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1. 发明申请

WO2008120985A1 LIQUID CURABLE RESIN COMPOSITION FOR OPTICAL FIBER TAPES 审中-公开
标题翻译：用于光纤带的液体可固化树脂组合物
公开(公告)号：WO2008120985A1
公开(公告)日：2008-10-09
申请号：PCT/NL2008/050180
申请日：2008-03-28
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , YAMAGUCHI, Hiroshi , KAMO, Satoshi , KUROSAWA, Takahiko
发明人： YAMAGUCHI, Hiroshi , KAMO, Satoshi , KUROSAWA, Takahiko
IPC分类号： C09D4/06 , C09D175/00 , C03C25/00
CPC分类号： C09D4/06 , C08G18/672 , C08G18/8175 , C09D175/16 , G02B6/448 , G02B6/4486 , C08G18/48
摘要： An optical fiber ribbon with a double layer structure comprising a first ribbon formed by bundling optical fibers using a first ribbon layer and a second ribbon formed by bundling the first ribbons using a second ribbon layer is described and claimed. The first ribbon layer is produced by curing a curable liquid resin composition, Composition 1, comprising: (Al) a urethane (meth)acrylate having a bisphenol structure; (A2) si urethane (meth)acrylate obtained by reacting an aliphatic polyather polyol, a polyisocyanate, and a hydroxyl group-containing (meth)acrylate; (B) a compound having a bisphenol structure and an ethylenically unsaturated group; and (C) a compound having an ethylenically unsaturated group other than the components (Al), (A2), and (B). The second ribbon layer is produced by curing a curable liquid resin composition, Composition 2, comprising: (D) 30 to '90 mass% of a urethane (meth)acrylate having a structure derived from polypropylene glycol with a number average molecular weight determined by gel permeation chromatography of 400 to 1,000; (E) 1 to 70 mass% of a compound having an ethylenically unsaturated group; (F) 0.1 to 10 mass% of a polymerization initiator; and (G) 1 to 50 mass% of a silicone compound with an average molecular weight of 1,500 to 35,000; wherein 50 to 100 mass% of the component (E) is a compound having two or more ethylenically unsaturated groups.
摘要翻译：描述并要求保护具有双层结构的光纤带，该带状结构包括通过使用第一带状层捆束光纤形成的第一带和通过使用第二带状层捆扎第一带而形成的第二带。第一带状层是通过固化可固化液体树脂组合物，组合物1制备的，其包含：（A1）具有双酚结构的氨基甲酸酯（甲基）丙烯酸酯; （A2）通过使脂肪族聚酯多元醇，多异氰酸酯和含羟基的（甲基）丙烯酸酯反应得到的聚氨酯（甲基）丙烯酸酯; （B）具有双酚结构和烯属不饱和基团的化合物; 和（C）除了组分（A1），（A2）和（B）之外具有烯键式不饱和基团的化合物。第二带层是通过固化可固化液体树脂组合物组合物2制备的，组合物2包含：（D）30至90质量％的由聚丙二醇衍生的结构的氨基甲酸酯（甲基）丙烯酸酯，其数均分子量由凝胶渗透色谱法为400〜1000; （E）1〜70质量％的具有烯属不饱和基团的化合物; （F）0.1〜10质量％的聚合引发剂; 和（G）1〜50质量％的平均分子量为1500〜35,000的硅氧烷化合物; 其中，成分（E）的50〜100质量％为具有2个以上烯属不饱和基团的化合物。

