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    • 1. 发明申请
    • PROCESS FOR PRODUCING POLYOLEFIN FILMS
    • 生产聚烯烃膜的方法
    • WO2007027457A2
    • 2007-03-08
    • PCT/US2006/032409
    • 2006-08-17
    • FINA TECHNOLOGY, INC.MCLEOD, Michael, A.
    • MCLEOD, Michael, A.
    • B29C47/06B29C55/06
    • B29C55/06B29C47/0007B29C47/0021B29C47/065B29C47/145B29C47/8805B29C47/8845B29C55/023B29C55/14B29K2023/12B29K2105/0014
    • Process for producing an oriented polyolefm film using a multi- component polymer composition provided by a primary polymer component comprising an isotactic propylene homopolymer produced by the polymerization of propylene in the presence of a Ziegler-Natta catalyst and a secondary polymer component comprising a metallocene polymerized isotactic propylene polymer having a xylene solubles content which is less than that of the primary polymer component. The secondary polymer component is a propylene homopolymer or an ethylene-propylene random copolymer having an ethylene content of about 0.5 wt.% or less. The polymer components are separately co-extruded to form a multilayer co-extrudate in which the primary polymer component is present in an amount greater than the secondary polymer component. The multilayer co-extrudate is oriented in at least one direction to form an oriented film.
    • 使用多组分聚合物组合物制备取向聚烯烃膜的方法,所述组合物由包含通过丙烯在齐格勒 - 纳塔催化剂存在下聚合而产生的全同立构丙烯均聚物的主聚合物组分提供, 第二聚合物组分包含茂金属聚合的全同立构丙烯聚合物,其二甲苯可溶物含量小于主聚合物组分的二甲苯可溶物含量。 第二聚合物组分是丙烯均聚物或乙烯含量为约0.5重量%或更低的乙烯 - 丙烯无规共聚物。 将聚合物组分分别共挤出以形成多层共挤出物,其中主要聚合物组分的存在量大于次要聚合物组分的量。 多层共挤出物沿至少一个方向取向以形成取向膜。
    • 3. 发明申请
    • PROCESS FOR PRODUCING POLYOLEFIN
    • 生产聚烯烃的方法
    • WO2007018762A1
    • 2007-02-15
    • PCT/US2006/024163
    • 2006-06-20
    • FINA TECHNOLOGY, INC.MCLEOD, Michael, A.SMITH, David
    • MCLEOD, Michael, A.SMITH, David
    • C08L23/16C08F4/64
    • C08L23/12C08L23/142C08L2205/02C08L2314/02C08L2314/06C08L2666/06
    • Process for the production of an oriented polyolefm film using multi- component polymer compositions. One polymer component comprises an isotactic propylene homopolymer produced by the polymerization of propylene with a Ziegler- Natta catalyst. A secondary component is a Ziegler-Natta polymerized ethylene- propylene random copolymer or a metallocene-polymerized ethylene-propylene random copolymer produced by the polymerization of propylene and ethylene in the presence of a metallocene polymerization catalyst. The Ziegler-Natta polymerized copolymer is produced by the polymerization of ethylene and propylene in the presence of a Ziegler- Natta catalyst and contains no more than 0.5 wt.% ethylene and has a xylene solubles content of at least 2 wt.%. The primary and secondary polymer components are mixed together to provide a blend in which, when the secondary component is a Ziegler-Natta polypropylene, is present in an amount within the range of 5-25 wt.% and the secondary polymer component is a metallocene-based copolymer present in an amount of less than 5 wt.%. After mixing the two polymer components together, the mixture is extruded and the formed into a biaxially oriented film.
    • 使用多组分聚合物组合物制备定向聚烯烃薄膜的方法。 一种聚合物组分包括通过丙烯与齐格勒 - 纳塔催化剂聚合制备的全同立构丙烯均聚物。 次要组分是齐格勒 - 纳塔聚合的乙烯 - 丙烯无规共聚物或通过丙烯和乙烯在金属茂聚合催化剂存在下聚合制备的茂金属聚合的乙烯 - 丙烯无规共聚物。 齐格勒 - 纳塔聚合共聚物是在齐格勒 - 纳塔催化剂存在下通过乙烯和丙烯的聚合制备的,含有不超过0.5%(重量)乙烯,二甲苯可溶物含量至少为2%(重量)。 将初级和次级聚合物组分混合在一起以提供共混物,其中当次要组分是齐格勒 - 纳塔聚丙烯时,其存在量为5-25重量%,并且次要聚合物组分为茂金属 基的共聚物的存在量小于5重量%。 将两种聚合物组分混合在一起后,将混合物挤出并形成双轴取向薄膜。
    • 8. 发明申请
    • PROCESS FOR PRODUCING POLYOLEFIN FILMS
    • 生产聚烯烃薄膜的方法
    • WO2007027457A3
    • 2007-10-11
    • PCT/US2006032409
    • 2006-08-17
    • FINA TECHNOLOGYMCLEOD MICHAEL A
    • MCLEOD MICHAEL A
    • C08L23/00C08L23/04
    • B29C55/06B29C47/0007B29C47/0021B29C47/065B29C47/145B29C47/8805B29C47/8845B29C55/023B29C55/14B29K2023/12B29K2105/0014
    • Process for producing an oriented polyolefm film using a multi- component polymer composition provided by a primary polymer component comprising an isotactic propylene homopolymer produced by the polymerization of propylene in the presence of a Ziegler-Natta catalyst and a secondary polymer component comprising a metallocene polymerized isotactic propylene polymer having a xylene solubles content which is less than that of the primary polymer component. The secondary polymer component is a propylene homopolymer or an ethylene-propylene random copolymer having an ethylene content of about 0.5 wt.% or less. The polymer components are separately co-extruded to form a multilayer co-extrudate in which the primary polymer component is present in an amount greater than the secondary polymer component. The multilayer co-extrudate is oriented in at least one direction to form an oriented film.
    • 使用由主要聚合物组分提供的多组分聚合物组合物制备取向聚烯烃薄膜的方法,该组合物包含通过在齐格勒 - 纳塔催化剂存在下丙烯聚合制备的全同立构丙烯均聚物和包含茂金属聚合全同立构的二次聚合物组分 丙烯聚合物的二甲苯可溶物含量小于初级聚合物组分的含量。 次级聚合物组分是乙烯含量为约0.5重量%或更低的丙烯均聚物或乙烯 - 丙烯无规共聚物。 聚合物组分分别共挤出以形成多层共挤出物,其中主要聚合物组分以大于次级聚合物组分的量存在。 多层共挤出物在至少一个方向取向以形成定向膜。