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1. 发明申请

WO2003104172A1 PROCESS FOR MANUFACTURING ALKANES 审中-公开
标题翻译：制造碱的方法
公开(公告)号：WO2003104172A1
公开(公告)日：2003-12-18
申请号：PCT/GB2003/002427
申请日：2003-06-04
申请人： BP CHEMICALS LIMITED , COPERET, Christophe , DOBSON, Ian , MAUNDERS, Barry, Martin , SOULIVONG, Daravong , SUNLEY, John, Glenn
发明人： COPERET, Christophe , DOBSON, Ian , MAUNDERS, Barry, Martin , SOULIVONG, Daravong , SUNLEY, John, Glenn
IPC分类号： C07C6/10
CPC分类号： C07C2/76 , B01J31/121 , B01J31/4015 , B01J37/0238 , B01J37/18 , C07C6/10 , C07C2531/12 , Y02P20/584 , C07C9/06 , C07C9/00
摘要： The present invention relates to a process for the manufacture of alkanes comprising an operation in which at least one starting alkane is contacted with a metal catalyst comprising at least one metal, Me, bonded to at least one hydrogen atom and/or to at least one hydrocarbon radical, characterized in that the catalyst is contacted with an agent which forms hydrogen "in situ" , during the manufacture of alkanes. The present invention also relates to a process for the activation of a metal catalyst intended to manufacture alkanes and comprising at least one metal, Me, bonded to at least one hydrogen atom and/or to at least one hydrocarbon radical, which process is characterized in that, during the manufacture of alkanes carried out by contacting the catalyst with at least one starting alkane, the catalyst is contacted with an agent which forms hydrogen "in situ" . The agent can be chosen from agents capable of releasing hydrogen, preferably by a physical action, and from agents capable of forming hydrogen by a chemical reaction, in particular in the presence of the metal catalyst. The metal Me of the catalyst can be chosen from the lanthanides, the actinides and the metals from Groups 2 to 12, preferably the transition metals from Groups 3 to 11 of the Periodic Table of the Elements. The metal catalyst can be preferably chosen from metal catalysts supported on and in particular grafted to a solid support.
摘要翻译：本发明涉及一种制备烷烃的方法，其中包括使至少一种起始烷烃与包含至少一种键合至至少一个氢原子的至少一种金属Me的金属催化剂接触的操作和/或至少一种烃基，其特征在于，在烷烃的制造期间，催化剂与“原位”形成氢的试剂接触。本发明还涉及一种用于活化用于制备烷烃并且包含至少一种键合至至少一个氢原子和/或至少一个烃基的金属Me的金属催化剂的方法，该方法的特征在于在通过使催化剂与至少一种起始烷烃接触进行的烷烃的制造过程中，催化剂与“原位”形成氢气的试剂接触。该试剂可以选自能够释放氢的试剂，优选通过物理作用，以及能够通过化学反应形成氢的试剂，特别是在金属催化剂的存在下。催化剂的金属Me可以选自镧系元素，锕系元素和第2至12族的金属，优选选自元素周期表第3至11族的过渡金属。金属催化剂可以优选选自负载在并且特别是接枝到固体载体上的金属催化剂。