2. 发明申请

WO2006025734A1 CURABLE LIQUID RESIN OPTICAL FIBER UPJACKET COMPOSITION 审中-公开
标题翻译：可固化液体树脂光纤上光组合物
公开(公告)号：WO2006025734A1
公开(公告)日：2006-03-09
申请号：PCT/NL2005/000627
申请日：2005-08-30
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , YAMAGUCHI, Hiroshi , KAMO, Satoshi , SUGIMOTO, Masanobu , SHIGEMOTO, Takeo , DAKE, Kenneth
发明人： YAMAGUCHI, Hiroshi , KAMO, Satoshi , SUGIMOTO, Masanobu , SHIGEMOTO, Takeo , DAKE, Kenneth
IPC分类号： C09D4/06
CPC分类号： C08G18/8175 , C03C25/1065 , C08F290/147 , C08G18/672 , C08L83/12 , C09D175/16 , C08G18/48
摘要： The present invention provides a curable liquid resin composition which, when cured, exhibits excellent removability from an adjacent coating layer and is suitable for an optical fiber upjacket material. The curable liquid resin optical fiber upjacket composition comprising a urethane (meth)acrylate or a (meth)acrylate oligomer, a reactive diluent, a polymerization initiator, and a polyol compound having a molecular weight of 1500 or more.
摘要翻译：本发明提供了一种可固化液体树脂组合物，其在固化时表现出相邻涂层的优异的可除去性，并且适用于光纤上护套材料。包含氨基甲酸酯（甲基）丙烯酸酯或（甲基）丙烯酸酯低聚物，反应性稀释剂，聚合引发剂和分子量为1500以上的多元醇化合物的可固化液体树脂光纤夹层组合物。

3. 发明申请

WO2010112491A1 RADIATION CURABLE RESIN COMPOSITION FOR WIRE COATING 审中-公开
标题翻译：辐射可固化树脂组合物用于电线涂层
公开(公告)号：WO2010112491A1
公开(公告)日：2010-10-07
申请号：PCT/EP2010/054171
申请日：2010-03-30
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , YAMAGUCHI, Hiroshi , KAMO, Satoshi , KUROSAWA, Takahiko
发明人： YAMAGUCHI, Hiroshi , KAMO, Satoshi , KUROSAWA, Takahiko
IPC分类号： C09D175/16 , H01B3/30 , C08G18/48 , C08G18/67 , C08K5/521 , C08G18/76 , C08F290/06
CPC分类号： C09D175/16 , C08F290/062 , C08F290/067 , C08G18/3215 , C08G18/4854 , C08G18/672 , C08K5/0025 , C08K5/521 , H01B3/30 , H01B3/302 , H01B3/308 , H01B3/447 , C08F230/02 , C08F220/18 , C08F220/36 , C08G18/48
摘要： This invention is a radiation curable resin composition for wire coatings that have excellent adhesion with the center conductor as well as having excellent manufacturing efficiency for the coating layer and sufficient strength. This radiation curable resin composition for wire coating comprising the following ingredients (A), (B) and (D): (A) a mixture of a urethane (meth)acrylate having a structure derived from an aliphatic polyol and a urethane (meth)acrylate not having a structure derived from a polyol, (B) a compound having a cyclic structure and one ethylenically unsaturated group, (D) a compound given by the following formula (4a) wherein, R 8 is a monovalent organic group having an ethylenically unsaturated group, and R 9 is a hydrogen atom or a monovalent organic group that may have an ethylenically unsaturated group.
摘要翻译：本发明是一种用于电线涂层的辐射固化树脂组合物，其与中心导体具有优异的粘合性，并且具有优异的涂层制造效率和足够的强度。这种用于线涂的可辐射固化树脂组合物包括以下成分（A），（B）和（D）：（A）具有衍生自脂族多元醇的结构的氨基甲酸酯（甲基）丙烯酸酯和氨基甲酸酯（甲基）丙烯酸酯，不具有衍生自多元醇的结构，（B）具有环状结构和一个烯键式不饱和基团的化合物，（D）由下式（4a）表示的化合物，其中，R 8为具有烯属不饱和基团的一价有机基团基团，R 9为氢原子或可具有烯属不饱和基团的一价有机基团。

