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1. 发明申请

WO2008120985A1 LIQUID CURABLE RESIN COMPOSITION FOR OPTICAL FIBER TAPES 审中-公开
标题翻译：用于光纤带的液体可固化树脂组合物
公开(公告)号：WO2008120985A1
公开(公告)日：2008-10-09
申请号：PCT/NL2008/050180
申请日：2008-03-28
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , YAMAGUCHI, Hiroshi , KAMO, Satoshi , KUROSAWA, Takahiko
发明人： YAMAGUCHI, Hiroshi , KAMO, Satoshi , KUROSAWA, Takahiko
IPC分类号： C09D4/06 , C09D175/00 , C03C25/00
CPC分类号： C09D4/06 , C08G18/672 , C08G18/8175 , C09D175/16 , G02B6/448 , G02B6/4486 , C08G18/48
摘要： An optical fiber ribbon with a double layer structure comprising a first ribbon formed by bundling optical fibers using a first ribbon layer and a second ribbon formed by bundling the first ribbons using a second ribbon layer is described and claimed. The first ribbon layer is produced by curing a curable liquid resin composition, Composition 1, comprising: (Al) a urethane (meth)acrylate having a bisphenol structure; (A2) si urethane (meth)acrylate obtained by reacting an aliphatic polyather polyol, a polyisocyanate, and a hydroxyl group-containing (meth)acrylate; (B) a compound having a bisphenol structure and an ethylenically unsaturated group; and (C) a compound having an ethylenically unsaturated group other than the components (Al), (A2), and (B). The second ribbon layer is produced by curing a curable liquid resin composition, Composition 2, comprising: (D) 30 to '90 mass% of a urethane (meth)acrylate having a structure derived from polypropylene glycol with a number average molecular weight determined by gel permeation chromatography of 400 to 1,000; (E) 1 to 70 mass% of a compound having an ethylenically unsaturated group; (F) 0.1 to 10 mass% of a polymerization initiator; and (G) 1 to 50 mass% of a silicone compound with an average molecular weight of 1,500 to 35,000; wherein 50 to 100 mass% of the component (E) is a compound having two or more ethylenically unsaturated groups.
摘要翻译：描述并要求保护具有双层结构的光纤带，该带状结构包括通过使用第一带状层捆束光纤形成的第一带和通过使用第二带状层捆扎第一带而形成的第二带。第一带状层是通过固化可固化液体树脂组合物，组合物1制备的，其包含：（A1）具有双酚结构的氨基甲酸酯（甲基）丙烯酸酯; （A2）通过使脂肪族聚酯多元醇，多异氰酸酯和含羟基的（甲基）丙烯酸酯反应得到的聚氨酯（甲基）丙烯酸酯; （B）具有双酚结构和烯属不饱和基团的化合物; 和（C）除了组分（A1），（A2）和（B）之外具有烯键式不饱和基团的化合物。第二带层是通过固化可固化液体树脂组合物组合物2制备的，组合物2包含：（D）30至90质量％的由聚丙二醇衍生的结构的氨基甲酸酯（甲基）丙烯酸酯，其数均分子量由凝胶渗透色谱法为400〜1000; （E）1〜70质量％的具有烯属不饱和基团的化合物; （F）0.1〜10质量％的聚合引发剂; 和（G）1〜50质量％的平均分子量为1500〜35,000的硅氧烷化合物; 其中，成分（E）的50〜100质量％为具有2个以上烯属不饱和基团的化合物。

