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1. 发明申请

WO2009146167A2 FLUORINATED IMPREGNATED CATALYST SYSTEMS AND METHODS OF FORMING THE SAME 审中-公开
标题翻译：氟化的印制催化剂体系及其形成方法
公开(公告)号：WO2009146167A2
公开(公告)日：2009-12-03
申请号：PCT/US2009/040470
申请日：2009-04-14
申请人： FINA TECHNOLOGY, INC. , MARIN, Vladimir
发明人： MARIN, Vladimir
IPC分类号： B01J27/12 , B01J27/125
CPC分类号： C08F10/00 , Y10S526/943 , C08F4/52 , C08F4/02
摘要： Methods of forming supported catalyst systems, supported catalyst systems and polymerization processes utilizing the supported catalyst systems are described herein. The methods generally include providing an inorganic support material and contacting the inorganic support material with a support solvent to form a support solution. The methods further include contacting the support solution with a fluorine containing compound represented by the formula AlF p X 3.p B q to impregnate the fluorine containing compound within the inorganic support material and form an intermediate, wherein X is selected from Cl, Br and OH', B is H 2 O, p is selected from 1 to 3 and q is selected from O to 6. hi addition, the methods include drying the intermediate to remove the solvent therefrom and heating the intermediate at a temperature of at least about 300°C to form an impregnated support and contacting the impregnated support with a transition metal compound to form a supported catalyst system, wherein the transition metal compound is represented by the formula [L] m M[A] n ; wherein L is a bulky ligand, A is a leaving group, M is a transition metal and m and n are such that a total ligand valency corresponds to the transition metal valency.
摘要翻译：在此描述形成负载型催化剂体系的方法，负载型催化剂体系和利用负载型催化剂体系的聚合方法。所述方法通常包括提供无机载体材料并使无机载体材料与支持溶剂接触以形成支持溶液。所述方法还包括使支持溶液与由式AlFpX3.pBq表示的含氟化合物接触以浸渍无机载体材料中的含氟化合物并形成中间体，其中X选自Cl，Br和OH'，B是 H 2 O，p选自1至3，q选自O至6.此外，所述方法包括干燥中间体以除去溶剂，并在至少约300℃的温度下加热中间体以形成浸渍支撑和接触浸渍的载体与过渡金属化合物以形成负载型催化剂体系，其中过渡金属化合物由式[L] mM [A] n表示; 其中L是大体积配体，A是离去基团，M是过渡金属，m和n使总配体的化合价对应于过渡金属的价态。

2. 发明申请

WO2007127426A3 FLUORINATED TRANSITION METAL CATALYSTS AND FORMATION THEREOF 审中-公开
标题翻译：氟化过渡金属催化剂及其形成
公开(公告)号：WO2007127426A3
公开(公告)日：2008-08-14
申请号：PCT/US2007010334
申请日：2007-04-27
申请人： FINA TECHNOLOGY , ABBAS RAZAVI , MARIN VLADIMIR , LOPEZ MARGARITO
发明人： ABBAS RAZAVI , MARIN VLADIMIR , LOPEZ MARGARITO
IPC分类号： C08F4/02 , B01J31/22 , C08F4/6392 , C08F4/6592
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65927 , C08F110/02 , C08F110/06 , C08F4/65916 , C08F2500/12 , C08F2500/15 , C08F2500/20 , C08F2500/04
摘要： Supported catalyst systems and methods of forming the same are generally described herein. The methods generally include providing a support material including silica-alumina prepared by cogel methods, contacting the support material with a fluorinating agent to form a fluorinated support and contacting the fluorinated support with a transition metal compound to form a supported catalyst system.
摘要翻译：载体催化剂体系及其形成方法一般在此描述。方法通常包括提供包括通过共凝胶法制备的二氧化硅 - 氧化铝的载体材料，使载体材料与氟化剂接触以形成氟化载体，并使氟化载体与过渡金属化合物接触以形成负载型催化剂体系。

