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    • 1. 发明申请
    • METHODS OF OPERATING SURFACE REACTORS FOR HIGHLY REACTIVE REACTANTS AND REACTORS EMPLOYING SUCH METHODS
    • 使用这种方法的高反应性反应物和反应物操作表面反应物的方法
    • WO2009051727A1
    • 2009-04-23
    • PCT/US2008/011765
    • 2008-10-15
    • HOLL, Richard, A.
    • HOLL, Richard, A.
    • B01J8/08
    • B01J19/247B01F5/0268B01F5/0451B01J4/002B01J10/007B01J10/02B01J14/005B01J19/26B01J2219/00085
    • Methods for operating surface reactors such as for reacting at least two highly reactive fluid reactants are described. Reactants are fed via two separate closely spaced coaxial inner and outer fluid flow passages so as to form an inner passage inner jet encased by a coaxial outer passage outer jet. The two jets upon discharge from their outlets simultaneously and perpendicularly impacted against an impact zone causing an immediately abrupt change in flow direction outward over a surface providing the impact zone as thin films that mix and react together. The impact and abrupt direction change produces shear forces having a maxima at the impact zone in the films which facilitate flow mixing. Precision metering pump means feed reactants at rates such that reactant velocities at impact zone and produced shear forces combine to disrupts molecular clusters in the thin films which facilitates molecular diffusion reaction between the reactants.
    • 描述了用于操作表面反应器的方法,例如用于使至少两种高反应性流体反应物反应。 反应物通过两个分离的紧密间隔的同轴的内部和外部流体流动通道进给,以形成由同轴的外部通道外部喷射器包围的内部通道内部射流。 两个喷嘴在从其出口同时排出并垂直地撞击冲击区域时,导致流动方向立即突然改变,提供冲击区域作为混合和反应在一起的薄膜的表面。 冲击和突然的方向变化产生在膜中的冲击区域具有最大值的剪切力,这有助于流动混合。 精密计量泵是指以反应速度使冲击区域反应速度和产生的剪切力相结合以破坏薄膜中分子簇的速率,促进反应物之间的分子扩散反应。
    • 2. 发明申请
    • METHODS AND APPARATUS FOR HIGH-SHEAR MIXING AND REACTING OF MATERIALS
    • 高剪切混合和材料反应的方法与装置
    • WO2004025260A2
    • 2004-03-25
    • PCT/US2003/028747
    • 2003-09-11
    • HOLL TECHNOLOGIES COMPANYHOLL, Richard, A.
    • HOLL, Richard, A.
    • G01N
    • B01F5/0679B01F5/0665B01F2215/0427B01F2215/0431B01J19/247B01J2219/00085B01J2219/00135B01J2219/00164
    • Methods and apparatus for high shear reacting and/or mixing of moving fluid streams of materials employ an interdiffusing and reacting zone formed in the space between two stationary surfaces, the surfaces being spaced apart a maximum distance of the sum of the thicknesses of the back-to-back boundary layers of the materials and/or resulting materials on the surfaces, to a value such that any third layer between the two boundary layers is too thin to support agitation characterized by turbulent convection and/or to cause channeling. The materials are interdiffused by high speed laminar shear produced by the flow of the materials rather than mixed by macroscopic convection, the materials being driven by high velocity inlet feeds, auxiliary high pressure gas flow pumped into the reaction/mixing zone, or auxiliary high-pressure gas flow created as an evolving gaseous byproduct of any chemical reaction that may occur.
