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    • 1. 发明申请
    • MULTI-SUBSTANCE MIXTURES BASED ON WATER-SOLUBLE ALKALI SILICATE COMPOUNDS AND THEIR USE
    • 更多的水为基础的含碱硅酸盐化合物及其用途
    • WO1995023841A1
    • 1995-09-08
    • PCT/EP1995000604
    • 1995-02-20
    • HENKEL KOMMANDITGESELLSCHAFT AUF AKTIENRÄHSE, WilfriedFUES, Johann, FriedrichPAATZ, KathleenBECK, WilhelmHLAVACEK, Wolfgang
    • HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
    • C11D03/08
    • C11D3/046C11D3/06C11D3/08C11D3/10C11D3/2075C11D3/3761C11D11/0082C11D11/02
    • The invention concerns a solid material (primary dry material) which contains alkali metal silicates in the modules range (SiO2: M2O molar ratio in which M= alkali metal) of 0.8 to 4 in a homogeneous mixture with other inorganic and/or organic valuable and/or auxiliary substances. This solid material has been dried, by means of a hot gas flow, from a finely sprayed aqueous preparation of mixtures of the alkali metal silicates and the inorganic and/or organic valuable and/or auxiliary substances. The solid material according to the invention is characterized in that, as a primary dry material in a homogeneous mixture with the alkali silicate, it has at least 10 wt % water-soluble inorganic and/or organic salts, apparent densities of at least 150 g/l and a microporous, absorbent inner material structure, and has been dried by means of superheated steam as the hot gas flow. The invention further relates, in particular, to builder systems for detergents and washing agents based on these multi-substance systems containing super-dried alkali silicate and their use for subsequent treatment with further, flowable, valuable substances and valuable substance mixtures from the field of detergents and washing agents, and to the detergents and washing agents produced thereby.
    • 本发明公开了所述模块区域的碱金属硅酸盐:0.8(摩尔比的SiO 2 :M 2 O,其中M =碱金属)至4与其它无机和/或有机有用的材料和/或固体材料(主要干基料)含有赋形剂-在均匀的混合物,由细碎 通过热气体流的装置中的碱金属硅酸盐和无机和/或有机的材料,并且/或助剂的混合物的喷涂水性制剂已经枯竭。 本发明的固体材料的特征在于它含有如在均匀的混合物的主干材料与碱金属硅酸盐是至少10重量的水溶性无机和/或有机盐%,至少150克/升的堆积密度有,除此之外,具有微孔的,吸收性Gutinnenstruktur和 干燥了由过热蒸汽的装置的热气体流。 本发明还涉及在用于洗涤和清洁基于含有多组分体系以及它们用于从洗涤剂和清洁剂领域的可流动的其它有用的材料和有用的材料的混合物的随后的应用中使用这些过干Alakalisilikat组合物和所产生的洗涤和清洁剂特别洗剂体系。
    • 3. 发明申请
    • SOLID USEFUL MATERIAL PREPARATIONS FOR THE MULTI-STAGE WASHING OF TEXTILES
    • 固定WERTSTOFF准备工作多级纺织WASH
    • WO1996014385A1
    • 1996-05-17
    • PCT/EP1995004163
    • 1995-10-24
    • HENKEL KOMMANDITGESELLSCHAFT AUF AKTIENRÄHSE, WilfriedFUES, Johann, FriedrichKOTTWITZ, BeatrixKOZMA, JozsefUPADEK, Horst
    • HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
    • C11D03/20
    • C11D17/0039C11D3/08C11D3/2082C11D3/2086
    • The invention concerns novel multi-component textile detergents in solid form which permit multi-stage washing of textiles even in only one wash. The main portion of the useful material mixture - surfactant compounds with a washing effect, alkalizing agents, builders which are soluble in the aqueous-alkali range and/or finely particulate and insoluble and which can bind with calcium and, if necessary, further conventional active and/or auxiliary components of textile detergents - is prepared to form a condensed, in particular granulated, mixing material with time-delayed solubility, at least in cold water. The invention is characterized in that at least one component which can also dissolve rapidly in cold water and is based on suitably soluble complexing agents for the polyvalent cations of the water hardness is provided additionally but separately, mixtures of these complexing agents with cold-soluble surfactant compounds in particular being present. When the components are jointly metered during the initial phase of the washing process the delayed dissolution of the main component is sufficient to ensure at least that the textile material is thoroughly wetted with the aqueous pre-liquor of the complexing agent. The invention further concerns a process for optimizing the washing and cleansing power of textile detergents in the area of alkali textile washing using the above-described multi-component textile detergent, and the use of the preparative forms of complexing agents for polyvalent metallic ions, which preparative forms can dissolve rapidly in cold water, in order to develop a multi-stage washing process and optimize the washing result on soiled textiles.
