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1. 发明申请

WO1995025065A1 LONG-SHELF-LIFE FIXED HYDROGEN PEROXIDE-CONTAINING MULTI-SUBSTANCE MIXTURES IN SOLID FORM, PROCESS FOR THEIR PRODUCTION AND THEIR USE 审中-公开
标题翻译：储存稳定的固定含氢更含有固体形式，其制造方法相同，它们的用途
公开(公告)号：WO1995025065A1
公开(公告)日：1995-09-21
申请号：PCT/EP1995000820
申请日：1995-03-06
申请人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN , RÄHSE, Wilfried , FUES, Johann, Friedrich , PAATZ, Kathleen , UPADEK, Horst
发明人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
IPC分类号： C01B15/10
CPC分类号： C11D3/3942 , C01B15/00 , C01B15/10
摘要： The invention describes a water-soluble multi-substance compound as a solid mixture which can in particular be used as a bleaching and/or disinfecting agent, containing absorbed and/or bonded hydrogen peroxide and possibly per compounds formed in situ through its action, included in a mixture of (K1) solid alkaline silicates of the modular range (mol ratio SiO2:M2O, where M = alkaline metal) from 0.8 to 10 and (K2) at least one other solid component from the class of water-soluble inorganic and/or organic salts which can in particular bond H2O and/or H2O2. The invention is characterised in that, in the multi-substance compound, the proportion (K1) is at least 5 wt % and that (K2) is at least 10 wt % - in relation to the sum (K1) + (K2) - where (K1) and (K2) are present in a microdispersed homogenous mixture through drying from a common aqueous preparation, and the H2O2 is included in the multi-substance compound during said drying and/or subsequently. The invention also relates to corresponding multi-functional multi-substance compounds in solid form for use in washing and/or cleaning agents, the process for producing the multi-substance compounds and their use in washing and cleaning agents.
摘要翻译：本发明描述了一种水溶性的多组分化合物，为固体混合物，其可特别用作漂白和/或消毒剂含有吸附和/或结合的过氧化氢，和任选在原位形成每化合物的作用下，包含在共混物（K1）模块面积的固体碱金属硅酸盐（摩尔比的SiO 2 :M 2 O，其中M =碱金属）为0.8至10，和（K2）从类的在特定的水溶性无机和/或有机盐为H 2 O的H 2 O 2的结合和/或至少一种其它固体组分能。本发明的教导的特征在于，（K1）至少5重量％和播放（K2）的量在于在至少10的多燃料化合物重量％的比例 - 重量％的总和（K1）+ （K2） - ，另外，（K1）和（K2）的存在通过从微分散-均匀混合物的一般的水性制剂干燥生产的，并且该H 2 O 2在此干燥随后进入向上和/或在多燃料化合物。本发明是在固体形式用于洗涤剂和/或清洁剂，在制造多组分化合物和它们在洗涤剂中的使用和清洁剂的方法中的其它合适的多官能多组分化合物。

2. 发明申请

WO1994029419A1 DETERGENTS CONTAINING AMINO ACIDS AND/OR THEIR SALTS 审中-公开
标题翻译：洗涤含有氨基和/或其盐
公开(公告)号：WO1994029419A1
公开(公告)日：1994-12-22
申请号：PCT/EP1994001828
申请日：1994-06-06
申请人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN , KOTTWITZ, Beatrix , DOLHAINE, Hans , UPADEK, Horst
发明人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
IPC分类号： C11D03/33
CPC分类号： C11D3/33 , C11D3/1273 , C11D3/128
摘要： Detergents containing amino acids and/or their salts in place of alkali metal carbonates have an improved secondary detergency with no loss in primary detergency.
摘要翻译：无损失发生在初次去污含有碱金属碳酸盐，而不是氨基酸和/或其盐的洗涤剂，具有改进的循环的洗涤性能。

3. 发明申请

WO1994024258A1 ENZYMATIC WASHING AGENT 审中-公开
标题翻译：加酶洗涤剂
公开(公告)号：WO1994024258A1
公开(公告)日：1994-10-27
申请号：PCT/EP1994001049
申请日：1994-04-05
申请人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN , ANDEXER, Heidi , UPADEK, Horst
发明人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
IPC分类号： C11D03/386
CPC分类号： C11D3/38627 , C11D3/38645 , C11D3/38672
摘要： The aim of the invention is to provide a washing agent which is based on enzymes alone and avoids, as far as possible, other usual washing-agent components, and which has a washing power at least equal to that of ordinary washing agents with an optimized composition. The enzymatic washing agent according to the invention contains protease, lipase, amylase and cellulase plus, optionally, small quantities of surfactants and/or builders. Washing agents with this kind of composition can be used as stand-alone washing agents or as washing auxiliaries in addition to ordinary washing agents.