2. 发明申请

WO2004087838A1 INTEGRATED PROCESS FOR THE PRODUCTION OF OLEFIN DERIVATIVES 审中-公开
标题翻译：用于生产烯烃衍生物的综合方法
公开(公告)号：WO2004087838A1
公开(公告)日：2004-10-14
申请号：PCT/GB2004/001265
申请日：2004-03-24
申请人： BP CHEMICALS LIMITED , LITTLE, Ian, Raymond , LUCY, Andrew, Richard , MAUNDERS, Barry, Martin
发明人： LITTLE, Ian, Raymond , LUCY, Andrew, Richard , MAUNDERS, Barry, Martin
IPC分类号： C10G11/22
CPC分类号： C10G50/00 , C10G11/22 , C10G57/00 , C10G57/005 , C10G57/02 , Y02P30/446
摘要： The present invention provides a process for the production of an olefin derivative, which process comprises the steps of: (a) cracking a paraffinic hydrocarbon containing feedstock to produce a first dilute olefins stream comprising both olefins and alkanes, (b) reacting at least a portion of said first dilute olefins stream produced in step (a) to produce a first olefin derivative stream, comprising a first olefin derivative, and a second dilute olefins stream, comprising alkanes and at least 5 mol % unreacted olefins, (c) auto-thermally cracking at least a portion of said second dilute olefins stream produced in step (b), said portion comprising alkanes and at least 5 mol % unreacted olefins.
摘要翻译：本发明提供一种生产烯烃衍生物的方法，该方法包括以下步骤：（a）裂解含链烷烃的原料以产生包含烯烃和烷烃的第一稀释烯烃流，（b）使至少一种在步骤（a）中产生的所述第一稀释烯烃流的一部分以产生包含第一烯烃衍生物的第一烯烃衍生物物流和包含烷烃和至少5摩尔％未反应的烯烃的第二稀烯烃物流，（c）热裂解步骤（b）中产生的所述第二稀释烯烃流的至少一部分，所述部分包含烷烃和至少5摩尔％未反应的烯烃。

3. 发明申请

WO2003061823A1 A SUPPORTED METAL COMPOUND, PREPARATION OF THE COMPOUND AND USE OF THE COMPOUND AS A CATALYST 审中-公开
标题翻译：支持的金属化合物，化合物的制备和作为催化剂的化合物的使用
公开(公告)号：WO2003061823A1
公开(公告)日：2003-07-31
申请号：PCT/GB2003/000173
申请日：2003-01-17
申请人： BP CHEMICALS LIMITED , BASSET, Jean-Marie , COPERET, Christophe , MAUNDERS, Barry, Martin , RATABOUL, Franck , SAGGIO, Guillaume , SOULIVONG, Daravong , TAOUFIK, Mostapha , THIVOLLE-CAZAT, Jean
发明人： BASSET, Jean-Marie , COPERET, Christophe , MAUNDERS, Barry, Martin , RATABOUL, Franck , SAGGIO, Guillaume , SOULIVONG, Daravong , TAOUFIK, Mostapha , THIVOLLE-CAZAT, Jean
IPC分类号： B01J31/12
CPC分类号： C07C6/10 , B01J31/121 , B01J37/0203 , B01J37/16 , B01J2231/12 , B01J2231/20 , B01J2231/52 , C07C2/08 , C07C5/2206 , C07C2531/12 , C08F10/00 , C08F4/025
摘要： The present invention relates to a supported metal compound comprising a solid support to which are grafted at least two types of metal atom, Me, one in a form (A) of a metal compound where the metal atom is bonded to at least one hydrogen atom and/or to at least one hydrocarbon, and the other in a form (B) of a metal compound where the metal atom is bonded solely to the support and optionally to at least one other element which is neither a hydrogen atom nor a hydrocarbon radical. The compound can be prepared (a) by grafting an organometallic precursor (P) comprising the metal Me, bonded to at least one hydrocarbon ligand, to the solid support, and (b) by treating the solid product resulting from step (a) with hydrogen or a reducing agent, at a temperature greater than the temperature, TI, at which the supported metal compound is formed solely in the form (A), and at a temperature lower than the temperature, T2, at which the supported metal compound is formed solely in the form (B). The compound can be used in particular as a catalyst in a process employing hydrocarbon splitting and recombination reactions, e.g. in a hydrocarbon metathesis reaction, with a greatly increased catalytic activity, in comparison with a supported metal compound which is identical but which would include only the form (A), the form (B) being inactive in this type of reaction.
摘要翻译：本发明涉及一种载体金属化合物，其包括固体载体，其接枝至少两种类型的金属原子Me，金属化合物的A形式，其中金属原子键合至至少一个氢原子和/ 或至少一种烃，另一种为金属化合物的形式B，其中金属原子仅与载体键合，并且任选地与至少一种不是氢原子或烃基的其它元素结合。该化合物可以通过将包含与至少一个烃配体结合的金属Me的有机金属前体P接枝到固体载体上来制备，b通过用氢或还原剂处理由步骤a产生的固体产物，温度高于仅以A型形成负载型金属化合物的温度TI，且温度低于仅以B型形成负载金属化合物的温度T2的温度。化合物可以特别是在使用烃分解和重组反应的方法中用作催化剂，例如在烃复分解反应中，与相同但仅包括A型的负载金属化合物相比，催化活性大大增加，B型在这种反应中是无活性的。

