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    • 6. 发明申请
    • LASER MARKING PROCESS AND ARTICLES
    • 激光标记过程和文章
    • WO2012121910A2
    • 2012-09-13
    • PCT/US2012/026680
    • 2012-02-27
    • 3M INNOVATIVE PROPERTIES COMPANYSMITHSON, Robert L.W.,EMSLANDER, Jeffrey O.,FLEMING, Danny L.,
    • SMITHSON, Robert L.W.,EMSLANDER, Jeffrey O.,FLEMING, Danny L.,
    • B23K26/18
    • B23K26/18B23K26/0054B23K26/0057B23K26/0063B23K26/009B41M5/267Y10T428/14Y10T428/1476
    • A process to mark a multilayered article having a release layer and an adhesive layer, using a laser to produce markings within more than one layer of the article. The process includes providing a multilayered article including a laser-markable release liner having a release layer, and a laser-markable adhesive film; and marking the laser-markable release liner and the laser-markable adhesive film by directing laser radiation from at least a first source of laser radiation into the multilayered article through at least the first release layer to induce an interaction between a first light-sensitive pigment and a first organic polymer in the laser-markable release liner, and a second light-sensitive pigment and a second organic polymer in the laser-markable adhesive film, to form at least one visually perceptible marking in each of the laser-markable release liner and the laser-markable adhesive film. The release layer is substantially transparent to the laser radiation. Multilayered articles having multi-layer laser markings are also disclosed.
    • 标记具有剥离层和粘合剂层的多层制品的方法,使用激光在制品的多于一层内产生标记。 该方法包括提供包括具有剥离层的可激光标记的剥离衬垫和可激光标记的粘合膜的多层制品; 以及通过将来自至少第一激光辐射源的激光辐射通过至少第一释放层引导到所述多层制品中来标记所述可激光标记的释放衬垫和所述可激光标记的粘合剂膜,以引起第一感光颜料 和可激光剥离衬垫中的第一有机聚合物和可激光标记粘合剂膜中的第二感光颜料和第二有机聚合物,以在每个可激光标记的剥离衬垫中形成至少一个视觉上可察觉的标记 和可激光标记的粘合膜。 释放层对于激光辐射基本上是透明的。 还公开了具有多层激光标记的多层制品。
    • 7. 发明申请
    • MULTI-LAYER SEALING FILMS
    • 多层密封膜
    • WO2011152977A1
    • 2011-12-08
    • PCT/US2011/036300
    • 2011-05-12
    • 3M INNOVATIVE PROPERTIES COMPANYTHAKKAR, Bimal V.EMSLANDER, Jeffrey O.FEISEL, Bryan C.
    • THAKKAR, Bimal V.EMSLANDER, Jeffrey O.FEISEL, Bryan C.
    • G02B5/124
    • G02B5/124G02B1/04G02B1/14Y10T428/24562Y10T428/24942
    • The present application generally relates to multi-layer sealing films, methods of making such films, materials for inclusion in such films, retroreflective sheeting and articles including such films, and methods of making retroreflective sheeting and articles including such films. The multi-layer sealing film may include two or more layers. One exemplary embodiment of a two-layer film includes a first layer including a thermoplastic polymeric material including reaction products of alkylene and reaction products of at least one non-acidic comonomer and a second layer including one of a polyolefin, a polyester, a polymethyl methacrylate, a polyamide, a polycarbonate, an ethylene-methacrylic acid, and a polyurethane. In some embodiments, at least one of the layers of the multi-layer sealing film has an elastic modulus of at least 3.5 x 10 5 kPa and the flexural rigidity of the retroreflective article is less than about 4.0 x 10 -8 N•m 2 .
    • 本申请通常涉及多层密封膜,制造这种膜的方法,用于包含在这种膜中的材料,回射片和包括这种膜的制品,以及制造回射片材和包括这种膜的制品的方法。 多层密封膜可以包括两层或更多层。 双层膜的一个示例性实施方案包括包含热塑性聚合物材料的第一层,其包含亚烷基的反应产物和至少一种非酸性共聚单体的反应产物,第二层包括聚烯烃,聚酯,聚甲基丙烯酸甲酯 ,聚酰胺,聚碳酸酯,乙烯 - 甲基丙烯酸和聚氨酯。 在一些实施方案中,多层密封膜的至少一层具有至少3.5×10 5 kPa的弹性模量,并且回射制品的抗弯刚度小于约4.0×10 -8 N°m 2。