4. 发明申请

WO1992011347A2 ENZYME PREPARATION FOR WASHING AND CLEANSING AGENTS 审中-公开
标题翻译：洗涤剂和清洁剂的酶制剂
公开(公告)号：WO1992011347A2
公开(公告)日：1992-07-09
申请号：PCT/EP1991002340
申请日：1991-12-06
申请人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN , PAWELCZYK, Hubert , RÄHSE, Wilfried , CARDUCK, Franz-Josef , KÜHNE, Norbert , RUNGE, Volker , UPADEK, Horst
发明人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
IPC分类号： C11D03/386
CPC分类号： C11D3/222 , C11D3/382 , C11D3/38672
摘要： In the production of enzyme granulates with grain sizes from 0.1 to 2 mm, containing 2 to 20 % wt. proteases, lipases, amylases and/or cellulases, 10 to 50 % wt. swellable starch, 5 to 50 % wt. granulating agent, 3 to 12 % wt. water and not more than 10 % wt. water-soluble salt, by extruding an enzyme pre-mixture obtained by mixing a fermentation liquor cleared of insoluble components and concentrated with additives and spheroidizing the extrudate in a rounder, the use of relatively highly concentrated fermentation liquours has previously been necessary. By removing the insoluble components from the fermentation liquor by micro-filtration and mixing with additives which, in relation to the finished granulate, contains 10 to 35 % wt. cereal flour, it is possible, by the use of low-concentration fermentation liquors, to obtain highly active enzyme granulates with a long shelf life which are suitable for inclusion in washing and cleansing agents and are distinguished by uniform solubility properties in aqueous washing and cleansing baths.

5. 发明申请

WO1992007928A1 BUILDER FOR DETERGENTS 审中-公开
标题翻译：建筑物用于检测
公开(公告)号：WO1992007928A1
公开(公告)日：1992-05-14
申请号：PCT/EP1991001976
申请日：1991-10-17
申请人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN , POETHKOW, Jörg , UPADEK, Horst , SMULDERS, Eduard
发明人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
IPC分类号： C11D03/12
CPC分类号： C11D3/3757 , C11D3/1273 , C11D3/128
摘要： Phosphate-free combinations of builders which contain zeolite, crystalline layer silicates of the formula (I): NaMsixO2x+1.yH2O, in which M is sodium or hydrogen, x is a number from 1.9 to 4 and y is a number from 0 to 20, and polymeric polycarboxylates can be used separately as water softeners or in washing and cleaning agents. Their primary and secondary washing properties are so good that it is possible largely or completely to eliminate the use of phosphonates.

6. 发明申请

WO1997025399A1 WASHING AGENTS WITH SPECIFIC OXIDIZED OLIGOSACCHARIDES 审中-公开
标题翻译： WASH特别氧化低聚糖
公开(公告)号：WO1997025399A1
公开(公告)日：1997-07-17
申请号：PCT/EP1996005713
申请日：1996-12-19
申请人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN , KOTTWITZ, Beatrix , POETHKOW, Jörg , UPADEK, Horst
发明人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
IPC分类号： C11D03/22
CPC分类号： C11D3/0036 , C11D3/223
摘要： The most effective substances are continually being sought for use as so-called biologically degradable builder substances, which refer to naturally occurring materials or minimally altered derivatives thereof, for which one assumes that they exhibit a better degradability than do synthetic polymers of unsaturated mono-and dicarboxylic acids. It was found that an oligosaccharide, which has a -COOH group at its original reducing end instead of the -CH(OH)-CHO group, could more advantageously be used as a builder or co-builder component.
摘要翻译：可以通过在使用所谓的可生物降解的助洗剂，这些天然化合物天然存在的物质或尽可能低改性的衍生物，被认为具有比不饱和单和二羧酸的合成聚合物更好的降解性，但它仍然寻找可能当中理解活性物质。已经发现，一个可以有利地采用在作为具有-COOH基团其原来还原性末端基团，而不是-CH（OH）-CHO的助洗剂或Cobuilderkomponente寡糖。

