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1. 发明申请

WO2009038919A1 METHODS OF EXCHANGING ANIONS OF TETRAALKYLAMMONIUM SALTS 审中-公开
标题翻译：交换四氯铵盐的方法
公开(公告)号：WO2009038919A1
公开(公告)日：2009-03-26
申请号：PCT/US2008/073583
申请日：2008-08-19
申请人： ALBEMARLE CORPORATION , MANIMARAN, Thanikavelu , HARKINS, Alvin, E.
发明人： MANIMARAN, Thanikavelu , HARKINS, Alvin, E.
IPC分类号： C07C209/12 , C07C211/63
CPC分类号： C07C211/63
摘要： Methods are provided for producing tetra-C 1 -C 20 alkyl or aryl-substituted Alkyl quaternary ammonium carbonates and bicarbonates. In methods of this invention, at least a tetra-C- 1 -C 20 alkyl or aryl-substituted alkyl quaternary ammonium bromide, a metal hydroxide, and a suitable solvent are combined, said metal hydroxide being present in a stoichiometric excess as to the quaternary ammonium bromide
摘要翻译：提供了用于生产四-C 1 -C 20烷基或芳基取代的烷基季铵碳酸酯和碳酸氢盐的方法。在本发明的方法中，至少合成四-C 1 -C 20烷基或芳基取代的烷基季铵溴化物，金属氢氧化物和合适的溶剂，所述金属氢氧化物以相对于季铵化合物的过量存在溴化铵

2. 发明申请

WO2006105115A3 IMPROVED POLYMER HALOGENATION PROCESS WITH CATALYST RECOVERY 审中-公开
标题翻译：改进聚合物反应过程与催化剂恢复
公开(公告)号：WO2006105115A3
公开(公告)日：2007-03-29
申请号：PCT/US2006011332
申请日：2006-03-24
申请人： ALBEMARLE CORP , MANIMARAN THANIKAVELU , HARKINS ALVIN E JR
发明人： MANIMARAN THANIKAVELU , HARKINS ALVIN E JR
IPC分类号： B01J27/32 , C01G30/00 , C08F8/20 , C08F12/08
CPC分类号： B01J27/08 , B01J23/18 , B01J27/10 , B01J27/32 , C01G30/007 , C08F6/02 , C08F8/20 , C08F12/16 , C22B7/007 , Y02P10/234 , Y02P20/584 , C08F12/08 , C08L25/18
摘要： The present invention relates to a process for brominating a styrenic polymer in the presence of an antimony halide catalyst. The present invention relates further to a method for recovering antimony halide catalysts wherein the formation of insoluble solids is reduced.
摘要翻译：本发明涉及在卤化锑催化剂存在下溴化苯乙烯类聚合物的方法。本发明还涉及一种回收卤化锑催化剂的方法，其中不溶性固体的形成减少。

3. 发明申请

WO2007143519A1 SEPARATION AND/OR RECOVERY OF PROPYL BROMIDE 审中-公开
标题翻译：丙烯酰胺的分离和/或回收
公开(公告)号：WO2007143519A1
公开(公告)日：2007-12-13
申请号：PCT/US2007/070168
申请日：2007-06-01
申请人： ALBEMARLE CORPORATION , HARKINS, Alvin, E. , TORRES, James, E. , ANDERSON, Keith, G.
发明人： HARKINS, Alvin, E. , TORRES, James, E. , ANDERSON, Keith, G.
IPC分类号： C07C17/38
CPC分类号： C07C17/38 , C07C17/08 , C07C17/383 , C07C19/075
摘要： Described is a process for separating an organic phase comprising mainly propyl bromide from a crude reaction mixture formed by free-radical catalyzed hydrobromination of propylene with hydrogen bromide. The process comprises (A) feeding cold water into an upper or mid- portion of a packed column; (B) concurrently feeding the crude reaction mixture into an upper portion and/or mid-portion of the column so that the water contacts the crude reaction mixture; to form a mixture of (i) an acidic aqueous phase comprising aqueous hydrogen bromide and (ii) an organic phase comprising propyl bromide; (C) withdrawing the resultant phases from said column, at a rate comparable to the feeds being made into the column; and (D) separating the phases to form an upper acidic aqueous phase comprising aqueous hydrogen bromide superposed on a lower liquid organic phase comprising propyl bromide, and separating these upper and lower phases from each other.
摘要翻译：描述了从由丙烯与溴化氢的自由基催化氢溴酸形成的粗反应混合物中分离主要包含丙基溴的有机相的方法。该方法包括（A）将冷水送入填充塔的上部或中部; （B）同时将粗反应混合物进料到塔的上部和/或中间部分，使得水接触粗反应混合物; 以形成（i）包含溴化氢水溶液的酸性水相和（ii）包含丙基溴的有机相的混合物; （C）以与进料塔进料相当的速率从所述塔中取出所得相; 和（D）分离相以形成上层酸性水相，其包含叠加在包含丙基溴的下部液体有机相上的溴化氢水溶液，并将这些上部和下部相分离。

