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1. 发明申请

WO2008029194A1 6-(BIPHENYL-ESTER) -3H-NAPHTHO [2, 1-B] PYRANS AS PHOTOCHROMIC DICHROIC DYES AND OPTICAL ARTICLE CONTAINING THEM 审中-公开
标题翻译： 6-（BIPHENYL-ESTER）-3H-NAPHTHO [2,1-B] PYRANS作为光致变色二色性染料和含有它们的光学物品
公开(公告)号：WO2008029194A1
公开(公告)日：2008-03-13
申请号：PCT/IB2006/003684
申请日：2006-09-06
申请人： ESSILOR INTERNATIONAL (COMPAGNIE GÉNÉRALE D'OPTIQUE) , AIKEN, Stuart , CANO, Jean-Paul , GABBUTT, Christopher, David , HERON, Bernard, Mark
发明人： AIKEN, Stuart , CANO, Jean-Paul , GABBUTT, Christopher, David , HERON, Bernard, Mark
IPC分类号： C07D311/92 , G02B1/04 , G03C1/73
CPC分类号： C07D311/92 , C07D405/10 , C07D455/04
摘要： A naphthopyran compound represented by the formula (I): wherein : n 1 , n 2 , p, m and q represent an integer; R 1 , R 2 and R 4 , represent a group selected from halogen, -R a , -OH, -OR a , -SH, -SR a , -NH 2 , -NR a R a1 , -NR b R c , -CO-R a , -CO 2 R a1 , -OC(O)-R d , -X-(R e )-Y, linear or branched (C 1 -C 18 ) perfluoroalkyl group, wherein R a , R al , R b , R c , X, Y, R e , and R d are as defined in the description; R 3 represents a group selected from halogen, -R a , linear or branched (C 1-18 ) perfluoroalkyl group -OH, -OR a , -SH, -SR a , -NH 2 , and -NR a R a1 ; R 6 represents a group selected from -R a which may be optionally substituted, linear or branched (C 1-18 ) perfluoroalkyl, cycloalkyl, heterocycloalkyl, aryl, and heteroaryl, which may be optionally substituted; R 5 represents a group selected from: halogen, -R a , linear or branched (C 1-18 ) perfluoroalkyl group, -OH, -OR a , -SH, -SR a , -NH 2 , -NR a R a1 , -CO-R a , -O-C(O)-R a and -CO 2 R a1 or when q is equal to 2, then two R 5 together represents further a group -O-(CH 2 ) q1 -O- wherein q1 represents an integer comprised from 1 to 3 inclusive.
摘要翻译：由式（I）表示的萘并吡喃化合物：其中：n1，n2，p，m和q表示整数; R 1，R 2和R 4，表示选自卤素，-R a a，-OH，，-OR a a，-SH，-SR a，-NH 2，-NR a，R a，N a， -CO 2 R a，-CO-R a，-CO 2 R a，（O）-R d，-X-（R e）= Y，直链或支链（C _{; R 6表示选自可以任意取代的直链或支链（C 1-18）全氟烷基的环烷基，环烷基，杂环烷基，芳基和杂芳基，其可以是任选取代的; R 5表示选自以下的基团：卤素，直链或支链（C 1-18）全氟烷基，-OH， -OR 1 a，-SH，-SR a a，-NH 2，-NR a，R a， -CO-R a a，-OC（O）-R a a和-CO 2 R a1 或当q等于2时，则两个R 5一起进一步代表基团-O-（CH 2）2， -O-，其中q1表示1〜3的整数，包括1和3。}