3. 发明申请

WO2007127415A8 PROCESS FOR POLYOLEFIN PRODUCTION USING FLUORINATED TRANSITION METAL CATALYSTS HAVING A LOW PH 审中-公开
标题翻译：使用具有低pH的氟化过渡金属催化剂生产聚烯烃的方法
公开(公告)号：WO2007127415A8
公开(公告)日：2008-04-03
申请号：PCT/US2007010317
申请日：2007-04-27
申请人： FINA TECHNOLOGY , ABBAS RAZAVI , MARIN VLADIMIR , LOPEZ MARGARITO
发明人： ABBAS RAZAVI , MARIN VLADIMIR , LOPEZ MARGARITO
IPC分类号： C08F4/06 , B01J21/00
CPC分类号： B01J21/12 , B01J37/26 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F10/06 , C08F110/06 , C08F210/06 , C08F2400/02 , C08F4/65916 , C08F4/025 , C08F2500/12 , C08F2500/15 , C08F2500/16 , C08F2/00 , C08F2500/20 , C08F2500/03 , C08F210/14 , C08F2500/04 , C08F210/16
摘要： Catalyst systems, polymers and methods of forming the same are described herein. The catalyst systems generally include an inorganic support material having a bonding sequence selected from Si-O-Al-F, F-Si-O-Al, F-Si-O-Al-F and combinations thereof, wherein the inorganic support material has an acid strength (pKa) of less than about 4.8 and a transition metal compound, wherein the transition metal compound is represented by the formula [L] m M[A] n ; wherein L is a bulky ligand, A is a leaving group, M is a transition metal and m and n are such that a total ligand valency corresponds to a transition metal valency.
摘要翻译：本文描述了催化剂体系，聚合物及其形成方法。催化剂体系通常包括具有选自Si-O-Al-F，F-Si-O-Al，F-Si-O-Al-F及其组合的键合顺序的无机载体材料，其中无机载体材料具有小于约4.8的酸强度（pKa）和过渡金属化合物，其中过渡金属化合物由式[L]表示：M [A] _{n ; 其中L是大体积配体，A是离去基团，M是过渡金属，m和n使得总配体价对应于过渡金属化合价。}

4. 发明申请

WO2007127465A3 FLUORINATED TRANSITION METAL CATALYSTS AND FORMATION THEREOF 审中-公开
标题翻译：氟化过渡金属催化剂及其形成
公开(公告)号：WO2007127465A3
公开(公告)日：2008-01-31
申请号：PCT/US2007010435
申请日：2007-04-27
申请人： FINA TECHNOLOGY , LOPEZ MARGARITO , MARIN VLADIMIR , ABBAS RAZAVI
发明人： LOPEZ MARGARITO , MARIN VLADIMIR , ABBAS RAZAVI
IPC分类号： C08F10/00
CPC分类号： B01J21/12 , B01J37/26 , C08F10/00 , C08F10/06 , C08F110/06 , C08F210/06 , C08F2400/02 , C08F2/00 , C08F4/025 , C08F2500/20 , C08F2500/03 , C08F2500/12 , C08F210/14 , C08F2500/04 , C08F210/16
摘要： Supported catalyst systems and methods of forming the same are generally described herein. The methods generally include providing an inorganic support composition, wherein the inorganic support composition includes a bonding sequence selected from Si-O-Al-F, F-Si-O-Al, F-Si1O-Al-F and combinations thereof and contacting the inorganic support composition with a transition metal compound to form a supported catalyst system, wherein the transition metal compound is represented by the formula [L]1nM[A]n; wherein L is a bulky ligand, A is a leaving group, M is a transition metal and m and n are such that a total ligand valency corresponds to the transition metal valency.
摘要翻译：载体催化剂体系及其形成方法一般在此描述。所述方法通常包括提供无机载体组合物，其中所述无机载体组合物包含选自Si-O-Al-F，F-Si-O-Al，F-Si10-Al-F及其组合的键合顺序，无机载体组合物与过渡金属化合物形成负载型催化剂体系，其中过渡金属化合物由式[L] 1nM [A] n表示; 其中L是大体积配体，A是离去基团，M是过渡金属，m和n使总配体的化合价对应于过渡金属的价态。