4. 发明申请

WO2007121228A2 PROCESS FOR PRODUCING N-PROPYL BROMIDE OR OTHER ALIPHATIC BROMIDES 审中-公开
标题翻译：生产N-丙基溴化物或其他脂肪族溴化物的方法
公开(公告)号：WO2007121228A2
公开(公告)日：2007-10-25
申请号：PCT/US2007/066409
申请日：2007-04-11
申请人： ALBEMARLE CORPORATION , TORRES, James, E. , HARKINS, Alvin, E., Jr. , MANIMARAN, Thanikavelu , MCKINNIE, B., Gary
发明人： TORRES, James, E. , HARKINS, Alvin, E., Jr. , MANIMARAN, Thanikavelu , MCKINNIE, B., Gary
CPC分类号： C07C17/08 , C07C19/075
摘要： A process for the production of an aliphatic bromide in which the bromine atom is attached to a terminal carbon atom, which process comprises continuously feeding olefin having a terminal double bond, gaseous hydrogen bromide, and a molecular oxygen-containing gas into a liquid phase reaction medium comprised of aliphatic bromide to cause anti-Markovnikov addition of HBr to terminal olefin, the feeds being proportioned and maintained to provide a molar excess of hydrogen bromide relative to terminal olefin in the range of about 1 to about 5 percent, and a molar ratio of molecular oxygen to terminal olefin of less than 0.005. The process is especially suited for production of n-propyl bromide.
摘要翻译：制备其中溴原子连接于末端碳原子的脂族溴化物的方法，该方法包括连续地供给具有末端双键的烯烃，气态溴化氢和分子氧将气体引入由脂肪族溴化物组成的液相反应介质中，使HBr与末端烯烃反马尔可夫尼克夫加成，将原料按比例配制并保持在相对于末端烯烃摩尔过量的溴化氢为约1〜约5％，并且分子氧与末端烯烃的摩尔比小于0.005。该工艺特别适用于生产正丙基溴。

5. 发明申请

WO2008027780A1 PREPARATION OF DECAHALODIPHENYL OXIDE 审中-公开
标题翻译：十氢化二氧化铅的制备
公开(公告)号：WO2008027780A1
公开(公告)日：2008-03-06
申请号：PCT/US2007/076608
申请日：2007-08-23
申请人： ALBEMARLE CORPORATION , HARKINS, Alvin, E. , BOONE, James, E.
发明人： HARKINS, Alvin, E. , BOONE, James, E.
IPC分类号： C07C41/22 , C07C43/29 , C08K5/06
CPC分类号： C08K5/06 , C07C41/22 , C07C43/29
摘要： This invention provides a process of preparing reaction-derived decahalodiphenyl oxide of high purity. The process comprises cofeeding separate feeds of (a) diphenyl oxide and/or partially brominated diphenyl oxide and (b) bromine chloride, bromine chloride and bromine, or bromine chloride and chlorine to a refluxing reaction mixture comprising bromine and at least one Lewis acid bromination catalyst so that high purity decahalodiphenyl oxide is formed.
摘要翻译：本发明提供了制备高纯度的反应衍生的十氢二苯醚的方法。该方法包括将（a）二苯基氧化物和/或部分溴化二苯醚和（b）溴氯化物，溴氯化物和溴或溴氯化物和氯的单独进料共进料到包含溴和至少一种路易斯酸溴化的回流反应混合物催化剂，从而形成高纯度的十氢二苯醚。

