C01B2203/0244 , C01B2203/0883 , C01B2203/0894 , C01B2203/1023 , C01B2203/1029 , C01B2203/1047 , C01B2203/1052 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1082 , C01B2203/1294 , C01B2203/1604 , Y02P20/129 , Y02P20/52 , B01J2523/25 , B01J2523/48 , B01J2523/822
摘要： The present invention relates to the make of a heterogeneous gas-solid catalytic reactor operated in autothermic conditions, but characterised by a flat temperature profile, to be used in the distributed production of hydrogen, obtained by catalytic conversion of light hydrocarbons, air and water. The autothermic reactor (ATR) as a whole consists of a central zone where the structured catalyst is positioned, of a zone where the reactants, pre-heated beforehand by the effluent gases of the reactor, meet up and mix, and of two heat exchangers for recovering the sensitive heat of output gases by the cold reactants. This system configuration allows feeding the reactor directly with cold reactants at room ambient temperature, in particular with water in liquid phase, which is vaporised and heated directly by the sensitive heat of the reaction products. The operating conditions of the reactor in terms of temperature are clearly fixed by the choice of the feeding ratios O 2 /C(x), H 2 O/C(y) and by spatial velocity (GHSV). Typical values of feeding ratios fall within the ranges 0.3-1 and 0.5-2, respectively for x and y, whereas spatial velocity is comprised between 10000 and 200000 h -1 , corresponding to contact times variable within the range 20-400 thousandths second. Generally, in typical ATR reactors used industrially, temperature profiles in the catalytic bed are characterised by large gradients between the inlet and the outlet section (usually even higher than 200°C). The forming of such gradients is due to at least three factors that operate in a concurrent manner. In fact, the first factor is related to the intrinsic mechanism by which the autothermic reforming reaction takes place on the catalyst surface, a second one to the typical features of bad heat conductors of the catalyst supports normally used, and the third one to the fluid-dynamic conditions that set in the catalytic bed, typically consisting of packed particles. This invention concurrently uses three actions aimed at limiting the negative effects of the three factors listed above, in order to obtain the temperature profile flattening so as to optimise the operation of the ATR reactor both in terms of energy and of catalytic activity. In particular, the proposal relates to the following three actions: 1. the adoption of a specifically formulated catalyst so as to favour a "direct type" reaction mechanism, as opposed to commonly used catalysts that operate through an indirect mechanism 2. the use and the make of the catalyst on a structured support with a high porosity and tortuosity, and characterised by a high thermal conductivity such as fecralloy and/or silicon carbide coated with noble elements inserted in a chemical structure of the perovskite type with formula BaZr 1-x (noble Metal) X O 3 . 3. the adoption of a radial flow geometry catalytic bed rather than axial, so as to locally optimize the contact time in the catalytic bed.
摘要翻译：本发明涉及在自热条件下操作的异相气体 - 固体催化反应器的制造方法，其特征在于通过轻质烃，空气和水的催化转化获得的氢的分布式生产中使用的平坦的温度分布。自热反应器（ATR）整体由结构化催化剂所在的中心区域组成，其中反应物预先被反应器的废气预先加热并混合的区域和两个热交换器用于回收冷反应物的输出气体的敏感热。该系统配置允许反应器在室温下直接与冷反应物一起进料，特别是与液相中的水反应，该反应物被反应产物的敏感的热量直接蒸发和加热。通过选择进料比例O2 / C（x），H 2 O / C（y）和空间速度（GHSV），反应器在温度方面的操作条件显然是固定的。进给比率的典型值分别对于x和y分别在0.3-1和0.5-2的范围内，而空间速度在10000和200000h-1之间，对应于可变范围在20-400秒秒内的接触时间。通常，在工业上使用的典型的ATR反应器中，催化床中的温度曲线的特征在于入口和出口部分之间的大梯度（通常甚至高于200℃）。这种梯度的形成是由于至少三个以同时方式操作的因素。事实上，第一个因素与催化剂表面上发生自热重整反应的内在机制有关，第二个因素是通常使用的催化剂载体的不良热导体的典型特征，第三个与流体设置在催化床中的动力学条件，通常由填充颗粒组成。本发明同时采取三种措施来限制上述三个因素的负面影响，以获得温度曲线平坦化，从而在能量和催化活性方面优化ATR反应器的运行。特别是，该提案涉及以下三个行动：1.采用专门配制的催化剂，以便有利于“直接型”反应机制，而不是通过间接机制运行的常用催化剂。2.使用和催化剂在具有高孔隙率和弯曲度的结构化载体上的制备，并且其特征在于高导热性，例如用以BaBr 1-x（式（B））钙钛矿型化学结构插入的贵金属涂覆的fecralloy和/或碳化硅贵金属）XO3。 3.采用径向流几何催化床而不是轴向，以便局部优化催化床中的接触时间。

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