    • 用于高剪切反应和/或混合材料的运动流体物流的方法和装置采用形成在两个固定表面(30,32)之间的空间中的相互扩散和反应区域,所述表面间隔开(22,22B)最大距离 是表面上材料和/或所得材料的背靠背边界层的厚度之和的值,使得两个边界层之间的任何第三层太薄而不能支持以湍流对流为特征的搅拌 和/或引起沟通。 材料通过材料流动产生的高速层流剪切相互扩散,而不是通过宏观对流混合,材料由高速入口进料(24,26)驱动,辅助高压气流泵入反应/混合区 ,或作为可能发生的任何化学反应的气态副产物产生的辅助高压气流。
    • 3. 发明申请
    • METHODS AND APPARATUS FOR TRANSFER OF HEAT ENERGY BETWEEN A BODY SURFACE AND HEAT TRANSFER FLUID
    • 用于传递体表面和传热流体之间的热能的方法和设备
    • WO2003022415A2
    • 2003-03-20
    • PCT/US2002/029093
    • 2002-09-13
    • HOLL TECHNOLOGIES COMPANYHOLL, Richard, A.
    • HOLL, Richard, A.
    • B01F13/00
    • F28D7/106B29C47/0009B29C47/82F28D2021/0077F28F13/02F28F13/125
    • In methods and apparatus for heat exchange to and from a body surface using a heat transfer fluid the fluid is impinged on the surface from a plurality of delivery inlets in the form of a corresponding plurality of spaced delivery streams and is immediately removed from the plenum upon rebounding from the surface through a plurality of spaced removal outlets distributed among the delivery streams, thus establishing corresponding very short uninterrupted flow paths between each inlet and its removal outlet/s. Preferably, the fluid stream velocity is sufficient for it to penetrate and disrupt a fluid boundary layer on the body surface. Each delivery inlet may have its outlet to the surface spaced from 0.001cm to 0.2cm (0.0004in to 0.08in) from that surface. Each delivery inlet may produce a jet impinging the surface of from 0.3cm to 1.5cm (0,12in to 0.6in) diameter. The delivery streams may impinge a flat body surface from a right angle to an acute angle, while when the body surface is curved the delivery streams may impinge from a right angle to one that is tangential thereto. A particular apparatus with which the heat exchanger may be used has a cylindrical rotor rotating within a cylindrical stator so that the body surface is cylindrical; the rotor diameter may be from 0.1cm to 500cm (0.04in to 200ins).
    • 在用于使用传热流体与身体表面进行热交换的方法和设备中,流体从多个输送入口以相应的多个间隔输送流的形式冲击在表面上 并在从表面通过分布在输送流之间的多个间隔开的排出口回弹时立即从充气室移除,由此在每个入口与其排出出口之间建立相应的非常短的不间断流动路径。 优选地,流体流速足以使其渗透并破坏身体表面上的流体边界层。 每个输送入口的出口可以离开该表面的距离为0.001cm至0.2cm(0.0004in至0.08in)。 每个输送入口可以产生撞击直径从0.3cm至1.5cm(0.12英寸至0.6英寸)的表面的射流。 输送流可以将平坦的身体表面从直角冲击到锐角,而当身体表面弯曲时,输送流可以从直角冲击到与其相切的输送流。 可以使用热交换器的特定设备具有在圆柱形定子内旋转的圆柱形转子,使得该体表面是圆柱形的; 转子直径可以从0.1厘米至500厘米(0.04英寸至200英寸)。
    • 6. 发明申请
    • MANUFACTURE OF COMPOSITES OF INORGANIC POWDER AND POLYMER MATERIALS
    • 无机粉末和聚合物材料复合材料的制备
    • WO9821272A2
    • 1998-05-22
    • PCT/US9719104
    • 1997-10-24
    • HOLL RICHARD A
    • HOLL RICHARD A
    • B01F3/12B01F15/04B29B9/04B29C35/16B29C67/24C08J3/215H05K1/03H05K3/02C08L
    • B01F15/0412B01F3/1271B29B9/04B29C35/16B29C67/245C08J3/215H05K1/0373H05K3/022H05K2201/0209
    • Composite materials comprising at least 70 volume % of particles of finely powdered inorganic material in a matrix of polymer material are made by forming separate mixtures of the components in respective liquid dispersion media, mixing the mixtures to produce thorough dispersion of the components together, dewatering the mixture and forming green articles therefrom. The green articles are heated and pressed to a temperature sufficient to melt the polymer and to a pressure sufficient to disperse the melted polymer into the interstices between the inorganic particles. Mixtures of different inorganic materials may be used to tailor the electrical and physical properties of the final materials. The inorganic materials may be obtained in finely divided form by precipitation or coprecipitation. The articles preferably comprise substrates for use in electronic circuits. The invention also comprises apparatus for carrying out the method and the composite materials that result. Polymer particles of required small size are made by cooling a strip or rod to a brittle fracture temperature and feeding it against a moving grinding surface of coarseness to produce the particles.
