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    • 3. 发明申请
    • ELECTROCHROMIC LITHIUM NICKEL GROUP 6 MIXED METAL OXIDES
    • 电致发光镍铬合金6混合金属氧化物
    • WO2014143410A1
    • 2014-09-18
    • PCT/US2014/012347
    • 2014-01-21
    • KINESTRAL TECHNOLOGIES, INC.
    • CHOI, Hye JinBAILEY, MarkBASS, John DavidVON KUGELGEN, Stephen WinthropLACHMAN, EricTURNER, Howard W.BIGI, Julian P.
    • G02F1/15
    • G02F1/1533G02F1/1523Y10T428/265
    • Multi-layer electrochromic structures comprising an anodic electrochromic layer comprising a lithium nickel oxide composition on a first substrate, the anodic electrochromic layer comprising lithium, nickel and a Group 6 metal selected from molybdenum, tungsten and a combination thereof, wherein (i) the atomic ratio of lithium to the combined amount of nickel, molybdenum, and tungsten in the anodic electrochromic layer is at least 0.4:1, respectively, (ii) the atomic ratio of the combined amount of molybdenum and tungsten to the combined amount of nickel, molybdenum and tungsten in the anodic electrochromic layer is at least about 0.025:1, respectively, and (iii) the anodic electrochromic layer exhibits an interplanar distance (d-spacing) of at least 2.5 as measured by X-ray diffraction (XRD), comprises at least 0.05 wt.% carbon, and/or has a coloration efficiency absolute value of at least 19 cm2/C.
    • 多层电致变色结构包括在第一衬底上包含锂镍氧化物组合物的阳极电致变色层,阳极电致变色层包含锂,镍和选自钼,钨及其组合的第6族金属,其中(i)原子 在阳极电致变色层中锂与镍,钼和钨的组合量的比例分别为至少0.4:1,(ii)钼和钨的组合量与镍,钼的组合量的原子比 阳极电致变色层中的钨分别为至少约0.025:1,(iii)通过X射线衍射(XRD)测量,阳极电致变色层的平面间距(d间距)至少为2.5,包括 至少0.05重量%的碳,和/或具有至少19cm 2 /℃的着色效率绝对值。
    • 4. 发明申请
    • PROCESS FOR PREPARING A MULTI-LAYER ELECTROCHROMIC STRUCTURE
    • 制备多层电致发光结构的方法
    • WO2014113795A1
    • 2014-07-24
    • PCT/US2014/012338
    • 2014-01-21
    • KINESTRAL TECHNOLOGIES, INC.
    • CHOI, Hye JinBAILEY, MarkBASS, John, DavidVON KUGELGEN, Stephen, WinthropLACHMAN, EricTURNER, Howard, W.
    • G02F1/15
    • G02F1/1523
    • A wet chemistry process for preparing a multi-layer electrochromic structure comprising depositing a film of a liquid mixture comprising lithium, nickel, and at least one bleached state stabilizing element on a surface of a substrate and treating the deposited film to form an anodic electrochromic layer comprising a lithium nickel oxide composition on the surface of the substrate, the anodic electrochromic layer comprising lithium, nickel and the bleached state stabilizing element(s) wherein (i) the atomic ratio of lithium to the combined amount of nickel and the bleached state stabilizing element(s) in the lithium nickel oxide composition is at least 0.4:1, respectively, (ii) the atomic ratio of the combined amount of the bleached state stabilizing element(s) to the combined amount of nickel and the bleached state stabilizing elements in the lithium nickel oxide composition is at least about 0.025:1, respectively, and (iii) the bleached state stabilizing element(s) is/are selected from the group consisting of Y, Ti, Zr, Hf, V, Nb, Ta, Mo, W, B, Al, Ga, In, Si, Ge, Sn, P, Sb and combinations thereof.
    • 一种用于制备多层电致变色结构的湿式化学方法,包括在基材的表面上沉积包含锂,镍和至少一种漂白状态稳定元素的液体混合物的膜,并处理沉积膜以形成阳极电致变色层 在基底表面上包含锂镍氧化物组合物,阳极电致变色层包含锂,镍和漂白状态稳定元素,其中(i)锂与镍的组合量的原子比和漂白状态稳定 锂镍氧化物组合物中的元素分别为至少0.4:1,(ii)漂白状态稳定化元素的组合量与镍和漂白状态稳定元素的组合量的原子比 在锂镍氧化物组合物中分别为至少约0.025:1,和(iii)漂白状态稳定化元素选自 m,由Y,Ti,Zr,Hf,V,Nb,Ta,Mo,W,B,Al,Ga,In,Si,Ge,Sn,P,Sb及其组合组成的组。