4. 发明申请

WO1996017811A1 ETHYLENE CONVERSION PROCESS 审中-公开
标题翻译：乙烯转化过程
公开(公告)号：WO1996017811A1
公开(公告)日：1996-06-13
申请号：PCT/GB1995002737
申请日：1995-11-23
申请人： BP CHEMICALS LIMITED , MAUNDERS, Barry, Martin
发明人： BP CHEMICALS LIMITED
IPC分类号： C07C11/02
CPC分类号： C07C2/10 , C07C6/04 , C07C11/02 , C07C2521/04 , C07C2521/08 , C07C2523/28 , C07C2523/30 , C07C2523/36 , C07C2523/75 , Y02P20/52
摘要： This invention relates to a process for converting ethylene to a mixture of 1-olefins by (a) feeding ethylene through an oligomerization catalyst bed to form an oligomer predominating in C2-C6 olefins and (b) feeding the oligomer, optionally admixed with fresh ethylene, containing at least 50 % by volume ethylene, through a metathesis catalyst bed to form a product predominating in C2-C6 1-olefins. Steps (a) and (b) can be carried out sequentially and in a single reactor under the same conditions of reaction temperature and pressure. This mitigates the perceived disadvantages of low activity and low conversions of relatively inexpensive oligomerization catalysts and forms oligomer having the desired distribution of 1-olefin components for use as comonomer in a polyolefin process.
摘要翻译：本发明涉及一种将乙烯转化为1-烯烃的混合物的方法，该方法是（a）通过低聚催化剂床进料乙烯以形成在C2-C6烯烃中占优势的低聚物，和（b）进料该低聚物，任选与新鲜乙烯混合，含有至少50体积％的乙烯，通过复分解催化剂床以形成主要在C 2 -C 6 1-烯烃中的产物。步骤（a）和（b）可以在相同的反应温度和压力条件下，在单个反应器中依次进行。这减轻了相对便宜的低聚催化剂的低活性和低转化率的感知缺点，并形成了具有所需分布的1-烯烃组分的低聚物，用作聚烯烃方法中的共聚单体。

5. 发明申请

WO2009063178A1 PROCESS FOR PRODUCING TRIPTANE 审中-公开
标题翻译：生产TRIPTANE的方法
公开(公告)号：WO2009063178A1
公开(公告)日：2009-05-22
申请号：PCT/GB2008/003777
申请日：2008-11-07
申请人： BP P.L.C. , DANIEL, Berian, John , GRACEY, Benjamin, Patrick , LAW, David, John , MAUNDERS, Barry, Martin , SUNLEY, John, Glenn , VAN DER WAAL, Jan, Cornelis
发明人： DANIEL, Berian, John , GRACEY, Benjamin, Patrick , LAW, David, John , MAUNDERS, Barry, Martin , SUNLEY, John, Glenn , VAN DER WAAL, Jan, Cornelis
IPC分类号： C07C2/86 , C07C9/16 , C07C11/02 , B01J29/06
CPC分类号： C07C2/864 , C07C2/865 , C07C2529/08 , C07C2529/12 , C07C2529/14 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/70 , C07C2529/74 , C07C2529/76 , C07C11/02 , C07C9/16
摘要： A process for the production of triptane and/or triptene from methanol and/or one or more derivatives thereof and one or more olefins in the presence of a catalyst at a temperature in the range of from 150 to 4000C, in which the catalyst is a zeolite having Brønsted acidity and has a structure selected from: i. Zeolites having frameworks comprising silicon and aluminium atoms and having channel structure comprising a ring size of 12 or more non-oxygen framework atoms in 2 or 3 dimensions; ii. Zeolites having frameworks comprising silicon and aluminium atoms and which have a framework ring comprising 12 or more non-oxygen atoms accessible on the external surface of the zeolite, and a channel structure in which all of the channels have a ring-size of less than 12 non-oxygen framework atoms, and wherein zeolites of type (ii) comprise alkali metal where methanol is not a reactant.
摘要翻译：在催化剂存在下，在150〜4000℃的温度范围内，由甲醇和/或其一种或多种衍生物和一种或多种烯烃制备三庚烷和/或三丁烯的方法，其中催化剂为沸石具有布朗斯台德酸性并具有选自以下的结构：i。沸石具有包含硅和铝原子并且具有包含2或3个维度的12个或更多个非氧骨架原子的环尺寸的通道结构的骨架; II。具有包含硅和铝原子并且具有包含12个或更多个非氧原子的骨架环的沸石在沸石的外表面上可接触的沸石，以及其中所有通道的环尺寸小于12的通道结构非氧骨架原子，其中（ii）型的沸石包含碱金属，其中甲醇不是反应物。

