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1. 发明申请

WO2013015997A3 CONTINUOUS CATALYTIC GENERATION OF POLYOLS FROM CELLULOSE 审中-公开
公开(公告)号：WO2013015997A3
公开(公告)日：2013-01-31
申请号：PCT/US2012/046348
申请日：2012-07-12
申请人： UOP LLC , DALIAN INSTITUTE OF CHEMICAL PHYSICS , ZHANG, Tao , WANG, Aiqin , ZHENG, Mingyuan , LI, Changzhi , PANG, Jifeng , KALNES, Tom N. , CHEN, John Q. , KOCAL, Joseph A.
发明人： ZHANG, Tao , WANG, Aiqin , ZHENG, Mingyuan , LI, Changzhi , PANG, Jifeng , KALNES, Tom N. , CHEN, John Q. , KOCAL, Joseph A.
IPC分类号： C07C29/94 , C07C31/26 , B01J23/44 , B01J21/04
摘要： A catalytic process for generating at least one polyol from a feedstock comprising cellulose is performed in a continuous manner using a catalyst comprising nickel tungsten carbide. The process involves, contacting, continuously, hydrogen, water, and a feedstock comprising cellulose, with the catalyst to generate an effluent stream comprising at least one polyol and recovering the polyol from the effluent stream.

2. 发明申请

WO2012082398A9 FUEL COMPOSITIONS AND METHODS BASED ON BIOMASS PYROLYSIS 审中-公开
公开(公告)号：WO2012082398A9
公开(公告)日：2012-11-15
申请号：PCT/US2011063014
申请日：2011-12-02
申请人： UOP LLC , KALNES TOM N
发明人： KALNES TOM N
IPC分类号： C10L1/04 , B09B3/00 , C10G3/00 , C10L1/02
CPC分类号： C10L1/023 , C10B53/02 , C10C5/00 , C10G1/02 , C10G1/06 , C10G1/08 , C10G3/42 , C10G3/50 , C10G2300/1014 , C10G2300/104 , C10G2300/202 , C10G2300/301 , C10G2300/305 , C10G2300/4043 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10L1/1616 , C10L1/18 , C10L1/1824 , C10L2200/0423 , C10L2200/0469 , C10L2290/02 , Y02E50/14 , Y02E50/32 , Y02P20/145 , Y02P30/10 , Y02P30/20
摘要： Fuel compositions exhibiting reduced greenhouse gas (GHG) emissions, based on a lifecycle assessment from the time of cultivation of feedstocks (in the case of plant materials) or extraction of feedstocks (in the case of fossil fuels) required for the compositions (up to and including the ultimate combustion of the fuel composition by the end user) are disclosed. The reduced level of emissions ("carbon footprint") is achieved by incorporating a pyrolysis derived component having a higher heating value than ethanol and meeting other applicable standards for fossil fuel (e.g., petroleum) derived components conventionally used for the same purpose, such as transportation fuels. Advantageously, fuel compositions comprising pyrolysis derived gasoline can exhibit lower GHG emissions than gasoline derived solely from petroleum, or even conventional blends of petroleum derived gasoline and ethanol.

3. 发明申请

WO2012082401A3 PROCESS FOR PRODUCING A RENEWABLE HYDROCARBON FUEL 审中-公开
公开(公告)号：WO2012082401A3
公开(公告)日：2012-06-21
申请号：PCT/US2011/063058
申请日：2011-12-02
申请人： UOP LLC , KALNES, Tom N.
发明人： KALNES, Tom N.
IPC分类号： C10G3/00 , C10L1/02 , C10B53/02 , B09B3/00
摘要： One exemplary embodiment can be a process for producing a renewable hydrocarbon fuel. The process can include providing a feed including a lignocellulosic material to a pyrolysis zone to produce a stream including a pyrolysis oil, providing the pyrolysis oil stream to a refining zone producing a refined stream, providing at least a portion of the refined stream to a reforming zone producing a stream including hydrogen, providing at least a portion of the hydrogen stream to the refining zone; and recovering the renewable hydrocarbon fuel from the refined stream.

