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1. 发明申请

WO2004047960A1 METHOD FOR PREPARATION AND ACTIVATION OF MULTIMETALLIC ZEOLITE CATALYSTS, A CATALYST COMPOSITION AND APPLICATION FOR N2O ABATEMENT 审中-公开
标题翻译：多元沸石催化剂的制备和活化方法，催化剂组合物及其应用N> 2
公开(公告)号：WO2004047960A1
公开(公告)日：2004-06-10
申请号：PCT/NO2002/000439
申请日：2002-11-25
申请人： NORSK HYDRO ASA , PÉREZ RAMÍREZ, Javier
发明人： PÉREZ RAMÍREZ, Javier
IPC分类号： B01D53/86
CPC分类号： B01J29/48 , B01D53/8628 , B01D2255/20738 , B01D2255/20746 , B01D2255/20761 , B01D2255/50 , B01D2257/402 , B01J29/46 , B01J29/7615 , B01J29/87 , B01J29/88 , B01J37/0246 , B01J2229/183 , C01B39/06 , Y02C20/10 , Y02P20/153
摘要： The present invention relates to the preparation and activation of multimetallic zeolites loaded with transition metals for N 2 0 abatement in tail-gases from different sources. The N 2 0-containing gas is brought in contact with a catalyst comprising Fe and a second, third, or any additional transition metal (Cu, Co, Ni, Mn, Cr, V), with a total metal content ranging from 0.1-1.0 wt.%, on a zeolite support (MFI or BEA) at 523-873 K. Not 10 only the combination and loading of metals, but also the method of incorporation in the zeolite and its activation is essential to obtain active and stable catalysts. The synergy between metals was observed in Fe-Cu, Fe-Co, and Fe-Co-Cu systems, but not with combinations of iron with other transition metals. The optimal catalysts show high N 2 0 conversions (>80%) at temperatures 2000 hours in pilot-scale tests with a zeolite-coated monolithic reactor.
摘要翻译：本发明涉及负载过渡金属的多金属沸石的制备和活化，其中来自不同来源的尾气中氮> 2 <0减少。使含N 2 O的气体与包含Fe和第二，第三或任何另外的过渡金属（Cu，Co，Ni，Mn，Cr，V）的催化剂接触，其总金属含量范围为 0.1-1.0重量％，在523-873K的沸石载体（MFI或BEA）上。不仅仅是金属的组合和加载，而且在沸石中引入的方法及其活化对于获得活性和稳定的催化剂。在Fe-Cu，Fe-Co和Fe-Co-Cu体系中观察到金属之间的协同作用，但不与铁与其它过渡金属的组合。最佳催化剂在623K的温度下显示高的N> 2 <0转化率（> 80％），并且在具有沸石涂层的整体式反应器的中试规模试验中，稳定行为> 2000小时。

2. 发明申请

WO2008107445A1 GOLD-BASED CATALYSTS FOR SELECTIVE HYDROGENATION OF UNSATURATED COMPOUNDS 审中-公开
标题翻译：用于选择性加氢不饱和化合物的金为基础的催化剂
公开(公告)号：WO2008107445A1
公开(公告)日：2008-09-12
申请号：PCT/EP2008/052635
申请日：2008-03-04
申请人： INSTITUT CATALÀ D'INVESTIGACIÓ QUÍMICA (ICIQ) , PÉREZ-RAMÍREZ, Javier , SEGURA, Yolanda
发明人： PÉREZ-RAMÍREZ, Javier , SEGURA, Yolanda
IPC分类号： B01J21/00 , B01J21/04 , B01J23/00 , B01J23/52 , B01J23/755 , B01J37/02 , B01J37/03 , C07C5/05 , C07C5/08 , C07C7/167 , C10G45/34
CPC分类号： B01J23/52 , B01J23/002 , B01J23/005 , B01J23/007 , B01J23/66 , B01J23/688 , B01J23/89 , B01J23/892 , B01J35/006 , B01J35/1019 , B01J37/03 , B01J37/031 , B01J2523/00 , C07C5/05 , C07C5/09 , C07C7/167 , C07C2523/66 , C07C2523/68 , C10G45/34 , Y02P20/52 , C07C11/06 , B01J2523/19 , B01J2523/31 , B01J2523/847
摘要： The present invention relates to novel selective hydrogenation gold-based catalysts for carrying out selective hydrogenation of molecules having triple bonds, and optionally also conjugated double bonds and/or triple and double bonds in the same molecule. The catalysts show a high selectivity and activity, and are also stable over time.
摘要翻译：本发明涉及用于对具有三键的分子进行选择性氢化的新型选择性氢化金基催化剂，以及任选地在同一分子中共轭双键和/或三键和双键。催化剂显示出高选择性和活性，并且随着时间的推移也是稳定的。