5. 发明申请

WO2007022243A3 BIDENTATE CATALYST FOR OLEFIN POLYMERIZATION, METHODS OF FORMING SUCH AND PRODUCTS THEREFROM 审中-公开
标题翻译：用于烯烃聚合的二元催化剂，其形成方法及其产物
公开(公告)号：WO2007022243A3
公开(公告)日：2007-12-13
申请号：PCT/US2006031949
申请日：2006-08-16
申请人： FINA TECHNOLOGY , RAZAVI ABBAS , MARIN VLADIMIR , LOPEZ MARGARITO
发明人： RAZAVI ABBAS , MARIN VLADIMIR , LOPEZ MARGARITO
IPC分类号： C07F7/00 , C07F7/28 , C07F9/00 , C08F4/602 , C08F4/64
CPC分类号： C08F10/00 , B01J31/1825 , B01J2231/122 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/65916 , C08F110/02 , C08F110/06 , C08F4/64048 , C08F4/659 , C08F2500/04 , C08F2500/15
摘要： Bidentate catalyst systems and the methods or forming such are described herein. The catalyst systems generally are compounds having the general formula: where R, R 1 , R 2 and R 3 are optional and independently selected from hydrogen, C 1 to C 20 alkyl groups or C6 to C20 aryl groups, A' and A" are independently selected from coordination groups, M is a Group 4 or 5 transition metal, X is selected from halogens, alkyl groups, aromatic groups or combinations thereof and n is less than 4.
摘要翻译：本文描述了双齿催化剂体系及其形成方法。催化剂体系通常是具有以下通式的化合物：其中R 1，R 2，R 2和R 3是任选的并且独立地选自氢，C 1至C 20烷基或C 6至C 20芳基，A'和A“独立地选自配位基，M为第4族或第5族过渡金属 X选自卤素，烷基，芳族基团或其组合，并且n小于4。

6. 发明申请

WO2007127417A2 PROCESS FOR POLYOLEFINE PRODUCTION USING FLUORINATED TRANSITION METAL CATALYSTS 审中-公开
标题翻译：使用氟化过渡金属催化剂生产聚烯烃的方法
公开(公告)号：WO2007127417A2
公开(公告)日：2007-11-08
申请号：PCT/US2007/010319
申请日：2007-04-27
申请人： FINA TECHNOLOGY, INC. , ABBAS, Razavi , MARIN, Vladimir , LOPEZ, Margarito
发明人： ABBAS, Razavi , MARIN, Vladimir , LOPEZ, Margarito
IPC分类号： C08F4/44 , B01J31/00
CPC分类号： C08F10/00 , B01J31/143 , B01J31/1616 , B01J31/2295 , B01J2231/122 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/65927 , C08F10/06 , C08F110/06 , C08F4/65916 , C08F4/025 , C08F2500/20
摘要： Supported catalyst systems, methods of forming polyolefins and the formed polymers are generally described herein. The methods generally include identifying desired polymer properties, providing a transition metal compound and selecting a support material capable of producing the desired polymer properties, wherein the support material includes a bonding sequence selected from Si-O-Al-F, F-Si-O-Al, F- Si-O-Al-F and combinations thereof.
摘要翻译：载体催化剂体系，形成聚烯烃的方法和形成的聚合物通常在本文中描述。所述方法通常包括鉴定所需的聚合物性质，提供过渡金属化合物和选择能够产生所需聚合物性质的载体材料，其中载体材料包括选自Si-O-Al-F，F-Si-O -Al，F-Si-O-Al-F及其组合。