4. 发明申请

WO2010065196A3 INTEGRATED WARM GAS DESULFURIZATION AND GAS SHIFT FOR CLEANUP OF GASEOUS STREAMS 审中-公开
标题翻译：集成式暖气脱硫和气体净化用于清理气体流
公开(公告)号：WO2010065196A3
公开(公告)日：2010-08-12
申请号：PCT/US2009060751
申请日：2009-10-15
申请人： UOP LLC , SERBAN MANUELA , KALNES TOM N , VANDEN BUSSCHE KURT M , BRADY JOHN P , JAMES JR ROBERT B
发明人： SERBAN MANUELA , KALNES TOM N , VANDEN BUSSCHE KURT M , BRADY JOHN P , JAMES JR ROBERT B
IPC分类号： B01D53/62 , B01D53/48 , B01D53/86 , C01B32/50
CPC分类号： B01D53/75 , B01D53/1456 , B01D53/58 , B01D53/64 , B01D53/8618 , B01D53/864 , B01D2256/16 , B01D2257/304 , B01D2257/308 , B01D2257/406 , B01D2257/408 , B01D2257/502 , B01D2257/504 , B01D2257/602 , B01D2257/706 , B01D2259/4009 , C01B3/16 , C01B3/56 , C01B2203/0288 , C01B2203/0415 , C01B2203/045 , C01B2203/0475 , C01B2203/0485 , C01B2203/82 , C01B2203/84 , Y02C10/04 , Y02P20/152
摘要： The present invention involves a catalytic process for purifying a gas stream comprising purifying the gas stream at a temperature from 250 to 550°C by removing sulfur compounds and including a gas shift reaction to convert carbon monoxide to carbon dioxide to produce a partially purified gas stream. The warm gas stream purification involves COS hydrolysis and hydrogenation to H2S, the removal of H2S, and a CO gas shift to convert CO to CO2 to produce a partially purified stream. Then the carbon dioxide and other impurities are removed from the partially purified gas stream.
摘要翻译：本发明涉及一种用于纯化气流的催化方法，包括在250-550℃的温度下通过除去硫化合物并包括气体转换反应来将气流纯化以将一氧化碳转化成二氧化碳以产生部分纯化的气流。热气流纯化涉及COS水解和氢化成H 2 S，去除H 2 S和CO气体转换以将CO转化为CO 2以产生部分纯化的流。然后从部分净化的气流中除去二氧化碳和其他杂质。

5. 发明申请

WO2006036293A1 CONVERSION OF AN ALCOHOLIC OXYGENATE TO PROPYLENE USING MOVING BED TECHNOLOGY AND AN ETHERIFICATION STEP 审中-公开
标题翻译：使用移动床技术和过滤步骤将醇性氧化剂转化为丙烯
公开(公告)号：WO2006036293A1
公开(公告)日：2006-04-06
申请号：PCT/US2005/027409
申请日：2005-08-01
申请人： UOP LLC , KALNES, Tom N. , WEI, Daniel H. , GLOVER, Bryan K.
发明人： KALNES, Tom N. , WEI, Daniel H. , GLOVER, Bryan K.
IPC分类号： C07C1/00
CPC分类号： C07C11/06 , C07C1/20 , C07C2529/40 , C07C2529/85 , Y02P20/52 , Y02P20/584
摘要： The average propylene selectivity per on-stream cycle of an alcoholic oxygenate to propylene (OTP) process using one or more fixed beds of a dual-function oxygenate conversion catalyst is substantially enhanced by the use of a feed pretreatment step involving a catalytic etherification reaction, by switching to moving bed reactor technology in the olefin synthesis portion of the OTP flow scheme in lieu of fixed bed technology and by the selection of a catalyst on-stream cycle time of 300 hours or less. These provisions hold the build-up of coke deposits to a level which does not substantially degrade catalyst activity, oxygenate conversion and propylene selectivity, thereby enabling maintenance of propylene average cycle yield at essentially start-of-cycle levels. The propylene average cycle yield improvement of the present invention over that achieved by the fixed bed system of the prior art is of the order of about 1.5 to 5.5 wt % or more.
摘要翻译：通过使用包含催化醚化反应的进料预处理步骤，使用一种或多种双功能含氧化合物转化催化剂的固定床的酒精含氧化合物对丙烯（OTP）方法的每个流动循环的平均丙烯选择性大大提高，通过在OTP流动方案的烯烃合成部分中切换到移动床反应器技术来代替固定床技术，并且通过选择300小时以下的催化剂流动循环时间。这些规定使焦炭沉积物的积聚达到不会显着降低催化剂活性，含氧化合物转化率和丙烯选择性的水平，从而能够在基本上循环水平的基础上维持丙烯平均循环产率。与现有技术的固定床系统相比，本发明的丙烯平均循环产率提高约为1.5〜5.5重量％以上。