6. 发明申请

WO2009063177A1 PROCESS FOR PRODUCING TRIPTANE 审中-公开
标题翻译：生产TRIPTANE的方法
公开(公告)号：WO2009063177A1
公开(公告)日：2009-05-22
申请号：PCT/GB2008/003772
申请日：2008-11-07
申请人： BP P.L.C. , DANIEL, Berian, John , LAW, David, John , MAUNDERS, Barry, Martin , SUNLEY, John, Glenn , VAN DER WAAL, Jan, Cornelis
发明人： DANIEL, Berian, John , LAW, David, John , MAUNDERS, Barry, Martin , SUNLEY, John, Glenn , VAN DER WAAL, Jan, Cornelis
IPC分类号： C07C1/20 , C07C9/16 , C07C11/02 , B01J29/06
CPC分类号： C07C29/151 , C07C1/20 , C07C2529/08 , C07C2529/12 , C07C2529/14 , C07C2529/16 , C07C2529/18 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/48 , C07C2529/70 , C07C2529/74 , C07C2529/76 , C07C2529/78 , Y02P20/52 , C07C9/16 , C07C11/02 , C07C31/04 , C07C31/08 , C07C31/10 , C07C31/12
摘要： A process for producing triptane and/or triptene from methanol and/or one or more derivatives thereof, and optionally one or more further alcohols and/or derivatives thereof at a temperature in the range of from 150 to 400 °C, in the presence of a zeolite catalyst having Brønsted acidity, in which all the carbon atoms in the triptane and/or triptene are derived from the methanol and/or one or more derivatives thereof and the optional further alcohols and/or derivatives thereof, the zeolite catalyst being selected from: i. zeolites having frameworks comprising silicon and aluminium atoms at a Si: Al mole ratio of greater than (2), which zeolites also have a channel structure comprising a ring size of (12) or more non-oxygen atoms in (2) or (3) dimensions; and ii. zeolites having frameworks comprising silicon and aluminium atoms, and which have a framework ring comprising (12) or more non-oxygen-atoms accessible on the external surface of the zeolite and a pore structure in which all of the channels have a ring-size of less than (12) non-oxygen atoms. There is also described a process for producing triptane and/or triptene wherein the zeolite catalyst is zeolite X, the reaction composition additionally comprises a C 3 alcohol and/or one or more derivatives thereof, in which the mole ratio of C 3 alcohol : methanol present in the reaction composition, or derivable from the one or more derivatives thereof present in the reaction composition, is greater than 0.23 : 10, and the temperature of the process is in the range of greater than 200° to 400 °C.
摘要翻译：在150-400℃的温度范围内，在甲醇和/或其一种或多种衍生物和任选的一种或多种其它醇和/或其衍生物的存在下，在具有布朗斯台德酸性的沸石催化剂，其中所述三庚烷和/或三丁烯中的所有碳原子来自甲醇和/或其一种或多种衍生物和任选的其它醇和/或衍生物，所述沸石催化剂选自：一世。具有Si：Al摩尔比大于（2）的硅和铝原子的骨架的沸石，该沸石还具有在（2）或（3）中具有包含（12）以上非氧原子的环尺寸的通道结构）尺寸; 和ii。具有包含硅和铝原子的框架的沸石，并且具有包含可在沸石的外表面上的（12）或更多个非氧原子的骨架环和其中所有通道的环状尺寸为小于（12）个非氧原子。还描述了一种制备三庚烷和/或三丁烯的方法，其中沸石催化剂是沸石X，反应组合物另外包含C3醇和/或其一种或多种衍生物，其中存在于C 3醇：甲醇中的摩尔比反应组合物或衍生自反应组合物中的一种或多种衍生物的反应组合物大于0.23:10，并且该方法的温度在大于200-400℃的范围内。