2. 发明申请

WO2008120982A1 RADIATION CURABLE RESIN COMPOSITIONS FOR ELECTRIC WIRE COATINGS 审中-公开
标题翻译：用于电线涂层的辐射可固化树脂组合物
公开(公告)号：WO2008120982A1
公开(公告)日：2008-10-09
申请号：PCT/NL2008/050177
申请日：2008-03-28
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , YAMAGUCHI, Hiroshi , KAMO, Satoshi , KUROSAWA, Takahiko
发明人： YAMAGUCHI, Hiroshi , KAMO, Satoshi , KUROSAWA, Takahiko
IPC分类号： C09D175/16 , C08G18/67 , H01B7/17 , H01B3/30
CPC分类号： C09D175/16 , C08G18/672 , H01B3/302 , C08G18/48 , C08G18/42
摘要： The present invention is a radiation curable resin composition comprising: (A) a urethane (meth) aerylate which is a reaction product of a polyol, a polyisocyanate, and a hydroxyl group-containing (meth) aerylate; (B) a compound having a cyclic structure and one ethylenically unsaturated group; (C) from about 0 to about 5 mass% of a compound having two or more ethylenically unsaturated group; and (D) a polyol having a number average molecular weight of about 1500 or more. In another embodiment of the invention component (A) must include a polyester polyol and the polyol of component (D) must have a number average molecular weight of from about 500 to about 1500. The composition is useful for coating electric wire.
摘要翻译：本发明是一种辐射固化树脂组合物，其包含：（A）作为多元醇，多异氰酸酯和含羟基的（甲基）丙烯酸酯的反应产物的氨基甲酸酯（甲基）（B）具有环状结构和一个烯键式不饱和基团的化合物; （C）约0〜约5质量％的具有2个以上烯键式不饱和基团的化合物; 和（D）数均分子量为约1500以上的多元醇。在本发明的另一个实施方案中，组分（A）必须包括聚酯多元醇，并且组分（D）的多元醇必须具有约500至约1500的数均分子量。该组合物可用于涂覆电线。

3. 发明申请

WO2010112491A1 RADIATION CURABLE RESIN COMPOSITION FOR WIRE COATING 审中-公开
标题翻译：辐射可固化树脂组合物用于电线涂层
公开(公告)号：WO2010112491A1
公开(公告)日：2010-10-07
申请号：PCT/EP2010/054171
申请日：2010-03-30
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , YAMAGUCHI, Hiroshi , KAMO, Satoshi , KUROSAWA, Takahiko
发明人： YAMAGUCHI, Hiroshi , KAMO, Satoshi , KUROSAWA, Takahiko
IPC分类号： C09D175/16 , H01B3/30 , C08G18/48 , C08G18/67 , C08K5/521 , C08G18/76 , C08F290/06
CPC分类号： C09D175/16 , C08F290/062 , C08F290/067 , C08G18/3215 , C08G18/4854 , C08G18/672 , C08K5/0025 , C08K5/521 , H01B3/30 , H01B3/302 , H01B3/308 , H01B3/447 , C08F230/02 , C08F220/18 , C08F220/36 , C08G18/48
摘要： This invention is a radiation curable resin composition for wire coatings that have excellent adhesion with the center conductor as well as having excellent manufacturing efficiency for the coating layer and sufficient strength. This radiation curable resin composition for wire coating comprising the following ingredients (A), (B) and (D): (A) a mixture of a urethane (meth)acrylate having a structure derived from an aliphatic polyol and a urethane (meth)acrylate not having a structure derived from a polyol, (B) a compound having a cyclic structure and one ethylenically unsaturated group, (D) a compound given by the following formula (4a) wherein, R 8 is a monovalent organic group having an ethylenically unsaturated group, and R 9 is a hydrogen atom or a monovalent organic group that may have an ethylenically unsaturated group.
摘要翻译：本发明是一种用于电线涂层的辐射固化树脂组合物，其与中心导体具有优异的粘合性，并且具有优异的涂层制造效率和足够的强度。这种用于线涂的可辐射固化树脂组合物包括以下成分（A），（B）和（D）：（A）具有衍生自脂族多元醇的结构的氨基甲酸酯（甲基）丙烯酸酯和氨基甲酸酯（甲基）丙烯酸酯，不具有衍生自多元醇的结构，（B）具有环状结构和一个烯键式不饱和基团的化合物，（D）由下式（4a）表示的化合物，其中，R 8为具有烯属不饱和基团的一价有机基团基团，R 9为氢原子或可具有烯属不饱和基团的一价有机基团。