    • 在聚合物材料基质中包含至少70体积%的细粉末状无机材料颗粒的复合材料通过在各自的液体分散介质中形成各组分的分离混合物,混合混合物以使组分完全分散在一起,脱水 混合物并从中形成绿色制品。 将绿色制品加热并压制至足以熔化聚合物的温度和足以将熔融的聚合物分散到无机颗粒之间的空隙中的压力。 可以使用不同无机材料的混合物来定制最终材料的电学和物理性能。 无机材料可以通过沉淀或共沉淀而以细碎的形式获得。 物品优选地包括用于电子电路的基底。 本发明还包括用于执行所产生的方法和复合材料的装置。 所需小尺寸的聚合物颗粒通过将条或棒冷却至脆性断裂温度并将其输送到移动的粗糙的研磨表面来制备颗粒。
    • 7. 发明申请
    • APPARATUS FOR TRANSFER OF HEAT ENERGY BETWEEN A BODY SURFACE AND HEAT TRANSFER FLUID
    • 身体表面和热传递液体之间的热能传递装置
    • WO2004030802A3
    • 2005-03-17
    • PCT/US0331302
    • 2003-10-03
    • KREIDO LABHOLL RICHARD A
    • HOLL RICHARD A
    • B01F7/00B01F15/06B01J19/00B01J19/18F28D11/02F28D7/10F28D11/00F28D11/08F28D21/00F28F5/02F28F27/02
    • B01F15/068B01F7/008B01J19/0013B01J19/1812B01J2219/00085B01J2219/182B01J2219/1943F28D11/02
    • In apparatus for heat exchange to and from a body surface using a heat transfer liquid a heat exchanger comprises a plurality of elements (30) within a casing (10) connected axially against one another with spacer tube elements. Each element (30) has its periphery spaced from the body surface to provide a flow gap (50) for heat transfer fluid in heat exchange contact with the surface. The element (30) have plenums (41, 42) separating each from one another forming connecting flow spaces (36, 37) for the heat transfer liquid between the heat transfer flow gap and inlet and outlet passages (38, 39) passing through the body. A preferred apparatus is a cylindrical rotor (16) within a cylindrical stator (10) with an annular processing space (20) between them, the rotor containing a stack of heat exchange elements (30) of the respective shape permitting high heat flux rates and uniform temperature distribution over the total rotor heat transfer surface.
    • 在使用传热液体与身体表面热交换的装置中,热交换器包括多个元件(30),所述多个元件(30)在与间隔管元件彼此轴向连接的壳体(10)内。 每个元件(30)的周边与主体表面间隔开,以提供与表面热交换接触的传热流体的流动间隙(50)。 元件(30)具有彼此分离的通风室(41,42),其形成用于传热流体间的传热液体的连通流动空间(36,37)和通过所述传热流动间隙的入口和出口通道(38,39) 身体。 优选的装置是圆柱形定子(10)内的圆柱形转子(16),在它们之间具有环形处理空间(20),转子包含一组允许高热通量速率的各种形状的热交换元件(30) 整个转子传热表面温度分布均匀。
    • 9. 发明申请
    • METHODS AND APPARATUS FOR HIGH-SHEAR MIXING AND REACTING OF MATERIALS
    • 高剪切混合和材料反应的方法和装置
    • WO2004025260A3
    • 2004-05-13
    • PCT/US0328747
    • 2003-09-11
    • KREIDO LABHOLL RICHARD A
    • HOLL RICHARD A
    • B01F5/06B01J19/24B81B7/00
    • B01F5/0679B01F5/0665B01F2215/0427B01F2215/0431B01J19/247B01J2219/00085B01J2219/00135B01J2219/00164
    • Methods and apparatus for high shear reacting and/or mixing of moving fluid streams of materials employ an interdiffusing and reacting zone formed in the space between two stationary surfaces (30, 32), the surfaces being spaced (22, 22B) apart a maximum distance of the sum of the thicknesses of the back-to-back boundary layers of the materials and/or resulting materials on the surfaces, to a value such that any third layer between the two boundary layers is too thin to support agitation characterized by turbulent convection and/or to cause channeling. The materials are interdiffused by high speed laminar shear produced by the flow of the materials rather than mixed by macroscopic convection, the materials being driven by high velocity inlet feeds (24, 26), auxiliary high pressure gas flow pumped into the reaction/mixing zone, or auxiliary high-pressure gas flow created as an evolving gaseous by product of any chemical reaction that may occur.