3. 发明申请

WO2007147881A3 A PROCESS FOR THE PREPARATION OF UNIFORM NANO-SIZED SOLID MATERIALS BY CONTINUOUS PRECIPITATION 审中-公开
公开(公告)号：WO2007147881A3
公开(公告)日：2007-12-27
申请号：PCT/EP2007/056228
申请日：2007-06-22
申请人： YARA INTERNATIONAL ASA , PÉREZ RAMÍREZ, Javier , ABELLÓ CROS, Sonia , SANTIAGO REDONDO, Marta
发明人： PÉREZ RAMÍREZ, Javier , ABELLÓ CROS, Sonia , SANTIAGO REDONDO, Marta
IPC分类号： B01J19/00 , B01J19/20 , B01J35/02 , C01F7/00 , B01J21/04
摘要： A process for the preparation of nano-sized solid materials with a uniform particle size and a uniform pore size distribution which comprises the continuous precipitation at atmospheric pressure under constant temperature, constant pH and preselected residence time, in a stirred reaction chamber simultaneously fed with at least two solutions, characterised in that the reaction chamber is a microreactor and in that the pH of the reaction mixture is controlled by the flow of the feeding solutions. Furthermore, hydrotalcites, dawsonites and aluminas with specific morphology, size distribution and pore size which can be prepared by said process.

4. 发明申请

WO2006041300A1 CATALYTIC MEMBRABE REACTOR FOR THE OXIDATION OF NH3 TO NO, AND METHOD FOR THE OXIDATION OF NH3 TO NO 审中-公开
标题翻译：用于将NH 3氧化成NO的催化膜反应器和用于将NO 3氧化成NO的方法
公开(公告)号：WO2006041300A1
公开(公告)日：2006-04-20
申请号：PCT/NO2004/000309
申请日：2004-10-13
申请人： YARA INTERNATIONAL ASA , PÉREZ-RAMÍREZ, Javier , VIGELAND, Bent, E. , JULSRUD, Stein
发明人： PÉREZ-RAMÍREZ, Javier , VIGELAND, Bent, E. , JULSRUD, Stein
IPC分类号： B01J19/24
CPC分类号： B01D71/024 , B01J12/007 , B01J19/0093 , B01J19/2475 , B01J2219/00063 , B01J2219/00788 , B01J2219/00835 , B01J2219/00844 , B01J2219/00891 , B01J2219/00907 , B01J2219/00961 , C01B21/265
摘要： The present invention relates to a catalytic membrane reactor for the oxidation of NH 3 to NO during the manufacture of nitric acid, where the membrane reactor comprises a mixed electronic and ionic conducting membrane which is capable of transporting oxygen, comprising a multi-component oxide having a perovskite or perovskite-related structure represented by the formula A X A' X , B0 3 - Z , wherein A represents a lanthanide element or a mixture thereof, A' represents an alkaline earth metal or a mixture thereof, B represents a transition metal or a mixture thereof, x and x' each represent numbers such that 0 ≤ X≤1.1, 0≤x'≤1.1 and 0.9 ≤ (x+x') ≤ 1.1, and z represents a number rendering the compound charge neutral. The invention also relates to a method for the oxidation of NH 3 to NO. The product and method according to the invention lead to NO selectivities up to 98 % and no N 2 0 formation during high-temperature NH 3 oxidation, giving rise to a highly efficient and intensified process for nitric acid manufacture.
摘要翻译：本发明涉及在硝酸制造期间将NH 3氧化为NO的催化膜反应器，其中膜反应器包括能够输送氧的混合电子和离子导电膜，其包含具有由式A X A，B，B，B，B，B，B，B，

