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    • 5. 发明申请
    • PROPYLENE HOMOPOLYMERS FOR BIAXIALLY ORIENTED FILMS
    • 用于双向定向膜的丙烯共聚物
    • WO2005056617A1
    • 2005-06-23
    • PCT/US2004/033752
    • 2004-10-13
    • SUNOCO, INC. (R & M)KIM, Sehyun
    • KIM, Sehyun
    • C08F110/06
    • C08J5/18C08F110/06C08J2323/12Y10S428/91Y10T428/31855C08F2500/12C08F2500/15C08F2500/26
    • Propylene homopolymers useful in the manufacture of biaxially oriented films are provided. More particularly, the propylene homopolymers of the present invention are useful as core material for a multilayer biaxially oriented film. The propylene homopolymers of the present invention attain these properties by control of the average meso sequence length, N m , in the xylene insoluble phase of the polymer concurrently with control of the quantity of xylene solubles in the polymer as a whole. The propylene homopolymers according to the current invention comprise from about 97 to about 91 percent by weight of a xylene insoluble fraction, and from about 9 to about 3 percent by weight of a xylene soluble fraction. The xylene insoluble fraction has a meso run length of less than or equal to 130. Further, the ratio, r , of the meso run length of the xylene insoluble fraction to the percent content of the xylene soluble fraction in the propylene homopolymers is 22 or less, as determined by the equation: where: Nm = average meso sequence length of the xylene insoluble fraction; and %XS = the percent content of xylene solubles in the propylene homopolymer.
    • 提供了可用于制造双轴取向膜的丙烯均聚物。 更具体地,本发明的丙烯均聚物可用作多层双轴取向膜的芯材。 本发明的丙烯均聚物通过控制聚合物的二甲苯不溶相的平均内消旋长度Nm,同时控制聚合物中二甲苯可溶物的总量而获得这些性能。 根据本发明的丙烯均聚物包含约97至约91重量%的二甲苯不溶部分和约9至约3重量%的二甲苯可溶部分。 二甲苯不溶级分的中间游程长度小于或等于130.此外,二甲苯不溶部分的介观游程长度与丙烯均聚物中二甲苯可溶部分的百分比的比值r为22或 由下式确定:其中:Nm =二甲苯不溶部分的平均中观序列长度; 和%XS =丙烯均聚物中二甲苯可溶物的含量百分比。