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    • 3. 发明申请
    • METHOD FOR ELECTROPHORETIC DEPOSITION OF CONDUCTIVE POLYMER INTO POROUS SOLID ANODES FOR ELECTROLYTE CAPACITOR
    • 导电聚合物电沉积在电解电容器多孔固体阳极中的方法
    • WO2007026364A3
    • 2007-06-07
    • PCT/IL2006001015
    • 2006-08-31
    • CEREL CERAMIC TECHNOLOGIES LTDTHON ASSAFZARBOV MARTIN
    • THON ASSAFZARBOV MARTIN
    • H01G9/028
    • H01G9/028H01G9/0036H01G9/042H01G9/0425
    • The invention discloses a method for forming a conductive polymer with an electrophoretic deposition cell, into porous anode for electrolytic capacitors. The conductive polymer is directly deposited on the oxide layer of the anode body. The electrolytic polymerized conductive polymer material form the cathode in solid electrolyte capacitors. The method allows low ESR capacitors to be produced. The invention provides a high yield and low cost industrial process with efficient materials utilization. The present invention successfully deposits particles from dispersion on continuous, highly insulating dielectric layers using electrophoretic deposition by use of EPD voltage near or above the anode dielectric formation voltage, where the anode body is positively biased relative to the EPD counter electrode, thereby allowing a current to be driven through the dielectric layer.
    • 本发明公开了一种用电泳沉积池形成导电聚合物的方法,用于电解电容器的多孔阳极。 导电聚合物直接沉积在阳极体的氧化物层上。 电解聚合的导电聚合物材料在固体电解质电容器中形成阴极。 该方法允许生产低ESR电容器。 本发明提供了高产率和低成本的工业过程,具有高效的材料利用。 本发明通过使用接近或高于阳极电介质形成电压的EPD电压,使用电泳沉积将分散的颗粒沉积在连续的高绝缘介电层上,其中阳极体相对于EPD对电极被正偏置,从而允许电流 被驱动通过介电层。
    • 7. 发明申请
    • IMPROVED METHOD OF ELECTROPHORETIC DEPOSITION OF FERROELECTRIC FILMS USING A TRI-FUNCTIONAL ADDITIVE AND COMPOSITIONS FOR EFFECTING SAME
    • 使用三功能添加剂和组合物进行电化学沉积的电解沉积的改进方法
    • WO0133608A2
    • 2001-05-10
    • PCT/IL0000679
    • 2000-10-25
    • CEREL CERAMIC TECHNOLOGIES LTDGAL OR LEAHGOLDNER RONISEZIN NINAPISMANY ALABRANDON DAVID
    • GAL-OR LEAHGOLDNER RONISEZIN NINAPISMANY ALABRANDON DAVID
    • C25D13/02H01L41/24H01L
    • C25D13/02H01L41/317H01L41/43
    • An improved method for depositing ferroelectric particles on a surface of a substrate to form films or stand-alone bodies. The improvement is based on electrophoretic deposition (EPD) of ferroelectric films by using a tri-functional phosphate ester additive having a concentration less than 10 volume percent in the EPD suspension, without the need for addition of a binder. The method includes preparation of the suspension by washing and dispersing ferroelectric particles, for example, commercially available PZT powder, in a polar solvent such as ethanol, followed by addition of the phosphate ester additive to the suspension, and an ultrasound treatment. The suspension is used in EPD of the ferroelectric particles on a prepared substrate. Following EPD, the green film is dried and sintered at high temperature. Visual and physical examination of stand alone and patterned PZT deposited films show excellent quality obtained in manufacturing a diversity of piezoelectric products, featuring exceptionally high green film uniformity, thickness distribution, and reproducibility to within +/- 2 microns for 20 micrometer film thickness. The phosphate ester additive functions by improving stabilization and control of suspension characteristics and properties during the electrophoretic migration process, and by improving desired dimensions, characteristics, and electrical properties of the deposited green film. Thin or thick ferroelectric films, either as stand alone products, or formed on geometrically demanding patterned or non-patterned substrates are produced by using the method. The improved method is applicable to different ferroelectric particulate materials and to different substrates used for manufacturing piezoelectric elements and devices, in a cost effective manner.
    • 一种用于在基板的表面上沉积铁电粒子以形成膜或独立体的改进方法。 通过在EPD悬浮液中使用浓度小于10体积%的三官能磷酸酯添加剂,而不需要添加粘合剂,改进是基于铁电体膜的电泳沉积(EPD)。 该方法包括通过在极性溶剂如乙醇中洗涤和分散铁电粒子,例如市售的PZT粉末,然后向悬浮液中加入磷酸酯添加剂和超声处理来制备悬浮液。 悬浮液用于制备的基板上的铁电粒子的EPD中。 在EPD之后,将绿膜干燥并在高温下烧结。 独立和图案化的PZT沉积膜的视觉和体检在制造多种压电产品时获得了极好的质量,其具有特别高的绿膜均匀性,厚度分布和重现性,在20微米厚度的+/- 2微米内。 磷酸酯添加剂通过改善在电泳迁移过程中的悬浮特性和性质的稳定和控制以及改善所沉积的绿膜所需的尺寸,特性和电性能来起作用。 通过使用该方法制备作为独立产品或形成在几何要求的图案化或非图案化衬底上的薄或厚的铁电体膜。 该改进的方法可以以成本有效的方式适用于不同的铁电颗粒材料和用于制造压电元件和装置的不同基板。