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1. 发明申请

WO2022023355A1 PROCESS TO CONDUCT AN ENDOTHERMIC DEHYDROGENATION AND/OR AROMATISATION REACTION IN A FLUIDIZED BED REACTOR 审中-公开
公开(公告)号：WO2022023355A1
公开(公告)日：2022-02-03
申请号：PCT/EP2021/071026
申请日：2021-07-27
申请人： TOTALENERGIES SE
发明人： VERYASOV, Gleb , NESTERENKO, Nikolai , VERMEIREN, Walter
IPC分类号： B01J8/00 , B01J8/18 , B01J8/32 , B01J8/24 , B01J8/42
摘要： The disclosure relates to a process to perform an endothermic dehydrogenation and/or aromatization reaction of hydrocarbons, said process comprising the steps of providing at least one fluidized bed reactor comprising at least two electrodes and a bed comprising particles; putting the particles in a fluidized state to obtain a fluidized bed; heating the fluidized bed to a temperature ranging from 480°C to 700°C to conduct the reaction; and obtaining a reactor effluent containing hydrogen, unconverted hydrocarbons, and olefins and/or aromatics; wherein the particles of the bed comprise electrically conductive particles and particles of a catalytic composition, wherein at least 10 wt.% of the particles are electrically conductive particles and have a resistivity ranging from 0.001 Ohm. cm to 500 Ohm. cm at 500°C and wherein the step of heating the fluidized bed is performed by passing an electric current of through the fluidized bed.

2. 发明申请

WO2022023346A1 PROCESS TO CONDUCT A STEAM CRACKING REACTION IN A FLUIDIZED BED REACTOR 审中-公开
公开(公告)号：WO2022023346A1
公开(公告)日：2022-02-03
申请号：PCT/EP2021/071011
申请日：2021-07-27
申请人： TOTALENERGIES SE
发明人： VERYASOV, Gleb , NESTERENKO, Nikolai , VERMEIREN, Walter
IPC分类号： C01B3/24 , B01J8/18 , B01J8/42 , C10G9/24 , C01B3/34 , C10G9/36
摘要： The disclosure relates to a process to perform a steam cracking reaction, said process comprising the steps of providing a fluidized bed reactor comprising at least two electrodes; and a bed comprising particles, wherein the particles are put in a fluidized state by passing upwardly through the said bed a fluid stream, to obtain a fluidized bed; heating the fluidized bed to a temperature ranging from 500°C to 1200°C to conduct the endothermic chemical reaction; wherein at least 10 wt.% of the particles based on the total weight of the particles of the bed are electrically conductive particles and have a resistivity ranging from 0.001 Ohm.cm to 500 Ohm.cm at 800°C and in that the step of heating the fluidized bed is performed by passing an electric current through the fluidized bed.

3. 发明申请

WO2021008693A1 VERFAHREN ZUR HERSTELLUNG VON POLYKRISTALLINEM SILICIUM 审中-公开
公开(公告)号：WO2021008693A1
公开(公告)日：2021-01-21
申请号：PCT/EP2019/069110
申请日：2019-07-16
申请人： WACKER CHEMIE AG
发明人： WOLFF, Jürgen , WENZEIS, Markus
IPC分类号： C01B33/035 , B01J8/42 , C01B33/029 , C01B33/03
摘要： Gegenstand der Erfindung ist ein Verfahren zur Herstellung von polykristallinem Silicium, umfassend Einleiten eines Reaktionsgases, das neben Wasserstoff Silan und/oder zumindest ein Halogensilan enthält, in einen Reaktionsraum eines Gasphasenabscheidungsreaktors, wobei der Reaktionsraum mindestens einen erhitzten Trägerkörper umfasst auf welchem durch Abscheidung Silicium unter Bildung des polykristallinen Siliciums abgeschieden wird. Während der Abscheidung wird zur Erkennung von Staubabscheidungen mit zumindest einer Messvorrichtung die Trübung innerhalb des Reaktionsraums bestimmt.