4. 发明申请

WO2008120984A1 CURABLE LIQUID RESIN COMPOSITION 审中-公开
标题翻译：可固化液体树脂组合物
公开(公告)号：WO2008120984A1
公开(公告)日：2008-10-09
申请号：PCT/NL2008/050179
申请日：2008-03-28
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , YAMAGUCHI, Hiroshi , KAMO, Satoshi , KUROSAWA, Takahiko
发明人： YAMAGUCHI, Hiroshi , KAMO, Satoshi , KUROSAWA, Takahiko
IPC分类号： C09D4/06 , C09D175/00 , C09D11/00 , C03C25/00 , G02B6/00
CPC分类号： C09D4/06 , C03C25/106 , C08F283/006 , C08F283/06 , C08G18/672 , C08L33/14 , C09D133/14 , C09D175/16 , G02B6/448 , G02B6/4486 , C08G18/48 , C08L2666/04
摘要： A curable liquid resin composition comprising: (A) a urethane (meth)acrylate having a structure derived from polypropylene glycol with a number average molecular weight of about 4,000 or less; (B) a urethane (meth)acrylate having a structure derived from a polypropylene glycol with a number average molecular weight of more then about 4000; (C) a (meth)acrylate monomer; and (D) a polymerization initiator; wherein from about 50 to about 80 mass% of the component (C) is 2-ethylhexyl (meth)acrylate, and from about 50 to about 90 mass% of the component (D) is 1-hydroxycyclohexyl phenyl ketone is described and claimed. This composition, when cured, provides a cured product having low self- adhesiveness and a high stress relaxation rate. The composition is suitable for use as a Secondary Coating or as a Matrix Coating for Optical Fibers.
摘要翻译：一种可固化液体树脂组合物，其包含：（A）具有衍生自数均分子量为约4000以下的聚丙二醇的结构的氨基甲酸酯（甲基）丙烯酸酯; （B）具有衍生自数均分子量大于约4000的聚丙二醇的结构的氨基甲酸酯（甲基）丙烯酸酯; （C）（甲基）丙烯酸酯单体; 和（D）聚合引发剂; 其中，（C）成分的约50〜约80质量％为（甲基）丙烯酸2-乙基己酯，（D）成分的约50〜约90质量％为1-羟基环己基苯基酮。该组合物在固化时提供具有低自粘性和高应力松弛率的固化产物。该组合物适合用作二次涂层或用作光纤的基质涂层。

5. 发明申请

WO2008120983A3 RIBBON MATRIX MATERIAL FOR OPTICAL FIBER WITH EXCELLENT BENDING RESISTANCE 审中-公开
公开(公告)号：WO2008120983A3
公开(公告)日：2008-10-09
申请号：PCT/NL2008/050178
申请日：2008-03-28
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , YAMAGUCHI, Hiroshi , KAMO, Satoshi , KUROSAWA, Takahiko
发明人： YAMAGUCHI, Hiroshi , KAMO, Satoshi , KUROSAWA, Takahiko
IPC分类号： C09D4/06
摘要： The instant claimed invention is a curable liquid resin composition comprising: (A) a urethane (meth)acrylate having a structure derived from polypropylene glycol with a number average molecular weight of from about 500 to about 4,000; (B) a urethane (meth)acrylate having a bisphenol structure; and (C) a compound having one ethylenically unsaturated group, the component (C) containing isobornyl (meth)acrylate in an amount of from about 40 to about 80 mass% of the total 100 mass% of the component (C). This composition has been found to exhibit high Young's modulus of elasticity and excellent bending resistance. The curable liquid resin composition is suitable for use as a matrix material for optical fiber ribbons.

6. 发明申请

WO2008120981A1 RADIATION CURABLE LIQUID RESIN COMPOSITION FOR OUTERMOST LAYER OF OPTICAL FIBER 审中-公开
标题翻译：用于光纤外层的辐射可固化液体树脂组合物
公开(公告)号：WO2008120981A1
公开(公告)日：2008-10-09
申请号：PCT/NL2008/050176
申请日：2008-03-28
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , YAMAGUCHI, Hiroshi , KAMO, Satoshi , KUROSAWA, Takahiko
发明人： YAMAGUCHI, Hiroshi , KAMO, Satoshi , KUROSAWA, Takahiko
IPC分类号： C09D4/06 , C09D11/00 , C09D175/00 , C03C25/00 , G02B6/00
CPC分类号： C09D4/06 , C03C25/106 , C03C25/1065 , C08F283/00 , C08F283/006 , C08F290/06 , C08F290/061 , C08F290/067 , C08G18/4879 , C08G18/672 , C09D175/16 , G02B6/02395 , C08G18/48
摘要： A curable liquid resin composition for coating an optical fiber outermost layer comprising: (Al) a urethane (meth) aery late having a bisphenol structure; (A2) a urethane (meth)acrylate obtained by reacting an aliphatic polyether polyol, a polyisocyanate, and a hydroxyl group -containing (meth) aery late; (B) a compound having a bisphenol structure and an ethylenically unsaturated group; (C) a compound having an ethylenically unsaturated group other than the components (A1), (A2), and (B); and (D) a polyol compound with a number average molecular weight of 1,500 or more is described and claimed. This composition is suitable for use in coating an optical fiber outermost layer which functions excellently as an optical fiber coating material and produces an optical fiber outermost layer which is hard enough not to be damaged easily and has excellent peelability from the adjacent coating layer.
摘要翻译： 1.一种光纤最外层的涂布用固化型液状树脂组合物，其特征在于，具有：（Al）具有双酚结构的氨基甲酸酯（甲基）丙烯酸酯; （A2）通过脂族聚醚多元醇，多异氰酸酯和含羟基的（甲基）丙烯酸酯反应得到的聚氨酯（甲基）丙烯酸酯; （B）具有双酚结构和烯属不饱和基团的化合物; （C）除组分（A1），（A2）和（B）之外具有烯属不饱和基团的化合物; 和（D）数均分子量为1500以上的多元醇化合物。该组合物适用于涂覆光纤最外层，其作为光纤涂层材料具有优异的功能，并且产生难以容易地损坏并且具有优异的相邻涂层剥离性的光纤最外层。

