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    • 2. 发明申请
    • SURFACE TREATMENT PROCESS, COMPOSITION FOR USE THEREIN, AND TREATED ARTICLE
    • 表面处理工艺,其使用的组合物和处理的物品
    • WO2012064653A1
    • 2012-05-18
    • PCT/US2011/059585
    • 2011-11-07
    • 3M INNOVATIVE PROPERTIES COMPANYRAJAGOPAL, Rama V.IYER, Suresh S.
    • RAJAGOPAL, Rama V.IYER, Suresh S.
    • C09D183/08C09D183/14C09D4/00
    • C09D7/1233C08G65/007C08G65/336C08G77/24C08G77/485C08G2650/48C09D4/00C09D7/63C09D171/02C09D183/08C09D183/14
    • A surface treatment process comprises (a) providing at least one substrate; (b) providing a curable surface treatment composition comprising (1) at least one fluorinated organosilane compound comprising (i) a monovalent segment selected from polyfluoroalkyl, polyfluoroether, polyfluoropolyether, and combinations thereof and (ii) a monovalent endgroup comprising at least one silyl moiety comprising at least one group selected from hydrolyzable groups, hydroxyl, and combinations thereof, and (2) at least one organosilane compound comprising (i) a multivalent non-fluorinated segment and (ii) at least two monovalent endgroups, each monovalent endgroup independently comprising at least one silyl moiety comprising at least one group selected from hydroxyl, hydrolyzable groups, and combinations thereof, and/or at least one organosilazane compound; (c) applying the curable surface treatment composition to the substrate; and (d) curing the applied, curable surface treatment composition.
    • 表面处理方法包括(a)提供至少一个基材; (b)提供可固化的表面处理组合物,其包含(1)至少一种氟化有机硅烷化合物,其包含(i)选自多氟烷基,多氟醚,多氟聚醚及其组合的单价链段和(ii)包含至少一个甲硅烷基部分的单价末端基 包括至少一个选自可水解基团,羟基及其组合的基团,和(2)至少一种有机硅烷化合物,其包含(i)多价非氟化链段和(ii)至少两个单价端基,每个单价端基独立地包含 包含至少一个选自羟基,可水解基团及其组合的基团的至少一个甲硅烷基部分和/或至少一种有机硅氮烷化合物; (c)将可固化表面处理组合物施加到基材上; 和(d)固化所施加的可固化表面处理组合物。
    • 10. 发明申请
    • SYSTEM AND PROCESS FOR THE REMOVAL OF FLUOROCHEMICALS FROM WATER
    • 从水中去除氟化物的系统和方法
    • WO2008101137A1
    • 2008-08-21
    • PCT/US2008/054042
    • 2008-02-15
    • 3M INNOVATIVE PROPERTIES COMPANYMADER, Brian T.,KLUN, Thomas P.,IYER, Suresh S.,
    • MADER, Brian T.,KLUN, Thomas P.,IYER, Suresh S.,
    • C02F1/42B01J41/04
    • C02F1/42B01J41/04B01J41/05B01J41/12C02F2101/14
    • Systems and processes for the removal of fluorochemicals from water are provided. Systems according to the invention include a vessel containing the ion exchange resin, the ion exchange resin including an insoluble matrix having functional groups bonded to the matrix, the functional groups being amines of the formula: N(R 1 R 2 R 3 ) Where N is nitrogen; and R 1 , R 2 and R 3 are hydrocarbon groups and can be the same or different, normal, branched and/or partially or fully substituted (e.g., fluorinated) and having a carbon chain length of C 1 or greater, the hydrocarbon chain optionally including polar groups (e.g., O, N, S). An inlet for directing a flow of water into the vessel is provided to facilitate contact between the water and the ion exchange resin; and an outlet is provided to direct a flow of water out of the vessel after the water is treated. A process for the removal of fluorochemicals from water is also provided by exposing water to the foregoing ion exchange resin, maintaining the water in contact with the resin for a period of time, and thereafter separating the water from the resin.
    • 提供了从水中除去含氟化合物的系统和方法。 根据本发明的系统包括含有离子交换树脂的容器,所述离子交换树脂包括具有与基质结合的官能团的不溶性基质,所述官能团是下式的胺:N(R 1) R 2 R 3 N)其中N是氮; 和R 1,R 2和R 3是烃基,并且可以是相同或不同的,正常的,支链的和/或部分的或完全的 取代(例如氟化)且碳链长度为C 1或更大,烃链任选地包括极性基团(例如O,N,S)。 提供用于将水流引导到容器中的入口以便于水和离子交换树脂之间的接触; 并且在处理水之后提供出口以将水流引导出容器。 通过将水暴露于上述离子交换树脂,保持水与树脂接触一段时间,然后将水从树脂中分离出来,还提供了从水中除去含氟化合物的方法。