7. 发明申请

WO2007022244A2 PREPARATION AND USE OF TETRASUBSTITUTED FLUORENYL CATALYSTS FOR POLMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的四取代芴酮催化剂的制备和应用
公开(公告)号：WO2007022244A2
公开(公告)日：2007-02-22
申请号：PCT/US2006/031950
申请日：2006-08-16
申请人： FINA TECHNOLOGY, INC. , MARIN, Vladimir , RAZAVI, Abbas
发明人： MARIN, Vladimir , RAZAVI, Abbas
IPC分类号： C08F4/44 , B01J31/00 , C08F110/06
CPC分类号： C07F7/00 , B01J31/2282 , B01J2231/122 , B01J2531/0263 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/06 , Y10S526/943 , C08F4/65927 , C08F2500/20 , C08F2500/12 , C08F2500/04 , C08F2500/03
摘要： Catalyst compositions and processes for the polymerization of ethylenically unsaturated monomers to produce polymers, including copolymers or homopolymers. Such monomers include ethylene, C 3+ alpha olefins and substituted vinyl compounds, such as styrene and vinyl chloride. The polymerization catalyst characterized by the formula B(FIuL)MQ n in which Flu is a fluorenyl group substituted at at least the 2,7- and 3,6-positions by hydrocarbyl groups, preferably relatively bulky hydrocarbyl groups. L is a substituted or unsubstituted cyclopentadienyl, indenyl or fluorenyl group or a heteroorgano group, XR, in which X is a heteroatom from Group 15 or 16 of the Periodic Table of Elements, such as nitrogen, R is an alkyl group, a cycloalkyl group or an aryl group and B is a structural bridge extending between the groups L and Flu, which imparts stereorigidity to the ligand structure, M is a Group 4 or Group 5 transition metal, such as titanium, zirconium or hafnium and Q is selected from the group consisting of chlorine, bromine, iodine, an alkyl group, an amino group, an aromatic group and mixtures thereof, with n being 1or 2.
摘要翻译：用于烯属不饱和单体聚合以制备聚合物（包括共聚物或均聚物）的催化剂组合物和方法。这样的单体包括乙烯，C 3 +α烯烃和取代的乙烯基化合物，例如苯乙烯和氯乙烯。由式B（FIuL）MQ n表示的聚合催化剂，其中Flu是在至少2,7-和3,6位被烃基取代的芴基，优选相对大体积的烃基组。 L是取代或未取代的环戊二烯基，茚基或芴基或杂环基XR，其中X是元素周期表第15或16族的杂原子，如氮，R是烷基，环烷基或芳基，B是在L和Flu之间延伸的结构桥，其赋予配体结构立体刚性，M是第4族或第5族过渡金属，如钛，锆或铪，Q选自由氯，溴，碘，烷基，氨基，芳族基及其混合物组成的基团，其中n为1或2。

8. 发明申请

WO2007022243A2 BIDENTATE CATALYST FOR OLEFIN POLYMERIZATION, METHODS OF FORMING SUCH AND PRODUCTS THEREFROM 审中-公开
标题翻译：用于烯烃聚合的双向催化剂，其形成方法和产品
公开(公告)号：WO2007022243A2
公开(公告)日：2007-02-22
申请号：PCT/US2006/031949
申请日：2006-08-16
申请人： FINA TECHNOLOGY, INC. , RAZAVI, Abbas , MARIN, Vladimir , LOPEZ, Margarito
发明人： RAZAVI, Abbas , MARIN, Vladimir , LOPEZ, Margarito
IPC分类号： C08F4/44 , B01J31/00 , C08F110/06
CPC分类号： C08F10/00 , B01J31/1825 , B01J2231/122 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/65916 , C08F110/02 , C08F110/06 , C08F4/64048 , C08F4/659 , C08F2500/04 , C08F2500/15
摘要： Bidentate catalyst systems and the methods or forming such are described herein. The catalyst systems generally are compounds having the general formula: where R, R 1 , R 2 and R 3 are optional and independently selected from hydrogen, C 1 to C 20 alkyl groups or C6 to C20 aryl groups, A' and A" are independently selected from coordination groups, M is a Group 4 or 5 transition metal, X is selected from halogens, alkyl groups, aromatic groups or combinations thereof and n is less than 4.
摘要翻译：双齿催化剂体系和方法或形成方法在本文中描述。催化剂体系通常是具有以下通式的化合物：其中R 1，R 2，R 2和R 3是任选的，并且独立地选自氢 C 1至C 20烷基或C 6至C 20芳基，A'和A“独立地选自配位基团，M为第4或5族过渡金属 X选自卤素，烷基，芳基或其组合，n小于4。