7. 发明申请

WO2010112493A1 RADIATION CURABLE RESIN COMPOSITION FOR WIRE COATING 审中-公开
标题翻译：辐射可固化树脂组合物用于电线涂层
公开(公告)号：WO2010112493A1
公开(公告)日：2010-10-07
申请号：PCT/EP2010/054173
申请日：2010-03-30
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , YAMAGUCHI, Hiroshi , KAMO, Satoshi , KUROSAWA, Takahiko
发明人： YAMAGUCHI, Hiroshi , KAMO, Satoshi , KUROSAWA, Takahiko
IPC分类号： C09D175/16 , H01B3/30 , C08G18/48 , C08G18/67 , C08K5/521 , C08F290/06 , C08G18/76
CPC分类号： C09D175/16 , C08F290/062 , C08F290/067 , C08G18/3215 , C08G18/4854 , C08G18/672 , C08K5/0025 , C08K5/521 , H01B3/30 , H01B3/302 , H01B3/308 , H01B3/447 , C08F230/02 , C08F220/18 , C08F220/36 , C08G18/48
摘要： A resin composition for wire coatings that has excellent adhesion with the center conductor as well as having excellent manufacturing efficiency for the coating layer and sufficient strength is described and claimed. This radiation curable resin composition for wire coating comprises the following ingredients (A), (B) and (D): (A) a urethane (meth)acrylate having two or more structural parts derived from an aliphatic polyol (B) a compound having a cyclic structure and one ethylenically unsaturated group, (D) a compound given by the following Formula (4a), wherein, R 8 is a monovalent organic group having an ethylenically unsaturated group, and R 9 is a hydrogen atom or a monovalent organic group that may have an ethylenically unsaturated group.
摘要翻译：描述和要求保护具有与中心导体的优异粘合性以及具有优异的涂层制造效率和足够的强度的用于电线涂层的树脂组合物。该用于线材涂布的可辐射固化树脂组合物包括以下成分（A），（B）和（D）：（A）具有两个或更多个结构部分的衍生自脂族多元醇（B）的聚氨酯（甲基）丙烯酸酯，环状结构和一个烯属不饱和基团，（D）由下式（4a）表示的化合物，其中，R 8为具有烯属不饱和基团的一价有机基团，R 9为氢原子或可以具有烯键式不饱和基团。

8. 发明申请

WO2009108056A1 OPTICAL FIBER TAPE WITH EPOXY MODIFIED SILICONE ADDITIVE 审中-公开
标题翻译：环氧改性硅胶添加剂的光纤胶带
公开(公告)号：WO2009108056A1
公开(公告)日：2009-09-03
申请号：PCT/NL2009/050090
申请日：2009-02-27
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , YAMAGUCHI, Hiroshi , TAKASE, Katsuyuki , KONDOU, Kazuyuki , KUROSAWA, Takahiko
发明人： YAMAGUCHI, Hiroshi , TAKASE, Katsuyuki , KONDOU, Kazuyuki , KUROSAWA, Takahiko
IPC分类号： C08F290/06 , C08G18/67 , G02B6/44
CPC分类号： C08F283/12 , C08F290/06 , C08F290/065 , C08F290/067 , C08F290/068 , C08G18/10 , C08G18/4845 , C08G18/61 , C08G18/672 , C08G18/7621 , G02B6/443 , G02B6/448 , C08G18/48
摘要： The invention is a curable liquid resin composition that is optimal for use as an optical fiber tape material providing excellent surface slidability and printability when cured. In order to achieve the desired result the composition was formulated using an epoxy- modified silicone to deliver the desired surface slidability and printability in the cured material. The curable liquid resin composition contains urethane (meth)acrylate, a compound containing an ethylenically unsaturated group and an epoxy- modified silicone.
摘要翻译：本发明是一种可固化液体树脂组合物，其可用作当固化时提供优异的表面滑动性和可印刷性的光纤带材料。为了达到所需的结果，使用环氧改性的硅氧烷来配制组合物以在固化的材料中提供所需的表面滑动性和可印刷性。可固化液体树脂组合物含有氨基甲酸酯（甲基）丙烯酸酯，含有烯键式不饱和基团的化合物和环氧改性聚硅氧烷。