6. 发明申请

WO2007121228A3 PROCESS FOR PRODUCING N-PROPYL BROMIDE OR OTHER ALIPHATIC BROMIDES 审中-公开
标题翻译：生产N-丙基溴或其他脂肪酸的方法
公开(公告)号：WO2007121228A3
公开(公告)日：2007-12-21
申请号：PCT/US2007066409
申请日：2007-04-11
申请人： ALBEMARLE CORP , TORRES JAMES E , HARKINS ALVIN E JR , MANIMARAN THANIKAVELU , MCKINNIE B GARY
发明人： TORRES JAMES E , HARKINS ALVIN E JR , MANIMARAN THANIKAVELU , MCKINNIE B GARY
IPC分类号： C07C17/08
CPC分类号： C07C17/08 , C07C19/075
摘要： A process for the production of an aliphatic bromide in which the bromine atom is attached to a terminal carbon atom, which process comprises continuously feeding olefin having a terminal double bond, gaseous hydrogen bromide, and a molecular oxygen-containing gas into a liquid phase reaction medium comprised of aliphatic bromide to cause anti-Markovnikov addition of HBr to terminal olefin, the feeds being proportioned and maintained to provide a molar excess of hydrogen bromide relative to terminal olefin in the range of about 1 to about 5 percent, and a molar ratio of molecular oxygen to terminal olefin of less than 0.005. The process is especially suited for production of n-propyl bromide.
摘要翻译：一种生产其中溴原子连接到末端碳原子上的脂族溴化物的方法，该方法包括将具有末端双键的烯烃，气态溴化氢和含分子氧的气体连续进料到液相反应介质由脂肪族溴化物引起，使马可夫尼科夫将HBr加入到末端烯烃中，进料成比例并保持为相对于末端烯烃的摩尔过量的溴化氢在约1至约5％的范围内，摩尔比的分子氧与末端烯烃的摩尔比小于0.005。该方法特别适用于生产正丙基溴。

7. 发明申请

WO2007044270A1 PROCESS FOR PRODUCING HIGH PURITY KETONES BY FRIEDEL-CRAFTS ACYLATION AT LOW TEMPERATURE 审中-公开
标题翻译：在低温下通过FRIEDEL-CRAFTS进行生产高纯度酮的方法
公开(公告)号：WO2007044270A1
公开(公告)日：2007-04-19
申请号：PCT/US2006/038286
申请日：2006-10-02
申请人： ALBEMARLE CORPORATION , MANIMARAN, Thanikavelu , HARKINS, Alvin, E.
发明人： MANIMARAN, Thanikavelu , HARKINS, Alvin, E.
IPC分类号： C07C45/46 , C07C49/76
CPC分类号： C07C45/46 , C07C49/76
摘要： The present invention relates to improved conditions for the Friedel-Crafts acylation of alkylbenzenes and to application of these improved conditions to the synthesis of para-isobutyl acetophenone and ibuprofen. The reaction conditions include operating the reaction at a temperature below 0°C and typically below -10° C.
摘要翻译：本发明涉及对烷基苯的Friedel-Crafts酰化改进的条件以及这些改进的条件在对异丁基苯乙酮和布洛芬的合成中的应用。反应条件包括在低于0℃，通常低于-10℃的温度下进行反应。