9. 发明申请

WO2007127466A3 PROCESS FOR POLYOLEFINE PRODUCTION USING FLUORINATED TRANSITION METAL CATALYSTS 审中-公开
标题翻译：用含氟过渡金属催化剂生产聚烯烃的方法
公开(公告)号：WO2007127466A3
公开(公告)日：2007-12-21
申请号：PCT/US2007010436
申请日：2007-04-27
申请人： FINA TECHNOLOGY , ABBAS RAZAVI , MARIN VLADIMIR , LOPEZ MARGARITO
发明人： ABBAS RAZAVI , MARIN VLADIMIR , LOPEZ MARGARITO
IPC分类号： C08F10/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65927 , C08F10/06 , C08F110/06 , C08F210/06 , C08F4/65916 , C08F4/025 , C08F2500/15 , C08F2500/03 , C08F2500/20 , C08F210/16 , C08F2500/12
摘要： Supported catalyst systems and methods of forming polyolefins are generally described herein. The polymerization methods generally include introducing an inorganic support material to a reaction zone, wherein the inorganic support material includes a bonding sequence selected from Si-O-Al-F, F-Si-O-Al, F-Si-O-Al-F and combinations thereof, introducing a transition metal compound to the reaction zone and contacting the transition metal compound with the inorganic support material for in situ activation/heterogenization of the transition metal compound to form a catalyst system. The method further includes introducing an olefin monomer to the reaction zone and contacting the catalyst system with the olefin monomer to form a polyolefin.
摘要翻译：本文一般描述负载型催化剂体系和形成聚烯烃的方法。聚合方法通常包括将无机载体材料引入反应区，其中无机载体材料包括选自Si-O-Al-F，F-Si-O-Al，F-Si-O-Al- F及其组合，将过渡金属化合物引入反应区并使过渡金属化合物与无机载体材料接触，以便过渡金属化合物原位活化/多相化以形成催化剂体系。该方法还包括将烯烃单体引入反应区并使催化剂体系与烯烃单体接触以形成聚烯烃。

10. 发明申请

WO2007127414A2 PROCESS FOR COPOLYMER PRODUCTION USING FLUORINATED TRANSITION METAL CATALYSTS 审中-公开
标题翻译：用含氟过渡金属催化剂生产共聚物的方法
公开(公告)号：WO2007127414A2
公开(公告)日：2007-11-08
申请号：PCT/US2007/010316
申请日：2007-04-27
申请人： FINA TECHNOLOGY, INC. , ABBAS, Razavi , MARIN, Vladimir , LOPEZ, Margarito
发明人： ABBAS, Razavi , MARIN, Vladimir , LOPEZ, Margarito
IPC分类号： C08F4/44 , B01J31/00
CPC分类号： C08F10/00 , B01J31/1658 , B01J31/2295 , B01J2231/122 , B01J2531/46 , B01J2531/48 , C08F4/65904 , C08F4/65912 , C08F4/65927 , C08F10/06 , C08F110/06 , C08F210/06 , C08F4/65916 , C08F4/025 , C08F2500/20 , C08F2500/03 , C08F2500/12 , C08F210/16 , C08F210/14 , C08F212/08
摘要： Copolymers and methods of forming copolymers are described herein. The methods generally include providing a transition metal compound represented by the formula [L] m M[A] n , wherein L is a bulky ligand including bis-indenyl, A is a leaving group, M is a transition metal and m and n are such that the total ligand valency corresponds to the transition metal valency and providing a support material having a bonding sequence selected from Si-O-Al-F, F-Si-O-Al, F-Si-O-Al-F and combinations thereof. The methods further include contacting the transition metal compound with the support material to form an active supported catalyst system, wherein the contact of the transition metal compound with the support material occurs in proximity to contact with monomer and contacting the active supported catalyst system with a plurality of monomers to form an olefin copolymer.
摘要翻译：本文描述了共聚物和形成共聚物的方法。该方法通常包括提供由式[L] m M [A] n表示的过渡金属化合物，其中L是庞大的配体，包括双茚基，A是离去基团，M是过渡金属，m和n是总配体价对应于过渡金属化合价并提供具有选自Si-O-Al-F，F-Si-O Al，F-Si-O-Al-F及其组合。所述方法进一步包括使所述过渡金属化合物与所述载体材料接触以形成活性负载型催化剂体系，其中所述过渡金属化合物与所述载体材料的接触发生在接近单体并使所述活性负载型催化剂体系与多个的单体形成烯烃共聚物。

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