9. 发明申请

WO2009108055A1 WATER SOLUBLE COATING MATERIAL FOR OPTICAL CABLES 审中-公开
标题翻译：水溶性涂层材料用于光纤电缆
公开(公告)号：WO2009108055A1
公开(公告)日：2009-09-03
申请号：PCT/NL2009/050089
申请日：2009-02-27
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , YAMAGUCHI, Hiroshi , KUROSAWA, Takahiko
发明人： YAMAGUCHI, Hiroshi , KUROSAWA, Takahiko
IPC分类号： C09D4/06
CPC分类号： C09D4/06
摘要： This invention relates to optical fiber coating materials, and more specifically a water soluble coating material for optical cables. The water soluble coating material has the following composition: (A) 20-70 wt% N-hydroxyalkyl (meth)acrylamide; (B) 0-5 wt% urethane (meth)acrylate; (C) 10-40 wt% of a compound having a (meth)acryloyl group which is a water-soluble homopolymer when the homopolymer has an atomic weight of 10 000; (D) 0-30 wt% non-ionic water soluble polymer, and (E) 0.1-10 wt% polymerization initiator relative to a total of 100 wt% of the compound.
摘要翻译：本发明涉及光纤涂层材料，更具体地说涉及光缆用水溶性涂料。水溶性涂料具有以下组成：（A）20-70重量％（甲基）丙烯酰氧基-N-羟烷基酯; （B）0-5重量％氨基甲酸酯（甲基）丙烯酸酯; （C）当均聚物的原子量为10 000时，具有（甲基）丙烯酰基的化合物为10〜40重量％，其为水溶性均聚物; （D）0-30wt％非离子水溶性聚合物，和（E）0.1-10wt％聚合引发剂相对于总共100wt％的化合物。

10. 发明申请

WO2011081519A1 D1499 RADIATION CURABLE RESIN COMPOSITION 审中-公开
标题翻译： D1499可辐射固化树脂组合物
公开(公告)号：WO2011081519A1
公开(公告)日：2011-07-07
申请号：PCT/NL2010/050877
申请日：2010-12-22
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , IMAI, Hirokazu , YAMASHITA, Yuutoku , YAMAGUCHI, Hiroshi , KUROSAWA, Takahiko
发明人： IMAI, Hirokazu , YAMASHITA, Yuutoku , YAMAGUCHI, Hiroshi , KUROSAWA, Takahiko
IPC分类号： C08G18/10 , C08G18/67 , C09D175/16 , C03C25/10
CPC分类号： C03C25/106 , C03C25/1065 , C08F290/147 , C08G18/10 , C08G18/672 , C09D175/16 , G02B6/02395 , G02B6/036 , C08G18/2825 , C08G18/48 , C08G18/42
摘要： A radiation curable resin composition, containing (A) urethane oligomer containing the reactants of an aliphatic polyester or polyether diol and a diisocyanate and a monohydric alcohol, or urethane oligomer obtained by reacting the reactants of an aliphatic polyester or polyether diol and a diisocyanate with a monohydric alcohol and then reacting a hydroxyl group-containing (meth)acrylate, and (B) monofunctional acrylic monomer, and the contained quantity of (C) polyfunctional acrylic monomer is 2 mass% or less is described and claimed.
摘要翻译：含有（A）含有脂肪族聚酯或聚醚二醇与二异氰酸酯和一元醇的反应物的氨基甲酸酯低聚物的聚氨酯低聚物或通过使脂肪族聚酯或聚醚二醇与二异氰酸酯的反应物与一元醇，然后使含羟基的（甲基）丙烯酸酯和（B）单官能丙烯酸类单体反应，并且含有（C）多官能丙烯酸类单体的含量为2质量％以下。

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