4. 发明申请

WO2009082221A1 RADIATION-CURABLE RESIN COMPOSITION CONTAINING DIPROPYL OR DIBUTYL AMINE 审中-公开
标题翻译：含有二溴或二苯胺的可辐射固化树脂组合物
公开(公告)号：WO2009082221A1
公开(公告)日：2009-07-02
申请号：PCT/NL2008/050831
申请日：2008-12-19
申请人： DSM IP ASSETS B.V , JSR CORPORATION , ISHII, Hiroyuki , MIYAZAWA, Hiroshi , KAMO, Satoshi , IMAI, Hirokazu , KUROSAWA, Takahiko
发明人： ISHII, Hiroyuki , MIYAZAWA, Hiroshi , KAMO, Satoshi , IMAI, Hirokazu , KUROSAWA, Takahiko
IPC分类号： C08F2/50
CPC分类号： C08F2/50 , C03C25/106 , C09D4/00
摘要： The invention is a liquid curable resin composition comprising: (A) 35-85 mass% urethane (meth) acrylate having a structure derived from polyether polyol, (B) 1-60 mass% ethylenically unsaturated group-containing compound other than (A), (C) 0.01-1 mass% dialkylamine having alkyl groups of 3 or 4 carbons, and (D) 0.01-10 mass% photopolymerization initiator, wherein the total quantity of the composition is 100 mass%. As a result of thorough research while considering this situation, the inventors discovered that, by using dialkylamine having alkyl groups of 3 or 4 carbons, a fast-curing liquid curable resin composition is obtained, by which optical fiber strands having high resistance to hot water immersion are obtained.
摘要翻译：本发明是一种液态固化树脂组合物，其包含：（A）具有来源于聚醚多元醇的结构的35-85质量％的聚氨酯（甲基）丙烯酸酯，（B）除（A）以外的1-60质量％的含烯属不饱和基团的化合物，，（C）0.01〜1质量％的烷基为3或4个碳原子的二烷基胺，（D）0.01〜10质量％的光聚合引发剂，其中组合物的总量为100质量％。作为考虑这种情况的深入研究的结果，本发明人发现通过使用具有3或4个碳原子的烷基的二烷基胺，获得快速固化的液体固化树脂组合物，通过该快速固化液体固化树脂组合物，具有高耐热水性的光纤线浸没。

5. 发明申请

WO2008120983A2 RIBBON MATRIX MATERIAL FOR OPTICAL FIBER WITH EXCELLENT BENDING RESISTANCE 审中-公开
标题翻译：用于具有优良弯曲电阻的光纤的RIBBON矩阵材料
公开(公告)号：WO2008120983A2
公开(公告)日：2008-10-09
申请号：PCT/NL2008050178
申请日：2008-03-28
申请人： DSM IP ASSETS BV , JSR CORP , YAMAGUCHI HIROSHI , KAMO SATOSHI , KUROSAWA TAKAHIKO
发明人： YAMAGUCHI HIROSHI , KAMO SATOSHI , KUROSAWA TAKAHIKO
IPC分类号： C09D4/06
CPC分类号： C09D4/06 , C03C25/106 , C08F283/04 , C08F290/06 , C08F290/061 , C08F290/067 , C08G18/3215 , C08G18/672 , C08L33/04 , C08L33/14 , C09D133/04 , C09D133/14 , C09D175/16 , G02B6/448 , G02B6/4486 , C08G18/48 , C08L2666/04
摘要： The instant claimed invention is a curable liquid resin composition comprising: (A) a urethane (meth)acrylate having a structure derived from polypropylene glycol with a number average molecular weight of from about 500 to about 4,000; (B) a urethane (meth)acrylate having a bisphenol structure; and (C) a compound having one ethylenically unsaturated group, the component (C) containing isobornyl (meth)acrylate in an amount of from about 40 to about 80 mass% of the total 100 mass% of the component (C). This composition has been found to exhibit high Young's modulus of elasticity and excellent bending resistance. The curable liquid resin composition is suitable for use as a matrix material for optical fiber ribbons.
摘要翻译：本发明是一种可固化液体树脂组合物，其包含：（A）具有衍生自数均分子量为约500至约4,000的聚丙二醇的结构的氨基甲酸酯（甲基）丙烯酸酯; （B）具有双酚结构的氨基甲酸酯（甲基）丙烯酸酯; 和（C）具有一个烯键式不饱和基团的化合物，（C）成分（C）含有（C）成分的总计100质量％的约40〜约80质量％的（甲基）丙烯酸异冰片酯。已经发现该组合物显示出高的杨氏弹性模量和优异的抗弯曲性。可固化液体树脂组合物适合用作光纤带的基质材料。