7. 发明申请

WO1997020905A1 WASHING AGENT COMPRISING A CARBONATE-CONTAINING BUILDER SYSTEM AND/OR PERCARBONATE-CONTAINING BLEACH 审中-公开
标题翻译：洗具碳酸盐BUILDER系统和/或PERCARBONATHALTIGEM BLEACH
公开(公告)号：WO1997020905A1
公开(公告)日：1997-06-12
申请号：PCT/EP1996005263
申请日：1996-11-28
申请人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN , KOTTWITZ, Beatrix , POETHKOW, Jörg , UPADEK, Horst
发明人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
IPC分类号： C11D03/22
CPC分类号： C11D3/3942 , C11D3/10 , C11D3/222 , C11D3/223
摘要： The object of so-called co-builders is to prevent the re-deposition of dirt released from fibres or generally from a surface to be cleaned and the formation of insoluble compounds produced by the reaction between cations and anions which form water hardness in each case on the cleaned textile or surface. Optionally oxidized dextrins are highly suitable for achieving this object, in particular in the presence of alkali carbonate and/or alkali percarbonate.
摘要翻译：以防止通常脱离的再沉积从光纤，或从待清洁表面的污物以及由水硬度形成阳离子的与水硬度形成阴离子的清洗织物或表面上形成不溶性化合物的反应是所谓的共助洗剂的对象。特别是，在碱金属碳酸盐和/或碱金属过碳酸盐的存在下氧化糊精任选地非常适合用于解决该问题。

8. 发明申请

WO1996014385A1 SOLID USEFUL MATERIAL PREPARATIONS FOR THE MULTI-STAGE WASHING OF TEXTILES 审中-公开
标题翻译：固定WERTSTOFF准备工作多级纺织WASH
公开(公告)号：WO1996014385A1
公开(公告)日：1996-05-17
申请号：PCT/EP1995004163
申请日：1995-10-24
申请人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN , RÄHSE, Wilfried , FUES, Johann, Friedrich , KOTTWITZ, Beatrix , KOZMA, Jozsef , UPADEK, Horst
发明人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
IPC分类号： C11D03/20
CPC分类号： C11D17/0039 , C11D3/08 , C11D3/2082 , C11D3/2086
摘要： The invention concerns novel multi-component textile detergents in solid form which permit multi-stage washing of textiles even in only one wash. The main portion of the useful material mixture - surfactant compounds with a washing effect, alkalizing agents, builders which are soluble in the aqueous-alkali range and/or finely particulate and insoluble and which can bind with calcium and, if necessary, further conventional active and/or auxiliary components of textile detergents - is prepared to form a condensed, in particular granulated, mixing material with time-delayed solubility, at least in cold water. The invention is characterized in that at least one component which can also dissolve rapidly in cold water and is based on suitably soluble complexing agents for the polyvalent cations of the water hardness is provided additionally but separately, mixtures of these complexing agents with cold-soluble surfactant compounds in particular being present. When the components are jointly metered during the initial phase of the washing process the delayed dissolution of the main component is sufficient to ensure at least that the textile material is thoroughly wetted with the aqueous pre-liquor of the complexing agent. The invention further concerns a process for optimizing the washing and cleansing power of textile detergents in the area of alkali textile washing using the above-described multi-component textile detergent, and the use of the preparative forms of complexing agents for polyvalent metallic ions, which preparative forms can dissolve rapidly in cold water, in order to develop a multi-stage washing process and optimize the washing result on soiled textiles.
摘要翻译：描述了在固体形式的新的多组分衣物洗涤剂，使在单个周期内的多级洗涤衣物。大多数有价值材料混合物的 - 洗涤剂表面活性剂，碱化剂，可溶于含水碱性范围和/或细分散的不溶助洗剂或助洗剂与能力钙结合和，如果需要的话，其它常规的有源和/或衣物洗涤剂的辅助组分 - 被压缩到特定造粒混合与至少在冷水中的溶解度延迟处理。它是本发明的教导的特征，除了 - 提供至少一种可迅速，甚至在冷水中部件对应的可溶性络合剂的水硬度的多价阳离子，在这种络合剂的特定混合物的基础上，溶解存在用冷的可溶性表面活性剂化合物 - 但作为一个单独的组件。主要成分的溶液延迟是足够用于在洗涤过程中的初始阶段一般用量，以确保至少所述纺织材料的穿透润湿与络合剂的水溶液Vorflotte。本发明的教导还描述了一种用于优化洗涤和清洁洗涤的功率用于使用上述多组分纺织洗涤剂，以及使用的多价金属离子的配位剂的快速冷水溶性的制剂形式的碱性洗涤纺织品的区域的方法，以形成的一个多级洗涤和优化洗导致到脏织物。