    • 用于高剪切反应和/或混合材料的运动流体物流的方法和装置采用在两个固定表面(30,32)之间的空间中形成的相互扩散和反应区域,所述表面间隔开(22,22B)最大距离 是表面上的材料和/或所得材料的背对边界层的厚度之和,使得两个边界层之间的任何第三层太薄而不能支持以湍流对流为特征的搅拌的值 和/或引起沟通。 材料通过材料流动产生的高速层流剪切相互扩散,而不是通过宏观对流混合,材料由高速进口进料(24,26)驱动,辅助高压气流泵入反应/混合区 ,或由可能发生的任何化学反应的产物产生的作为放出气体的辅助高压气流。
    • 10. 发明申请
    • METHODS AND APPARATUS FOR HIGH-SHEAR MATERIAL TREATMENT
    • 高剪切材料处理方法与装置
    • WO1994004275A1
    • 1994-03-03
    • PCT/US1993007931
    • 1993-08-24
    • HOLL, Richard, A.
    • B02C19/18
    • B01F7/00758B01F3/1221B01F3/1242B01F7/00791B01F7/008B01F7/00833B01F11/0225B01F11/0266B01F2215/0404B02C7/02B02C17/166B02C19/18Y10S977/70Y10S977/776Y10S977/892
    • High-shear treated materials are passed through a high-shear treatment zone which allows the coexistence of free supra-Kolmogoroff eddies larger than the smallest possible Kolmogoroff eddy diameter and forced sub-Kolmogoroff eddies smaller than this diameter. This zone includes a subsidiary higher-shear zone for suppressing these free eddies. The passage walls (40, 44, 102, 108) move relative to one another transverse to the flow to force the simultaneous development of supra-Kolmogoroff and sub-Kolmogoroff eddies while maintaining liquid films adherent to the passage surfaces. The movement produces only forced sub-Kolmogoroff eddies in the susidiary zone while maintaining a non-turbulent flow. Ultrasonic oscillations (52) may be applied to cause elastohydrodynamic pressure and viscosity increases and/or production of smaller sub-Kolmogoroff eddies. One apparatus includes an inner cylinder rotatable (46) inside a hollow outer cylinder (38), another consists of two circular coaxial plates, and the rotational axis can be vertical or horizontal.
    • 高剪切处理的材料通过高剪切处理区域,其允许大于最小可能的Kolmogoroff涡流直径的自由的上Kolmogoroff涡流并且小于该直径的强制的次Kolmogoroff涡流共存。 该区域包括用于抑制这些自由涡流的辅助高剪切区域。 通道壁(40,44,102,108)相对于流动相互相对地移动,以迫使同时发展超Kolmogoroff和次Kolmogoroff涡流,同时保持粘附到通道表面的液膜。 这个运动只会在苏维埃地区产生强迫的次Kolmogoroff涡流,同时保持非湍流的流动。 可以应用超声振荡(52)以引起弹性流体动力学压力和粘度增加和/或产生较小的次Kolmogoroff涡流。 一个装置包括在中空外筒(38)​​内部可旋转的内筒(46),另一个由两个圆形同轴板组成,并且旋转轴线可以是垂直的或水平的。