6. 发明申请

WO2008120984A1 CURABLE LIQUID RESIN COMPOSITION 审中-公开
标题翻译：可固化液体树脂组合物
公开(公告)号：WO2008120984A1
公开(公告)日：2008-10-09
申请号：PCT/NL2008/050179
申请日：2008-03-28
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , YAMAGUCHI, Hiroshi , KAMO, Satoshi , KUROSAWA, Takahiko
发明人： YAMAGUCHI, Hiroshi , KAMO, Satoshi , KUROSAWA, Takahiko
IPC分类号： C09D4/06 , C09D175/00 , C09D11/00 , C03C25/00 , G02B6/00
CPC分类号： C09D4/06 , C03C25/106 , C08F283/006 , C08F283/06 , C08G18/672 , C08L33/14 , C09D133/14 , C09D175/16 , G02B6/448 , G02B6/4486 , C08G18/48 , C08L2666/04
摘要： A curable liquid resin composition comprising: (A) a urethane (meth)acrylate having a structure derived from polypropylene glycol with a number average molecular weight of about 4,000 or less; (B) a urethane (meth)acrylate having a structure derived from a polypropylene glycol with a number average molecular weight of more then about 4000; (C) a (meth)acrylate monomer; and (D) a polymerization initiator; wherein from about 50 to about 80 mass% of the component (C) is 2-ethylhexyl (meth)acrylate, and from about 50 to about 90 mass% of the component (D) is 1-hydroxycyclohexyl phenyl ketone is described and claimed. This composition, when cured, provides a cured product having low self- adhesiveness and a high stress relaxation rate. The composition is suitable for use as a Secondary Coating or as a Matrix Coating for Optical Fibers.
摘要翻译：一种可固化液体树脂组合物，其包含：（A）具有衍生自数均分子量为约4000以下的聚丙二醇的结构的氨基甲酸酯（甲基）丙烯酸酯; （B）具有衍生自数均分子量大于约4000的聚丙二醇的结构的氨基甲酸酯（甲基）丙烯酸酯; （C）（甲基）丙烯酸酯单体; 和（D）聚合引发剂; 其中，（C）成分的约50〜约80质量％为（甲基）丙烯酸2-乙基己酯，（D）成分的约50〜约90质量％为1-羟基环己基苯基酮。该组合物在固化时提供具有低自粘性和高应力松弛率的固化产物。该组合物适合用作二次涂层或用作光纤的基质涂层。

7. 发明申请

WO2008120983A3 RIBBON MATRIX MATERIAL FOR OPTICAL FIBER WITH EXCELLENT BENDING RESISTANCE 审中-公开
公开(公告)号：WO2008120983A3
公开(公告)日：2008-10-09
申请号：PCT/NL2008/050178
申请日：2008-03-28
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , YAMAGUCHI, Hiroshi , KAMO, Satoshi , KUROSAWA, Takahiko
发明人： YAMAGUCHI, Hiroshi , KAMO, Satoshi , KUROSAWA, Takahiko
IPC分类号： C09D4/06
摘要： The instant claimed invention is a curable liquid resin composition comprising: (A) a urethane (meth)acrylate having a structure derived from polypropylene glycol with a number average molecular weight of from about 500 to about 4,000; (B) a urethane (meth)acrylate having a bisphenol structure; and (C) a compound having one ethylenically unsaturated group, the component (C) containing isobornyl (meth)acrylate in an amount of from about 40 to about 80 mass% of the total 100 mass% of the component (C). This composition has been found to exhibit high Young's modulus of elasticity and excellent bending resistance. The curable liquid resin composition is suitable for use as a matrix material for optical fiber ribbons.