2. 发明申请

WO2009109546A1 PHOTOCHROMIC DICHROIC NAPHTHO-PYRANS AND OPTICAL ARTICLES CONTAINING THEM 审中-公开
标题翻译：光电二极管石墨和包含它们的光学文章
公开(公告)号：WO2009109546A1
公开(公告)日：2009-09-11
申请号：PCT/EP2009/052452
申请日：2009-03-02
申请人： ESSILOR INTERNATIONAL (COMPAGNIE GENERALE D'OPTIQUE) , AIKEN, Stuart , GABBUT, Christopher, David , HERON, Bernard, Mark , KERSHAW, Christopher, Stephen , SMITH, Nicola Jane , CANO, Jean-Paul
发明人： AIKEN, Stuart , GABBUT, Christopher, David , HERON, Bernard, Mark , KERSHAW, Christopher, Stephen , SMITH, Nicola Jane , CANO, Jean-Paul
IPC分类号： C07D311/92 , C07D409/04 , C07D409/10 , C09K9/00
CPC分类号： C07D311/92 , C07D409/04 , C07D409/10 , C09K9/02 , C09K2211/1007 , C09K2211/1029 , C09K2211/1088 , C09K2211/1092
摘要： A naphthopyran compound represented by the formulae (I) to (II) wherein : ▪ mi, Hi2, p, q are each an integer comprised from O to 4 or 5 inclusive; ▪ Ri, R2 and R4, represent a group selected from halogen, H, -Ra, aryl, -OH, -ORa, -SH, -SRa, -NH2, -NR8RaI, -NRbRc, -NRalCORa, -NRaiCO(aryl), -NRai aryl, -N-aryfe, -N(aryl)CO(aryl), -CO-R3, -CO2R3I, -OC(O)-Rd, and -X-(Re)-Y, and linear or branched (Ci-Ci8) perfluoroalkyl group, wherein R3, Rai, Rb, Rc, X, Y, Re, Rd are as defined into the description; ▪ Zi re resent a group selected from: (formules)
摘要翻译：由式（I）至（II）表示的萘并吡喃化合物，其中： mi，Hi2，p，q各自为包含0至4或5的整数; ？ R 1，R 2和R 4表示选自卤素，H，-R a，芳基，-OH，-OR a，-SH，-SR a，-NH 2，-NR 8 R 1a，-NR b R c，-NR a COR a，-NR a CO（芳基）（芳基）CO（芳基），-CO-R 3，-CO 2 R 3 I，-OC（O）-R d和-X-（Re）-Y，直链或支链（ C 1 -C 18）全氟烷基，其中R 3，R e，R b，R c，X，Y，Re，R d如说明书中所定义; ？ Zi重新选择一个选自：（配方）

3. 发明申请

WO2008030226A1 3H-NAPHTH0 [2, 1-B] PYRANS AS PHOTOCHROMIC DICHROIC DYES AND OPTICAL ARTICLE CONTAINING THEM 审中-公开
标题翻译： 3H-NAPHTH0 [2,1-B] PYRANS作为光致变色二色染料和含有它们的光学物品
公开(公告)号：WO2008030226A1
公开(公告)日：2008-03-13
申请号：PCT/US2006/034507
申请日：2006-09-06
申请人： ESSILOR INTERNATIONAL (COMPAGNIE GENERALE D'OPTIQUE) , ALPHAMICRON, INC. , AIKEN, Stuart , CANO, Jean Paul , GABBUTT, Christoper David , HERON, Bernard Mark , KOSA, Tamas , SU, Linli , SUKHOMLINOVA, Ludmila , TAHERI, Bahman
发明人： AIKEN, Stuart , CANO, Jean Paul , GABBUTT, Christoper David , HERON, Bernard Mark , KOSA, Tamas , SU, Linli , SUKHOMLINOVA, Ludmila , TAHERI, Bahman
IPC分类号： C07D311/92 , C07D455/04 , G02B1/04 , G03C1/73
CPC分类号： C07D471/04 , C07D311/92 , C07D405/10 , C07D455/04
摘要： A naphthopyran compound represented by the formula (I): wherein: n 1 , n 2 , p, q is an integer comprised from 0 to 5 inclusive; m is an integer comprised from 0 to 4 inclusive; R1 and R2 represent a group selected from halogen, -R a , -OH, -OR a , - SH, -SR a , -NH 2 , -NR a R a1 , -NR b R c , -CO-R a , and -CO 2 R a1 , wherein R a , R a1 , R b and R c , are as defined in the description ; R 3 represents a group selected from halogen, -R a , -OH, -OR a , -SH, -SR a , -NH 2 , and -Nr a R a1 ; R 4 represents a group selected from halogen, -R a , -OH, -OR a , -SH, -SR a , -NH 2 , -NR a R a1 , -CO-R a , and -CO 2 R a1 ; R 5 represents a group selected from: o halogen, -R a , -OH, -OR a , -SH, -SR a , -NH 2 , and -NR a R a1 , wherein R a and R a1 are as defined hereinbefore, o or when q is equal to 2, then two R 5 together represent further a group -O-(CH 2 ) q1 -O- wherein ql represents an integer comprised from 1 to 3 inclusive.
摘要翻译：由式（I）表示的萘并吡喃化合物：其中：n 1，n 2，p，q为0至5的整数，包括端值; m为0〜4的整数， R 1和R 2表示选自以下的基团：-R a a a，-OH，-OR a a，-S SH，-SR a a， NH 2，-NR a，R a，C 1，R 2，R 3， -CO-R a a和-CO 2 R a a1，其中R a a，R a1， R b，R b和R c c如说明书中所定义; R 3表示选自以下的基团：R a a a，-OH，-OR a a，-SH，-SR a a -NH 2，和-Nr a，a，b，...， R 4表示选自以下的基团：R a a a，-OH，-OR a a，-SH，-SR a a -NH 2，-NH 2，-CO-R a a，和/或N 2， -CO _{2 - [R _{A1 ; R 5表示选自以下的基团：卤素，-R a，a，-OH，-OR a a，-SH，-SR}}