    • 描述了在固体形式的新的多组分衣物洗涤剂,使在单个周期内的多级洗涤衣物。 大多数有价值材料混合物的 - 洗涤剂表面活性剂,碱化剂,可溶于含水碱性范围和/或细分散的不溶助洗剂或助洗剂与能力钙结合和,如果需要的话,其它常规的有源和/或衣物洗涤剂的辅助组分 - 被压缩到特定造粒混合 与至少在冷水中的溶解度延迟处理。 它是本发明的教导的特征,除了 - 提供至少一种可迅速,甚至在冷水中部件对应的可溶性络合剂的水硬度的多价阳离子,在这种络合剂的特定混合物的基础上,溶解存在用冷的可溶性表面活性剂化合物 - 但作为一个单独的组件。 主要成分的溶液延迟是足够用于在洗涤过程中的初始阶段一般用量,以确保至少所述纺织材料的穿透润湿与络合剂的水溶液Vorflotte。 本发明的教导还描述了一种用于优化洗涤和清洁洗涤的功率用于使用上述多组分纺织洗涤剂,以及使用的多价金属离子的配位剂的快速冷水溶性的制剂形式的碱性洗涤纺织品的区域的方法,以形成的一个多级洗涤和优化 洗导致到脏织物。
    • 6. 发明申请
    • PROCESS FOR THE FACILITATED WASTE DISPOSAL OF WORKING SUBSTANCES BASED ON WATER-IN-OIL INVERT EMULSIONS
    • 方法有利于处理工作设备基于W / O反相乳液
    • WO1998018882A1
    • 1998-05-07
    • PCT/EP1997005798
    • 1997-10-21
    • HENKEL KOMMANDITGESELLSCHAFT AUF AKTIENMÜLLER, HeinzHEROLD, Claus-PeterFÖRSTER, ThomasVON TAPAVICZA, StephanFUES, Johann-Friedrich
    • HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
    • C09K07/06
    • C09K3/00C09K8/28C09K8/36
    • The invention concerns a process for the facilitated waste disposal of flowable and pumpable working substances based on water-in-oil invert emulsions containing emulsifiers - in particular corresponding auxiliary agents from the field of exploratory boring of the earth, such as oil-based water-in-oil invert bore-flushing substances - and for the facilitated cleaning of solids surfaces contaminated therewith, optionally also using flowable rinsing aids. The process is characterized in that, by selecting and adapting the emulsifier/emulsifier systems to the oil phase of the invert emulsion, temperature-controlled phase inversion is ensured by solidification in the temperature range below the operating temperatures of the water-in-oil invert emulsions, but above the solidification temperature of the aqueous phase, and waste disposal or cleaning is carried out in the temperature range of the phase inversion and/or at temperatures lying therebelow. The invention further concerns the application of this process for the cleaning and waste disposal of the cuttings charged with residual amounts of boring mud from boring of the ground during and/or preferably before it is disposed of on-shore or off-shore.
    • 本发明的主题是用于促进处置含基的乳化剂W / O反相乳液的可流动和可泵送的工作材料的方法 - 从地质勘探领域更特别地对应助剂,如油基的w / o反相钻井泥浆 - 和用于简化清洁所以 弄脏的固体表面,可流动的,如果需要的话同时使用漂洗助剂,所述方法的特征在于,通过选择和乳化剂/乳化剂体系的反相乳液的油相中的匹配具有的温度范围内的W / O反相乳液的操作温度以下的温度控制的倒相, 但是,水相的凝固上述确保通过冷冻和使在温度范围内的相转化和/或温度低于的处置或清洁。 本发明还涉及使用这种方法的用于载货的纯化和处理与来自土壤Erbohrung和/或,优选地,钻井泥浆屑(切屑)的残余馏分,之前它的岸上或离岸倾倒。
    • 8. 发明申请
    • LONG-SHELF-LIFE FIXED HYDROGEN PEROXIDE-CONTAINING MULTI-SUBSTANCE MIXTURES IN SOLID FORM, PROCESS FOR THEIR PRODUCTION AND THEIR USE
    • 储存稳定的固定含氢更含有固体形式,其制造方法相同,它们的用途
    • WO1995025065A1
    • 1995-09-21
    • PCT/EP1995000820
    • 1995-03-06
    • HENKEL KOMMANDITGESELLSCHAFT AUF AKTIENRÄHSE, WilfriedFUES, Johann, FriedrichPAATZ, KathleenUPADEK, Horst
    • HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
    • C01B15/10
    • C11D3/3942C01B15/00C01B15/10
    • The invention describes a water-soluble multi-substance compound as a solid mixture which can in particular be used as a bleaching and/or disinfecting agent, containing absorbed and/or bonded hydrogen peroxide and possibly per compounds formed in situ through its action, included in a mixture of (K1) solid alkaline silicates of the modular range (mol ratio SiO2:M2O, where M = alkaline metal) from 0.8 to 10 and (K2) at least one other solid component from the class of water-soluble inorganic and/or organic salts which can in particular bond H2O and/or H2O2. The invention is characterised in that, in the multi-substance compound, the proportion (K1) is at least 5 wt % and that (K2) is at least 10 wt % - in relation to the sum (K1) + (K2) - where (K1) and (K2) are present in a microdispersed homogenous mixture through drying from a common aqueous preparation, and the H2O2 is included in the multi-substance compound during said drying and/or subsequently. The invention also relates to corresponding multi-functional multi-substance compounds in solid form for use in washing and/or cleaning agents, the process for producing the multi-substance compounds and their use in washing and cleaning agents.
