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    • 2. 发明申请
    • COMPOSITE BODY AND PROCESS FOR ITS PRODUCTION
    • 复合体与方法研究
    • WO1997007260A1
    • 1997-02-27
    • PCT/DE1996001425
    • 1996-07-27
    • WIDIA GMBHTABERSKY, RalfWESTPHAL, HartmutVAN DEN BERG, HendrikusKÖNIG, UdoSOTTKE, Volkmar
    • WIDIA GMBH
    • C23C16/36
    • C23C16/36Y10T407/27Y10T428/31678
    • The invention relates to a composite body consisting of a hard metal, cermet, steel or ceramic substrate and at least one hard metal-carbo-nitride layer and a process for producing said hard carbo-nitride layer. According to the invention, the metal-carbo-nitride layer is obtained by a CVD or PCVD process, in which the metal of the metal-carbo-nitride layer consists of two or more elements from the IVa or VIa group of the periodic system. To produce said layer, either a carbon and nitrogen donor containing a -CN- molecular group is introduced into the CVD gas phase or a PCVD atmosphere is created which, besides hydrogen, argon, two or more different chlorides of the metals of the IVa to VIa groups of the periodic system, also contains ionised and/or non-ionised carbon-nitrogen donors with triple bonds.
    • 本发明涉及一种由硬质金属,金属陶瓷,钢或陶瓷基板主体和至少一种金属的碳氮化物硬质材料层的复合体,并为这些Carbonitridhartstoffschicht的制备方法的一个基团。 根据本发明,所述金属碳氮化物层通过CVD法或PCVD方法,其中所述IVA到VIA族的两种或多种元素的金属碳氮化物层的金属包括元素周期表的沉积。 为了生产该层的任一被引入在CVD气相碳和氮供体,其具有CN-分子基团,,或PCVD气氛,其除了氢气,氩气中,两个或IVa的金属到的多个不同的氯化物 经由基团的周期表的还含有离子化和/或与三键非离子碳 - 氮供体。
    • 3. 发明申请
    • TOOL, PROCESS AND DEVICE FOR PRODUCING IT AND ITS USE
    • 工具和手段和设备用于生产工具的工具,并使用
    • WO1995032317A1
    • 1995-11-30
    • PCT/DE1995000449
    • 1995-04-01
    • WIDIA GMBHKÖNIG, Udo
    • WIDIA GMBH
    • C23C16/40
    • C23C30/005C23C16/36C23C16/44C23C16/56Y10T83/9372Y10T83/9411Y10T409/300056
    • The invention relates to a tool consisting of a basic body of hard metal or cermet and a multi-layer surface coating of carbides, nitrides and/or carbonitrides of titanium and/or zirconium and/or aluminium oxide applied by a CVD process. The CVD process used is repeatedly interrupted while a high temperature remains substantially constant by a plasma treatment in which gases or gas mixtures of argon, hydrogen and/or nitrogen are fed into the coating vessel at pressures of 10 to 1000 Pa and a glow discharge is maintained at the cathodically connected basic body or partly coated basic body by the application of a negative d.c. voltage of 200 to 1000 V for 1 to 30 minutes. This provides a uniform fine-grained structure.
    • 本发明涉及一种硬质金属或金属陶瓷和施加到基体上的层的基体的工具,由碳化物,氮化物和/或钛和/或锆和/或氧化铝由CVD工艺现有多层的碳氮化物施加表面涂层。 所施加的CVD法是多个基本均匀地高温通过等离子体处理中断,已经在气体或气体混合物的辅助氩气,氢气和/或氮气在涂覆容器至1000帕10的压力和在阴极辉光放电被引入 连接基体或部分地涂覆基体通过施加200至1000V 1〜30分钟负的直流电压被维持。 以这种方式,获得了均匀的细粒结构。
    • 6. 发明申请
    • COMPOSITE BODY, ITS USE AND PROCESS FOR PRODUCING IT
    • 复合体,其使用及其生产工艺
    • WO1992017623A1
    • 1992-10-15
    • PCT/DE1992000249
    • 1992-03-27
    • KRUPP WIDIA GMBHVAN DEN BERG, HendrikusKÖNIG, UdoREITER, NorbertTABERSKY, Ralf
    • KRUPP WIDIA GMBH
    • C23C16/40
    • C23C16/515C04B41/5031C23C16/403
    • In order to improve the adhesion and wearing properties of a composite body with a hard metal, steel or cermet substrate or a substrate body of a nickel or cobalt-based alloy and one or more surface layers, of which the outer one preferably consists of alpha aluminium oxide, it is proposed that this outer layer has a fine-crystalline alpha modification, the diffraction lines of which measured through the half-widths with X-ray beams have half-widths which are at least three times as great as those of a powdered alpha aluminium oxide compact body. In order to produce this alpha aluminium oxide layer, it is proposed to perform a plasma-activated CVD process at temperatures of 400 to 750 DEG C. The composite body is highly suitable as a cutting material, a high-temperature material or a hard-wearing material for friction components.
    • 为了提高具有硬金属,钢或金属陶瓷基板或镍或钴基合金的基体和一个或多个表面层的复合体的粘合性和磨损性,其中外表面优选由α 氧化铝,建议该外层具有细晶α改性,通过X射线束的半宽度测量的衍射线具有至少三倍于 粉状α氧化铝致密体。 为了生产这种α氧化铝层,建议在400至750℃的温度下进行等离子体激活的CVD工艺。复合体非常适合作为切削材料,高温材料或硬质合金, 耐磨材料用于摩擦部件。