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1. 发明申请

WO1996035655A1 AROMATIC ETHER ACYLATION PROCESS 审中-公开
标题翻译：芳香醚类化学方法
公开(公告)号：WO1996035655A1
公开(公告)日：1996-11-14
申请号：PCT/FR1996000716
申请日：1996-05-10
申请人： RHONE-POULENC CHIMIE , INSTITUT FRANÇAIS DU PETROLE , SPAGNOL, Michel , GILBERT, Laurent , BENAZZI, Eric , MARCILLY, Christian
发明人： RHONE-POULENC CHIMIE , INSTITUT FRANÇAIS DU PETROLE
IPC分类号： C07C45/46
CPC分类号： B01J29/084 , C07C45/46 , C07C49/84
摘要： An aromatic ether acylation process is described, particularly a process for acylating a substituted aromatic ether and more particularly veratrol. The method of the invention includes reacting the ether with an acylation agent in the presence of a zeolite catalyst, and is characterised in that the acylation reaction is conducted in the presence of an effective amount of a catalyst containing a faujasite type zeolite or zeolite Y with the following physical and chemical characteristics: an atomic ratio, designated as "global Si:Me ", between the number of atoms of the silicon component and the number of atoms of any trivalent component Me contained in the zeolite, in the range of 2.4 to 90, preferably of 2.4 to 75 and even more preferably of 2.4 to 60, and an alkali metal Me content such that the atomic ratio Me :Me between the number of atoms of the alkali metal Me and that of any trivalent component Me contained in the zeolite matrix, is lower that 0.2, preferably lower than 0.1 and even more preferably, lower than 0.05.
摘要翻译：描述了芳族醚酰化方法，特别是用于酰化取代的芳族醚，更特别是藜芦醇的方法。本发明的方法包括使醚与酰化剂在沸石催化剂存在下反应，其特征在于酰化反应在有效量的含有八面沸石型沸石或沸石Y的催化剂存在下进行，以下物理和化学特性：在硅组分的原子数与沸石中所含的任何三价组分Me 1的原子数之间的原子比，称为“全局Si：Me <1” 在2.4至90，优选2.4至75，甚至更优选2.4至60的范围内，并且碱金属Me 2的含量使得原子比Me 2之间的原子比Me 2（IV）包含在沸石基质中的碱金属Me 2和任何三价组分Me <1（IV）>的原子数小于0.2，优选低于0.1，甚至更优选低于0.05。

2. 发明申请

WO1997009397A1 SELECTIVE HYDROISOMERISATION METHOD FOR STRAIGHT AND/OR SLIGHTLY BRANCHED LONG PARAFFINS, USING A MOLECULAR SIEVE CATALYST 审中-公开
标题翻译：选择性水解方法用于直接和/或轻度分配的长尾巴，使用分子筛催化剂
公开(公告)号：WO1997009397A1
公开(公告)日：1997-03-13
申请号：PCT/FR1996001364
申请日：1996-09-05
申请人： INSTITUT FRANÇAIS DU PETROLE , MARTENS, Johan , SOUVERIJNS, Wim , PARTON, Rudy , FROMENT, Gilbert , MARCILLY, Christian , BENAZZI, Eric , GEORGE-MARCHAL, Nathalie
发明人： INSTITUT FRANÇAIS DU PETROLE
IPC分类号： C10G45/64
CPC分类号： B01J29/7284 , B01J29/126 , B01J29/65 , B01J29/70 , B01J29/72 , B01J29/74 , B01J29/7484 , B01J29/78 , B01J29/7884 , B01J2229/26 , B01J2229/42 , C10G45/64
摘要： The invention pertains to a selective hydroisomerisation method for compounds with one or more n-alkane chains containing 10 carbon atoms or less, wherein said compound to be treated is contacted with a catalyst including at least one hydro-dehydrogenating component and at least one molecular sieve with a one- or two-dimensional porous matrix, the accessible pore openings being defined by 10 hydrogen atoms, and the so-called bridge width between the pores being less that 0.70 nm. The catalyst, under a standard n-heptadecane isomerisation test and for a conversion rate of 95 %, has an isomerised product selectivity of at least 70 %. The sieve is preferably a NU-10, NU-23, NU-87, EU-13 or Theta-1 zeolite.
摘要翻译：本发明涉及具有一个或多个含有10个或更少碳原子的正烷烃链的化合物的选择性加氢异构化方法，其中所述待处理化合物与包含至少一种加氢脱氢组分和至少一种分子筛使用一维或二维多孔基质，可接近的孔隙由10个氢原子定义，所谓的孔之间的桥宽小于0.70nm。在标准正十七烷异构化试验和95％的转化率下，催化剂具有至少70％的异构化产物选择性。筛子优选为NU-10，NU-23，NU-87，EU-13或Theta-1沸石。

3. 发明申请

WO1996035656A1 AROMATIC ETHER ACYLATION PROCESS 审中-公开
标题翻译：芳香醚类化学方法
公开(公告)号：WO1996035656A1
公开(公告)日：1996-11-14
申请号：PCT/FR1996000717
申请日：1996-05-10
申请人： RHONE-POULENC CHIMIE , INSTITUT FRANÇAIS DU PETROLE , SPAGNOL, Michel , GILBERT, Laurent , BENAZZI, Eric , MARCILLY, Christian
发明人： RHONE-POULENC CHIMIE , INSTITUT FRANÇAIS DU PETROLE
IPC分类号： C07C45/46
CPC分类号： B01J29/04 , C07C45/46 , C07C49/84
摘要： An aromatic ether acylation process is described, particularly a process for acylating an unsubstituted aromatic ether and more particularly anisol. The process of the invention includes reacting the ether with an acylation agent in the presence of a zeolite catalyst, and is characterised in that the acylation reaction is conducted in the presence of an effective amount of a catalyst containing a beta zeolite with an atomic ratio, designated as "global Si:Me " between the number of atoms of the silicon component and the number of atoms of any trivalent component Me contained in the zeolite, higher or equal to 15, preferably in the range of 15 to 55 and even more preferably of 18 to 35.
摘要翻译：描述了芳族醚酰化方法，特别是用于酰化未取代的芳族醚，更特别是苯甲醚的方法。本发明的方法包括在沸石催化剂存在下使醚与酰化剂反应，其特征在于酰化反应在有效量的含有原子比的β沸石的催化剂的存在下进行，在硅组分的原子数和沸石中所含的任何三价组分Me 1的原子数之间的“全局Si：Me”指定为“全局Si：Me”，高于或等于15，优选在15的范围内至55，甚至更优选为18至35。

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