7. 发明申请

WO2004087626A1 AUTOTHERMAL CRACKING PROCESS 审中-公开
标题翻译：自动破碎过程
公开(公告)号：WO2004087626A1
公开(公告)日：2004-10-14
申请号：PCT/GB2004/001278
申请日：2004-03-24
申请人： BP CHEMICALS LIMITED , LITTLE, Ian, Raymond , MAUNDERS, Barry, Martin , MESSENGER, Brian, Edward
发明人： LITTLE, Ian, Raymond , MAUNDERS, Barry, Martin , MESSENGER, Brian, Edward
IPC分类号： C07C5/333
CPC分类号： C07C4/025 , C07C2521/04 , C07C2523/42 , C07C2523/44 , C07C2523/72 , C10G2400/20 , Y02P20/52 , C07C11/04
摘要： The present invention provides a process for the production of olefins which process comprises co-feeding at least one unsaturated hydrocarbon with a paraffinic hydrocarbon-containing feedstock and a molecular oxygen-containing gas to an autothermal cracker, wherein they are reacted in the presence of a catalyst capable of supporting combustion beyond the normal fuel rich limit of flammability to provide a hydrocarbon product stream comprising olefins.
摘要翻译：本发明提供了一种制备烯烃的方法，该方法包括将至少一种不饱和烃与含链烷烃的原料和含分子氧的气体共同给予自热裂化器，其中它们在催化剂能够支持燃烧超过正常燃料富含的可燃性极限以提供包含烯烃的烃产物流。

8. 发明申请

WO2003104173A1 PROCESS FOR MANUFACTURING ALKANES 审中-公开
标题翻译：制造碱的方法
公开(公告)号：WO2003104173A1
公开(公告)日：2003-12-18
申请号：PCT/GB2003/002439
申请日：2003-06-04
申请人： BP CHEMICALS LIMITED , LEFORT, Laurent , MAUNDERS, Barry, Martin , SUNLEY, John, Glenn
发明人： LEFORT, Laurent , MAUNDERS, Barry, Martin , SUNLEY, John, Glenn
IPC分类号： C07C9/00
CPC分类号： C07C2/76 , B01J31/121 , C07C6/10 , C07C2531/12 , C07C9/06 , C07C9/00
摘要： The present invention relates to the manufacture of alkanes comprising an operation in which at least one starting alkane is contacted with a metal catalyst comprising at least one metal, Me, bonded to at least one hydrogen atom and/or to at least one hydrocarbon radical, characterized in that the catalyst is contacted with hydrogen during the manufacture of alkanes. The present invention also relates to a process for the activation of a metal catalyst intended to manufacture alkanes and comprising at least one metal, Me, bonded to at least one hydrogen atom and/or to at least one hydrocarbon radical, which process is characterized in that, during the manufacture of alkanes carried out by contacting the catalyst with at least one starting alkane, the catalyst is contacted with hydrogen. The hydrogen can be used in conjunction with an agent forming hydrogen "in situ" . The starting alkane(s) can be chosen from linear alkanes, branched alkanes and cycloalkanes substituted by at least one linear or branched alkane chain, and from methane and mixtures of methane with one or more of the above-mentioned starting alkanes. The contacting of the catalyst with the hydrogen can be carried out in the presence of the starting alkane(s) in a single zone, in a liquid phase or preferably in a gas phase, and in particular continuously. The contacting can be also carried out in the absence of the starting alkane(s), and the manufacture of alkanes and the activation of the catalyst can be carried out separately, in two separate zones, preferably continuously.
摘要翻译：烷烃的制备本发明涉及烷烃的制备，其包括使至少一种起始烷烃与包含至少一种与至少一个氢原子键合的至少一种金属Me和/或至少一个烃基的金属催化剂接触的操作，其特征在于在烷烃的制造期间催化剂与氢接触。本发明还涉及一种用于活化用于制备烷烃并且包含至少一种键合至至少一个氢原子和/或至少一个烃基的金属Me的金属催化剂的方法，该方法的特征在于在通过使催化剂与至少一种起始烷烃接触而进行的烷烃的制造中，催化剂与氢气接触。氢可以与原位形成氢的试剂结合使用。起始烷烃可以选自被至少一个直链或支链烷烃链取代的直链烷烃，支链烷烃和环烷烃，以及甲烷和甲烷与一种或多种上述起始烷烃的混合物。催化剂与氢的接触可以在起始烷烃存在下在单一区域，液相或优选气相中，特别是连续进行。接触也可以在不存在起始烷烃的情况下进行，烷烃的制备和催化剂的活化可以在两个分开的区域中分开进行，优选连续进行。

