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    • 1. 发明申请
    • METHOD FOR TREATING CARBONACEOUS MATERIALS
    • 处理碳材料的方法
    • WO2003074639A1
    • 2003-09-12
    • PCT/AU2003/000258
    • 2003-03-05
    • KARALEE RESEARCH PTY LTDLLOYD, Robert
    • LLOYD, Robert
    • C10L9/02
    • C10L9/02
    • Process for reducing the amount of sulfur-containing impurities in carbonaceous materials are described. One process comprises contacting the materials with an aqueous solution of hydrofluorosilicic acid in the absence of hydrogen fluoride under conditions wherein at least some of the sulfur-containing impurities react with the hydrofluorosilicic acid to form reaction products and separating the reaction products from the carbonaceous materials. Another process comprises contacting the materials with an aqueous solution of hydrofluorosilicic acid in the absence of hydrogen fluoride under conditions wherein at least some of the sulfur-containing impurities react with the hydrofluorosilicic acid to form reaction products, separating the reaction products and the hydrofluorosilicic acid from the carbonaceous materials and subsequently treating the carbonaceous materials with a fluorine acid solution which comprises an aqueous solution of hydrofluorosilicic acid and hydrogen fluoride. A further process comprises treating the carbonaceous materials with a fluorine acid solution which comprises an aqueous solution of hydrofluorosilicic acid and hydrogen fluoride, separating the carbonaceous materials from the aqueous solution of hydrofluorosilicic acid and hydrogen fluoride, and then contacting the carbonaceous materials with an organic solvent capable of dissolving elemental sulfur.
    • 描述了用于减少碳质材料中的含硫杂质的量的方法。 一种方法包括在不存在氟化氢的条件下使材料与氢氟硅酸的水溶液接触,其中至少一些含硫杂质与氢氟硅酸反应以形成反应产物并将反应产物与碳质材料分离。 另一种方法包括在不存在氟化氢的条件下使材料与氢氟硅酸的水溶液接触,其中至少一些含硫杂质与氢氟硅酸反应以形成反应产物,将反应产物和氢氟硅酸从 碳质材料,随后用包含氢氟硅酸和氟化氢水溶液的氟酸溶液处理碳质材料。 另外的方法包括用包含氢氟硅酸和氟化氢水溶液的氟酸溶液处理含碳物质,从含氟硅酸和氟化氢的水溶液中分离含碳材料,然后将碳质材料与有机溶剂接触 能够溶解元素硫。