5. 发明申请

WO2005105711A1 METHOD AND APPARATUS FOR N20-MEDIATED OXIDATIVE DEHYDROGENATION OF ALKANES TO ALKENES OVER IRON ZEOLITES 审中-公开
标题翻译：用于N2O介导的氧化脱氢的方法和装置通过铁沸石来烷基化
公开(公告)号：WO2005105711A1
公开(公告)日：2005-11-10
申请号：PCT/NO2004/000125
申请日：2004-04-30
申请人： YARA INTERNATIONAL ASA , PÉREZ-RAMÍREZ, Javier , GALLARDO-LLAMAS, Amalia
发明人： PÉREZ-RAMÍREZ, Javier , GALLARDO-LLAMAS, Amalia
IPC分类号： C07C5/42
CPC分类号： C07C5/42 , C07C11/06
摘要： Steam-activated Fe-zeolites are highly efficient catalysts for the oxidative dehydrogenation of propane using N 2 0, with initial propene yields up to 25% at 723-773 K, but they deactivate due to coking. Since catalyst deactivation is reversible, a cyclically-operated process for continuous propene production, with alternation of reaction and regeneration cycles, has been developed. In order to rationally design the sequence in the cyclic experiments, a tapered element oscillating microbalance (TEOM) coupled to on-line analysis of products has been applied. The TEOM provides information on activity, deactivation, and regeneration by simultaneous measurement of reaction and mass changes. In a system with two fixed-bed reactors in parallel using FeZSM-5, stable propene yields >20% have been demonstrated during cycling for 1000 min, using reaction and regeneration temperatures of 723 K and 823 K, respectively. This novel catalytic process leads to the simultaneous valorization of C 3 H 8 and N 2 0 and can be economically applied in tail-gases of processes where N 2 0 is produced in high concentration, including the manufacture of adipic acid, caprolactam, glyoxal, and in general organic syntheses using nitric acid as the oxidant or processes involving ammonia oxidation.
摘要翻译：蒸汽激活的Fe-沸石是使用N2O对丙烷进行氧化脱氢的高效催化剂，初始丙烯在723-773K时产率高达25％，但是它们由于焦化而失活。由于催化剂失活是可逆的，已经开发了具有交替的反应和再生循环的连续丙烯生产的循环操作方法。为了合理设计循环实验中的顺序，已经应用了耦合到产品在线分析的锥形元件振荡微量天平（TEOM）。 TEOM通过同时测量反应和质量变化来提供有关活动，停用和再生的信息。在使用FeZSM-5的两个固定床反应器的系统中，使用723K和823K的反应和再生温度分别在循环1000分钟期间证明稳定丙烯产率> 20％。这种新型催化过程导致C3H8和N20的同时增值，可以经济地应用于高浓度生产N20的方法的尾气中，包括己二酸，己内酰胺，乙二醛的制备，一般使用硝酸的有机合成酸作为氧化剂或涉及氨氧化的方法。

6. 发明申请

WO2011104212A1 CATALYST FOR CHLORINE PRODUCTION 审中-公开
标题翻译：氯化氢生产催化剂
公开(公告)号：WO2011104212A1
公开(公告)日：2011-09-01
申请号：PCT/EP2011/052557
申请日：2011-02-22
申请人： BAYER MATERIALSCIENCE AG , PÉREZ-RAMÍREZ, Javier , GOMEZ-SEGURA, Jordi
发明人： PÉREZ-RAMÍREZ, Javier , GOMEZ-SEGURA, Jordi
IPC分类号： B01J21/04 , B01J23/72 , C01B7/04
CPC分类号： B01J23/72 , B01J21/04 , B01J23/002 , B01J37/031 , C01B7/04 , C01B7/0743
摘要： The subject of the present invention is a copper (I) aluminate-containing catalyst to be used for the stable production of chlorine from hydrogen chloride by thermocatalytic oxidation with oxygen-containing gases, wherein the preparation procedure of the catalyst comprises an annealing step to produce a copper (I) aluminate-containing catalyst in which at least 50 wt-% of the copper altogether present in the catalyst is present as copper (I).
摘要翻译：本发明的主题是用于通过用含氧气体的热催化氧化从氯化氢稳定生产氯的含铜（I）铝酸盐催化剂，其中催化剂的制备方法包括退火步骤以产生含有铜（I）的含铝酸盐催化剂，其中存在于催化剂中的至少50重量％的铜作为铜（I）存在。

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