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    • 5. 发明申请
    • PROCESS FOR PREPARING INTRINSICALLY FOAMED THERMOPLASTIC POLYMER
    • 制备本发明的热塑性聚合物的方法
    • WO1992015638A1
    • 1992-09-17
    • PCT/NL1992000040
    • 1992-02-27
    • DSM N.V.GEESINK, Johannes, HendrikBOYENS, Joseph, Paulus, HubertusKLUMPERMAN, Lubertus
    • DSM N.V.
    • C08J09/02
    • C08J9/02
    • Process and intermediate for preparing an intrinsically foamed thermoplastic polymer comprising a vinyl monomer and maleic acid and/or maleic anhydride, in which process a polymer composition comprising: a) a core polymer based on: a.1) 12-50 moles % maleic acid and/or maleic anhydride; a.2) a vinyl monomer, and a.3) optionally a third monomer, where the sum total of a1 + a2 + a3 is 100 moles % and the weight average molecular weight of the core polymer is 50000-500000, and b) optionally a nucleating agent, is introduced into equipment suited for making foam, in which process the core polymer, and optionally the nucleating agent, are brought to a temperature which is high enough to release CO2 from the core polymer, and in which process the polymer melt is expanded to form a polymer foam with the desired density. The core polymer is preferably a polymer of styrene and maleic anhydride.
    • 制备包含乙烯基单体和马来酸和/或马来酸酐的固有发泡热塑性聚合物的方法和中间体,其中聚合物组合物包括:a)基于以下的核心聚合物:a)12-50摩尔%的马来酸 和/或马来酸酐; a.2)乙烯基单体和a.3)任选的第三单体,其中a1 + a2 + a3的总和为100摩尔%,芯聚合物的重均分子量为50000-500000,b) 可选地,成核剂被引入适于制备泡沫的设备中,其中芯聚合物和任选的成核剂达到足够高的温度以从芯聚合物释放CO 2,并且在该过程中聚合物 熔体膨胀以形成具有所需密度的聚合物泡沫。 核心聚合物优选为苯乙烯和马来酸酐的聚合物。