4. 发明申请

WO2011047962A3 METHOD FOR PERFORMING A PHASE CONVERSION BY HEATING A CARRIER MEDIUM BY MEANS OF ELECTROMAGNETIC INDUCTION 审中-公开
标题翻译： FOR相变的执行程序THROUGH加热载体介质无线感应
公开(公告)号：WO2011047962A3
公开(公告)日：2011-06-23
申请号：PCT/EP2010064974
申请日：2010-10-07
申请人： HENKEL AG & CO KGAA , FRIESE CARSTEN , KASPER DIRK
发明人： FRIESE CARSTEN , KASPER DIRK
IPC分类号： B01J8/02 , B01J8/42
CPC分类号： B01J8/0285 , B01J8/42 , B01J2208/0038 , B01J2208/00469 , B01J2208/00513 , F28D20/02
摘要： The invention relates to a method for performing a phase conversion, in particular a melting process, by means of heating a carrier medium that comprises or constitutes a phase-variable material, in a reactor, wherein the carrier medium is brought into contact with a solid heating medium, which can be heated by means of electromagnetic induction and which is located within the reactor and surrounded by the carrier medium, and the heating medium is heated by means of electromagnetic induction using an inductor, wherein the phase-variable material enters a phase conversion and wherein the carrier medium is separated from the heating medium after the phase conversion. Said method preferably takes place in a flow reactor. The inductor preferably generates an alternating field having a frequency in the range of 1 to 100 kHz.
摘要翻译：一种用于通过一个包含相变材料，或表示的载体介质的加热进行的相变，尤其是熔化过程中，在反应器中，该方法包括用由电磁感应固体传热介质的可加热，其位于反应器内，并且使所述载体介质中接触的方法这是由载体介质，并通过电磁感应由电感器来加热所述加热介质，其中所述相变材料经历相变包围，并且其中所述载体介质的加热介质的转换阶段之后分离。优选地，这在流动反应器进行。电感器优选地在1至100千赫兹的范围内的频率产生一个交变磁场。

5. 发明申请

WO2009144764A3 PHOTOCATALYTIC FLUIDIZED BED REACTOR WITH HIGH ILLUMINATION EFFICIENCY FOR PHOTOCATALYTIC OXIDATION PROCESSES 审中-公开
标题翻译：光化学氧化工艺具有高照明效率的光催化流化床反应器
公开(公告)号：WO2009144764A3
公开(公告)日：2010-05-06
申请号：PCT/IT2009000239
申请日：2009-05-29
申请人： UNIV DEGLI STUDI SALERNO , CIAMBELLI PAOLO , SANNINO DIANA , PALMA VINCENZO , VAIANO VINCENZO
发明人： CIAMBELLI PAOLO , SANNINO DIANA , PALMA VINCENZO , VAIANO VINCENZO
IPC分类号： B01J8/42 , B01D53/88 , B01J19/12 , B01J23/22 , B01J23/28 , B01J35/00 , C07C5/48 , C07C45/29 , C07C45/38
CPC分类号： B01J19/123 , B01D53/885 , B01D2255/20707 , B01D2255/20723 , B01D2255/20769 , B01D2255/2092 , B01D2255/802 , B01D2257/7022 , B01D2257/7027 , B01D2257/708 , B01D2259/804 , B01J8/42 , B01J23/22 , B01J23/28 , B01J35/004 , B01J2208/00513 , B01J2219/0871 , B01J2219/0875 , B01J2219/0892 , C07C5/48 , C07C45/002 , C07C2521/04 , C07C2521/06 , C07C2523/22 , C07C2523/28 , C07C2527/053 , Y02P20/52 , C07C15/46 , C07C15/04 , C07C47/06
摘要： The invention relates to the realization of synthesis of organic com¬ pounds or abatement of volatile organic compounds (VOCs) in gas-solid fluid- ised bed photocatalytic reactor with improved illumination efficiency. The photoreactor consists of a two-dimensional fluidized bed catalytic reactor with two walls transparent to ultraviolet radiation, by an illumination system based on an array of LEDs positioned near its external walls, and heated by Joule effect inside the catalytic bed to control the reaction temperature. Through the use of the reactor it is possible to carry out both partial and total oxidation re¬ actions with high activity and selectivity and, in addition, the illuminated cata¬ lyst surface area per unit of irradiated volume reaches values in the order of 106 m"1, significantly higher than the values typical of microreactors and slurry reactors. The photocatalytic system reported in the present invention is shown to have high illumination efficiency due to the use of UV-LEDs, which, ensur¬ ing a direction of light irradiation orthogonal to the emission point, minimize the dispersion of photons.
摘要翻译：本发明涉及在气体 - 固体流化床光催化反应器中合成有机物或减少挥发性有机化合物（VOC）的实现，其具有改善的照明效率。光反应器由具有两个对紫外线辐射透明的壁的二维流化床催化反应器组成，通过基于位于其外壁附近的LED阵列的照明系统，并且通过焦耳效应在催化床内加热以控制反应温度。通过使用反应器，可以以高活性和选择性进行部分氧化反应和全部氧化反应，此外，每单位辐照体积的照射量表达面积达到106 m量级 “1，显着高于微反应器和浆料反应器的典型值。本发明报道的光催化体系由于使用UV-LED而被证明具有高的照明效率，这确保了光照射的方向正交到发射点，使光子的分散最小化。