9. 发明申请

WO9518766A3 SILICATE BUILDERS AND THEIR USE IN WASHING OR CLEANING AGENTS AND MULTI-SUBSTANCE MIXTURES FOR USE IN THIS FIELD 审中-公开
标题翻译：硅酸盐建筑物及其在洗涤或清洁剂中的用途和用于本领域的多种物质混合物
公开(公告)号：WO9518766A3
公开(公告)日：1995-07-27
申请号：PCT/EP9404322
申请日：1994-12-27
申请人： HENKEL KGAA , BREUER WOLFGANG , BAUER VOLKER , POETHKOW JOERG , KOTTWITZ BEATRIX , JACOBS JOCHEN , DOLHAINE HANS , SEITER WOLFGANG , STEVERMANN BIRGIT , UPADEK HORST
发明人： BREUER WOLFGANG , BAUER VOLKER , POETHKOW JOERG , KOTTWITZ BEATRIX , JACOBS JOCHEN , DOLHAINE HANS , SEITER WOLFGANG , STEVERMANN BIRGIT , UPADEK HORST
IPC分类号： C01B33/32 , C11D1/83 , C11D3/08
CPC分类号： C11D3/08 , C01B33/325
摘要： The description relates to sodium silicates in the modular range (mole ratio SiO2/NaO2) from 1.3 to 4 in the form of a finely divided solid in fragmented structure or compounds containing these silicates, with the property of reducing incrustation when used as builders in washing or cleaning agents. The features of these agents are that they are X-ray-amorphous overdried (primary drying) products with water contents below 15 wt % and apparent densities of the uncompressed solid of 500g/1 or less, which are produced by drying an aqueous sodium silicate preparation using a hot gas phase as the drying agent and/or by baking spray-dried sodium silicate with water contents of at least 15 wt % at temperature from 120 to 450°C, with the simultaneous or subsequent application of force to form the fragmented structure, if necessary. The invention also relates to multi-substance mixtures in the field of solid washing or cleaning agents or multi-substance compounds for this application, characterised by the use of the sodium silicates defined above.

10. 发明申请

WO1995018766A2 SILICATE BUILDERS AND THEIR USE IN WASHING OR CLEANING AGENTS AND MULTI-SUBSTANCE MIXTURES FOR USE IN THIS FIELD 审中-公开
标题翻译：硅质建设者和它们在洗涤剂和清洗剂而愈包含使用在这一领域
公开(公告)号：WO1995018766A2
公开(公告)日：1995-07-13
申请号：PCT/EP1994004322
申请日：1994-12-27
申请人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN , BREUER, Wolfgang , BAUER, Volker , POETHKOW, Jörg , KOTTWITZ, Beatrix , JACOBS, Jochen , DOLHAINE, Hans , SEITER, Wolfgang , STEVERMANN, Birgit , UPADEK, Horst
发明人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
IPC分类号： C01B33/32
CPC分类号： C11D3/08 , C01B33/325
摘要： The description relates to sodium silicates in the modular range (mole ratio SiO2/NaO2) from 1.3 to 4 in the form of a finely divided solid in fragmented structure or compounds containing these silicates, with the property of reducing incrustation when used as builders in washing or cleaning agents. The features of these agents are that they are X-ray-amorphous overdried (primary drying) products with water contents below 15 wt % and apparent densities of the uncompressed solid of 500g/1 or less, which are produced by drying an aqueous sodium silicate preparation using a hot gas phase as the drying agent and/or by baking spray-dried sodium silicate with water contents of at least 15 wt % at temperature from 120 to 450 DEG C, with the simultaneous or subsequent application of force to form the fragmented structure, if necessary. The invention also relates to multi-substance mixtures in the field of solid washing or cleaning agents or multi-substance compounds for this application, characterised by the use of the sodium silicates defined above.
摘要翻译：描述的是1.3模块面积（摩尔比的SiO 2 /的Na 2 O）的硅酸钠至4中的形式，如洗涤剂或清洁剂助洗剂组分时细碎在碎片或含有这些硅酸盐，以及减少积垢的能力的化合物的固体，这些有价值的物质的特征在于它们作为X射线无定形过干良好（初次干燥）等于或与使用热气体相在低于15重量％的范围内的水含量，和非压实固体材料低于500克/升，通过含水硅酸钠制备的干燥而得到的堆积密度已被确立为干燥介质和/或通过在温度为120至450℃，加热的喷雾干燥的硅酸钠具有至少15重量％的水含量，如果必要与用于形成片状结构的力同时或随后应用。本发明还包括从固体洗涤剂或清洁剂，分别为这方面的合适的多组分化合物，其特征在于同时使用前面定义的硅酸钠的应用的领域的多组分混合物。

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