8. 发明申请

WO2008120981A1 RADIATION CURABLE LIQUID RESIN COMPOSITION FOR OUTERMOST LAYER OF OPTICAL FIBER 审中-公开
标题翻译：用于光纤外层的辐射可固化液体树脂组合物
公开(公告)号：WO2008120981A1
公开(公告)日：2008-10-09
申请号：PCT/NL2008/050176
申请日：2008-03-28
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , YAMAGUCHI, Hiroshi , KAMO, Satoshi , KUROSAWA, Takahiko
发明人： YAMAGUCHI, Hiroshi , KAMO, Satoshi , KUROSAWA, Takahiko
IPC分类号： C09D4/06 , C09D11/00 , C09D175/00 , C03C25/00 , G02B6/00
CPC分类号： C09D4/06 , C03C25/106 , C03C25/1065 , C08F283/00 , C08F283/006 , C08F290/06 , C08F290/061 , C08F290/067 , C08G18/4879 , C08G18/672 , C09D175/16 , G02B6/02395 , C08G18/48
摘要： A curable liquid resin composition for coating an optical fiber outermost layer comprising: (Al) a urethane (meth) aery late having a bisphenol structure; (A2) a urethane (meth)acrylate obtained by reacting an aliphatic polyether polyol, a polyisocyanate, and a hydroxyl group -containing (meth) aery late; (B) a compound having a bisphenol structure and an ethylenically unsaturated group; (C) a compound having an ethylenically unsaturated group other than the components (A1), (A2), and (B); and (D) a polyol compound with a number average molecular weight of 1,500 or more is described and claimed. This composition is suitable for use in coating an optical fiber outermost layer which functions excellently as an optical fiber coating material and produces an optical fiber outermost layer which is hard enough not to be damaged easily and has excellent peelability from the adjacent coating layer.
摘要翻译： 1.一种光纤最外层的涂布用固化型液状树脂组合物，其特征在于，具有：（Al）具有双酚结构的氨基甲酸酯（甲基）丙烯酸酯; （A2）通过脂族聚醚多元醇，多异氰酸酯和含羟基的（甲基）丙烯酸酯反应得到的聚氨酯（甲基）丙烯酸酯; （B）具有双酚结构和烯属不饱和基团的化合物; （C）除组分（A1），（A2）和（B）之外具有烯属不饱和基团的化合物; 和（D）数均分子量为1500以上的多元醇化合物。该组合物适用于涂覆光纤最外层，其作为光纤涂层材料具有优异的功能，并且产生难以容易地损坏并且具有优异的相邻涂层剥离性的光纤最外层。

