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    • 10. 发明申请
    • IN-LINE BLENDING OF PLASTICIZERS WITH A BASE POLYMER
    • 使用基础聚合物在线混合塑料
    • WO2009035579A1
    • 2009-03-19
    • PCT/US2008/010516
    • 2008-09-09
    • EXXONMOBIL RESEARCH AND ENGINEERING COMPANYKISS, GaborGALUSKA, Alan, A.
    • KISS, GaborGALUSKA, Alan, A.
    • C08F2/01
    • C08F10/00C08F210/16C08F2/001C08F2/01C08F210/14C08F2500/12C08F2500/08C08F2500/20
    • A process for in-line blending of plasticizers and polymers in a single reactor train including one or more serially configured reactors, a high-pressure separator downstream fluidly connected to the train, and one or more storage tanks, wherein the train produces one or more base polymer components and the one or more storage tanks store one or more off-line produced plasticizers; contacting in the reactor train olefin monomers, catalyst systems and optional comonomers, scavengers, diluents or solvents, at a temperature above the solid-fluid phase transition temperature of the polymerization system and a pressure no lower than 10 MPa below the cloud point pressure of the polymerization system and less than 1500 MPa, forming a reactor effluent including a homogeneous mixture; passing the reactor effluent through theseparator to separate a monomer-rich phase from a polymer-rich phase; and feeding the plasticizers to the process after the reactor train.
    • 在包括一个或多个串联构造的反应器,流体连接到列车的下游的高压分离器和一个或多个储存罐的单个反应堆列中将增塑剂和聚合物在线共混的方法,其中该列车产生一个或多个 基础聚合物组分和一个或多个储存罐存储一个或多个离线生产的增塑剂; 在高于聚合体系的固体 - 流体相转变温度的温度下,在反应器中与烯烃单体,催化剂体系和任选的共聚单体,清除剂,稀释剂或溶剂接触,并且压力低于低于聚合体系的浊点压力10MPa 聚合体系和小于1500MPa,形成包含均匀混合物的反应器流出物; 使反应器流出物通过分离器以将富含单体的相与富聚合物相分离; 并在反应器列车之后将增塑剂进料到该过程。