4. 发明申请

WO2008028930A1 6-(BIPHENYL-ESTER)-3H-NAPHTHO[2, 1-B]PYRANS AS PHOTOCHROMIC DICHROIC DYES AND OPTICAL ARTICLE CONTAINING THEM 审中-公开
标题翻译： 6-（BIPHENYL-ESTER）-3H-NAPHTHO [2,1-B] PYRANS作为光致变色二色性染料和含有它们的光学物品
公开(公告)号：WO2008028930A1
公开(公告)日：2008-03-13
申请号：PCT/EP2007/059298
申请日：2007-09-05
申请人： ESSILOR INTERNATIONAL (COMPAGNIE GENERALE D'OPTIQUE) , AIKEN, Stuart , CANO, Jean-Paul , GABBUTT, Christopher, David , HERON, Bernard, Mark
发明人： AIKEN, Stuart , CANO, Jean-Paul , GABBUTT, Christopher, David , HERON, Bernard, Mark
IPC分类号： C07D311/92 , G02B1/04 , G03C1/73
CPC分类号： C07D311/92 , C07D405/10 , C07D455/04
摘要： A naphthopyran compound represented by the formula (I) wherein: n 1 , n 2 , p, m and q represent an integer; R 1 , R 2 and R 4 , represent a group selected from halogen, -R a , -OH, -OR a , -SH, -SR a , -NH 2 , -NR a R a1 , -NR b R c , -CO-R a , -CO 2 R a1 , -OC(O)-R d , -X-(R e )-Y, linear or branched (C 1 -C 18 ) perfluoroalkyl group, wherein R a , R a1 , R b , R c , X, Y, R e , and R d are as defined in the description; Z represents a group selected from CO, CS, SO, SO 2 , CO 2 , C(O)S, CS 2 , C(O)NH, C(O)NR a , C(S)NH, C(S)NR a and C=NR a ; R 3 represents a group selected from halogen, -R a , linear or branched (C 1-18 ) perfluoroalkyl group -OH, -OR a , -SH, -SR a , -NH 2 , and -NR a R a1 ; R 6 represents a group selected from -R a which may be optionally substituted, linear or branched (C 1-18 ) perfluoroalkyl, cycloalkyl, heterocycloalkyl, aryl, and heteroaryl, which may be optionally substituted; R 5 represents a group selected from: halogen, -R a , linear or branched (C 1-18 ) perfluoroalkyl group, -OH, -OR a , -SH, -SR a , -NH 2 , -NR a R a1 , -CO-R a , -O-C(O)-R a and -CO 2 R a1 ; or when q is equal to 2, then two R 5 together represents further a group -O-(CH 2 ) q1 -O- wherein q1 represents an integer comprised from 1 to 3 inclusive.
摘要翻译：由式（I）表示的萘并吡喃化合物，其中：n 1，n 2，p，m和q表示整数; R 1，R 2和R 4，表示选自卤素，-R a a，-OH，，-OR a a，-SH，-SR a，-NH 2，-NR a，R a，N a， -CO 2 R a，-CO-R a，-CO 2 R a，（O）-R d，-X-（R e）= Y，直链或支链（C _{; R 6表示选自可以任意取代的直链或支链（C 1-18）全氟烷基的环烷基，环烷基，杂环烷基，芳基和杂芳基，其可以是任选取代的; R 5表示选自以下的基团：卤素，直链或支链（C 1-18）全氟烷基，-OH， -OR 1 a，-SH，-SR a a，-NH 2，-NR a，R a， -CO-R a a，-OC（O）-R a a和-CO 2 R a1 ; 或当q等于2时，则两个R 5一起进一步代表基团-O-（CH 2 CH 2）q1-O-，其中 q1表示1〜3的整数。}

