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    • 4. 发明申请
    • COATING AGENT AND METHOD OF COATING, IN PARTICULAR FOR USE ON PLASTIC SUBSTRATES
    • 盖装置和方法涂料,是塑料基板
    • WO1997022644A1
    • 1997-06-26
    • PCT/EP1996005625
    • 1996-12-14
    • HERBERTS GESELLSCHAFT MIT BESCHRÄNKTER HAFTUNGKERBER, HermannMANN, FriedrichMASS, ManfredSTEGEN, Helga
    • HERBERTS GESELLSCHAFT MIT BESCHRÄNKTER HAFTUNG
    • C08G18/62
    • C08J7/047C08G18/6283C08J7/04C08J2323/02C08J2475/00
    • The disclosure relates to a coating agent suitable in particular for use on plastic substrates and containing the following: A) 5-40 wt.% binder containing OH groups and including tertiary amino groups and/or substituted by a tertiary alkyl group; said binder being obtainable by conversion of one or more copolymers of one or more (meth)acrylic acid esters and/or (meth)acrylic amides with a tertiary amino group or an amino group substituted by a tertiary alkyl group, one or more hydroxyalkyl (meth)acrylates and one or more olefinically unsaturated compounds capable of being copolymerised and different from said hydroxyalkyl (meth)acrylates, the copolymers having a mean molecular weight (Mn) of 1500-10,000 and a glass transition temperature of between -20 and +75 DEG C, with polyisocyanates; B) 1-20 wt.% conversion products of the reaction between aromatic diglycidyl ethers and dimerised fatty acids as cross-linking agents; C) 0-30 wt.% one or more additional binders other than those of A); D) 30-70 wt.% organic solvents; E) 15-45 wt.% pigments and/or fillers; and F) 0-15 wt.% standard paint additives.
    • 对于特定的塑料基材的涂料合适的包衣剂,溶剂型,含有A)重量的OH基团的粘合剂5〜40,第三的%氨基团和/或具有由叔烷基取代的氨基基团,其由可获得 丙烯酸酯的反应的一种或一种或多种(甲基)丙烯酸酯多种共聚物和/或(甲基)含叔氨基或由取代的氨基具有叔烷基丙烯酰胺,一种或多种羟烷基(甲基)丙烯酸酯和 或其更多种不同的可共聚的烯属不饱和化合物,其共聚物的数均分子量(Mn)为1500至10,000和-20的玻璃化转变温度为75℃,与聚异氰酸酯,B)1至20重量%的反应产物 芳香族二缩水甘油基与二聚脂肪酸作为交联剂,C)0至30重量%醚蛋 网元或更多,从A)还粘合剂,D)30至不同的70重量%的一种或多种有机溶剂的%,E)15〜45重量%的颜料和/或填料和F)0至15重量% 习惯性技术涂料助剂。
    • 5. 发明申请
    • MULTI-COAT PAINTING PROCESS
    • 方法多层镀膜
    • WO1996038235A1
    • 1996-12-05
    • PCT/EP1996002234
    • 1996-05-24
    • HERBERTS GESELLSCHAFT MIT BESCHRÄNKTER HAFTUNGBLUM, JoachimSTRANGHÖNER, DieterENGEL, DieterKLEIN, KlausjörgKÜHHIRT, WalterKIMPEL, MatthiasSIEVER, Friedrich-Ludwig
    • HERBERTS GESELLSCHAFT MIT BESCHRÄNKTER HAFTUNG
    • B05D07/00
    • B05D7/576B05D7/577
    • A process for multi-coat painting in which a first coating of an electrophoretically separable aqueous coating (I) is electrophoretically applied to an electrically conductive substrate and then baked, whereupon further coatings are applied, where the coating agent (I) is such as to provide an electrically conductive coating when baked, whereupon, after the first coating has been baked an electrically insulating second coating of an electrophoretically separable aqueous coating agent (II) differing from (I) is electrophoretically separated and baked, whereupon as a third coating a basic paint coat of a coloured and/or effect-producing coating is applied and covered with a fourth transparent coat of a clear lacquer coating agent and baked together therewith, whereupon one or more further transparent topcoats are applied, in which the total dry coating thickness of the paint system is 90 to 130 mu m and the dry coating thickness of the transparent topcoat or coats is 40 to 80 mu m.