    • 本发明描述了一种水溶性的多组分化合物,为固体混合物,其可特别用作漂白和/或消毒剂含有吸附和/或结合的过氧化氢,和任选在原位形成每化合物的作用下,包含在共混物(K1) 模块面积的固体碱金属硅酸盐(摩尔比的SiO 2 :M 2 O,其中M =碱金属)为0.8至10,和(K2)从类的在特定的水溶性无机和/或有机盐为H 2 O的H 2 O 2的结合和/或至少一种其它固体组分 能。 本发明的教导的特征在于,(K1)至少5重量%和播放(K2)的量在于在至少10的多燃料化合物重量%的比例 - 重量%的总和(K1)+ (K2) - ,另外,(K1)和(K2)的存在通过从微分散-均匀混合物的一般的水性制剂干燥生产的,并且该H 2 O 2在此干燥随后进入向上和/或在多燃料化合物。 本发明是在固体形式用于洗涤剂和/或清洁剂,在制造多组分化合物和它们在洗涤剂中的使用和清洁剂的方法中的其它合适的多官能多组分化合物。
    • 9. 发明申请
    • SILICATE BUILDERS AND THEIR USE IN DETERGENTS AND WASHING AGENTS, AND MULTI-SUBSTANCE MIXTURES FOR USE IN THIS FIELD
    • 硅质建设者和它们在洗涤剂和清洗剂而愈包含使用在这一领域
    • WO1995023763A1
    • 1995-09-08
    • PCT/EP1995000605
    • 1995-02-20
    • HENKEL KOMMANDITGESELLSCHAFT AUF AKTIENRÄHSE, WilfriedFUES, Johann, FriedrichPAATZ, KathleenSTEIN, NorbertBAUER, VolkerKOTTWITZ, BeatrixJACOBS, JochenPOETHKOW, Jörg
    • HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
    • C01B33/32
    • C11D11/02B01D1/18C01B33/325C11D3/08
    • The subject matter of the invention is alkali metal silicates in the modulus range (SiO2 to M2O molar ratio in which M = alkali metal) of 1 to 4 as a solid material which has been dried, by means of a hot gas flow, from an aqueous alkali metal silicate preparation sprayed in droplet form (primary dry material) but which can also be comminuted and/or compacted by the simultaneous and/or subsequent effect of mechanical force (secondary dry material). The teaching of the invention is characterized in that the primary dry material has apparent densities of less than 150 g/l and is produced by means of superheated steam as the hot gas flow. This primary dry material can be broken up and/or compacted in particular into the form of flakes (secondary dry material). The primary dry material and thus also the material which has possibly been comminuted or compacted is preferably in the form of superdried material having maximum water contents of approximately 15 wt %. The subject matter of the invention is further multi-substance mixtures, in particular from the field of detergents and washing agents, characterized in that they contain these superdried alkali metal silicates. Finally, the subject matter of the invention is the use of X-ray amorphous superdried alkali metal silicates as multi-purpose mixing components having a builder effect and a high absorption capacity for flowable auxiliary and valuable substances in mixtures in the field of solid detergents and washing agents.
    • 本发明涉及的模块面积的碱金属硅酸盐(摩尔比的SiO 2 :M 2 O,其中M =碱金属)为1〜4作为已经从以液滴喷洒干燥了的固体材料形成由热气体流(初次干燥)的装置中的碱金属硅酸盐的水性制剂,还通过同时 可压碎的和机械力和/或压实的(次级干基料)/或后续的动作。 本发明的教导的特征在于,具有低于150克/升的堆积密度的初级干燥材料并通过过热蒸汽的手段已经被制备为热气流。 该初级干燥材料可以特别破碎碎片以形成和/或压实(二次干基料)。 初级干燥材料并因此也任选粉碎或压缩材料优选作为具有至多约15重量%的水含量过干的材料。 本发明进一步的多组分混合物,特别是从洗涤剂和清洁产品,其特征在于这样的内容的领域过干燥的碱金属硅酸盐。 最后,本发明是利用X射线无定形过干的碱金属硅酸盐的作为具有助洗剂作用,在固体洗涤剂和清洁剂的面积的混合物高吸收能力用于可流动助剂和有用的材料的多官能混合物组分。