5. 发明申请

WO9842693A3 NEUTRAL COLOURING PHOTOCHROMIC 2H-NAPHTHO(1,2-B)PYRANS AND HETEROCYCLIC PYRANS 审中-公开
标题翻译：中性色光照相2H-NAPHTHO（1,2-B）PYRANS AND HEOCOCYCLIC PYRANS
公开(公告)号：WO9842693A3
公开(公告)日：1999-02-11
申请号：PCT/GB9800904
申请日：1998-03-25
申请人： JAMES ROBINSON LTD , CLARKE DAVID ALLAN , HERON BERNARD MARK , GABBUTT CHRISTOPHER DAVID , HEPWORTH JOHN DAVID , PARTINGTON STEVEN MICHAEL , CORNS STEPHEN NIGEL
发明人： CLARKE DAVID ALLAN , HERON BERNARD MARK , GABBUTT CHRISTOPHER DAVID , HEPWORTH JOHN DAVID , PARTINGTON STEVEN MICHAEL , CORNS STEPHEN NIGEL
IPC分类号： G02C7/10 , C07D311/92 , C07D491/04 , C07D491/052 , C07D493/04 , C07D495/04 , C09K9/02 , G02B5/23 , C07D311/00
CPC分类号： C07D491/04 , C07D311/92 , C07D495/04
摘要： A naphtho[1,2-b]pyran of general formula (I) wherein R?1 and R2¿ are each selected from unsubstituted, mono-, di- or polysubstituted aryl groups, phenyl and naphthyl and heteroaryl groups. R5 is selected from linear or branched C¿1?-C10 alkyl, C1-C20 cycloalkyl, C1-C20 bicycloalkyl, C1-C20 polycycloalkyl, linear or branched C1-C10 haloalkyl, linear or branched C1-C10 perhaloalkyl, linear or branched C1-C10 perhaloalkenyl, linear or branched C1-C10 alkenyl, C1-C10 alkynyl, linear or branched C1-C10 alkoxy, linear or branched C1-C10 alkylthio, linear or branched C1-C10 alkoxy (linear or branched C1-C10 alkyl), linear or branched C1-C10 hydroxyalkyl, linear or branched C1-C10 aminoalkyl, aryl, phenyl, heteroaryl, halogen, nitrile, nitro, amino, linear or branched C1-C20 alkoxycarbonyl, hydroxyl, formyl, acetyl, amido, C1-C5 alkyl amido, C1-C5 dialkylamido, aroyl, benzoyl, alkyl C1-C5 amino, dialkyl C1-C5 amino, arylamino, diarylamino, aryl C1-C5 alkylamino and cyclicamino groups, arylsulfinyl, arylsulfanyl, arylsulfonyl, linear or branched C1-C10 alkylsulfonyl, P(O)(O-C1-C10 alkyl)2 or is an alkenyl function of general formula (a) wherein R?11¿ and/or R12 and/or R13 is hydrogen or R?5, R3, R4, R6, R8 and R10¿ are each hydrogen, R?1, R2 or R5; and R7¿ and/or R9 is hydrogen or an amino group provided that R?7 and R9¿ are not both hydrogen. The compounds may be combined with a polymeric host material such as plastic or glass to make a sunglass lens, an ophthalmic lens or a window.
摘要翻译：包含式（I）的萘并[1,2-b]吡喃的组合物：其中R 7和/或R 9为氢或氨基，条件是R 7和R 9不同时为氢，其它取代基如本说明书中所定义。

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