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    • 4. 发明申请
    • IMPROVEMENTS IN AND RELATING TO PACKAGING
    • 与包装有关的改进
    • WO1989008557A1
    • 1989-09-21
    • PCT/GB1989000243
    • 1989-03-10
    • MB GROUP PLCADAMS, John, Francis, EdwardCOCHRAN, Michael, AlexanderFOLLAND, RickworthNICHOLAS, James, WilliamROBINSON, Melvin, Edward, Riddell
    • MB GROUP PLC
    • B32B27/18
    • B32B27/08B32B7/02B32B7/12B32B15/085B32B15/09B32B15/20B32B27/18B32B27/32B32B27/36B32B2307/7244B32B2367/00B32B2439/70B65D81/267C08K5/005C08K5/098C08L23/06C08L23/10C08L23/12C08L27/08C08L51/06C08L67/00C08L67/02C08L75/04C08L79/04Y10T428/1359Y10T428/1379Y10T428/26Y10T428/31797C08L2666/14C08L2666/20C08L77/00
    • The present invention provides a wall for a package comprising: (a) an outer set of one or more layers (1-4) and (b) an inner set of one or more layers (5-6) which layer or the outermost of which layers (5) comprises a composition comprising a polymer and having oxygen-scavenging properties, wherein (i) the outer set of layers would have, if separate from the inner set and in the absence of any oxygen-scavenging properties in any of the layers or the layer constituting the set, a permeance, for oxygen, of not more than 1.5 cm3/(m2 atm day); (ii) the inner set of layers would have, if separate from the outer set and in the absence of oxygen-scavenging properties in any of the layers or the layer constituting the set, a permeance, for oxygen, of at least 2.0 cm3/(m2 atm day); and (iii) the inner set of layers would have, if separate from the outer set, a permeance, for oxygen, less than the permeance specified in (ii) by at least 1.0 cm3/(m2 atm day) by virtue of oxygen-scavenging in at least the layer specified in (b). In a preferred combination one of the outer layers (3) is of metal and the composition in the outermost of the inner layers (5) scavenges oxygen through the metal-catalysed oxidation of an oxidisable organic component thereof. The wall is suitable for packaging uses, with the inner set of layers disposed towards the product, where headspace scavenging is especially desired.
    • 包装壁包括(a)一个或多个层(1-4)的外层系列和(b)一个或多个层(5-6)的内层系列,单层或顶层(5) 含有包含聚合物并能够吸收氧的化合物。 在上述包装中,(i)外层系列层与内层系列分离时,构成该系列的层不具有吸氧性,具有渗透性 对于氧气,不超过1.5立方厘米/(平方米每天); (ii)当内层系列层与外层分离并且构成该系列的层中没有一层具有吸氧性质时,内层系列对于氧气具有渗透性 至少2.0厘米3 /(平方米/天); 和(iii)当内层系列与外层系列分离时,对氧气的渗透性小于(i)中规定的渗透性不小于1.0立方厘米/(平方米/平方米) 由于(b)中规定的层至少吸收了氧气。 在优选的组合中,外层(3)中的一个是金属,而内层(5)的上层中的化合物通过其可氧化有机化合物之一的金属催化氧化来吸收氧 。 上述壁适于包装在特别希望在储存器自由空间中具有吸收效果的地方,内层系列层布置在产品侧。
    • 5. 发明申请
    • METHODS AND APPARATUS FOR FORMING TUBULAR CLOSED-ENDED ARTICLES OF THERMOFORMABLE POLYMER MATERIAL
    • 形成热塑性聚合物材料的管状封闭文章的方法和装置
    • WO1984003657A1
    • 1984-09-27
    • PCT/GB1984000078
    • 1984-03-13
    • METAL BOX P.L.C.DICK, David, AllanFOLLAND, RickworthSMITH, Desmond, PeterSTAINES, Glyn
    • METAL BOX P.L.C.
    • B29C17/03
    • B29C51/08B29C51/426Y10S264/901
    • A tubular article with a closed end is formed from a thermoformable polymer material, e.g. a high molecular weight saturated linear polyester such as polyethylene terephthalate, by forcing a punch (21) through the plane of a pre-heated and clamped sheet (13) of the polymer, centrally within an annular die (10) so as to draw the sheet into tubular form without exerting compressive stresses on the sheet between the punch and die, the punch being maintained at a temperature below the glass transition temperature of the polymer, e.g. by passing cooling fluid through internal passages (16), and being moved at a speed of at least 1/2 metre per second to effect the drawing. The punch head (21) may be convex or concave to produce a shaped closed end on the article, e.g. for making a pressure-resistant container, and the punch may co-operate with a shaped movable anvil (201) at the end or at an intermediate point in its stroke. Replaceable annular spacers (24) can be used to adjust the point in the punch stroke at which it co-operates with the anvil.
    • 具有封闭端的管状制品由可热成型的聚合物材料形成,例如, 高分子量饱和线性聚酯如聚对苯二甲酸乙二醇酯,通过迫使冲头(21)穿过聚合物的预加热和夹紧的片材(13)的平面,居中在环形模具(10)内,以便拉伸 片材变成管状,而不会在冲头和模具之间的片材上施加压应力,冲头保持在低于聚合物的玻璃化转变温度的温度,例如 通过冷却流体通过内部通道(16),并以每秒至少1/2米的速度移动以实现拉伸。 打孔头(21)可以是凸形或凹形的,以在制品上产生成形的封闭端,例如。 用于制造耐压容器,并且冲头可以在其行程的末端或中间点处与成形的活动砧座(201)配合。 可更换的环形间隔件(24)可用于调节冲头冲程中与砧座配合的点。