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    • 2. 发明申请
    • METHOD OF GROWING GROUP III NITRIDE CRYSTALS
    • 生长III族氮化物晶体的方法
    • WO2006039065A2
    • 2006-04-13
    • PCT/US2005031621
    • 2005-09-01
    • REPRESENTED BY THE SECRETARY OFEIGELSON BORIS NHENRY RICHARD L
    • FEIGELSON BORIS NHENRY RICHARD L
    • C30B23/00C30B25/00C30B28/12C30B28/14
    • C30B29/403C30B9/12C30B29/406
    • In one embodiment, this invention pertains to a process for making single crystal gallium nitride in the region of the phase diagram of gallium nitride where gallium nitride is thermodynamically stable. The process includes the steps of placing a charged reaction vessel into a chamber, the reaction vessel containing a gallium nitride source and a slat-based solvent in contact therewith; heating the charge in the reaction vessel to render the solvent molten and to provide a temperature gradient in the molten solvent between the gallium nitride source and the growing single crystal gallium nitride in such a way that growing the single crystal gallium nitride will be in the region of the reaction vessel which, under operating conditions, will have a temperature near the low end of the temperature gradient and the gallium nitride source will be in the region of the reaction vessel which, under operating conditions, will have temperature near the high end of the temperature gradient; maintaining process conditions whereby the solvent is molten, with the gallium nitride from the gallium nitride source dissolving in the solvent under the impetus of the temperature gradient; precipitating gallium nitride out of the solvent; and discontinuing the heating step.
    • 在一个实施方案中,本发明涉及在氮化镓热力学稳定的氮化镓相图区域中制造单晶氮化镓的方法。 该方法包括以下步骤:将带电荷的反应容器放入室中,该反应容器含有氮化镓源和与之接触的板条基溶剂; 加热反应容器中的电荷以使溶剂熔化,并且在氮化镓源和生长的单晶氮化镓之间的熔融溶剂中提供温度梯度,使得生长单晶氮化镓将位于该区域内 在操作条件下,温度将接近温度梯度的低端并且氮化镓源将在反应容器的区域中,在操作条件下,该反应容器将具有接近高温的温度 温度梯度; 在温度梯度的推动下维持溶剂熔融的工艺条件,其中来自氮化镓源的氮化镓溶解在溶剂中; 从溶剂中沉淀氮化镓; 并停止加热步骤。