    • 一种用于生产多层面漆,其中电泳沉积一个导电基底上的过程中,电泳沉积的水性涂料介质(I),然后的第一涂层烘烤,随后进一步涂布层被施加,其中,存在被用作涂覆介质(I)是其中一个 导致在烘烤状态被覆层导电,随后从(I)烘焙第一涂层,不同的电绝缘第二涂层电泳沉积的水性涂料介质(II)电泳沉积和烘干,于是,作为第三涂层,的底涂层 被施加的颜色和/或赋予效果的涂料组合物,并用清漆涂料组合物的第四,透明涂层涂覆并与后者,WOR烘烤一起 被施加到任选的一种或多种另外的透明涂层,其特征在于,在90〜130微米的涂料体系的总干膜厚度与透明涂层或透明涂层40至80微米的干燥厚度。
    • 7. 发明申请
    • BINDER COMPOSITION, A COATING AGENT CONTAINING SAID BINDER COMPOSITION, ITS PRODUCTION AND USE
    • 粘合剂组合物含涂层剂,生产和使用
    • WO1995030719A1
    • 1995-11-16
    • PCT/EP1995001663
    • 1995-05-03
    • HERBERTS GESELLSCHAFT MIT BESCHRÄNKTER HAFTUNGDUECOFFRE, VolkerFLOSBACH, CarmenHERRMANN, FriedrichREIFFERSCHEIDT, Heinz-WalterSCHUBERT, Walter
    • HERBERTS GESELLSCHAFT MIT BESCHRÄNKTER HAFTUNG
    • C09D175/04
    • C09D167/00C08L63/00C08L75/04C09D133/062C09D133/068C09D163/00C09D175/04Y10T428/31551C08L2666/04C08L2666/14C08L33/00
    • Disclosed are: a binder composition, a coating agent based on the said binder composition, and the use of the composition, in particular for multiple-layer coatings. The binder composition contains the following components: (A) 25-75 wt. % reaction product of one or more carboxy-functionalised (meth)acrylic copolymers containing urethane groups, and/or one or more carboxy-functionalised polyesters containing urethane groups, each with an acid number of 30-200 mg KOH/g, with one or more lactones; (B) 25-75 wt. % one or more epoxy-functionalised cross-linking agents with at least two epoxy functions in the molecule, with a number average molecular weight (Mn) of 200 to 10,000 g/mole; (C) 0-60 wt. % one or more polyols with at least two hydroxyl functions in the molecule; (D1) 0-20 wt. % one or more melamine resins; (D2) 0-40 wt. % one or more free or capped polyisocyanates (the sum of the weight percentages of components A, B, C, D1 and D2 being 100); and (E) 0-10 wt. % (relative of the sum of the weights of components A-D2) one or more catalysts for catalysing the reaction of carboxyl- and epoxy groups.
    • 粘合剂组合物,制备涂料组合物从中和它们的用途,特别是用于多层涂层。 粘合剂组合物含有:A)25至75重量的一个或多个氨基甲酸酯基团的反应产物的%羧基官能化的(甲基)丙烯酸共聚物和/或一个或多个氨基甲酸酯基团的羧基官能聚酯,每一个都具有30至200mg KOH / g的酸值,与一种或 多种内酯,B)25至75重量%的一种或多种epoxidfunktionalisierter交联剂在分子中具有至少两个环氧官能团的数均分子量(Mn)为200至10,000克/摩尔,C)0至60重量的%的% 或在分子中具有至少两个羟基官能团,D1)多种多元醇0至20重量%的一种或多种的三聚氰胺树脂的%,D2)0〜40重量%的一种或多种游离或封端的多异氰酸酯的%,其中的部件的重量的总和的百分比 ),B),C)D1)和D2)加起来为100%(重量),以及e)0至10重量%的一种或多种催化剂的%用于催化羧基和Expoxidgrup的反应 笔,基于组分A的权重的总和)至D2)。
    • 9. 发明申请
    • POLYOL AND POLYISOCYANATE-BASED WATER-DILUTABLE COATING AGENT, PROCESS FOR PREPARING THE SAME AND ITS USE
    • 多元醇和多异氰酸酯基水稀释涂层剂,其制备方法及其用途
    • WO1994003512A1
    • 1994-02-17
    • PCT/EP1993002134
    • 1993-08-09
    • HERBERTS GESELLSCHAFT MIT BESCHRÄNKTER HAFTUNGPATZSCHKE, Hans-PeterSCHWAN, HeinrichGOL, Franjo
    • HERBERTS GESELLSCHAFT MIT BESCHRÄNKTER HAFTUNG
    • C08G18/08
    • C09D175/06C08G18/0819C08G18/10C08G18/4263C08G18/4288C08G18/6659C08G18/73C08G18/765C09D167/08C08G18/72C08L75/04
    • A water-dilutable coating agent, a process for preparing the same and its use are disclosed. The coating agent contains A) 40 to 95 % by weight of a film-forming, OH group-containing polyurethane resin or a mixture of such resins, available as an aqueous dispersion. The polyurethane resin or said mixture has in average a hydroxyl number from 25 to 250, a urethane group content from 2 to 20 % by weight, with respect to the solid resin, a numeric average of the molar mass (Mn) from 1 000 to 100 000 and, with respect to 100 g solid resin, a content of acid functionalities lower than 80 mEqu and/or a content of ethylene oxide units lower than 150 mEqu. When acid functionalities and ethylene oxide units are both present, the sum of acid functionalities and ethylene oxide units is comprised between 1 to 200 mEqu, and the acid functionalities are if required at least partially neutralised. The coating agent also contains B) 60 to 5 % by weight of one or several polyisocyanates with more than one free isocyanate group which are liquid at room temperature, if required by admixture of one or several organic solvents, the percentages by weight of (A) and (B) relating to the content of solid resin and adding up to 100 % by weight and C) if required one or several additional binders, usual pigments, fillers and/or lacquer-usual additives and auxiliary substances.
    • 阿可稀释涂布剂中的水,其制造工艺和其用途。 涂层剂含有A)40-95重量%的含OH的成膜聚氨酯树脂或水性分散体形式的这些树脂的混合物。 聚氨酯树脂或该混合物具有25和250之间的平均羟基数为2%至20%的氨基甲酸乙酯基团的含量以重量计的固体树脂,数均分子量(Mn)为 1000和100000且相对于100g固体树脂,酸官能含量小于80mEqu和/或乙氧基单元含量小于150mEqu。 如果酸官能团和乙基氧化物单元一起存在,则酸官能团和乙基氧化物单元的总和在1和200mEqu之间。 如果需要,酸官能团至少部分被中和。 该涂布装置还含有B)60-5重量%的一种或多种具有多于一个游离异氰酸酯基团的多异氰酸酯,其在室温下为液体,任选在加入一种或多种 有机溶剂,A)和B)各自涉及固体树脂含量和累积以形成100重量%的重量百分数,以及C),任选地一种或 几种粘合剂,常用颜料,填料和/或添加剂以及通常用于漆的辅助剂。