6. 发明申请

WO2005022667A3 SYSTEM AND METHOD FOR NANOPARTICLE AND NANOGGLOMERATE FLUIDIZATION 审中-公开
标题翻译：用于纳米颗粒和纳米粒子流化的系统和方法
公开(公告)号：WO2005022667A3
公开(公告)日：2006-03-30
申请号：PCT/US2004025514
申请日：2004-07-28
申请人： NEW JERSEY TECH INST
发明人： PFEFFER ROBERT , NAM CAROLINE H , DAVE RAJESH N , LIU GUANGLIANG , QUEVEDO JOSE A , YU QUN , ZHU CHAO
IPC分类号： B01F11/02 , B01F13/02 , B01F13/08 , B01J8/24 , B01J8/40 , B01J8/42 , B01J19/10 , H01M20060101 , B02C19/06
CPC分类号： B01F13/0809 , B01F11/0266 , B01F13/0255 , B01J8/1872 , B01J8/40 , B01J8/42 , B01J19/10 , B01J2208/00681 , B82Y15/00
摘要： With the coupling of an external field and aeration (or a flow of another gas), nanoparticles can be smoothly and vigorously fluidized. Multiple external fields and/or pretreatment may be employed with the fluidizing gas: sieving, magnetic assistance, vibration, acoustic/sound or rotational/centrifugal forces. Any of these forces, either alone or in combination, when coupled with a fluidizing medium, provide excellent means for achieving homogenous nanofluidization. The additional force(s) help to break channels as well as provide enough energy to disrupt the strong interparticle forces, thereby establishing an advantageous agglomerate size distribution. Enhanced fluidization is reflected by at least one of the following performance-related attributes: reduced levels of bubbles within the fluidized system, reduced gas bypass relative to the fluidized bed, smooth fluidization behavior, reduced elutriation, a high level of bed expansion, reduced gas velocity levels to achieve desired fluidization performance, and/or enhanced control of agglomerate size/distribution. The fluidized nanoparticles may be coated, surface-treated and/or surfacemodified in the fluidized state. In addition, the fluidized nanoparticles may participate in a reaction, either as a reactant or a catalyst, while in the fluidized state.
摘要翻译：通过外场和通气（或另一种气体的流动）的耦合，纳米颗粒可以顺利且剧烈流化。多种外部场和/或预处理可以与流化气体一起使用：筛分，磁辅助，振动，声/声或旋转/离心力。当与流化介质结合时，单独或组合的这些力中的任何一个提供了实现均匀纳米流化的极好手段。额外的力有助于破坏通道，并提供足够的能量来破坏强大的颗粒间力，从而建立有利的聚集体尺寸分布。增强的流化反应由以下性能相关属性中的至少一个反映：流化系统内的气泡水平降低，相对于流化床的气体旁路减少，流化性能平稳，淘汰率降低，床膨胀高度降低速度水平以实现期望的流化性能，和/或增强聚集体尺寸/分布的控制。流化的纳米颗粒可以在流化状态下被涂覆，表面处理和/或表面改性。此外，流化的纳米颗粒可以在流化状态下作为反应物或催化剂参与反应。