8. 发明申请

WO2005068513A1 RECOVERY OF ANTIMONY CATALYST RESIDUES FROM BROMINATION REACTION MIXTURES 审中-公开
标题翻译：从反应混合物中回收反应性催化剂残留物
公开(公告)号：WO2005068513A1
公开(公告)日：2005-07-28
申请号：PCT/US2004/031598
申请日：2004-09-24
申请人： ALBEMARLE CORPORATION , MANIMARAN, Thanikavelu , HARKINS, Alvin, E., Jr. , DUBOIS, Samuel, H. , CALLENDER, Thomas, J.
发明人： MANIMARAN, Thanikavelu , HARKINS, Alvin, E., Jr. , DUBOIS, Samuel, H. , CALLENDER, Thomas, J.
IPC分类号： C08F8/20
CPC分类号： C08F6/02 , C08F8/20 , Y02P20/584 , C08L25/04 , C08L25/18 , C08F12/08
摘要： A process for brominating a styrenic polymer in an organic solvent in the presence of an antimony trihalide catalyst such that a reaction mass containing brominated styrenic polymer in an organic phase is formed is improved by mixing hydrochloric acid or hydrobromic acid, or both, with said reaction mass at least once to extract antimony catalyst residues from said reaction mass as an acidic aqueous phase. Preferably, catalyst residues are recovered from the acidic aqueous phase and still more preferably, recovered antimony trihalide catalyst residues are recycled to constitute at least a portion of the antimony trihalide catalyst used in preparing the brominated styrenic polymer.
摘要翻译：在三卤化锑催化剂的存在下，在有机溶剂中溴化苯乙烯类聚合物的方法，通过将盐酸或氢溴酸或二者混合，形成有机相中含有溴化苯乙烯类聚合物的反应物质，质量至少一次以从酸性水相从所述反应物料中提取锑催化剂残余物。优选地，从酸性水相中回收催化剂残余物，还更优选回收的三卤化锑催化剂残余物被再循环以构成用于制备溴化苯乙烯类聚合物的至少一部分三卤化锑催化剂。

9. 发明申请

WO2008027737A1 PREPARATION OF DECAHALODIPHENYL ETHANE 审中-公开
标题翻译：十氢二苯乙烯的制备
公开(公告)号：WO2008027737A1
公开(公告)日：2008-03-06
申请号：PCT/US2007/076166
申请日：2007-08-17
申请人： ALBEMARLE CORPORATION , HARKINS, Alvin, E., Jr. , BOONE, James, E.
发明人： HARKINS, Alvin, E., Jr. , BOONE, James, E.
IPC分类号： C07C17/12 , C09K21/08
CPC分类号： C09K21/08 , C07C17/12 , C07C25/18
摘要： This invention provides a process of preparing reaction-derived decahalodiphenylethane of high purity. The process comprises cofeeding separate feeds of (a) diphenylethane and (b) bromine chloride, bromine chloride and bromine, or bromine chloride and chlorine to a refluxing reaction mixture comprising bromine and at least one Lewis acid bromination catalyst so that high purity decahalodiphenylethane is formed.
摘要翻译：本发明提供了制备高纯度的反应衍生的十氢二苯基乙烷的方法。该方法包括将（a）二苯基乙烷和（b）溴氯化物，溴氯化物和溴或溴氯化物和氯的单独进料共进料到包含溴和至少一种路易斯酸溴化催化剂的回流反应混合物中，从而形成高纯度的十氢二苯基乙烷。

10. 发明申请

WO2006105115A2 IMPROVED POLYMER HALOGENATION PROCESS WITH CATALYST RECOVERY 审中-公开
标题翻译：改进聚合物反应过程与催化剂恢复
公开(公告)号：WO2006105115A2
公开(公告)日：2006-10-05
申请号：PCT/US2006/011332
申请日：2006-03-24
申请人： ALBEMARLE CORPORATION , MANIMARAN, Thanikavelu , HARKINS, Alvin, E., Jr.
发明人： MANIMARAN, Thanikavelu , HARKINS, Alvin, E., Jr.
CPC分类号： B01J27/08 , B01J23/18 , B01J27/10 , B01J27/32 , C01G30/007 , C08F6/02 , C08F8/20 , C08F12/16 , C22B7/007 , Y02P10/234 , Y02P20/584 , C08F12/08 , C08L25/18
摘要： The present invention relates to a method for recovering antimony catalysts wherein the formation of insoluble solids is reduced.
摘要翻译：本发明涉及回收锑催化剂的方法，其中不溶性固体的形成减少。

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