6. 发明申请

WO2006033759A2 CONVERSION OF OXYGENATE TO PROPYLENE WITH SELECTIVE HYDROGEN TREATMENT OF HEAVY OLEFIN RECYCLE STREAM 审中-公开
标题翻译：氧化锌转化为丙烯用选择性氢处理重组烯烃循环物流
公开(公告)号：WO2006033759A2
公开(公告)日：2006-03-30
申请号：PCT/US2005/030075
申请日：2005-08-25
申请人： UOP LLC , KALNES, Tom, N. , WEI, Daniel, H. , GLOVER, Bryan, K.
发明人： KALNES, Tom, N. , WEI, Daniel, H. , GLOVER, Bryan, K.
IPC分类号： C07C1/00
CPC分类号： C07C11/06 , C07C1/20 , C07C2529/40 , C07C2529/80 , C07C2529/85 , Y02P20/52 , Y02P20/582 , Y02P20/584
摘要： The average cycle propylene selectivity of an oxygenate to propylene (OTP) process using one or more fixed or moving beds of a dual-function oxygenate conversion catalyst with recycle of one or more C4+ olefin-rich fractions is substantially enhanced by the use of selective hydrotreating technology on these C4+ olefin-rich recycle streams to substantially eliminate detrimental coke precursors such as dienes and acetylenic hydrocarbons. This hydrotreating step helps hold the build-up of detrimental coke deposits on the catalyst to a level which does not substantially degrade dual-function catalyst activity, oxygenate conversion and propylene selectivity, thereby enabling a substantial improvement in propylene average cycle yield. The propylene average cycle yield improvement enabled by the present invention over the prior art system but without the use of the hydrotreating step on the C4+ olefin-rich recycle stream is of the order of 1.5 to 5.5 wt-% or more.
摘要翻译：使用双功能含氧化合物转化催化剂的一个或多个固定床或移动床并回收一种或多种C 4+富含烯烃的馏分的含氧化合物转化为丙烯（OTP）工艺的平均循环丙烯选择性为通过在这些富含C 4 +烯烃的再循环物流上使用选择性加氢处理技术大大增强，以基本上消除有害的焦炭前体如二烯烃和炔烃。该加氢处理步骤有助于将催化剂上积聚的有害焦炭沉积物保持在基本上不会降低双功能催化剂活性，含氧化合物转化率和丙烯选择性的水平上，从而使丙烯平均循环收率得到显着改善。与现有技术系统相比，本发明使丙烯平均循环产率提高，但对富C4 +烯烃的再循环料流不使用加氢处理步骤，其量级为1.5-5.5重量％或更多。

7. 发明申请

WO2013015997A2 CONTINUOUS CATALYTIC GENERATION OF POLYOLS FROM CELLULOSE 审中-公开
标题翻译：从纤维素连续催化生成多元醇
公开(公告)号：WO2013015997A2
公开(公告)日：2013-01-31
申请号：PCT/US2012046348
申请日：2012-07-12
申请人： UOP LLC , DALIAN CHEMICAL PHYSICS INST , ZHANG TAO , WANG AIQIN , ZHENG MINGYUAN , LI CHANGZHI , PANG JIFENG , KALNES TOM N , CHEN JOHN Q , KOCAL JOSEPH A
发明人： ZHANG TAO , WANG AIQIN , ZHENG MINGYUAN , LI CHANGZHI , PANG JIFENG , KALNES TOM N , CHEN JOHN Q , KOCAL JOSEPH A
IPC分类号： C07C29/94 , B01J21/04 , B01J23/44 , C07C31/26
CPC分类号： C12P7/18 , C07C29/132 , Y02P20/582 , C07C31/20
摘要： A catalytic process for generating at least one polyol from a feedstock comprising cellulose is performed in a continuous manner using a catalyst comprising nickel tungsten carbide. The process involves, contacting, continuously, hydrogen, water, and a feedstock comprising cellulose, with the catalyst to generate an effluent stream comprising at least one polyol and recovering the polyol from the effluent stream.
摘要翻译：使用包含碳化镍碳化物的催化剂以连续方式进行从包含纤维素的原料生成至少一种多元醇的催化方法。该方法包括使氢气，水和包含纤维素的原料与催化剂连续接触以产生包含至少一种多元醇的流出物流并从流出物流中回收多元醇。