7. 发明申请

WO02038523A1 HIGH FREQUENCY ENERGY APPLICATION TO PETROLEUM FEED PROCESSING 审中-公开
标题翻译：高频能量石油进料加工应用
公开(公告)号：WO02038523A1
公开(公告)日：2002-05-16
申请号：PCT/US2001/032418
申请日：2001-10-18
IPC分类号： B01J8/20 , B01J8/42 , B01J19/00 , B01J19/12 , C10G15/08 , C10G32/02 , C07C1/00 , B01D5/00 , C07F1/00
CPC分类号： C10G49/02 , B01J8/20 , B01J8/42 , B01J19/0026 , B01J19/12 , B01J19/121 , B01J19/126 , B01J19/128 , B01J2208/00707 , B01J2219/0854 , B01J2219/0877 , B01J2219/0892 , B01J2219/1227 , C10G15/08 , C10G32/02 , C10G2300/703 , Y10S44/904 , Y10S44/905
摘要： The present invention provides a method and apparatus for maintaining the active life of a catalyst (10) in organic feed (22) processing by applying a series of electromagnetic radiation pulses (30) to the catalyst in a reactor (24). The pulsing of the catalyst selectively heats and cools the catalyst and can regulate the relative internal pressure of the catalyst particles to stimulate the acceleration of oil macromolecules mass-exchange through the catalyst pores and surface. This allows for the removal of cracked oil molecules from the particles. The application of electromagnetic pulses also regulates the activity of the catalyst. The electromagnetic radiation reduces the formation of coke on the catalyst and increases the life of the catalyst in the reactor. Further, the present invention provides a method and apparatus for removing water and salt from an organic feed. Water and salt is removed by applying a series of electromagnetic radiation pulses to the organic feed.
摘要翻译：本发明提供一种通过在反应器（24）中向催化剂施加一系列电磁辐射脉冲（30）来保持催化剂（10）在有机进料（22）处理中的活性寿命的方法和装置。催化剂的脉冲选择性地加热和冷却催化剂，并且可以调节催化剂颗粒的相对内部压力，以刺激油大分子通过催化剂孔和表面的质量交换的加速。这允许从颗粒中除去裂化的油分子。电磁脉冲的应用也调节催化剂的活性。电磁辐射减少了催化剂上焦炭的形成，并增加了反应器中催化剂的寿命。此外，本发明提供了从有机进料中除去水和盐的方法和装置。通过向有机进料施加一系列电磁辐射脉冲来除去水和盐。