9. 发明申请

WO2003104171A1 PROCESS FOR CONVERTING METHANE INTO ETHANE 审中-公开
标题翻译：将甲烷转化成乙烷的方法
公开(公告)号：WO2003104171A1
公开(公告)日：2003-12-18
申请号：PCT/GB2003/002426
申请日：2003-06-04
申请人： BP CHEMICALS LIMITED , BASSET, Jean-Marie , BRES, Philippe , COPERET, Christophe , MAUNDERS, Barry, Martin , SOULIVONG, Daravong , TAOUFIK, Mostafa , THIVOLLE-CAZAT, Jean
发明人： BASSET, Jean-Marie , BRES, Philippe , COPERET, Christophe , MAUNDERS, Barry, Martin , SOULIVONG, Daravong , TAOUFIK, Mostafa , THIVOLLE-CAZAT, Jean
IPC分类号： C07C2/76
CPC分类号： C07C2/76 , C07C2531/12 , Y10S585/943 , C07C9/06
摘要： The invention relates to a process for producing ethane comprising contacting methane with a metal catalyst selected from metal hydrides, metal organic compounds and mixtures thereof. It also relates to a process for the conversion of methane to carbon-containing products comprising contacting methane with a metal catalyst comprising at least one metal, Me, chosen from the lanthanides, the actinides and the metals from Groups 2 to 12 of the Periodic Table of the Elements, so as to produce ethane in a proportion of at least 65%, especially at least 98% or 99% by weight with respect to carbon-containing products formed in the process. The process can be a single-step process, preferably carried out under conditions involving a non-oxidative catalytic coupling of methane, in particular under operating conditions maintained substantially constant, preferably continuously, during the ethane production, e.g. at a temperature ranging from - 30°C to +80°C, preferably from 20°C to 500°C, under a total absolute pressure ranging from 10 -3 to 100 MPa, preferably from 0.1 to 50 MPa. The metal catalyst may be chosen from metal catalysts supported on and preferably grafted to a solid support. One of the main advantages of the present invention is to produce ethane with a very high selectivity.
摘要翻译：本发明涉及一种生产乙烷的方法，包括使甲烷与选自金属氢化物，金属有机化合物及其混合物的金属催化剂接触。它还涉及将甲烷转化为含碳产物的方法，包括使甲烷与包含至少一种金属的金属催化剂接触，所述金属催化剂选自镧系元素，锕系元素和元素周期表第2至12族中的金属的元素，以便相对于在该方法中形成的含碳产品，以至少65重量％，特别是至少98重量％或99重量％的比例制备乙烷。该方法可以是单步骤方法，优选在涉及甲烷的非氧化催化偶合的条件下进行，特别是在乙烷生产期间，优选连续保持基本上恒定的操作条件下，例如乙烷生产。在-30℃至+ 80℃，优选20℃至500℃的温度范围内，在10 -3至100MPa，优选0.1至50MPa的绝对压力下进行。金属催化剂可以选自负载在并优选接枝到固体载体上的金属催化剂。本发明的主要优点之一是以非常高的选择性生产乙烷。

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