8. 发明申请

WO2013015996A2 GENERATION OF POLYOLS FROM SACCHARIDE CONTAINING FEEDSTOCK 审中-公开
标题翻译：来自含有饲料的多糖的产生
公开(公告)号：WO2013015996A2
公开(公告)日：2013-01-31
申请号：PCT/US2012046342
申请日：2012-07-12
申请人： UOP LLC , CHEN JOHN Q , KALNES TOM N , KOCAL JOSEPH A
发明人： CHEN JOHN Q , KALNES TOM N , KOCAL JOSEPH A
IPC分类号： C07C29/94 , B01J21/04 , B01J31/12 , C07C31/18 , C07C31/26
CPC分类号： C07C29/157 , B01J23/888 , B01J27/188 , Y02P20/52 , C07C31/205 , C07C31/202
摘要： A process for generating at least one polyol from a feedstock comprising saccharide is performed in a continuous or batch manner using a catalyst system. The process involves, contacting hydrogen, water, and a feedstock comprising saccharide, with a catalyst system to generate an effluent stream comprising at least one polyol and recovering the polyol from the effluent stream. The catalyst system comprises at least one metal component with an oxidation state greater than or equal to 2+.
摘要翻译：使用催化剂体系以连续或间歇方式进行从包含糖的原料产生至少一种多元醇的方法。该方法涉及使氢，水和包含糖的原料与催化剂体系接触以产生包含至少一种多元醇的流出物流并从流出物流中回收多元醇。催化剂体系包含至少一种氧化态大于或等于2+的金属组分。

9. 发明申请

WO2013015990A2 CATALYTIC PROCESS FOR CONTINUOUSLY GENERATING POLYOLS 审中-公开
标题翻译：连续生成多元醇的催化方法
公开(公告)号：WO2013015990A2
公开(公告)日：2013-01-31
申请号：PCT/US2012/046223
申请日：2012-07-11
申请人： UOP LLC , KALNES, Tom, N. , CHEN, John, Q. , KOCAL, Joseph, A.
发明人： KALNES, Tom, N. , CHEN, John, Q. , KOCAL, Joseph, A.
IPC分类号： C07C29/94 , C07C31/26 , C07C31/18 , B01J23/42 , B01J23/46
CPC分类号： C07C29/132 , C10G3/44 , C10G3/46 , C10G3/48 , C10G3/52 , C10G3/56 , C10G2300/1014 , Y02P20/52 , Y02P30/20 , C07C31/202 , C07C31/205
摘要： A catalytic process for generating at least one polyol from a feedstock comprising cellulose is performed in a continuous manner. The process involves, contacting, continuously, hydrogen, water, and a feedstock comprising cellulose, with a catalyst to generate an effluent stream comprising at least one polyol, water, hydrogen, and at least one co-product. The water, hydrogen, and at least one co-product are separated from the effluent stream and recycled to the reaction zone. The polyol is recovered from the effluent stream.
摘要翻译：用于以包含纤维素的原料生成至少一种多元醇的催化方法以连续方式进行。该方法包括使氢气，水和包含纤维素的原料与催化剂连续接触以产生包含至少一种多元醇，水，氢气和至少一种副产物的流出物料流。将水，氢气和至少一种副产物从流出物流中分离出来并循环到反应区。多元醇从流出物流中回收。

10. 发明申请

WO2013015989A3 CATALYTIC PROCESS FOR CONTINUOUSLY GENERATING POLYOLS 审中-公开
公开(公告)号：WO2013015989A3
公开(公告)日：2013-01-31
申请号：PCT/US2012/046202
申请日：2012-07-11
申请人： UOP LLC , KALNES, Tom N. , CHEN, John Q. , KOCAL, Joseph A.
发明人： KALNES, Tom N. , CHEN, John Q. , KOCAL, Joseph A.
IPC分类号： C07C29/94 , C07C31/26 , B01J21/04 , B01J23/44
摘要： A catalytic process for generating at least one polyol from a feedstock comprising cellulose is performed in a continuous manner. The process involves, contacting, continuously, hydrogen, water, and a feedstock comprising cellulose, with a catalyst to generate an effluent stream comprising at least one polyol, water, hydrogen, and at least one co-product. The water, hydrogen, and at least one co-product are separated from the effluent stream and recycled to the reaction zone. The polyol is recovered from the effluent stream.

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