9. 发明申请

WO2006049488A1 CURABLE LIQUID RESIN OPTICAL FIBER UPJACKET COMPOSITION 审中-公开
标题翻译：可固化液体树脂光纤上光组合物
公开(公告)号：WO2006049488A1
公开(公告)日：2006-05-11
申请号：PCT/NL2005/000672
申请日：2005-09-15
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , YAMAGUCHI, Hiroshi , KAMO, Satoshi , SUGIMOTO, Masanobu , SHIGEMOTO, Takeo , MURPHY, Edward, Joseph
发明人： YAMAGUCHI, Hiroshi , KAMO, Satoshi , SUGIMOTO, Masanobu , SHIGEMOTO, Takeo , MURPHY, Edward, Joseph
IPC分类号： C08G18/28 , C08G18/67 , C09D175/16 , C08G18/48 , C08G18/76 , C08G18/10
CPC分类号： C09D175/16 , C08G18/289 , C08G18/61 , C08G18/672 , C08G18/7621 , C08G18/8175 , C08L75/16 , C08G18/48 , C08L2666/20
摘要： The present invention provides a curable liquid resin composition which, when cured, exhibits excellent removability from an adjacent coating layer and is suitable as an optical fiber upjacket material. The curable liquid resin optical fiber upjacket composition comprising a urethane (meth) acrylate or a (meth) acrylate oligomer containing two or more (meth) acryloyl groups, a reactive diluent, a polymerization initiator, and a urethane (meth) acrylate compound containing at least one (meth) acryloyl group and selected from (Dl) to (D4) shown by the following general formula (1). (Dl) In the formula (1), R 1 represents a methyl group, R 2 and R 3 individually represent a divalent organic group, and R 4 represents a monovalent organic group. (D2) In the formula (1), R 1 represents a hydrogen atom, R 2 and R 3 individually represent divalent organic groups, and R4 represents a polyol residue having a molecular weight of 1500 or more. (D3) In the formula (1), R1 represents a hydrogen atom or a methyl group, R 2 and R 3 individually represent divalent organic groups, and R 4 represents a silicone residue having a molecular weight of 1000 to 30000. (D4) In the formula (1), R represents a hydrogen atom, R and R individually represent divalent organic groups, and R 4 represents a polyol monoalkyl ether residue having a molecular weight of 500 to 20000.
摘要翻译：本发明提供一种可固化液体树脂组合物，其在固化时表现出相邻涂层的优异的可除去性，并且适合作为光纤上护套材料。包含氨基甲酸酯（甲基）丙烯酸酯或含有两个或更多个（甲基）丙烯酰基的（甲基）丙烯酸酯低聚物，反应性稀释剂，聚合引发剂和氨基甲酸酯（甲基）丙烯酸酯）化合物的可固化液体树脂光纤上衣组合物，至少一个（甲基）丙烯酰基，并且选自下列通式（1）所示的（D1）至（D4）。（D1）在式（1）中，R 1表示甲基，R 2和R 3各自表示二价有机基团， R 4表示一价有机基团。（D2）在式（1）中，R 1表示氢原子，R 2和R 3各自代表二价有机基团，和 R4表示分子量为1500以上的多元醇残基。（D3）在式（1）中，R 1表示氢原子或甲基，R 2和R 3各自表示二价有机基团， 4表示分子量为1000〜30000的硅氧烷残基。（D4）在式（1）中，R表示氢原子，R和R分别表示二价有机基团，R 4， / SUP>表示分子量为500〜20000的多元醇单烷基醚残基。

10. 发明申请

WO2009070024A1 RADIATION CURABLE CLADDING LAYER FOR POLYMER-CLAD OPTICAL FIBER 审中-公开
标题翻译：用于聚合物光纤的辐射可固化层
公开(公告)号：WO2009070024A1
公开(公告)日：2009-06-04
申请号：PCT/NL2008/050759
申请日：2008-11-28
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , ISHII, Hiroyuki , KUROSAWA, Takahiko , KAMO, Satoshi
发明人： ISHII, Hiroyuki , KUROSAWA, Takahiko , KAMO, Satoshi
IPC分类号： C03C17/00 , C08F220/00 , C09J4/00
CPC分类号： C09D4/00 , C03C25/105 , C08F220/00 , C09J4/00
摘要： A liquid radiation curable coating composition suitable for use as a cladding layer on an optical fiber is described and claimed. The composition is as follows: (A) a fluorine-containing urethane (meth)acrylate; (B) a compound shown by the following formula (1), CH 2 =CR 1 COO(CH 2 ) X (CF 2 ) Y X (1) wherein R1 represents a hydrogen atom or a methyl group, X represents a hydrogen atom or a fluorine atom, x represents 1 or 2, and y represents an integer from 2 to 8; (C) (meth)acrylic acid; and (D) a silane coupling agent.
摘要翻译：描述和要求保护适用于光纤上的包覆层的液体辐射固化涂料组合物。组成如下：（A）含氟氨基甲酸酯（甲基）丙烯酸酯; （B）由下式（1）表示的化合物，CH2 = CR1COO（CH2）X（CF2）YX（1）其中R1表示氢原子或甲基，X表示氢原子或氟原子，x 表示1或2，y表示2至8的整数; （C）（甲基）丙烯酸; 和（D）硅烷偶联剂。

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