8. 发明申请

WO00020111A1 FLUIDIZED BED REACTOR HAVING A CENTRALLY POSITIONED INTERNAL HEAT SOURCE 审中-公开
标题翻译：具有中央定位的内部热源的流化床反应器
公开(公告)号：WO00020111A1
公开(公告)日：2000-04-13
申请号：PCT/US1999/022749
申请日：1999-10-01
IPC分类号： H05B6/24 , B01J8/18 , B01J8/42 , B01J19/02 , B01J19/12 , B22F1/02 , C01G23/02 , C09C1/30 , C09C1/36 , F27B15/14 , F27D11/02 , F27D11/06 , C01B33/027
CPC分类号： C09C1/3054 , B01J8/1836 , B01J8/42 , B01J19/02 , B01J19/129 , B01J2208/00398 , B01J2208/00469 , B01J2219/025 , B01J2219/0286 , C01G23/02 , C01P2004/84 , C09C1/3661
摘要： Fluidized bed reactors having centrally positioned heating means, as well as methods for their use, are provided. The subject reactors (10) comprise a centrally positioned heating means (e.g. a susceptor rod (12)) that, during operation, is at least partially immersed in a fluidized bed of particles (16). Preferably the susceptor rod (12) is heated by externally positioned radio-frequency coils in operational relationship with an RF source (18). The subject reactors are further characterized in that, during use, a temperature gradient is produced within the reactor. The subject reactors find use in the production of electronic grade silicon and in the silica coating of titania particles.
摘要翻译：提供了具有中心定位加热装置的流化床反应器，以及其使用方法。目标反应器（10）包括中心定位的加热装置（例如基座杆（12）），其在操作期间至少部分地浸没在颗粒（16）的流化床中。优选地，基座杆（12）由与RF源（18）处于操作关系的外部放置的射频线圈加热。本发明的反应器的特征还在于，在使用期间，在反应器内产生温度梯度。本发明的反应器可用于生产电子级硅和二氧化钛颗粒的二氧化硅涂层。

9. 发明申请

WO2023017209A1 METHOD AND APPARATUS FOR TREATING RAW MATERIAL AND USE 审中-公开
公开(公告)号：WO2023017209A1
公开(公告)日：2023-02-16
申请号：PCT/FI2022/050517
申请日：2022-08-09
申请人： TEKNOLOGIAN TUTKIMUSKESKUS VTT OY
发明人： NIEMINEN, Matti , PELTOLA, Juho , NIEMI, Timo , KERÄNEN, Janne Sami
IPC分类号： B01J6/00 , B01J4/00 , B01J8/18 , B01J8/34 , B01J8/38 , B01J8/44 , B01J8/42 , B01J8/28
摘要： The invention relates to a method and an apparatus for treating raw material in a fluidized bed reactor (1) which comprises at least two bed materials. The second bed material (4) is subjected into a lower part (2) of the fluidized bed reactor in which the lower part of the reactor comprises the first bed material (3) comprising electroconductive material, a fluidizing agent (6) is fed to a bottom (7) of the fluidized bed reactor, and the fluidizing agent is arranged to flow through the lower part of the reactor to an upper part (5) of the fluidized bed reactor, the first bed material (3) is heated by induction heating in the lower part (2) of the reactor and heat is transferred from the first bed material to the fluidizing agent (6) and/or to the second bed material (4,4b) in the lower part of the reactor, the heated second bed material (4a) is fluidized by the fluidizing agent to the upper part (5) of reactor, and the raw material (9) is fed to the upper part of the reactor where the raw material is treated. Further, the invention relates to the use of the apparatus.

10. 发明申请

WO2021041430A1 A SYSTEM AND METHOD USING PHOTOCHEMICAL OXYGEN STORAGE AND RELEASE 审中-公开
公开(公告)号：WO2021041430A1
公开(公告)日：2021-03-04
申请号：PCT/US2020/047829
申请日：2020-08-25
申请人： PORTLAND STATE UNIVERSITY
发明人： MCCORMICK, Theresa , LUTKUS, Luke
IPC分类号： A61K41/00 , B01J8/26 , B01J8/42 , C01B13/02 , A61M16/1005 , A61M16/101 , A61M2202/0208 , A61M2205/3368 , A61M2205/3606 , A61M2205/362 , A61M2205/3653 , A61M2205/3673 , A62B21/00 , A62B7/08 , C01B13/0211
摘要： Disclosed herein is a method for converting light energy into mechanical energy and/or oxygen storage, purification, isolation, concentration, and/or removed. The method may comprise exposing a mixture of a polycyclic aromatic compound and a photosensitizer to oxygen and light to form an endoperoxide, and decomposing the endoperoxide to reform the polycyclic aromatic compound and oxygen. The polycyclic aromatic compound may be a naphthalene compound or anthracene compound and/or may have a formula (I).

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